CN109439453A - A kind of heavy greasy dirt detergent and preparation method thereof - Google Patents
A kind of heavy greasy dirt detergent and preparation method thereof Download PDFInfo
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- CN109439453A CN109439453A CN201811473923.3A CN201811473923A CN109439453A CN 109439453 A CN109439453 A CN 109439453A CN 201811473923 A CN201811473923 A CN 201811473923A CN 109439453 A CN109439453 A CN 109439453A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2044—Dihydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
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Abstract
The invention discloses a kind of heavy greasy dirt detergents, it is composed of the following components by mass percentage: Pagoda Flower extracting solution 15%~30%, efficient emulsifier 5%~15%, greasy dirt detersive 5%~12%, triethanolamine 0.6%~3%, butanediol 0.5%~2%, isothiazolinone 0.2%~0.6%, pH adjusting agent 0%~2%, deionized water 37.4%~71.8%, the sum of the above components mass percent are 100%；The invention also discloses weight greasy dirt detergent preparation methods, the following steps are included: preparing Pagoda Flower extracting solution, being uniformly mixed in deionized water addition Pagoda Flower extracting solution, efficient emulsifier, greasy dirt detersive, triethanolamine, butanediol, isothiazolinone, and adjust PH be 6-8 to get to weight greasy dirt detergent.The surfactant that heavy greasy dirt detergent of the invention uses all is the green product for belonging to hypotoxicity, high activity, does not generate injury to skin and environment.
Description
Technical field
The invention belongs to technical field of fine, and in particular to a kind of heavy greasy dirt detergent further relates to heavy oil dirt cleaning
The preparation method of agent.
Background technique
Industrial equipment is in maintenance and in use, can all generate some greasy dirts in equipment surface, influence is beautiful over time
Sight and equipment performance；In oil/gas well workover treatment, always have some heavy oil dirts spray to the clothes of equipment and staff and
Hand；Cooking also has weight oil pollution cooking apparatus and metope inside kitchen in life, unclear for a long time to comprehend making for shortening equipment
With the beauty in aging effects kitchen.Cleaning agent generally on the market is difficult to clean these heavy oil dirt dirts, even if can clean
Dosage is also bigger, uneconomical material benefit.It is domestic most of using surfactant-based cleaning agent at present, cleaning agent is protruded emphatically
Viscosity inveigles customer, client is allowed to think that the bigger active matter content of viscosity is higher, and effect is better, and actually not so, cleaning agent thickening is
In order to allow cleaning agent that can be attached to cleaned body surface, there is the time come into full contact with, improve washing rate.Domestic weight at present
Greasy dirt detergent is not many with respect to type, is mostly by increasing active matter content, to have the function that remove heavy oil dirt, originally
Invention is had studied between various surfactants by screening newest emulsifier and degreasing surfactant both at home and abroad
Synergistic effect, it was found that a high-efficiency heavy oil dirt cleaning agent with numerous advantages.
Summary of the invention
The object of the present invention is to provide a kind of heavy greasy dirt detergent, solve that conventional greasy dirt detergent usage amount is big, removal
The problem of greasy dirt effect difference.
The object of the invention is also to provide a kind of preparation methods of heavy greasy dirt detergent.
The first technical solution of the present invention is a kind of heavy greasy dirt detergent, by mass percentage by with the following group
It is grouped as: Pagoda Flower extracting solution 15%~30%, efficient emulsifier 5%~15%, greasy dirt detersive 5%~12%, three ethyl alcohol
Amine 1%~3%, butanediol 0.5%~2%, isothiazolinone 0.2%~0.6%, pH adjusting agent 0%~2%, deionized water
37.4%~71.8%, the sum of the above components mass percent is 100%；Pagoda Flower extracting solution is after smashing fresh locust flower to pieces
The liquid of extraction.
The features of the present invention also characterized in that
Efficient emulsifier is C9-11 alcohol ethoxylate BEROL266 or C9-11 the fatty alcohol ethoxy of narrow ditribution
One of glycolylate BEROL609.
