CN109453065A - Light high SPF/PA value water-in-oil type sunscreen frost and preparation method thereof - Google Patents
Light high SPF/PA value water-in-oil type sunscreen frost and preparation method thereof Download PDFInfo
- Publication number
- CN109453065A CN109453065A CN201811635411.2A CN201811635411A CN109453065A CN 109453065 A CN109453065 A CN 109453065A CN 201811635411 A CN201811635411 A CN 201811635411A CN 109453065 A CN109453065 A CN 109453065A
- Authority
- CN
- China
- Prior art keywords
- oil type
- parts
- zinc oxide
- type sunscreen
- titanium dioxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8158—Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
- A61K8/064—Water-in-oil emulsions, e.g. Water-in-silicone emulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/27—Zinc; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/29—Titanium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/41—Particular ingredients further characterized by their size
- A61K2800/413—Nanosized, i.e. having sizes below 100 nm
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/48—Thickener, Thickening system
Abstract
The present invention provides a kind of light high SPF/PA value water-in-oil type sunscreen frosts, contain the following parts by weight: 5-20 parts of the titanium dioxide or zinc oxide of hydrophobically modified, sodium acrylate/sodium acryloyldimethyl taurate copolymers/isohexadecane/3-4 parts of Polyoxyethylene Sorbitan Monooleate mixture, 15-25 parts of moisturizing grease.Surface-active possessed by the titanium dioxide of nano-scale or the Zinc oxide particles of hydrophobically modified of water-in-oil type sunscreen frost of the invention using hydrophobically modified is emulsified.Meanwhile thickener is added in water phase to assist stablizing, skin sense that water phase thickener would generally have comparison salubrious different from oil phase thickeners is white the high SPF/PA value water-in-oil type sunscreen with salubrious skin sense is made.
Description
Technical field
Cosmetic field of the present invention, more particularly to a kind of light high SPF/PA value water-in-oil type sunscreen frost and its preparation side
Method.
Background technique
The titanium dioxide and zinc oxide of inorganic sunscreen are a kind of insoluble particulate matters, and the water phase for being dispersed in cosmetics is worked as
In, agglomeration can occur during smearing on the skin, thus greatly reduce sun-proof result.Therefore it applies in sun-proofization
Titanium dioxide or zinc oxide in cosmetic generally use the nano-scale particle of hydrophobically modified, are then dispersed in the oily phase of cosmetics
In.Since oil-in-water type suncream causes SPF the and PA value of formula lower.The sunscreen cosmetic that high SPF and PA value can be reached is logical
Often selection is made with the dosage form of Water-In-Oil.Water-in-oil type sunscreen cosmetic generally has two classes: (1) suncream；(2) with before needing to shake
Even sunscreen.Sunscreen with salubrious skin sense is in the majority, and thick and heavy skin sense is often presented in suncream.
However in Water-In-Oil suncream, more water-in-oil emulsifier can be added to keep the stabilization and water phase of system
Emulsified particle is not reunited, and because the content of oily phase is higher, need to add more lards or other oil phase thickeners to maintain body
System stablizes.But this way can make obtained suncream that thick and heavy sticky skin sense be presented.
Therefore, seek a kind of light not sticking greasy and high SPF/PA value water-in-oil type sunscreen frost to become this field urgently to be resolved
The problem of.
Summary of the invention
The present invention provides a kind of light high SPF/PA value water-in-oil type sunscreen frost, suncream of the invention does not add oil
The poor ingredient of the skins sense such as water-in type emulsifier and lard and other oil phase thickeners, suncream skin sense ratio obtained
It is relatively salubrious.
To achieve the purpose of the present invention, a kind of the technical solution adopted by the present invention are as follows: light high SPF/PA value Water-In-Oil
Type suncream, contains the following parts by weight: the titanium dioxide or 5-20 parts of zinc oxide, sodium acrylate/propylene of hydrophobically modified
Acyl dimethyltaurine sodium copolymer/isohexadecane/3-4 parts of Polyoxyethylene Sorbitan Monooleate, 15-25 parts of moisturizing grease.
Sodium acrylate/sodium acryloyldimethyl taurate copolymers/isohexadecane/Polyoxyethylene Sorbitan Monooleate is a kind of mixing
Object is the commodity SIMUGEL EG produced by SEPPIC company.It is good in addition to having compared to conventional propylene acids thickener
Other than electrolyte-resistant ability and Interfacial Adsorption ability, also there is good resistance to metal ion ability, be not easy to form metal complex, because
This is preferable with the compatibility of inorganic sunscreens powder.
