CN109438765A - 一种塑料薄膜 - Google Patents

一种塑料薄膜 Download PDF

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Publication number
CN109438765A
CN109438765A CN201811136794.9A CN201811136794A CN109438765A CN 109438765 A CN109438765 A CN 109438765A CN 201811136794 A CN201811136794 A CN 201811136794A CN 109438765 A CN109438765 A CN 109438765A
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Prior art keywords
parts
plastic film
tert
phenyl
butyl
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李厚力
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Nanjing Green Force New Material Co Ltd
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Nanjing Green Force New Material Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/04—Ingredients characterised by their shape and organic or inorganic ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2296—Oxides; Hydroxides of metals of zinc
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K3/2279—Oxides; Hydroxides of metals of antimony
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/52—Phosphorus bound to oxygen only
    • C08K5/524—Esters of phosphorous acids, e.g. of H3PO3
    • C08K5/526—Esters of phosphorous acids, e.g. of H3PO3 with hydroxyaryl compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/56—Organo-metallic compounds, i.e. organic compounds containing a metal-to-carbon bond
    • C08K5/57—Organo-tin compounds
    • C08K5/58—Organo-tin compounds containing sulfur
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/02—Fibres or whiskers
    • C08K7/04—Fibres or whiskers inorganic
    • C08K7/10—Silicon-containing compounds

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

本发明公开了一种塑料薄膜，包括三[2,4‑二叔丁基苯基]亚磷酸酯8‑19份、氧化锌11‑25份、三氧化二锑5‑18份、硅灰石纤维10‑22份、硫醇甲基锡3‑12份。本发明的塑料薄膜不仅耐候性佳，具有较好的抗静电及稳定性、且长时间处于高温环境仍能够保持良好的机械性能、不易变脆易碎，使用寿命长，突破了传统改塑料的缺陷，具有很强的实用价值。

Description

一种塑料薄膜
技术领域
本发明属于塑料组合物，尤其涉及一种塑料薄膜。
背景技术
塑料是高分子量的聚合物材料。随着分子量的增加，聚合物材料从气体变为液体或固体。固体材料具有越高的分子量，它的流动性则越小，但是机械性能或耐热性会提升，并且具有可用作为日常生活中所需的材料(如金属、木材、陶瓷、橡胶等)的性能。塑料是通过混合各种类型的添加剂(包括改性剂、着色剂、加强剂、填料等)并进行成型加工而得的聚合物材料。塑料的性能由合成树脂(如PE、PP、PVC等)的化学结构决定，而相同的树脂的性能可能根据许多因素而有所不同，因此该特征可用于塑料的改性。在化学结构方面，塑料的性能根据分子量、分子量分布、基于聚合物制备(即聚合)条件的主链和侧链状态、端基、交联、立构规整性和共聚物组成分布等而变化。通常，配合(compounding)是指通过向聚合物原料添加各种类型的添加剂或各种配合剤(例如增强剂、改性剂等)而制备适于预期用途的组合物，并且由此制备的组合物以颗粒形式流通。
发明内容
发明目的：本发明的目的是提供一种耐候性佳、抗静电及稳定性强的塑料薄膜。
技术方案：本发明的塑料薄膜，包括如下组分：三[2,4-二叔丁基苯基]亚磷酸酯8-19份、氧化锌11-25份、三氧化二锑5-18份、硅灰石纤维10-22份、硫醇甲基锡3-12份。
优选的，三[2,4-二叔丁基苯基]亚磷酸酯10-15份。氧化锌15-20份。三氧化二锑8-10份。硅灰石纤维15-20份。硫醇甲基锡8-10份。
有益效果：与现有技术相比，本发明的显著优点为：该塑料薄膜不仅耐候性佳，具有较好的抗静电及稳定性、且长时间处于高温环境仍能够保持良好的机械性能、不易变脆易碎，使用寿命长，突破了传统改塑料的缺陷，具有很强的实用价值。
具体实施方式
下面结合实施例对本发明的技术方案做进一步详细说明。
实施例1
本发明的塑料薄膜包括：三[2,4-二叔丁基苯基]亚磷酸酯10份、氧化锌15份、三氧化二锑8份、硅灰石纤维15份、硫醇甲基锡8份。
实施例2
本发明的塑料薄膜包括：三[2,4-二叔丁基苯基]亚磷酸酯15份、氧化锌20份、三氧化二锑10份、硅灰石纤维20份、硫醇甲基锡10份。
实施例3
本发明的塑料薄膜包括：三[2,4-二叔丁基苯基]亚磷酸酯8份、氧化锌11份、三氧化二锑5份、硅灰石纤维10份、硫醇甲基锡3份。
实施例4
本发明的塑料薄膜包括：三[2,4-二叔丁基苯基]亚磷酸酯19份、氧化锌25份、三氧化二锑18份、硅灰石纤维22份、硫醇甲基锡12份。

Claims (6)

1.一种塑料薄膜，其特征在于包括如下组分：三[2,4-二叔丁基苯基]亚磷酸酯8-19份、氧化锌11-25份、三氧化二锑5-18份、硅灰石纤维10-22份、硫醇甲基锡3-12份。
2.根据权利要求1所述的塑料薄膜，其特征在于：所述三[2,4-二叔丁基苯基]亚磷酸酯10-15份。
3.根据权利要求1所述的塑料薄膜，其特征在于：所述氧化锌15-20份。
4.根据权利要求1所述的塑料薄膜，其特征在于：所述三氧化二锑8-10份。
5.根据权利要求1所述的塑料薄膜，其特征在于：所述硅灰石纤维15-20份。
6.根据权利要求1所述的塑料薄膜，其特征在于：所述硫醇甲基锡8-10份。
CN201811136794.9A 2018-09-28 2018-09-28 一种塑料薄膜 Pending CN109438765A (zh)

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Application publication date: 20190308