Greasy dirt detersive is one of Shuangzi propyl ethyoxyl alcohol ether or Shuangzi alkyl glycosides or two kinds of mixing.
PH adjusting agent is one of citric acid or sodium carbonate.
Second of technical solution of the present invention be,
A kind of preparation method of heavy greasy dirt detergent, specific steps are as follows:
Step 1: preparation Pagoda Flower extracting solution；
Step 2: weighing following raw material: Pagoda Flower extracting solution 15%~30% prepared by step 1 by mass percentage, efficiently
Emulsifier 5%~15%, greasy dirt detersive 5%~12%, triethanolamine 1%~3%, butanediol 0.5%~2%, isothiazole
Quinoline ketone 0.2%~0.6%, pH adjusting agent 0%~2%, deionized water 37.4%~71.8%, the above component summation are 100%；
Step 3: the weighed deionized water of step 2 being added in reaction kettle, Pagoda Flower is added after being warming up to 40 DEG C in stirring
Extracting solution stirs 0.5~1h, sequentially adds efficient emulsifier and greasy dirt detersive, add triethanolamine and butanediol, finally
Isothiazolinone is added, continues 1~2h of stirring；It is adjusted after pH value of solution is 6-8 using pH adjusting agent and stops stirring, be down to solution
Room temperature to get to weight greasy dirt detergent.
The features of the present invention also characterized in that
Prepare Pagoda Flower extracting solution specific steps are as follows:
Step 1.1: fresh locust flower being smashed to pieces with crusher, is obtained after the fresh locust flower filtering smashed to pieces is then removed residue
Coarse filtration liquid；
Step 1.2: coarse filtration liquid being added to inside reaction kettle, then deionized water is added inside reaction kettle, is warming up to 95
DEG C, it boils 2 hours, then allows its Temperature fall, the liquid A of clear is obtained after refined filtration, isothiazoline is added in liquid A
The mass ratio of ketone, isothiazolinone and liquid A is 1:1000；It stirs evenly and obtains Pagoda Flower extracting solution；
Step 1.2 deionized water and coarse filtration liquid mass ratio are 1:2.5~3；Refined filtration uses the bag type filtering net of 1250 meshes.
Efficient emulsifier is C9-11 alcohol ethoxylate BEROL266 or C9-11 the fatty alcohol ethoxy of narrow ditribution
One of glycolylate BEROL609.
Greasy dirt detersive is one of Shuangzi propyl ethyoxyl alcohol ether or Shuangzi alkyl glycosides or two kinds of mixing.
PH adjusting agent is one of citric acid or sodium carbonate.
The beneficial effects of the present invention are: the surfactant that a kind of heavy greasy dirt detergent of the invention uses all be belong to it is low
Toxicity, high activity green product does not generate injury to skin and environment.
A kind of heavy greasy dirt detergent of the present invention can be used for the cleaning of heavy oil dirt in kitchen, mechanical equipment in workover treatment
With the cleaning of clothing and skin, the cleaning of industrial equipment, lease tank and the pipeline-cleaning operation of worker, dirt-removing power is common clear
More than the three times of lotion, it is a kind of greasy dirt detergent efficient as mild as a dove, can applies in the washing and cleaning operation of every field,
With very big commercial value.Meanwhile using the unique Pagoda Flower in northern Shensi as main component, the economic valence of locust tree is not only increased
Value, also brings meagre promotion to local economy.
Specific embodiment
A kind of heavy greasy dirt detergent provided by the invention, including composed of the following components by mass percentage: Pagoda Flower mentions
Take liquid 15%~30%, efficient emulsifier 5%~15%, greasy dirt detersive 5%~12%, triethanolamine 0.6%~3%, fourth
Glycol 0.5%~2%, isothiazolinone 0.2%~0.6%, pH adjusting agent 0%~2%, deionized water 37.4%~
71.8%, the sum of the above components mass percent is 100%；Pagoda Flower extracting solution is the liquid extracted after smashing fresh locust flower to pieces
Body.
Efficient emulsifier is C9-11 alcohol ethoxylate BEROL266 or C9-11 the fatty alcohol ethoxy of narrow ditribution
One of glycolylate BEROL609.