Preferably, the mass ratio of the titanium dioxide or zinc oxide and moisturizing grease is 1:1-1.5.
Preferably, the titanium dioxide be aluminium hydroxide and stearic acid handle titanium dioxide, at dimethyl silicone polymer
The titanium dioxide of reason.
Preferably, the zinc oxide is the zinc oxide of triethoxy octyl silane treatment, hydrogenates at dimethyl silicone polymer
The zinc oxide of reason.
Preferably, the moisturizing grease is ethylhexyl methoxy cinnamate, Octocrilene, Homosalate, salicylic acid second
The own ester of base, dimethyl silicone polymer, five dimethione of ring, octyl dimethyl silicone polymer, isononyl isononanoate, different 13
Alcohol isononoate, ethylhexyl palmitate, cetanol ethylhexoate, glycerol three (thylhexoic acid) ester, caprylic/capric glycerol three
One of which in ester or any combination thereof.
Preferably, the light high SPF/PA value water-in-oil type sunscreen frost, contain the following parts by weight: hydrogenation is poly-
20 parts of zinc oxide, 10 parts of the dimethyl silicone polymer, 10 parts of isononyl isononanoate, sodium acrylate/the third of dimethyl siloxane processing
Alkene acyl dimethyltaurine sodium copolymer/isohexadecane/3 parts of Polyoxyethylene Sorbitan Monooleate mixture.
The present invention also provides a kind of preparation methods of light high SPF/PA value water-in-oil type sunscreen frost as described above, including
Following steps:
(1) first the titanium dioxide of hydrophobically modified or zinc oxide are dispersed in moisturizing grease under conditions of high speed homogenization,
Form slurry；
(2) sodium acrylate/sodium acryloyldimethyl taurate copolymers/isohexadecane/polysorbate-that will have been thickened
80 mixtures are added in the slurry in step (1) under dispersion condition, and homogeneous is smooth to lotion surface.
The beneficial effects of the present invention are: in Water-In-Oil suncream of the invention, traditional water-in-oil emulsion is not added
Agent, using surface-active possessed by the titanium dioxide of the nano-scale of hydrophobically modified or the Zinc oxide particles of hydrophobically modified come into
Row emulsification (i.e. Pickering emulsification).Meanwhile thickener (sodium acrylate/sodium acryloyldimethyl taurate is added in water phase
Copolymer/isohexadecane/Polyoxyethylene Sorbitan Monooleate mixture) it assists stablizing, different from oil phase thickeners, water phase thickener is logical
The skin sense that can often have comparison salubrious, the high SPF/PA value water-in-oil type sunscreen frost with salubrious skin sense is made.
Detailed description of the invention
Fig. 1 suncream sample microscope figure of the present invention.
Fig. 2 suncream sample petrographic microscope figure of the present invention.
Specific embodiment
For more concise displaying technical solution of the present invention, objects and advantages, combined with specific embodiments below
And attached drawing is described in further detail the present invention.
The formula of 1 sunscreen cosmetic of embodiment 1-4 and comparative example, such as table 1:
Embodiment 5
The present embodiment provides a kind of preparation method of light high SPF/PA value water-in-oil type sunscreen frost, the method includes
Following steps:
(1) titanium dioxide or triethoxy that first 15 parts of aluminium hydroxides and stearic acid are handled under conditions of high speed homogenization
The zinc oxide of octyl silane treatment is dispersed in moisturizing grease and forms slurry, wherein the soothing oil rouge includes following parts by weight
Component: 5 parts of ethylhexyl methoxy cinnamates, 5 parts of Homosalates, 6 parts of five dimethiones of ring, 1 part of octyl poly dimethyl
In siloxanes, 5 parts of cetanol ethylhexoates；
(2) 3 parts of sodium acrylate/sodium acryloyldimethyl taurate copolymers/isohexadecane/polysorbates thickened are taken
- 80 mixture of ester is added in the slurry in step (1) under dispersion condition, and homogeneous is smooth to lotion surface, this can be obtained
The suncream of invention.
