CN101818104B - Neutral cleaning agent for bathroom equipment and preparation method thereof - Google Patents
Neutral cleaning agent for bathroom equipment and preparation method thereof Download PDFInfo
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- CN101818104B CN101818104B CN2010101731025A CN201010173102A CN101818104B CN 101818104 B CN101818104 B CN 101818104B CN 2010101731025 A CN2010101731025 A CN 2010101731025A CN 201010173102 A CN201010173102 A CN 201010173102A CN 101818104 B CN101818104 B CN 101818104B
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- ether
- cleaning agent
- deionized water
- neutral cleaning
- bathroom equipment
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Abstract
The invention relates to a neutral cleaning agent for bathroom equipment and a preparation method thereof. The neutral cleaning agent is prepared by using fatty alcohol-polyoxyethylene (9) ether, fatty alcohol-polyoxyethylene (8) ether, alkyl polyglucoside, dodecyldimethyl betaine, hydroxypropyl guar gum, zinc ricinoleate, acrylic copolymer, 3-methoxyl-2-methyl-1-butanol, sodium citrate, citric acid monohydrate, dodecyldimethylbenzylammonium chloride, essence and deionized water as raw materials, and by mainly using a nonionic surfactant with excellent dirt-removing, emulsifying and foaming capacities and auxiliarily combining a mild and low-irritation ampholytic surfactant with anti-static and wetting performances, a film-forming agent and a deodorant for synergism, so the neutral cleaning agent has the advantages of achieving a good dirt-removing and descaling effect, removing odor, forming a protective film on the hard surfaces of the bathroom equipment to prevent dirt adhesion and finishing the steps of cleaning, removing peculiar smell and protecting at one time, along with environmental protection, no toxicity and no irritation.
Description
Technical field
The present invention relates to chemical field, particularly be used for neutral cleaning agent for bathroom equipment and preparation method thereof.This is used for neutral cleaning agent for bathroom equipment and the time can reduces or reduce the corrodibility of sanitary bath equipment and make sanitary bath equipment bright and clean beautiful in cleaning.
Background technology
Usually said sanitary bath equipment is as minute surface, hand basin, bathtub, tap, ceramic tile, toilet etc., and the dirt that pollutes sanitary bath equipment mainly contains incrustation scale, iron rust, soap scum, grease etc.Commercially available cleaning supplies generally adopt the method for pickling, and this method can be removed incrustation scale, iron rust effectively, but relatively poor to the cleaning capacity of soap scum, grease.Though acidic cleaning agent has descale effect preferably, but life-time service can be to pottery, corrosion is caused on the surface of sanitary bath equipment such as cement, metal, hot spot can further form dirt deposition again, cause follow-up scale removal process can strengthen the usage quantity of acidic cleaning agent, to such an extent as to and then increase the weight of acid attack and form vicious cycle, the purpose that makes the human consumer not only can not reach the cleaning sanitary bath equipment has also produced nonvolatil damage to sanitary bath equipment.
In order to solve the existing in prior technology problem, await providing a kind of
Can clean sanitary bath equipment, can not cause burn into can also increase the cleaning product of aesthetics again it.
Summary of the invention
The object of the present invention is to provide a kind of neutral cleaning agent for bathroom equipment that is used for; this mild detergent is to have the nonionogenic tenside of good decontamination, emulsification and foaming power; composite gentleness, the low amphoterics with antistatic and wettability, membrane-forming agent, the deodovization agent synergy that stimulates; when reaching good decontamination contaminant releasing ability; eliminate peculiar smell; and can form protective membrane at the crust of sanitary bath equipment, adhere to prevent dirt.Of the present invention to be used for neutral cleaning agent for bathroom equipment environmentally friendly, cleaning, taste removal, protection once can be finished, and nontoxic, non-stimulated, can be used for the cleaning surfaces of sanitary bath equipments such as pottery, metal, minute surface, plastics.
Another object of the present invention is to provide a kind of preparation method who is used for neutral cleaning agent for bathroom equipment.