Greasy dirt detersive is one of Shuangzi propyl ethyoxyl alcohol ether or Shuangzi alkyl glycosides or two kinds of mixing.
PH adjusting agent is one of citric acid or sodium carbonate, and the pH value for adjusting weight greasy dirt detergent is 6-8.
A kind of preparation method of heavy greasy dirt detergent of the invention, specific steps are as follows:
Step 1: preparation Pagoda Flower extracting solution
Step 1.1: fresh locust flower being smashed to pieces with crusher, is obtained after the fresh locust flower filtering smashed to pieces is then removed residue
Coarse filtration liquid；
Step 1.2: coarse filtration liquid being added to inside reaction kettle, then deionized water is added inside reaction kettle, is warming up to 95
DEG C, it boils 2 hours, then allows its Temperature fall, the liquid A of clear is obtained after refined filtration, isothiazoline is added in liquid A
The mass ratio of ketone, isothiazolinone and liquid A is 1:1000；It stirs evenly and obtains Pagoda Flower extracting solution；
Step 1.2 deionized water and coarse filtration liquid mass ratio are 1:2.5~3；Refined filtration uses the bag type filtering net of 1250 meshes.
Step 2: following raw material: Pagoda Flower extracting solution 15%~30% prepared by step 1.2 is weighed by mass percentage, it is high
Effect emulsifier 5%~15%, greasy dirt detersive 5%~12%, triethanolamine 0.6%~3%, butanediol 0.5%~2% are different
Thiazolinone 0.2%~0.6%, pH adjusting agent 0%~2%, deionized water 37.4%~71.8%, the above component summation are
100%
Step 3: the weighed deionized water of step 2 being added in reaction kettle, Pagoda Flower is added after being warming up to 40 DEG C in stirring
Extracting solution stirs 0.5~1h, sequentially adds efficient emulsifier and greasy dirt detersive, add triethanolamine and butanediol, finally
Isothiazolinone is added, continues 1~2h of stirring；It is adjusted after pH value of solution is 6-8 using pH adjusting agent and stops stirring, be down to solution
Room temperature to get to weight greasy dirt detergent.
Efficient emulsifier is C9-11 alcohol ethoxylate BEROL266 or C9-11 the fatty alcohol ethoxy of narrow ditribution
One of glycolylate BEROL609；Than this efficient emulsifier it is a kind of environment-friendly products with OP-10, does not have in OP-10 product
Carcinogen dioxanes, environmental protection, to no damage to human body.
Greasy dirt detersive is one of Shuangzi propyl ethyoxyl alcohol ether or Shuangzi alkyl glycosides or two kinds of mixing.
PH adjusting agent is one of citric acid or sodium carbonate.
The preparation of Pagoda Flower extracting solution: fresh locust flower 500kg is smashed to pieces with crusher, and then the Pagoda Flower liquid smashed to pieces is filtered
The coarse filtration liquid that 270kg or so is obtained after removing slag is added to coarse filtration liquid inside reaction kettle, then 700kg is added inside reaction kettle
Left and right deionized water, is warming up to 95 DEG C, boils 2 hours, then allows its Temperature fall, using the bag type filtering net essence of 1250 meshes
The liquid A with locust tree flowery odour of clear is obtained after filter, the isothiazolinone of liquid A weight 0.1% is then added, i.e.,
For Pagoda Flower extracting solution, it is spare to be then charged into pail pack；Following embodiment is all made of the Pagoda Flower extracting solution of the method extraction.
Embodiment 1
Step 1: weighing following raw material: Pagoda Flower extracting solution 300kg, the C9-11 alcohol ethoxylate of above-mentioned preparation
BEROL266 150kg, Shuangzi propyl ethyoxyl alcohol ether 120kg, triethanolamine 30kg, butanediol 20kg, isothiazolinone 6kg,
Deionized water 374kg；
Step 2: the weighed deionized water of step 1 being added in reaction kettle, Pagoda Flower is added after being warming up to 40 DEG C in stirring
Extracting solution stirs 0.8h, sequentially adds C9-11 alcohol ethoxylate BEROL266 and Shuangzi propyl ethyoxyl alcohol ether, then
Triethanolamine and butanediol is added, is eventually adding the isothiazolinone, continues to stir 1.5h；To solution be down to room temperature to get
To weight greasy dirt detergent.