The performance of suncream prepared by embodiment 1-4 and comparative example 1 is compared, has been used in comparative example 1 and reality
The identical sun-screening agent of example 4 and moisturizing grease are applied, the difference is that comparative example 1 uses traditional oil phase thickeners and water-in-oil type
Emulsifier (such as glyceryl behenate/20 acid esters and laruyl alcohol PEG-9 Polydimethylsiloxyethyl Dimethicone) comes
Stablize the suncream, and embodiment 4 then stablizes the suncream with water phase thickener.Skin sensing examination is respectively asked for by 10 volunteers
0.2g is applied to the back of the hand about 100cm2Region in Blind Test, judge skin sense simultaneously provide score, be averaged.The results are shown in Table 2:
Table 2: the results of property of suncream prepared by embodiment 1-4 and comparative example 1
As shown in Table 2, the embodiment of the present invention 1-4 has quality slim and graceful compared with comparative example, and lotion is smooth, and ductility is preferable
Performance, skin sense comparing result show to stablize using gel aqueous phase agent water-in-oil type sunscreen frost can make the appearance of suncream compared with
Traditional water-in-oil type sunscreen frost is more more coarse, but all can be more salubrious in the skin sense that smearing process is experienced, and has
There is better ductility, while smearing finishes later toga sense and also can more lack with glossy, more meets masses to suncream skin
The requirement of sense.The indices of embodiment 4 are above other embodiments, therefore it is preferred embodiment of the invention.
In the case where general high-content sun-screening agent titanium dioxide or zinc oxide, although parts of traditional acrylic thickener has
There is outstanding electrolyte-resistant ability, but still metal complex can be formed because of the titanium ion or zinc ion dissolved out on a small quantity, causes
Structure changes, to lose thickening capabilities, therefore system viscosity also reduces.But sodium acrylate/the acryloyl used in the present invention
Dimethyltaurine sodium copolymer/isohexadecane/Polyoxyethylene Sorbitan Monooleate is compared to conventional propylene acids thickener (such as acrylic acid
Ester/C10-30 alkyl acrylate cross-linked polymer or polyacrylamide etc.), in addition to having good electrolyte-resistant ability and interface
Other than adsorption capacity, also there is good resistance to metal ion ability, be not easy to be formed metal complex, thus with inorganic sunscreens powder
It is compatible preferable.
From attached drawing 1 as can be seen that the hydrogel particle of irregular character be dispersed in oil quite in, and it is common round
Emulsified particle is different.From attached drawing 2 this it appears that there is bright Maltese cross halation at hydrogel particle edge, this is because
Without other crystal structure substances in system, it can prove that nano sunlight screening agent particle of the invention is assembled simultaneously in oil-water interfaces really
With stable emulsifying effect, alternative water-in-oil emulsifier.
The embodiments described above only express several embodiments of the present invention, and the description thereof is more specific and detailed, but simultaneously
It cannot therefore be construed as limiting the scope of the patent.It should be pointed out that coming for those of ordinary skill in the art
It says, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to protection of the invention
Range.Therefore, the scope of protection of the patent of the invention shall be subject to the appended claims.
Claims (7)
1. light high SPF/PA value water-in-oil type sunscreen frost, which is characterized in that contain the following parts by weight: hydrophobically modified
Titanium dioxide or 5-20 parts of zinc oxide, sodium acrylate/sodium acryloyldimethyl taurate copolymers/isohexadecane/poly- sorb
3-4 parts, 15-25 parts of moisturizing grease of -80 mixture of alcohol ester.
2. light high SPF/PA value water-in-oil type sunscreen frost as described in claim 1, which is characterized in that the titanium dioxide
Or the mass ratio of zinc oxide and moisturizing grease is 1:1-1.5.
3. light high SPF/PA value water-in-oil type sunscreen frost as described in claim 1, which is characterized in that the titanium dioxide
The titanium dioxide of the titanium dioxide or dimethyl silicone polymer processing that are handled for aluminium hydroxide and stearic acid.
4. light high SPF/PA value water-in-oil type sunscreen as described in claim 1 is white, which is characterized in that the zinc oxide is
The zinc oxide of triethoxy octyl silane treatment or the zinc oxide of hydrogenation dimethyl silicone polymer processing.
5. light high SPF/PA value water-in-oil type sunscreen frost as described in claim 1, which is characterized in that the moisturizing grease
It is poly- for ethylhexyl methoxy cinnamate, Octocrilene, Homosalate, ethylhexyl salicylate, dimethyl silicone polymer, ring five
Diformazan siloxanes, octyl dimethyl silicone polymer, isononyl isononanoate, different tridecanol isononoate, ethylhexyl palmitate, whale
Ceryl alcohol ethylhexoate, glycerol three (thylhexoic acid) ester, one of which in caprylic/capric triglyceride or any combination thereof.