The objective of the invention is to be achieved through the following technical solutions: a kind of neutral cleaning agent for bathroom equipment that is used for is prepared from by its ratio of weight and number by following raw material:
Aliphatic alcohol polyethenoxy (9) ether 0.5～8
Aliphatic alcohol polyethenoxy (8) ether 0.5～4
Alkyl-glucoside 1～10
Varion CDG-K 0.5～6
Hydroxypropyl guar bean gum 0.05～2
Ricinoleate zinc 0.05～3
Acrylic copolymer 0.05～2
3-methoxyl group-3-methyl isophthalic acid-butanols 0.5～5
Trisodium Citrate 0.5～5
Citric acid monohydrate Food grade 0.05～2
Dodecyl benzyl dimethyl ammonium chloride 0.1
Essence 0.1～0.3
Deionized water 70～90.
A kind of preparation method who is used for neutral cleaning agent for bathroom equipment, preparation process is as follows:
With the deionized water total amount that will add 30% under normal temperature condition in the placing material still, add the hydroxypropyl guar bean gum then while stirring, after stirring, adjusting the pH value with Citric acid monohydrate Food grade is 4～5, after treating that solution system is transparence, adding the deionized water and the interior solution temperature of making material still that account for total amount 30% again is 35～40 ℃, after holding temperature stirring 15～20min is the transparent and homogeneous shape to solution system, add Varion CDG-K while stirring successively, alkyl-glucoside, aliphatic alcohol polyethenoxy (9) ether, aliphatic alcohol polyethenoxy (8) ether and 3-methoxyl group-3-methyl isophthalic acid-butanols are to dissolving fully, add ricinoleate zinc again, acrylic copolymer, Trisodium Citrate, dodecyl benzyl dimethyl ammonium chloride, essence and remaining deionized water, adjusting the pH value with Citric acid monohydrate Food grade again after stirring is 6～8, leave standstill after stirring, obtain the described neutral cleaning agent for bathroom equipment that is used for.
The present invention compared with prior art has following advantage:
1, the neutral cleaning agent for bathroom equipment that is used for of the present invention can reduce or reduce sanitary bath equipment in the suffered corrosion of washing process, and the sanitary bath equipment of having degenerated through outward appearance that repetitive scrubbing caused and color can also be given significantly outward appearance and improve.
2, the neutral cleaning agent for bathroom equipment that is used for of the present invention adopts tensio-active agent (aliphatic alcohol polyethenoxy (9) ether), permeate agent (aliphatic alcohol polyethenoxy (8) ether) and sequestrant composite, can remove grease, soap scum and incrustation scale effectively; Macromolecule component (acrylic copolymer) can form protective membrane at the sanitary bath equipment crust, prevents dirt deposition; Solubility promoter (3-methoxyl group-3-methyl isophthalic acid-butanols), emulsifying agent (alkyl-glucoside, Varion CDG-K) and ricinoleate zinc synergy, may command peculiar smell.
3, of the present invention to be used for the neutral cleaning agent for bathroom equipment use range wide, promptly can be used for multiple sanitary bath equipment surfaces such as pottery, metal, minute surface, plastics.
4. product of the present invention meets every index of GB-T 21241-2007 sanitary ware clean-out system regulation.
5, of the present invention to be used for neutral cleaning agent for bathroom equipment environmentally friendly, nontoxic, non-stimulated, and decontamination, taste removal, protection are once finished.
Embodiment
The invention will be further described below in conjunction with embodiment.
A kind of neutral cleaning agent for bathroom equipment that is used for is prepared from by its ratio of weight and number by following raw material:
Aliphatic alcohol polyethenoxy (9) ether 0.5～8
Aliphatic alcohol polyethenoxy (8) ether 0.5～4
Alkyl-glucoside 1～10
Varion CDG-K 0.5～6
Hydroxypropyl guar bean gum 0.05～2
Ricinoleate zinc 0.05～3
Acrylic copolymer 0.05～2
3-methoxyl group-3-methyl isophthalic acid-butanols 0.5～5
Trisodium Citrate 0.5～5
Citric acid monohydrate Food grade 0.05～2
Dodecyl benzyl dimethyl ammonium chloride 0.1
Essence 0.1～0.3
Deionized water 70～90.