The heavy greasy dirt detergent of the method for the present invention preparation, which is applied, is extending the manufacture of the equipment used in oil field Co., Ltd machining vehicle
Between, the volatilization of the cleaning of lathe and milling machine surface, mechanical equipment greasy dirts such as lubricating oil and machine oil of maintenance in use adds
The dust in workshop, accumulating in equipment surface slowly, forms one layer of greasy dirt of yellow, is difficult to be cleaned.Using upper
Effect is fine after stating the heavy greasy dirt detergent of formula production, and 3kg weight greasy dirt detergent is added in 97kg water, then sets in machine
Standby surface and oil contaminant goes out uniformly to smear to be wiped with rag one after five minutes, and equipment surface becomes bright as new.At the same time with traditional oil
Dirty cleaning agent A and B has done an oil removal rate comparison, and the oil removal rate of identical usage amount foregoing invention can reach 99.5%, A's
The oil removal rate that oil removal rate can achieve 65%, B is only capable of reaching 50%.
Embodiment 2
Step 1: weighing following raw material: Pagoda Flower extracting solution 150kg, the C9-11 alcohol ethoxylate of above-mentioned preparation
BEROL266 70kg, Shuangzi alkyl glycosides 50kg, Shuangzi propyl ethyoxyl alcohol ether 50kg, triethanolamine 10kg, butanediol 5kg,
Isothiazolinone 2kg, deionized water 663kg；
Step 2: the weighed deionized water of step 1 being added in reaction kettle, Pagoda Flower is added after being warming up to 40 DEG C in stirring
Extracting solution stirs 1h, sequentially adds C9-11 alcohol ethoxylate BEROL266, Shuangzi alkyl glycosides and Shuangzi propyl second
Oxygroup alcohol ether, adds triethanolamine and butanediol, is eventually adding the isothiazolinone, continues to stir 2h；It is down to solution
Room temperature to get to weight greasy dirt detergent.
Embodiment 3
Step 1: weighing following raw material: Pagoda Flower extracting solution 150kg, the C9-11 alcohol ethoxylate of preparation
BEROL609 150kg, Shuangzi alkyl glycosides 80kg, triethanolamine 6kg, butanediol 3kg, isothiazolinone 2kg, deionized water
609kg；
Step 2: the weighed deionized water of step 1 being added in reaction kettle, Pagoda Flower is added after being warming up to 40 DEG C in stirring
Extracting solution stirs 1h, sequentially adds C9-11 alcohol ethoxylate BEROL609 and Shuangzi alkyl glycosides, add three second
Hydramine and butanediol are eventually adding the isothiazolinone, continue to stir 2h；Room temperature is down to solution to get dirty clear to heavy oil
Lotion.
Apply the cleaning of oil well rig and the cleaning of well workover worker clothing and skin in extending oil well repairing operation, well workover
Have a small amount of crude oil when operation to leak out, and spray on oil well surface and well workover worker clothing and skin, usual practice be using
The very strong washing powder of alkalinity goes to clean, and dosage is big, and effect is general, and oil removal rate can only achieve 85%, has corrosion to oil well, to clothing
Object and skin also have slight damage, so that skin is dry and astringent, clothing hardens.Use above-mentioned formula weight greasy dirt detergent, cleaning effect
Obviously, and mildly do not hurt clothing and skin, be also safe from harm to environment, oil removal rate can achieve 99%.
Embodiment 4
Step 1: weighing following raw material: Pagoda Flower extracting solution 150kg, the C9-11 alcohol ethoxylate of preparation
BEROL609 25kg, Shuangzi propyl ethyoxyl alcohol ether 60kg, triethanolamine 15kg, butanediol 10kg, isothiazolinone 3kg are gone
Ionized water 237kg.