6. light high SPF/PA value water-in-oil type sunscreen frost as described in claim 1, which is characterized in that include following weight
The component of part: 20 parts of zinc oxide, 10 parts of the dimethyl silicone polymer, isononyl isononanoate 10 of hydrogenation dimethyl silicone polymer processing
Part, sodium acrylate/sodium acryloyldimethyl taurate copolymers/isohexadecane/3 parts of Polyoxyethylene Sorbitan Monooleate mixture.
7. a kind of preparation method of light high SPF/PA value water-in-oil type sunscreen frost described in any one of claims 1-6, packet
Include following steps:
(1) first the titanium dioxide of hydrophobically modified or zinc oxide are dispersed in moisturizing grease under conditions of high speed homogenization, are formed
Slurry；
(2) sodium acrylate/sodium acryloyldimethyl taurate copolymers/isohexadecane/Polyoxyethylene Sorbitan Monooleate thickened is mixed
It closes object to be added under dispersion condition in the slurry in step (1), homogeneous is smooth to lotion surface.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811635411.2A CN109453065B (en) | 2018-12-29 | 2018-12-29 | Fresh water-in-oil type sunscreen cream with high SPF/PA value and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811635411.2A CN109453065B (en) | 2018-12-29 | 2018-12-29 | Fresh water-in-oil type sunscreen cream with high SPF/PA value and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109453065A true CN109453065A (en) | 2019-03-12 |
| CN109453065B CN109453065B (en) | 2021-12-28 |
Family
ID=65615637
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811635411.2A Active CN109453065B (en) | 2018-12-29 | 2018-12-29 | Fresh water-in-oil type sunscreen cream with high SPF/PA value and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109453065B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113397992A (en) * | 2021-07-12 | 2021-09-17 | 广州立白企业集团有限公司 | Sunscreen composition and water-in-oil type emulsified cosmetic with sunscreen composition |
| CN114259428A (en) * | 2021-12-31 | 2022-04-01 | 诺斯贝尔化妆品股份有限公司 | Anhydrous sunscreen gel of pure physical sunscreen agent and preparation method thereof |
| CN115006311A (en) * | 2022-07-06 | 2022-09-06 | 浙江宜格企业管理集团有限公司 | Transparent two-phase sunscreen composition and preparation method thereof |
| CN115813786A (en) * | 2022-12-23 | 2023-03-21 | 安庆科思化学有限公司 | Water-resistant sunscreen composition with water outlet capacity and preparation method thereof |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103402963A (en) * | 2010-12-06 | 2013-11-20 | 赛泽恩有限公司 | Compositions and methods for stabilizing ingredients using 2,4-pentanedione compounds |
| CN103443207A (en) * | 2011-02-04 | 2013-12-11 | 莱雅公司 | Composite pigment and method for preparation thereof |
| US20140178315A1 (en) * | 2012-12-20 | 2014-06-26 | Arch Chemicals, Inc. | Topical Compositions Comprising Ionic Fluids |
| CN103976893A (en) * | 2014-05-09 | 2014-08-13 | 广州百孚润化工有限公司 | Novel macromolecule emulsifier for cosmetics and preparation method thereof |
| CN106619194A (en) * | 2016-12-27 | 2017-05-10 | 广州市科能化妆品科研有限公司 | Sunscreen composition containing composite solid powder and polymer film-forming agent |
| CN107149559A (en) * | 2017-05-15 | 2017-09-12 | 佛山文森特知识产权服务有限公司 | A kind of water-in-oil type titanium dioxide dispersion pulp |
| US20180085293A1 (en) * | 2016-09-23 | 2018-03-29 | The Procter & Gamble Company | Stable Foam Compositions and Methods of Using the Same to Provide Enhanced Sensory and Visual Benefits to Skin |
| CN108514519A (en) * | 2018-05-11 | 2018-09-11 | 珠海伊斯佳科技股份有限公司 | A kind of skin care compositions and methods and its application method of whitening and anti-aging |
-
2018
- 2018-12-29 CN CN201811635411.2A patent/CN109453065B/en active Active
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103402963A (en) * | 2010-12-06 | 2013-11-20 | 赛泽恩有限公司 | Compositions and methods for stabilizing ingredients using 2,4-pentanedione compounds |
| CN103443207A (en) * | 2011-02-04 | 2013-12-11 | 莱雅公司 | Composite pigment and method for preparation thereof |