In the above-mentioned raw materials composition, aliphatic alcohol polyethenoxy (9) ether is tensio-active agent, can play good wetting emulsifying effect; Aliphatic alcohol polyethenoxy (8) ether is permeate agent, can promote the osmosis of product; Trisodium Citrate is a sequestrant; Acrylic copolymer is a macromolecule component, can form protective membrane, prevents dirt deposition; 3-methoxyl group-3-methyl isophthalic acid-butanols is a solubility promoter; Alkyl-glucoside, Varion CDG-K are emulsifying agent, and ricinoleate zinc is deodovization agent.
Above-described various raw material is technical grade.
Embodiment 1: a kind of neutral cleaning agent for bathroom equipment that is used for is prepared from by its ratio of weight and number by following raw material:
Aliphatic alcohol polyethenoxy (9) ether 0.5
Aliphatic alcohol polyethenoxy (8) ether 4
Alkyl-glucoside 5
Varion CDG-K 3
Hydroxypropyl guar bean gum 0.4
Ricinoleate zinc 0.5
Acrylic copolymer 0.5
3-methoxyl group-3-methyl isophthalic acid-butanols 3
Trisodium Citrate 5
Citric acid monohydrate Food grade 2
Dodecyl benzyl dimethyl ammonium chloride 0.1
Essence 0.2
Deionized water 75.8.
The neutral cleaning agent for bathroom equipment that is used for of present embodiment is applicable to light dirty sanitary bath equipment.
The described preparation method who is used for neutral cleaning agent for bathroom equipment is an example to produce this product of 100kg, and its preparation process is as follows:
With the 23kg deionized water under normal temperature condition in the placing material still, add hydroxypropyl guar bean gum 0.4kg then while stirring, after stirring, adjusting the pH value with Citric acid monohydrate Food grade 0.15kg is 4～5, after treating that solution system is transparence, add in 23kg deionized water and the making material still solution temperature again and be 35～40 ℃ (difference of the temperature visual operation environment of the deionized water that is added is adjusted; It is the deionized water that can use normal temperature summer; Use after deionized water suitably can being heated winter, with solution temperature in the assuranceization material still is 35～40 ℃), after holding temperature stirring 15～20min is the transparent and homogeneous shape to solution system, add Varion CDG-K 3kg while stirring successively, alkyl-glucoside 5kg, aliphatic alcohol polyethenoxy (9) ether 0.5kg, aliphatic alcohol polyethenoxy (8) ether 4 kg and 3-methoxyl group-3-methyl isophthalic acid-butanols 3kg is to dissolving fully, add ricinoleate zinc 0.5 kg again, acrylic copolymer 0.5kg, Trisodium Citrate 5kg, dodecyl benzyl dimethyl ammonium chloride 0.1kg, essence 0.2kg and remaining deionized water 29.8 kg, adjusting the pH value with Citric acid monohydrate Food grade 1.85kg again after stirring is 6～8, leave standstill after stirring, obtain the described neutral cleaning agent for bathroom equipment that is used for.
Embodiment 2: in the present embodiment, be used for neutral cleaning agent for bathroom equipment and be prepared from by its ratio of weight and number by following raw material:
Aliphatic alcohol polyethenoxy (9) ether 5
Aliphatic alcohol polyethenoxy (8) ether 0.5
Alkyl-glucoside 1
Varion CDG-K 6
Hydroxypropyl guar bean gum 0.05
Ricinoleate zinc 0.05
Acrylic copolymer 1
3-methoxyl group-3-methyl isophthalic acid-butanols 0.5
Trisodium Citrate 0.5
Citric acid monohydrate Food grade 0.06
Dodecyl benzyl dimethyl ammonium chloride 0.1
Essence 0.1
Deionized water 85.14.