Step 2: the weighed deionized water of step 1 being added in reaction kettle, Pagoda Flower is added after being warming up to 40 DEG C in stirring
Extracting solution stirs 0.5h, sequentially adds C9-11 alcohol ethoxylate BEROL609 and Shuangzi propyl ethyoxyl alcohol ether, then
Triethanolamine and butanediol is added, is eventually adding the isothiazolinone, continues to stir 1h；PH tune is added after reducing mixing speed
Section agent citric acid, adjusts after pH value of solution is 6 and stops stirring, is down to room temperature to solution to get weight greasy dirt detergent is arrived.
Embodiment 5
Step 1: weighing following raw material: Pagoda Flower extracting solution 80kg, the C9-11 alcohol ethoxylate of preparation
BEROL266 25kg, Shuangzi propyl ethyoxyl alcohol ether 25kg, triethanolamine 5kg, butanediol 5kg, isothiazolinone 1kg, go from
Sub- water 359kg.
Step 2: the weighed deionized water of step 1 being added in reaction kettle, Pagoda Flower is added after being warming up to 40 DEG C in stirring
Extracting solution stirs 1h, sequentially adds C9-11 alcohol ethoxylate BEROL266 and Shuangzi propyl ethyoxyl alcohol ether, then plus
Enter triethanolamine and butanediol, be eventually adding the isothiazolinone, continues to stir 2h；PH adjusting is added after reducing mixing speed
Agent sodium carbonate, adjusts after pH value of solution is 8 and stops stirring, is down to room temperature to solution to get weight greasy dirt detergent is arrived.
The heavy greasy dirt detergent of the method for the present invention preparation is also applicable in the cleaning of family exhauster for removing kitchen fumes and metope greasy dirt,
Although family kitchen has smoke exhaust ventilator can be the time has grown the surface of kitchen ventilator and kitchen wall surface also has the sticky of one layer of yellow
Greasy dirt, the dish washing liquid of normal domestic use have no idea to remove these greasy dirts at all, can only be cleaned with this heavy oil dirt specially designed
This greasy dirt is cleaned in agent, and the heavy greasy dirt detergent that foregoing invention obtains has good washing and cleaning operation for these greasy dirts, and use
Amount is also little, and specifically used method is the aqueous solution that weight greasy dirt detergent is first made into 3%, is sprayed on greasy surfaces, infiltrates 5 points
Then clock directly squeezes a small amount of weight greasy dirt detergent on wet rag again, wipes greasy surfaces, kitchen ventilator after wiping back and forth
Surface and metope are clean as new；The greasy dirt detergent dosage of the method preparation is few, has a wide range of application.
The present invention is using shrub Pagoda Flower common on the mountain of North Shaanxi, by simply extracting, with the liquid extracted
Body is as a kind of important source material for producing weight greasy dirt detergent.Rutin sophorin, the robinin, reseda contained in locust tree extracting solution
Element, Quercetin etc. have the effects of antibiotic and sterilizing, anti-aging with skin contact, while Pagoda Flower is that a kind of natural plant is fragrant again
Material, has pleasant fragrance, is able to extend the shelf-life of cleaning agent；Efficient emulsifier is the C9-11 fatty alcohol of narrow ditribution simultaneously
One kind of ethoxylate BEROL 266 or BEROL 609 than this efficient emulsifier are a kind of environment-friendly products with OP-10, no
With the carcinogen dioxanes in OP-10 product, environmental protection；Each raw produce proportion of cleaning agent of the invention is so that cleaning agent is gone
Dirty effect is powerful, and dirt-removing power is the three times of common cleaning agent or more.North Shaanxi locust tree can not only be played by this processing
Application value, moreover it is possible to bring meagre power for local economic development.
Claims (10)
1. a kind of heavy greasy dirt detergent, which is characterized in that composed of the following components by mass percentage: Pagoda Flower extracting solution 15%
~30%, efficient emulsifier 5%~15%, greasy dirt detersive 5%~12%, triethanolamine 0.6%~3%, butanediol 0.5%
~2%, isothiazolinone 0.2%~0.6%, pH adjusting agent 0%~2%, deionized water 37.4%~71.8%, the above each group
Dividing the sum of mass percent is 100%；The Pagoda Flower extracting solution is the liquid extracted after smashing fresh locust flower to pieces.
2. a kind of heavy greasy dirt detergent according to claim 1, which is characterized in that the efficient emulsifier is narrow ditribution
One of C9-11 alcohol ethoxylate BEROL266 or C9-11 alcohol ethoxylate BEROL609.
3. a kind of heavy greasy dirt detergent according to claim 1, which is characterized in that the greasy dirt detersive is Shuangzi propyl
One of ethyoxyl alcohol ether or Shuangzi alkyl glycosides or two kinds of mixing.
4. a kind of heavy greasy dirt detergent according to claim 1, which is characterized in that the pH adjusting agent is citric acid or carbon
One of sour sodium.
5. a kind of preparation method of heavy greasy dirt detergent, which is characterized in that specific steps are as follows:
Step 1: preparation Pagoda Flower extracting solution；
Step 2: weigh following raw material by mass percentage: Pagoda Flower extracting solution 15%~30% prepared by step 1 efficiently emulsifies
Agent 5%~15%, greasy dirt detersive 5%~12%, triethanolamine 1%~3%, butanediol 0.5%~2%, isothiazolinone
0.2%~0.6%, pH adjusting agent 0%~2%, deionized water 37.4%~71.8%, the above component summation is 100%
Step 3: the weighed deionized water of step 2 being added in reaction kettle, stirring is added Pagoda Flower after being warming up to 40 DEG C and extracts
Liquid stirs 0.5~1h, sequentially adds efficient emulsifier and greasy dirt detersive, add triethanolamine and butanediol, be eventually adding
The isothiazolinone continues 1~2h of stirring；It is adjusted after pH value of solution is 6-8 using pH adjusting agent and stops stirring, be down to solution
Room temperature to get to weight greasy dirt detergent.
6. a kind of preparation method of heavy greasy dirt detergent according to claim 5, which is characterized in that preparation Pagoda Flower is extracted
Liquid specific steps are as follows:
Step 1.1: fresh locust flower being smashed to pieces with crusher, obtains coarse filtration after the fresh locust flower filtering smashed to pieces is then removed residue
Liquid；
Step 1.2: the coarse filtration liquid being added to inside reaction kettle, then deionized water is added inside reaction kettle, is warming up to 95
DEG C, it boils 2 hours, then allows its Temperature fall, the liquid A of clear is obtained after refined filtration, different thiophene is added in the liquid A
The mass ratio of oxazoline ketone, the isothiazolinone and liquid A is 1:1000；It stirs evenly and obtains Pagoda Flower extracting solution.
7. a kind of preparation method of heavy greasy dirt detergent according to claim 6, which is characterized in that gone described in step 1.2
Ionized water and coarse filtration liquid mass ratio are 1:2.5~3；The refined filtration uses the bag type filtering net of 1250 meshes.
8. a kind of preparation method of heavy greasy dirt detergent according to claim 5, which is characterized in that the efficient emulsifier
For in the C9-11 alcohol ethoxylate BEROL266 or C9-11 alcohol ethoxylate BEROL609 of narrow ditribution
It is a kind of.
9. a kind of preparation method of heavy greasy dirt detergent according to claim 5, which is characterized in that the greasy dirt detersive
It is mixed for one of Shuangzi propyl ethyoxyl alcohol ether or Shuangzi alkyl glycosides or two kinds.
10. a kind of preparation method of heavy greasy dirt detergent according to claim 5, which is characterized in that the pH adjusting agent
For one of citric acid or sodium carbonate.
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| CN110777007A (en) * | 2019-10-22 | 2020-02-11 | 山立欣业新材料(广东)有限公司 | Bacteriostatic oil stain cleaning agent for kitchen and preparation process thereof |
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| CN110777007A (en) * | 2019-10-22 | 2020-02-11 | 山立欣业新材料(广东)有限公司 | Bacteriostatic oil stain cleaning agent for kitchen and preparation process thereof |
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