| US20140178315A1 (en) * | 2012-12-20 | 2014-06-26 | Arch Chemicals, Inc. | Topical Compositions Comprising Ionic Fluids |
| CN103976893A (en) * | 2014-05-09 | 2014-08-13 | 广州百孚润化工有限公司 | Novel macromolecule emulsifier for cosmetics and preparation method thereof |
| US20180085293A1 (en) * | 2016-09-23 | 2018-03-29 | The Procter & Gamble Company | Stable Foam Compositions and Methods of Using the Same to Provide Enhanced Sensory and Visual Benefits to Skin |
| CN106619194A (en) * | 2016-12-27 | 2017-05-10 | 广州市科能化妆品科研有限公司 | Sunscreen composition containing composite solid powder and polymer film-forming agent |
| CN107149559A (en) * | 2017-05-15 | 2017-09-12 | 佛山文森特知识产权服务有限公司 | A kind of water-in-oil type titanium dioxide dispersion pulp |
| CN108514519A (en) * | 2018-05-11 | 2018-09-11 | 珠海伊斯佳科技股份有限公司 | A kind of skin care compositions and methods and its application method of whitening and anti-aging |
Non-Patent Citations (1)
| Title |
|---|
| 裘炳毅等: "《现代化妆品科学与技术 下》", 31 March 2016, 中国轻工业出版社 * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113397992A (en) * | 2021-07-12 | 2021-09-17 | 广州立白企业集团有限公司 | Sunscreen composition and water-in-oil type emulsified cosmetic with sunscreen composition |
| CN113397992B (en) * | 2021-07-12 | 2023-03-31 | 广州立白企业集团有限公司 | Sunscreen composition and water-in-oil type emulsified cosmetic with sunscreen composition |
| CN114259428A (en) * | 2021-12-31 | 2022-04-01 | 诺斯贝尔化妆品股份有限公司 | Anhydrous sunscreen gel of pure physical sunscreen agent and preparation method thereof |
| CN115006311A (en) * | 2022-07-06 | 2022-09-06 | 浙江宜格企业管理集团有限公司 | Transparent two-phase sunscreen composition and preparation method thereof |
| CN115006311B (en) * | 2022-07-06 | 2024-03-26 | 浙江宜格企业管理集团有限公司 | Transparent double-phase sun-screening composition and preparation method thereof |
| CN115813786A (en) * | 2022-12-23 | 2023-03-21 | 安庆科思化学有限公司 | Water-resistant sunscreen composition with water outlet capacity and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN109453065B (en) | 2021-12-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN109453065A (en) | Light high SPF/PA value water-in-oil type sunscreen frost and preparation method thereof | |
| CN109512684B (en) | Sunscreen agent with high content of titanium dioxide or zinc oxide and preparation method thereof | |
| US7879779B2 (en) | Oil-cleansing composition | |
| EP2749265A1 (en) | Water-in-oil emulsion sunscreen cosmetic | |
| US5304334A (en) | Method of preparing a multiphase composition | |
| JP4643377B2 (en) | One-phase microemulsion composition and method for producing O / W ultrafine emulsion external preparation | |
| TWI505840B (en) | Sunscreen makeup | |
| TWI604856B (en) | In-water oil emulsion composition | |
| TWI788547B (en) | Cosmetics | |
| KR101422758B1 (en) | Water-in-oil-type emulsion skin cosmetic | |
| CA2168425A1 (en) | Cosmetic compositions | |
| JP2017206450A (en) | Oily cleansing cosmetic | |
| KR20150082870A (en) | A water-in-oil pickering emulsion cosmetic composition and process of the preparation thereof | |
| JP2012031116A (en) | Ufenamate-containing skin care preparation | |
| JP2012031068A (en) | Ufenamate-containing skin care preparation | |
| JP2010184908A (en) | Emulsified composition and cosmetic comprising the same, and skin care preparation for external use | |
| JP2022103271A (en) | Pickering emulsion containing acrylic polymer | |
| JP5114089B2 (en) | Milky skin cosmetic | |
| EP0767658A1 (en) | Anti-acne cosmetic compositions | |
| CN114259428A (en) | Anhydrous sunscreen gel of pure physical sunscreen agent and preparation method thereof | |
| KR101288236B1 (en) | Manufacturing Method for Cosmetic Emulsion Using High Content Silicone Derivatives and The Cosmetic Composition Containing This Method | |
| JP7408890B2 (en) | sunscreen cosmetics | |
| JP2012001500A (en) | Oil-in-water type emulsified cosmetic | |
| JP2011088882A (en) | Emulsion-type cosmetic | |
| JP2005194229A (en) | O/w ultrafine emulsion preparation for external use and method for producing the same |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |