CN109430260A - A kind of granula and preparation method thereof for agent for removing grass in paddy field - Google Patents

A kind of granula and preparation method thereof for agent for removing grass in paddy field Download PDF

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Publication number
CN109430260A
CN109430260A CN201811527268.5A CN201811527268A CN109430260A CN 109430260 A CN109430260 A CN 109430260A CN 201811527268 A CN201811527268 A CN 201811527268A CN 109430260 A CN109430260 A CN 109430260A
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China
Prior art keywords
paddy field
granula
agent
parts
removing grass
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CN201811527268.5A
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Chinese (zh)
Inventor
宋鹏
李刚
袁泮玖
祝志干
郭天娥
杨齐伟
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WEIFANG CYNDA CHEMICAL CO Ltd
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WEIFANG CYNDA CHEMICAL CO Ltd
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Priority to CN201811527268.5A priority Critical patent/CN109430260A/en
Publication of CN109430260A publication Critical patent/CN109430260A/en
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/12Powders or granules
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A01N37/22Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof the nitrogen atom being directly attached to an aromatic ring system, e.g. anilides
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N39/00Biocides, pest repellants or attractants, or plant growth regulators containing aryloxy- or arylthio-aliphatic or cycloaliphatic compounds, containing the group or, e.g. phenoxyethylamine, phenylthio-acetonitrile, phenoxyacetone
    • A01N39/02Aryloxy-carboxylic acids; Derivatives thereof
    • A01N39/04Aryloxy-acetic acids; Derivatives thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A01N41/10Sulfones; Sulfoxides
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/541,3-Diazines; Hydrogenated 1,3-diazines
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/86Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/36Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof

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  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Agronomy & Crop Science (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Toxicology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The granula and preparation method thereof that the invention discloses a kind of for agent for removing grass in paddy field, efficiently, low toxicity, environmental protection, it can directly be thrown into paddy field when in use, by itself superior diffusion, granula floatability influences smaller in the water surface, climate factor, and it can be spread rapidly under the action of itself auxiliary agent and water surface diffusant, it is uniformly distributed in paddy field, to play the role of weeding, is conducive to paddy field weed improvement.In addition, the present invention is high to the control efficiency of paddy field weed, can reduce dosage, improve the degree of safety to rice, control cost is saved, it is preparation method simple process, at low cost, it is convenient for industrialized production, is suitable for long-term preservation, and there is no dust drift in use process, it is time saving and energy saving to operator and neighbouring crop safety, it has broad application prospects.

Description

A kind of granula and preparation method thereof for agent for removing grass in paddy field
Technical field
The present invention relates to paddy field weed prevention and control fields, especially a kind of for the granula of agent for removing grass in paddy field and its preparation side Method.
Background technique
Usually there are many dosage forms, such as wettable powder, missible oil, aqua, water to dissipate for herbicide used in rice field at present Granula, suspending agent etc., however these dosage forms had using the shortcomings that difficult, the amount of labour is big, low efficiency.When application need mix soil, It mixes fertilizer to spread fertilizer over the fields or water spray is added to walk using and field, time-consuming, large labor intensity.And wettable powder is in application Dust drift is had, can user or environment be caused damages or be polluted.
In recent years, from the point of view of the burden increase of the aging of peasant, part-timeization and woman worker, need to save application agrochemicals The labour of product.It is therefore not necessary to the use of any mechanical and the reduction manpower without coming into paddy field applications of pesticide method be very Welcome.On the other hand, the concern influenced due to society on Pesticide environment is higher and higher, is sought after easily applying Pesticidal preparations are to reduce risk that pesticide is lost from Tanaka and reduce the harm to operator.
In this case, the exploitation of granule becomes to adapt to very much current situation at present, this is because its is advantageous Characteristic, it is convenient without going to the field such as to apply, time saving and energy saving ultrahigh in efficiency, without dust drift to operator and Environmental security, application When influenced the risk that smaller, pesticide is lost from spray by weather and reduced etc..Although effervescent tablet also has the advantages of Labor-saving, But the risks such as swollen bag, failure are generated because acid-base neutralization reaction occurs for its moisture-sensitive, thus application is extremely limited, and particle Agent does not have the risk of this respect.To sum up, granule combines the excellent dispersibility of missible oil, wettable powder storing conveniently and does outstanding Floating agent advantage easy to use, has the advantages that full field is spread automatically, significantly reduces labor intensity, and environmental pollution Small, formulation rate is easily mastered, and climate Effects of Factors is small, has apparent application value.
Summary of the invention
In view of this, the granula and preparation method thereof that the object of the present invention is to provide a kind of for agent for removing grass in paddy field, is made Granula it is high to the control efficiency of paddy field weed, dosage can be reduced, improve the degree of safety to rice, climate factor shadow Sound is smaller, and to operator and neighbouring crop safety.
To achieve the goals above, the invention provides the following technical scheme:
A kind of granula for agent for removing grass in paddy field, the raw material including following weight percent:
Preferably, the herbicide is selected from pyrazosulfuron, bensulfuron-methyl, KIH 6127, oxaziclomefone, 2,4- Embutox, different Dislike careless pine, pretilachlor, butachlor, mesotrione, benzobicylon, oxadiazon, oxadiargyl, cyhalofop-butyl, penoxsulam One of amine, piperazine pyrazosulfuron, dichloro quinolinic acid, fenoxapropPethyl are a variety of.
Preferably, the surfactant is selected from fatty acid salt, alkyl sulfate, alkylbenzene sulfonate, alkyl naphthalene sulfonic acid Salt, dialkyl sulfosuccinates, fatty acid amide sulfonate, lignosulfonates, naphthalenesulfonate formaldehyde condensation compound, polycarboxylic acids Salt, alkyl phosphate, alkyl ether phosphate, phenethyl phenol polyethenoxy ether phosphate, phenethyl phenol polyethenoxy ether sulfate, Octyl sodium naphthalene sulfonate, alkyl phenol polyoxyethylene ether, castor oil polyoxyethylene ether, polyoxyethylene carboxylate, fatty amine polyoxy second Alkene ether, alkylaryl sulfonates, polyoxyethylene polyoxypropylene block copolymer, fatty alcohol polyoxyethylene ether, lauroyl propyl Glycine betaine, fatty acid glyceride, sorbitan fatty acid esters, one in sorbitan fatty acid esters polyoxyethylene ether Kind is a variety of.
Preferably, the floatability carrier is selected from float stone, calcining float stone, calcined pozzolans, calcining obsidian, calcining leech Stone, expansion zeolite, expansion sepiolite, diatomite, vitreous floating bead, polymeric foam, cork, sawdust, crushes jade at expanded perlite One of meter Xin or a variety of.
Preferably, the partial size of the floatability carrier is 1~000 μm.
