CN109437976A - One kind is except antibacterial ceramic tile of formaldehyde and preparation method thereof - Google Patents
One kind is except antibacterial ceramic tile of formaldehyde and preparation method thereof Download PDFInfo
- Publication number
- CN109437976A CN109437976A CN201811202812.9A CN201811202812A CN109437976A CN 109437976 A CN109437976 A CN 109437976A CN 201811202812 A CN201811202812 A CN 201811202812A CN 109437976 A CN109437976 A CN 109437976A
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- layer
- formaldehyde
- ceramic tile
- tile
- inorganic nano
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention provides one kind except antibacterial ceramic tile of formaldehyde and preparation method thereof, the ceramic tile is by tile substrate layer, inorganic nano ceramic layer, anion glaze layer, the five-layer structure that decorative layer and wearing layer are constituted, the tile substrate layer is set to the bottom of ceramic tile, the inorganic nano ceramic layer is adsorbed on tile substrate layer surface, the anion glaze layer drenches glaze by wet process and is sprayed on inorganic nano surface ceramii layer, the inorganic nano ceramic layer is the carrier of anion glaze layer, anion glaze layer is covered on inorganic nano ceramic layer by the decorative layer, the antifriction layer is coated in decorative layer, the decorative layer is set to the top layer of ceramic tile.The present invention is equipped with anion glaze layer, the formaldehyde in indoor environment can be removed and increase the biocidal property of ceramic tile, and the present invention increases anion glaze layer using inorganic nano ceramic layer as the carrier of anion glaze layer, avoids leading to the disabler except formaldehyde because of being worn away.
Description
Technical field
The present invention relates to ceramic tile fields, and in particular to one kind is except antibacterial ceramic tile of formaldehyde and preparation method thereof.
Background technique
First killer of the formaldehyde as indoor environment, its acquisition time are up to 3 years~15 years, to human body especially baby children
Youngster, pregnant women, old man and chronic are very serious.The source of indoor formaldehyde is mainly in new clothes house, Long Term Contact
Low concentration formaldehyde steam can have the symptoms such as headache, weak and feeble；Formaldehyde can also cause tactile, the pain sensation and sense of heat obstacle, body one
Side perspires excessively, and body two sides skin temperature differs, to health hazard than more serious, in air toxic gas deenergized period compared with
Long, occupant is not noticeable when slight exceeded；At exceeded 4 times~5 times, occupant can just smell smell, therefore, ask testing agency
It does indoor air environment formaldehyde examination and has become an essential program for moving in the new home now, on the other hand, the modern times are logical
News technology it is universal, household electrical appliance increase, and cause electromagnetic radiation serious, and cation increases in air, anion is deficient, etc. it is a variety of
The pollution of environment for human survival is also to cause the core reasons of current human condition.
Anion glaze layer is coated on ceramic tile currently, existing in the market, removal effect well is played to indoor formaldehyde
Fruit, but poor adhesive force of the existing anion glaze layer on ceramic tile are easy to be rubbed off, and there is no great practical valences
Value.
Summary of the invention
In view of the deficiencies of the prior art, the present invention provides it is a kind of increase anion glaze layer wearability except formaldehyde bear from
Sub- ceramic tile and preparation method thereof.
One kind remove the antibacterial ceramic tile of formaldehyde, the ceramic tile by tile substrate layer, inorganic nano ceramic layer, anion glaze layer,
The five-layer structure that decorative layer and wearing layer are constituted, the tile substrate layer are set to the bottom of ceramic tile, the inorganic nano pottery
Enamel coating is adsorbed on tile substrate layer surface, and the anion glaze layer drenches glaze by wet process and is sprayed on inorganic nano ceramic layer table
Face, the inorganic nano ceramic layer are the carrier of anion glaze layer, and anion glaze layer is covered on inorganic by the decorative layer
On nano-ceramic layer, the antifriction layer is coated in decorative layer, and the decorative layer is set to the top layer of ceramic tile.
Preferably, the anion glaze layer is made of negative ion powder, and the negative ion powder is graininess, and partial size is little
In 60um.
Preferably, the negative ion powder includes following components in percentage by weight: feldspar 25-40%, rare earth 10-
15%, calcium oxide 3-5%, anionic additive 15-20%, quartz 3-5%, diatomite 20-15%, surplus are clay.
Preferably, ready-made mosaic coating after the anion glaze layer surface is contacted with inorganic nano surface ceramii layer, it is described
Mosaic coating thickness not 0.8-1um.
Preferably, the thickness of the tile substrate layer is no more than 10mm.
Preferably, the inorganic nano ceramic layer with a thickness of 0.5-3um.
Preferably, the anion glaze layer with a thickness of 1-5um.
Preferably, the decorative layer includes following components in percentage by weight: the water of formaldehyde catching agent 5-25%, surplus
Property coating, the decorative layer with a thickness of 1-2um.
Preferably, the thickness of the wearing layer is not more than 1um.
A kind of preparation method except the antibacterial ceramic tile of formaldehyde, following making step:
Step 1: be ready to ceramic tile hair training, using sander by ceramic tile hair training surface be machined to it is smooth, as tile substrate
Layer.
Step 2: behind the face that inorganic nano ceramic layer coats have been polished to tile substrate layer, placing shady place and stand
10min。
Step 3: the component of weight percent: feldspar 25-40%, rare earth 10-15%, calcium oxide 3-5%, anion is added
Adding agent 15-20%, quartz 3-5%, diatomite 20-15%, surplus is that clay pours into grinder respectively, and grinder is with 800r/
The revolving speed of min grinds 60min, produces the negative ion powder that partial size is not more than 60um.
Step 4: negative ion powder being sprayed into ready-made anion glaze layer on inorganic nano ceramic layer using leaching glaze, is placed into baking
5min in dry machine is mounted to anion glaze layer in inorganic nano ceramic layer, ready-made mosaic coating.
Step 5: by deployed cosmetic layer in anion glaze layer.
Step 6: wearing layer is coated in decorative layer.
The invention has the benefit that anion glaze layer, which is coated on ceramic tile, can permanently discharge anion, and discharge negative
Amount of ions is higher, is conducive to remove indoor formaldehyde for a long time, and anion glaze layer itself has the effect of antibacterial, therefore improves
The biocidal property of ceramic tile, carrier of the inorganic nano ceramic layer as anion glaze layer, the surface coated in ceramic tile increases anion
Glaze layer wearability avoids anion glaze layer and is worn away and leads to the disabler except formaldehyde.
Detailed description of the invention
Fig. 1 is cross-sectional view of the invention.
In figure: tile substrate layer 1, inorganic nano ceramic layer 2, mosaic coating 3, anion glaze layer 4, decorative layer 5, wearing layer 6.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete
Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments, is based on
Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts every other
Embodiment shall fall within the protection scope of the present invention.
As shown in connection with fig. 1, a kind of to remove the antibacterial ceramic tile of formaldehyde, the ceramic tile is by tile substrate layer 1, inorganic nano ceramic layer
2, the five-layer structure that anion glaze layer 4, decorative layer 5 and wearing layer 6 are constituted, the tile substrate layer 1 are set to the bottom of ceramic tile,
The inorganic nano ceramic layer 2 is adsorbed on 1 surface of tile substrate layer, and the anion glaze layer 4 is drenched glaze by wet process and sprayed
On 2 surface of inorganic nano ceramic layer, the inorganic nano ceramic layer 2 is the carrier of anion glaze layer 4, the decorative layer 5
Anion glaze layer 4 is covered on inorganic nano ceramic layer 2, the antifriction layer 6 is coated in decorative layer 5, the decoration
Layer 5 is set to the top layer of ceramic tile.
The anion glaze layer 4 is made of negative ion powder, and the negative ion powder is graininess, and partial size is not more than
60um。
The negative ion powder includes following components in percentage by weight: feldspar 25-40%, rare earth 10-15%, calcium oxide
3-5%, anionic additive 15-20%, quartz 3-5%, diatomite 20-15%, surplus are clay.
Ready-made mosaic coating 3 after 4 surface of anion glaze layer is contacted with 2 surface of inorganic nano ceramic layer, the edge
The thickness of inlay 3 not 0.8-1um.
The thickness of the tile substrate layer 1 is no more than 10mm.
The inorganic nano ceramic layer 2 with a thickness of 0.5-3um.
The anion glaze layer 4 with a thickness of 1-5um.
The decorative layer 5 includes following components in percentage by weight: the aqueous painting of formaldehyde catching agent 5-25%, surplus
Material, the decorative layer with a thickness of 1-2um.
The thickness of the wearing layer 6 is not more than 1um.
A kind of preparation method except the antibacterial ceramic tile of formaldehyde, following making step:
Step 1: be ready to ceramic tile hair training, using sander by ceramic tile hair training surface be machined to it is smooth, as tile substrate
Layer 1.
Step 2: after inorganic nano ceramic layer 2 to be coated to the face that tile substrate layer 1 has been polished, placing shady place and stand
10min。
Step 3: the component of weight percent: feldspar 25-40%, rare earth 10-15%, calcium oxide 3-5%, anion is added
Adding agent 15-20%, quartz 3-5%, diatomite 20-15%, surplus is that clay pours into grinder respectively, and grinder is with 800r/
The revolving speed of min grinds 60min, produces the negative ion powder that partial size is not more than 60um.
Step 4: negative ion powder being sprayed into ready-made anion glaze layer 4 on inorganic nano ceramic layer using leaching glaze, is placed into
5min in dryer is mounted to anion glaze layer 4 in inorganic nano ceramic layer 2, ready-made mosaic coating 3.
Step 5: deployed decorative layer 5 is coated in anion glaze layer 4.
Step 6: wearing layer 6 is coated in decorative layer 5.
Case 1: inorganic nano ceramic layer 4 tests anion after sand paper polishing ceramic tile 1 hour with a thickness of 0.5um
Release concentration is 823/cm3.
Case 2: inorganic nano ceramic layer 4 tests anion after sand paper polishing ceramic tile 1 hour with a thickness of 1.5um
Release concentration is 1008/cm3.
Case 3: inorganic nano ceramic layer 4 with a thickness of 3um, after being polished ceramic tile 1 hour using sand paper, test anion is released
Putting concentration is 1248/cm3.
Case 4: inorganic nano ceramic layer 4 with a thickness of 0um, after being polished ceramic tile 1 hour using sand paper, test anion is released
Putting concentration is 221/cm3
Learnt according to case, when the thickness of anion glaze layer 2 is constant, the thickness effect of inorganic nano ceramic layer 4 bear from
The burst size of the anion of sub- glaze layer 2.
The invention has the benefit that anion glaze layer, which is coated on ceramic tile, can permanently discharge anion, and discharge negative
Amount of ions is higher, is conducive to remove indoor formaldehyde for a long time, and anion glaze layer itself has the effect of antibacterial, therefore improves
The biocidal property of ceramic tile, carrier of the inorganic nano ceramic layer as anion glaze layer, the surface coated in ceramic tile increases anion
Glaze layer wearability avoids anion glaze layer and is worn away and leads to the disabler except formaldehyde.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding
And modification, the scope of the present invention is defined by the appended.
Claims (10)
1. one kind removes the antibacterial ceramic tile of formaldehyde, which is characterized in that the ceramic tile is by tile substrate layer, inorganic nano ceramic layer, negative
The five-layer structure that ion glaze layer, decorative layer and wearing layer are constituted, the tile substrate layer are set to the bottom of ceramic tile, the nothing
Machine nano-ceramic layer is adsorbed on tile substrate layer surface, and the anion glaze layer drenches glaze by wet process and is sprayed on inorganic nano pottery
Enamel coating surface, the inorganic nano ceramic layer are the carrier of anion glaze layer, and the decorative layer covers anion glaze layer
On inorganic nano ceramic layer, the antifriction layer is coated in decorative layer, and the decorative layer is set to the top layer of ceramic tile.
2. according to claim 1 a kind of except the antibacterial ceramic tile of formaldehyde, the anion glaze layer is made of negative ion powder, institute
The negative ion powder stated is graininess, and partial size is not more than 60um.
3. according to claim 2 a kind of except the antibacterial ceramic tile of formaldehyde, the negative ion powder includes following weight percent
Component: feldspar 25-40%, rare earth 10-15%, calcium oxide 3-5%, anionic additive 15-20%, quartz 3-5%, diatom
Native 20-15%, surplus are clay.
4. according to claim 1 a kind of except the antibacterial ceramic tile of formaldehyde, the anion glaze layer surface and inorganic nano are made pottery
Ready-made mosaic coating after the contact of enamel coating surface, the thickness of the mosaic coating not 0.8-1um.
5. according to claim 1 a kind of except the antibacterial ceramic tile of formaldehyde, the thickness of the tile substrate layer is no more than 10mm.
6. it is according to claim 1 it is a kind of remove the antibacterial ceramic tile of formaldehyde, the inorganic nano ceramic layer with a thickness of 0.5-
3um。
7. it is according to claim 1 it is a kind of remove the antibacterial ceramic tile of formaldehyde, the anion glaze layer with a thickness of 1-5um.
8. according to claim 1 a kind of except the antibacterial ceramic tile of formaldehyde, the decorative layer includes following weight percent
Component: the water paint of formaldehyde catching agent 5-25%, surplus, the decorative layer with a thickness of 1-2um.
9. according to claim 1 a kind of except the antibacterial ceramic tile of formaldehyde, the thickness of the wearing layer is not more than 1um.
10. a kind of preparation method except the antibacterial ceramic tile of formaldehyde, which is characterized in that following making step:
Step 1: be ready to ceramic tile hair training, using sander by ceramic tile hair training surface be machined to it is smooth, as tile substrate layer.
Step 2: behind the face that inorganic nano ceramic layer coats have been polished to tile substrate layer, placing shady place and stand 10min.
Step 3: by the component of weight percent: feldspar 25-40%, rare earth 10-15%, calcium oxide 3-5%, anionic additive
15-20%, quartz 3-5%, diatomite 20-15%, surplus are that clay pours into grinder respectively, and grinder is with 800r/min's
Revolving speed grinds 60min, produces the negative ion powder that partial size is not more than 60um.
Step 4: negative ion powder being sprayed into ready-made anion glaze layer on inorganic nano ceramic layer using leaching glaze, is placed into dryer
Middle 5min is mounted to anion glaze layer in inorganic nano ceramic layer, ready-made mosaic coating.
Step 5: by deployed cosmetic layer in anion glaze layer.
Step 6: wearing layer is coated in decorative layer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811202812.9A CN109437976A (en) | 2018-10-16 | 2018-10-16 | One kind is except antibacterial ceramic tile of formaldehyde and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811202812.9A CN109437976A (en) | 2018-10-16 | 2018-10-16 | One kind is except antibacterial ceramic tile of formaldehyde and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109437976A true CN109437976A (en) | 2019-03-08 |
Family
ID=65545466
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811202812.9A Pending CN109437976A (en) | 2018-10-16 | 2018-10-16 | One kind is except antibacterial ceramic tile of formaldehyde and preparation method thereof |
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| CN (1) | CN109437976A (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN201321698Y (en) * | 2008-09-22 | 2009-10-07 | 信益陶瓷(中国)有限公司 | Anion tile |
| CN202071407U (en) * | 2011-05-31 | 2011-12-14 | 马强 | Device of using microcrystal nanometer ceramic |
| CN103408327A (en) * | 2013-08-08 | 2013-11-27 | 李涛 | Building decoration material and production method thereof |
| CN205777242U (en) * | 2016-05-19 | 2016-12-07 | 佛山市高明贝斯特陶瓷有限公司 | A kind of nano-negative ion Antimicrobial anti-soil tile |
| CN107288293A (en) * | 2017-06-21 | 2017-10-24 | 信益陶瓷(中国)有限公司 | A kind of negative ion health ceramic tile |
| CN107313569A (en) * | 2017-06-21 | 2017-11-03 | 信益陶瓷(中国)有限公司 | A kind of high abrasion Dali stone ceramic tile |
-
2018
- 2018-10-16 CN CN201811202812.9A patent/CN109437976A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN201321698Y (en) * | 2008-09-22 | 2009-10-07 | 信益陶瓷(中国)有限公司 | Anion tile |
| CN202071407U (en) * | 2011-05-31 | 2011-12-14 | 马强 | Device of using microcrystal nanometer ceramic |
| CN103408327A (en) * | 2013-08-08 | 2013-11-27 | 李涛 | Building decoration material and production method thereof |
| CN205777242U (en) * | 2016-05-19 | 2016-12-07 | 佛山市高明贝斯特陶瓷有限公司 | A kind of nano-negative ion Antimicrobial anti-soil tile |
| CN107288293A (en) * | 2017-06-21 | 2017-10-24 | 信益陶瓷(中国)有限公司 | A kind of negative ion health ceramic tile |
| CN107313569A (en) * | 2017-06-21 | 2017-11-03 | 信益陶瓷(中国)有限公司 | A kind of high abrasion Dali stone ceramic tile |
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| PB01 | Publication | ||
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190308 |
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| RJ01 | Rejection of invention patent application after publication |