Present embodiment be used for the sanitary bath equipment that neutral cleaning agent for bathroom equipment is applicable to that soap scum is heavier.
The described preparation method who is used for neutral cleaning agent for bathroom equipment is an example to produce this product of 100kg, and its preparation process is as follows:
With the 26kg deionized water under normal temperature condition in the placing material still, add hydroxypropyl guar bean gum 0.05kg then while stirring, after stirring, adjusting the pH value with Citric acid monohydrate Food grade 0.05kg is 4～5, after treating that solution system is transparence, adding the interior solution temperature of 26kg deionized water and making material still again is 35～40 ℃ (adjustment of the deionized water temperature that is added is with embodiment 1), after holding temperature stirring 15～20min is the transparent and homogeneous shape to solution system, add Varion CDG-K 6kg while stirring successively, alkyl-glucoside 1kg, aliphatic alcohol polyethenoxy (9) ether 5kg, aliphatic alcohol polyethenoxy (8) ether 0.5 kg and 3-methoxyl group-3-methyl isophthalic acid-butanols 0.5kg is to dissolving fully, add ricinoleate zinc 0.05 kg again, acrylic copolymer 1kg, Trisodium Citrate 0.5kg, dodecyl benzyl dimethyl ammonium chloride 0.1kg, essence 0.1kg and remaining deionized water 33.14 kg, adjusting the pH value with Citric acid monohydrate Food grade 0.01kg again after stirring is 6～8, leave standstill after stirring, obtain the described neutral cleaning agent for bathroom equipment that is used for.
Embodiment 3: in the present embodiment, be used for neutral cleaning agent for bathroom equipment and be prepared from by its ratio of weight and number by following raw material:
Aliphatic alcohol polyethenoxy (9) ether 2
Aliphatic alcohol polyethenoxy (8) ether 2
Alkyl-glucoside 10
Varion CDG-K 0.5
Hydroxypropyl guar bean gum 2
Ricinoleate zinc 3
Acrylic copolymer 0.5
3-methoxyl group-3-methyl isophthalic acid-butanols 1
Trisodium Citrate 3
Citric acid monohydrate Food grade 2
Dodecyl benzyl dimethyl ammonium chloride 0.1
Essence 0.3
Deionized water 73.6.
The neutral cleaning agent for bathroom equipment that is used for of present embodiment is applicable to high-grade sanitary bath equipment, especially the sanitary bath equipment of surface-brightening.
With the 22kg deionized water under normal temperature condition in the placing material still, add hydroxypropyl guar bean gum 2kg then while stirring, after stirring, adjusting the pH value with Citric acid monohydrate Food grade 0.6kg is 4～5, after treating that solution system is transparence, adding the interior solution temperature of 22kg deionized water and making material still again is 35～40 ℃ (adjustment of the deionized water temperature that is added is with embodiment 1), after holding temperature stirring 15～20min is the transparent and homogeneous shape to solution system, add Varion CDG-K 0.5kg while stirring successively, alkyl-glucoside 10kg, aliphatic alcohol polyethenoxy (9) ether 2kg, aliphatic alcohol polyethenoxy (8) ether 2kg and 3-methoxyl group-3-methyl isophthalic acid-butanols 1kg is to dissolving fully, add ricinoleate zinc 3 kg again, acrylic copolymer 0.5kg, Trisodium Citrate 3kg, dodecyl benzyl dimethyl ammonium chloride 0.1kg, essence 0.3kg and remaining deionized water 29.6 kg, adjusting the pH value with Citric acid monohydrate Food grade 1.4kg again after stirring is 6～8, leave standstill after stirring, obtain the described neutral cleaning agent for bathroom equipment that is used for.
Embodiment 4: in the present embodiment, be used for neutral cleaning agent for bathroom equipment and be prepared from by its ratio of weight and number by following raw material:
Aliphatic alcohol polyethenoxy (9) ether 8
Aliphatic alcohol polyethenoxy (8) ether 0.5
Alkyl-glucoside 2
Varion CDG-K 3
Hydroxypropyl guar bean gum 1
Ricinoleate zinc 2
Acrylic copolymer 1.5
3-methoxyl group-3-methyl isophthalic acid-butanols 3
Trisodium Citrate 1
Citric acid monohydrate Food grade 0.5
Dodecyl benzyl dimethyl ammonium chloride 0.1
Essence 0.3
Deionized water 77.1.
The neutral cleaning agent for bathroom equipment that is used for of present embodiment is applicable to grease, the sanitary bath equipment that soap scum is heavier.
The described preparation method who is used for neutral cleaning agent for bathroom equipment is an example to produce this product of 100kg, and its preparation process is as follows:
With the 23kg deionized water under normal temperature condition in the placing material still, add hydroxypropyl guar bean gum 1kg then while stirring, after stirring, adjusting the pH value with Citric acid monohydrate Food grade 0.3kg is 4～5, after treating that solution system is transparence, adding the interior solution temperature of 23kg deionized water and making material still again is 35～40 ℃ (adjustment of the deionized water temperature that is added is with embodiment 1), after holding temperature stirring 15～20min is the transparent and homogeneous shape to solution system, add Varion CDG-K 3kg while stirring successively, alkyl-glucoside 2kg, aliphatic alcohol polyethenoxy (9) ether 8kg, aliphatic alcohol polyethenoxy (8) ether 0.5 kg and 3-methoxyl group-3-methyl isophthalic acid-butanols 3kg is to dissolving fully, add ricinoleate zinc 2kg again, acrylic copolymer 1.5kg, Trisodium Citrate 1kg, dodecyl benzyl dimethyl ammonium chloride 0.1kg, essence 0.3kg and remaining deionized water 31.1 kg, adjusting the pH value with Citric acid monohydrate Food grade 0.2kg again after stirring is 6～8, leave standstill after stirring, obtain the described neutral cleaning agent for bathroom equipment that is used for.
Embodiment 5: in the present embodiment, be used for neutral cleaning agent for bathroom equipment and be prepared from by its ratio of weight and number by following raw material:
Aliphatic alcohol polyethenoxy (9) ether 2
Aliphatic alcohol polyethenoxy (8) ether 4
Alkyl-glucoside 6
Varion CDG-K 4
Hydroxypropyl guar bean gum 1.5
Ricinoleate zinc 0.5
Acrylic copolymer 2
3-methoxyl group-3-methyl isophthalic acid-butanols 1
Trisodium Citrate 2.5
Citric acid monohydrate Food grade 1.5
Dodecyl benzyl dimethyl ammonium chloride 0.1
Essence 0.2
Deionized water 74. 7.
The neutral cleaning agent for bathroom equipment that is used for of present embodiment is applicable to incrustation scale, the sanitary bath equipment that iron rust is heavier.
The described preparation method who is used for neutral cleaning agent for bathroom equipment is an example to produce this product of 100kg, and its preparation process is as follows:
With the 22kg deionized water under normal temperature condition in the placing material still, add hydroxypropyl guar bean gum 1.5kg then while stirring, after stirring, adjusting the pH value with Citric acid monohydrate Food grade 0.4kg is 4～5, after treating that solution system is transparence, adding the interior solution temperature of 22kg deionized water and making material still again is 35～40 ℃ (adjustment of the deionized water temperature that is added is with embodiment 1), after holding temperature stirring 15～20min is the transparent and homogeneous shape to solution system, add Varion CDG-K 4kg while stirring successively, alkyl-glucoside 6kg, aliphatic alcohol polyethenoxy (9) ether 2kg, aliphatic alcohol polyethenoxy (8) ether 4 kg and 3-methoxyl group-3-methyl isophthalic acid-butanols 1kg is to dissolving fully, add ricinoleate zinc 0.5 kg again, acrylic copolymer 2kg, Trisodium Citrate 2.5kg, dodecyl benzyl dimethyl ammonium chloride 0.1kg, essence 0.2kg and remaining deionized water 30.7 kg, adjusting the pH value with Citric acid monohydrate Food grade 1.1kg again after stirring is 6～8, leave standstill after stirring, obtain the described neutral cleaning agent for bathroom equipment that is used for.
Claims (6)
1. one kind is used for neutral cleaning agent for bathroom equipment, it is characterized in that: be prepared from by its ratio of weight and number by following raw material:
Straight-chain fatty alcohol polyoxyethylene (9) ether 0.5～8
Aliphatic alcohol polyethenoxy (8) ether 0.5～4
Alkyl-glucoside 1～10
Varion CDG-K 0.5～6
Hydroxypropyl guar bean gum 0.05～2
Ricinoleate zinc 0.05～3
Acrylic copolymer 0.05～2
3-methoxyl group-3-methyl isophthalic acid-butanols 0.5～5
Trisodium Citrate 0.5～5
Citric acid monohydrate Food grade 0.05～2
Dodecyl benzyl dimethyl ammonium chloride 0.1
Essence 0.1～0.3
Deionized water 70～90;
The described neutral cleaning agent for bathroom equipment that is used for is to prepare as follows: with the deionized water total amount that will add 30% under normal temperature condition placing material still, add the hydroxypropyl guar bean gum then while stirring, after stirring, adjusting the pH value with Citric acid monohydrate Food grade is 4～5, after treating that solution system is transparence, adding the deionized water and the interior solution temperature of making material still that account for total amount 30% again is 35～40 ℃, after holding temperature stirring 15～20min is the transparent and homogeneous shape to solution system, add Varion CDG-K while stirring successively, alkyl-glucoside, straight-chain fatty alcohol polyoxyethylene (9) ether, aliphatic alcohol polyethenoxy (8) ether and 3-methoxyl group-3-methyl isophthalic acid-butanols are to dissolving fully, add ricinoleate zinc again, acrylic copolymer, Trisodium Citrate, dodecyl benzyl dimethyl ammonium chloride, essence and remaining deionized water, adjusting the pH value with Citric acid monohydrate Food grade again after stirring is 6～8, leave standstill after stirring, obtain the described neutral cleaning agent for bathroom equipment that is used for.
2. the neutral cleaning agent for bathroom equipment that is used for according to claim 1 is characterized in that: be prepared from by its ratio of weight and number by following raw material:
Straight-chain fatty alcohol polyoxyethylene (9) ether 0.5
Aliphatic alcohol polyethenoxy (8) ether 4
Alkyl-glucoside 5
Varion CDG-K 3
Hydroxypropyl guar bean gum 0.4
Ricinoleate zinc 0.5
Acrylic copolymer 0.5
3-methoxyl group-3-methyl isophthalic acid-butanols 3
Trisodium Citrate 5
Citric acid monohydrate Food grade 2
Dodecyl benzyl dimethyl ammonium chloride 0.1
Essence 0.2
Deionized water 75.8.
3. the neutral cleaning agent for bathroom equipment that is used for according to claim 1 is characterized in that: be prepared from by its ratio of weight and number by following raw material:
Straight-chain fatty alcohol polyoxyethylene (9) ether 5
Aliphatic alcohol polyethenoxy (8) ether 0.5
Alkyl-glucoside 1
Varion CDG-K 6
Hydroxypropyl guar bean gum 0.05
Ricinoleate zinc 0.05
Acrylic copolymer 1
3-methoxyl group-3-methyl isophthalic acid-butanols 0.5
Trisodium Citrate 0.5
Citric acid monohydrate Food grade 0.06
Dodecyl benzyl dimethyl ammonium chloride 0.1
Essence 0.1
Deionized water 85.14.
4. the neutral cleaning agent for bathroom equipment that is used for according to claim 1 is characterized in that: be prepared from by its ratio of weight and number by following raw material:
Straight-chain fatty alcohol polyoxyethylene (9) ether 2
Aliphatic alcohol polyethenoxy (8) ether 2
Alkyl-glucoside 10
Varion CDG-K 0.5
Hydroxypropyl guar bean gum 2
Ricinoleate zinc 3
Acrylic copolymer 0.5
3-methoxyl group-3-methyl isophthalic acid-butanols 1
Trisodium Citrate 3
Citric acid monohydrate Food grade 2
Dodecyl benzyl dimethyl ammonium chloride 0.1
Essence 0.3
Deionized water 73.6.
5. the neutral cleaning agent for bathroom equipment that is used for according to claim 1 is characterized in that: be prepared from by its ratio of weight and number by following raw material:
Straight-chain fatty alcohol polyoxyethylene (9) ether 8
Aliphatic alcohol polyethenoxy (8) ether 0.5
Alkyl-glucoside 2
Varion CDG-K 3
Hydroxypropyl guar bean gum 1
Ricinoleate zinc 2
Acrylic copolymer 1.5
3-methoxyl group-3-methyl isophthalic acid-butanols 3
Trisodium Citrate 1
Citric acid monohydrate Food grade 0.5
Dodecyl benzyl dimethyl ammonium chloride 0.1
Essence 0.3
Deionized water 77.1.
6. the neutral cleaning agent for bathroom equipment that is used for according to claim 1 is characterized in that: be prepared from by its ratio of weight and number by following raw material:
Straight-chain fatty alcohol polyoxyethylene (9) ether 2
Aliphatic alcohol polyethenoxy (8) ether 4
Alkyl-glucoside 6
Varion CDG-K 4
Hydroxypropyl guar bean gum 1.5
Ricinoleate zinc 0.5
Acrylic copolymer 2
3-methoxyl group-3-methyl isophthalic acid-butanols 1
Trisodium Citrate 2.5
Citric acid monohydrate Food grade 1.5
Dodecyl benzyl dimethyl ammonium chloride 0.1
Essence 0.2
Deionized water 74.7.
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| Application Number | Priority Date | Filing Date | Title |
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| CN2010101731025A CN101818104B (en) | 2010-05-17 | 2010-05-17 | Neutral cleaning agent for bathroom equipment and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010101731025A CN101818104B (en) | 2010-05-17 | 2010-05-17 | Neutral cleaning agent for bathroom equipment and preparation method thereof |
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| CN101818104B true CN101818104B (en) | 2011-09-28 |
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| CN104017662A (en) * | 2014-06-03 | 2014-09-03 | 北京洛娃日化有限公司 | Deodorant-containing acidic toilet cleaning agent |
| CN112680293B (en) * | 2019-10-18 | 2022-07-08 | 中国石油化工股份有限公司 | Emulsifier, preparation method and application thereof, and method for emulsifying butter in alkaline washing tower |
| CN112029593B (en) * | 2020-07-21 | 2022-08-30 | 名臣健康用品股份有限公司 | Low-viscosity foam type toilet cleaning liquid composition with foam spraying effect and preparation method thereof |
| CN111979054A (en) * | 2020-08-19 | 2020-11-24 | 河南昇阳生物科技有限公司 | Neutral environment-friendly bathroom cleaner and preparation method thereof |
| CN114686315B (en) * | 2021-12-31 | 2024-04-12 | 北京绿伞科技股份有限公司 | Foam cleaning agent for closestool and preparation method thereof |
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| CN1060512C (en) * | 1996-03-13 | 2001-01-10 | 上海白猫(集团)有限公司 | Neutral bathtub cleaning agent |
| WO2001023515A1 (en) * | 1999-09-29 | 2001-04-05 | Rhodia Inc. | Novel polymer based cleaning compositions for use in hard surface cleaning and laundry applications |
| CN1354243A (en) * | 2000-11-22 | 2002-06-19 | 上海白猫有限公司 | Preparation method of liquid toilet pan cleaning agent |
| DE102007019373A1 (en) * | 2007-04-23 | 2008-10-30 | Henkel Ag & Co. Kgaa | Liquid washing or cleaning agent with yield point |
| CN100532526C (en) * | 2007-12-10 | 2009-08-26 | 北京绿伞化学股份有限公司 | Non-toxic class floor furniture detergent having sterilizing function and preparation method thereof |
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