Preferably, the water surface diffusant is selected from atoleine, soybean oil, palm oil, turpentine oil, glyceride, first Base vegetable oil, bobbin oil, mineral oil, alkyl ether nonionic, fatty acid ester nonionic, alkynol or acetylenic glycols nonionic, One of siloxanes and fluorine system surfactant are a variety of.
Preferably, the filler is selected from kaolin, diatomite, white carbon black, attapulgite, clay, bentonite, corn and forms sediment Powder, cyclodextrin, lactose, urea, sodium sulphate, ammonium sulfate, sodium chloride, calcium chloride, potassium chloride, sodium carboxymethylcellulose, hydroxypropyl Methylcellulose, hydroxyethyl cellulose, polyvinyl alcohol, Sodium Polyacrylate, xanthan gum, gelatin, citric acid, tartaric acid, sodium carbonate, One of sodium bicarbonate, sodium tripolyphosphate, calgon are a variety of.
The present invention also provides a kind of above-mentioned preparation methods of the granula for agent for removing grass in paddy field, comprising the following steps:
Herbicide, surfactant and filler are uniformly mixed, obtain being granulated after airslide disintegrating mill pulverizes female Powder;Female powder and floatability carrier, water surface diffusant will be granulated after mixing, and put into kneader plus water is mediated, then be transferred to and make Grain equipment in be granulated, most afterwards through drying, screening, detection, pack up to be used for agent for removing grass in paddy field granule.
The granula and preparation method thereof that the invention discloses a kind of for agent for removing grass in paddy field, efficient, low toxicity, environmental protection, makes Used time can directly be thrown into paddy field, and by itself superior diffusion, granula floatability is in the water surface, climate factor shadow Sound is smaller, and can spread rapidly under the action of itself auxiliary agent and water surface diffusant, is uniformly distributed in paddy field, thus Play the role of weeding, is conducive to paddy field weed improvement.In addition, the present invention is high to the control efficiency of paddy field weed, it can Dosage is reduced, is improved to the degree of safety of rice, has saved control cost, it is preparation method simple process, at low cost, convenient for industry Metaplasia produces, and is suitable for long-term preservation, and do not have dust drift in use process, time saving and energy saving to operator and neighbouring crop safety, It has broad application prospects.
Specific embodiment
In order to further illustrate the present invention, below with reference to embodiment to provided by the invention a kind of for agent for removing grass in paddy field Granula and preparation method thereof is described in detail, but they cannot be interpreted as limiting the scope of the present invention.
Embodiment 1
By 3 parts of pyrazosulfurons, 4 parts of naphthalenesulfonic acid-formaldehyde condensates, 1 part of lauryl sodium sulfate, 3 parts of white carbon blacks, 1 part of carboxylic Sodium carboxymethylcellulose pyce, 10 parts of sodium sulphate, 38 parts of kaolin are uniformly mixed, and obtain female powder after airslide disintegrating mill pulverizes.It will Female powder is uniformly mixed in kneader with 35 parts of vitreous floating beads, 5 parts of bobbin oil, and a small amount of water is added and is mediated, then is transferred to extruding It is granulated in Granulation Equipments, obtains cylindrical particle, by particle drying, screening, detection, obtain the big granula of 3% pyrazosulfuron.
Embodiment 2
By 2 parts of KIH 6127s, 4 parts of sodium lignin sulfonates, 2 parts of neopelexes, 5 parts of white carbon blacks, 2 parts of bentonites, 8 Part urea, 27 parts of diatomite are uniformly mixed, and obtain female powder after airslide disintegrating mill pulverizes.By female powder and 40 parts of calcining leech Stone, 10 parts of atoleines are uniformly mixed in kneader, and a small amount of water is added and is mediated, then is transferred in extruding granulation equipment and carries out It is granulated, obtains cylindrical particle, by particle drying, screening, detection, obtain 2% KIH 6127 granule.
Embodiment 3
By 3 parts of oxaziclomefones, 3 parts of sodium polycarboxylates, 3 parts of dialkyl sodium sulfosuccinates, 4 parts of white carbon blacks, 1 part of hydroxypropyl first Base cellulose, 10 parts of sodium chloride, 23 parts of cornstarch are uniformly mixed, and obtain female powder after airslide disintegrating mill pulverizes.It will be female Powder is uniformly mixed in kneader with 45 parts of expanded perlites, 8 parts of alkyl ether nonionics, and a small amount of water is added and is mediated, then turns Enter in extruding granulation equipment and be granulated, obtain cylindrical particle, by particle drying, screening, detection, obtains 3% oxaziclomefone Granula.
Embodiment 4
By 2 parts of oxaziclomefones, 6 parts of mesotriones, 4 parts of naphthalenesulfonic acid-formaldehyde condensates, 2 parts of Negels, 7 parts it is white Carbon black, 1 part of hydroxyethyl cellulose, 12 parts of ammonium sulfate, 23 parts of kaolin are uniformly mixed, and are obtained after airslide disintegrating mill pulverizes Female powder.Female powder is uniformly mixed in kneader with 40 parts of vitreous floating beads, 3 parts of decynediol nonionics, a small amount of water is added and carries out It mediates, then is transferred in extruding granulation equipment and is granulated, obtain cylindrical particle, by particle drying, screening, detection, obtain 8% evil The big granula of metribuzin mesotrione.
Embodiment 5
By 15 parts of pretilachlors, 2 parts of pyrazosulfurons, 6 parts of sodium lignin sulfonates, 3 parts of dialkyl sulfosuccinates, 2 parts of benzene Ethyl phenol polyethenoxy ether, 12 parts of white carbon blacks, 1 part of sodium carboxymethylcellulose, 6 parts of sodium sulphate are uniformly mixed, through airslide disintegrating mill Female powder is obtained after ultramicro grinding.Female powder is uniformly mixed in kneader with 38 parts of vitreous floating beads, 15 parts of atoleines, is added few Amount water is mediated, then is transferred in extruding granulation equipment and is granulated, and cylindrical particle is obtained, and by particle drying, screening, is detected, Obtain 17% pretilachlor pyrazosulfuron granule.
Embodiment 6
By 2 parts of oxaziclomefones, 2 parts of pyrazosulfurons, 4 parts of phenethyl phenol polyethenoxy ether sodium sulphate, 2 parts of detergent alkylate sulphurs Sour sodium, 8 parts of white carbon blacks, 8 parts of ammonium sulfate, 17 parts of attapulgites are uniformly mixed, and obtain female powder after airslide disintegrating mill pulverizes. Female powder is uniformly mixed in kneader with 50 parts of corks, 7 parts of glyceride, a small amount of water is added and is mediated, then is transferred to extruding and makes It is granulated in grain equipment, obtains cylindrical particle, by particle drying, screening, detection, obtain 4%, oxaziclomefone pyrazosulfuron Big granula.
Embodiment 7
By 2 parts of KIH 6127s, 2 parts of pyrazosulfurons, 3 parts of sodium alklyarylsulfonates, 2 parts of sodium butylnaphthalenesulfonates, 3 parts of white carbon blacks, 2 Part cyclodextrin, 6 parts of lactose, 25 parts of kaolin are uniformly mixed, and obtain female powder after airslide disintegrating mill pulverizes.By female powder and 45 Part calcining obsidian, 10 parts of atoleines are uniformly mixed in kneader, and a small amount of water is added and is mediated, then is transferred to extrusion granulation It is granulated in equipment, obtains cylindrical particle, by particle drying, screening, detection, obtain 4% KIH 6127 pyrazosulfuron particle Agent.
Embodiment 8
By 5 parts of 2,4- Embutoxs, 4 parts of calcium lignosulfonates, 2 parts of Negels, 5 parts of white carbon blacks, 5 parts of tripolyphosphates Sodium, 2 parts of polyvinyl alcohol, 31 parts of diatomite are uniformly mixed, and obtain female powder after airslide disintegrating mill pulverizes.By female powder and 40 parts Vitreous floating bead, 6 parts of dimethyl polysiloxane nonionics are uniformly mixed in kneader, and a small amount of water is added and is mediated, then is transferred to It is granulated in extruding granulation equipment, obtains cylindrical particle, by particle drying, screening, detection, it is big to obtain 5%2,4- Embutox Granula.
For made from the embodiment 3 3% KIH 6127 granule, by the granule be applied to transplanting rice field carry out it is miscellaneous Careless efficiency test.
Application method: after the rice transplanting of transplanting rice field is turned green, in 1 leaf of barnyard grass to 1 heart stage of 2 leaf, by water made from embodiment 3 Field herbicide granule is uniformly thrown and is applied in paddy field, throws apply at 20~30 per acre.Water layer keeps 5~7cm when application, is retained after application 7d.Using 10% KIH 6127 wettable powder as comparison medicament.
Investigation method: the herbicidal effect of granule made from 15 days investigation the present embodiment 3 and the safety to rice after application Property, fresh weight preventive effect calculation formula are as follows:
Fresh weight preventive effect (%)=[(control weeds overground part fresh weight-processing weeds overground part fresh weight)/control weeds overground part Fresh weight] × 100
1 experimental result of table
Above description can be realized professional and technical personnel in the field or using this to stating in the disclosed embodiments It is bright, it enables those skilled in the art to implement or use the present invention.Various modifications to these embodiments are to this field It will be apparent for professional technician, the general principles defined herein can not depart from spirit of the invention Or in the case where range, realize in other embodiments.Therefore, the present invention is not intended to be limited to these implementations shown in this article Example, and it is to fit to the widest scope consistent with principles disclosed herein and novel features.

Claims (9)

1. a kind of granula for agent for removing grass in paddy field, which is characterized in that the raw material including following weight percent:
2. being used for the granula of agent for removing grass in paddy field as described in claim 1, which is characterized in that the herbicide is selected from the phonetic sulphur of pyrrole Grand, bensulfuron-methyl, KIH 6127, oxaziclomefone, 2,4- Embutox, clomazone, pretilachlor, butachlor, mesotrione, bicyclic sulphur Humulone, oxadiazon, oxadiargyl, cyhalofop-butyl, penoxsuam, piperazine pyrazosulfuron, dichloro quinolinic acid, fenoxapropPethyl One of or it is a variety of.
3. being used for the granula of agent for removing grass in paddy field as described in claim 1, which is characterized in that the surfactant is selected from fat Hydrochlorate, alkyl sulfate, alkylbenzene sulfonate, alkylnaphthalene sulfonate, dialkyl sulfosuccinates, fatty acid amide sulfonate, Lignosulfonates, naphthalenesulfonate formaldehyde condensation compound, polycarboxylate, alkyl phosphate, alkyl ether phosphate, phenethyl phenol polyoxy Ethylene ether phosphate, phenethyl phenol polyethenoxy ether sulfate, octyl sodium naphthalene sulfonate, alkyl phenol polyoxyethylene ether, castor oil are poly- Ethylene oxide ether, polyoxyethylene carboxylate, aliphatic amine polyoxyethylene ether, alkylaryl sulfonates, polyoxyethylene polyoxypropylene are embedding Section copolymer, fatty alcohol polyoxyethylene ether, lauroyl propyl betaine, fatty acid glyceride, sorbitan-fatty acid One of ester, sorbitan fatty acid esters polyoxyethylene ether are a variety of.
4. being used for the granula of agent for removing grass in paddy field as described in claim 1, which is characterized in that the floatability carrier is selected from floating Stone, calcining float stone, calcined pozzolans, calcining obsidian, calcining vermiculite, expanded perlite, expansion zeolite, expansion sepiolite, silicon One of diatomaceous earth, vitreous floating bead, polymeric foam, cork, sawdust, crushing maize core are a variety of.
5. being used for the granula of agent for removing grass in paddy field as described in claim 1, which is characterized in that the partial size of the floatability carrier is 1~000 μm.
6. being used for the granula of agent for removing grass in paddy field as described in claim 1, which is characterized in that the water surface diffusant is selected from Atoleine, soybean oil, palm oil, turpentine oil, glyceride, methylated vegetable oils, bobbin oil, mineral oil, alkyl ether it is non-from One of son, fatty acid ester nonionic, alkynol nonionic, siloxanes and fluorine system surfactant are a variety of.
7. being used for the granula of agent for removing grass in paddy field as described in claim 1, which is characterized in that the filler is selected from kaolin, silicon Diatomaceous earth, white carbon black, attapulgite, clay, bentonite, cornstarch, cyclodextrin, lactose, urea, sodium sulphate, ammonium sulfate, chlorination Sodium, calcium chloride, potassium chloride, sodium carboxymethylcellulose, hydroxypropyl methyl cellulose, hydroxyethyl cellulose, polyvinyl alcohol, polypropylene One of sour sodium, xanthan gum, gelatin, citric acid, tartaric acid, sodium carbonate, sodium bicarbonate, sodium tripolyphosphate, calgon Or it is a variety of.
8. being used for the granula of agent for removing grass in paddy field as described in claim 1, which is characterized in that the granula is granule or big grain Agent.
9. a kind of preparation method of the granula as described in any one of claims 1 to 8 for agent for removing grass in paddy field, feature exist In, comprising the following steps:
Herbicide, surfactant and filler are uniformly mixed, obtain being granulated female powder after airslide disintegrating mill pulverizes;It will It is granulated female powder and floatability carrier, water surface diffusant after mixing, puts into kneader plus water is mediated, then be transferred to Granulation Equipments In be granulated, most afterwards through drying, screening, detection, pack up to be used for agent for removing grass in paddy field granula.
CN201811527268.5A 2018-12-13 2018-12-13 A kind of granula and preparation method thereof for agent for removing grass in paddy field Withdrawn CN109430260A (en)

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CN110692630A (en) * 2019-09-23 2020-01-17 南京高正农用化工有限公司 Floating carrier for floating large granules and preparation method thereof
CN112715315A (en) * 2020-12-08 2021-04-30 广西环保产业发展研究院有限公司 Organic vegetable seedling and cultivation medium and preparation method thereof
CN112772647A (en) * 2021-01-26 2021-05-11 江苏润丰致远作物科技有限公司 Production formula of butachlor and 2, 4-D isooctyl ester herbicide composition

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CN103688971A (en) * 2013-12-20 2014-04-02 南京高正农用化工有限公司 Weeding macro granule for paddy field and preparation method thereof
CA2974355A1 (en) * 2015-01-20 2016-07-28 Everris International B.V. Synergistic granular herbicidal compositions
CN108432750A (en) * 2018-03-14 2018-08-24 安徽丰乐农化有限责任公司 A kind of big granula of rice terrace weeding and preparation method thereof

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Publication number Priority date Publication date Assignee Title
CN103688971A (en) * 2013-12-20 2014-04-02 南京高正农用化工有限公司 Weeding macro granule for paddy field and preparation method thereof
CA2974355A1 (en) * 2015-01-20 2016-07-28 Everris International B.V. Synergistic granular herbicidal compositions
CN108432750A (en) * 2018-03-14 2018-08-24 安徽丰乐农化有限责任公司 A kind of big granula of rice terrace weeding and preparation method thereof

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CN112715315A (en) * 2020-12-08 2021-04-30 广西环保产业发展研究院有限公司 Organic vegetable seedling and cultivation medium and preparation method thereof
CN112715315B (en) * 2020-12-08 2023-12-12 广西环保产业发展研究院有限公司 Organic vegetable seedling raising and cultivating substrate and preparation method thereof
CN112772647A (en) * 2021-01-26 2021-05-11 江苏润丰致远作物科技有限公司 Production formula of butachlor and 2, 4-D isooctyl ester herbicide composition

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Application publication date: 20190308