CN109404940A - A kind of catalyst converter of quick start organic exhaust gas degradation - Google Patents

A kind of catalyst converter of quick start organic exhaust gas degradation Download PDF

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Publication number
CN109404940A
CN109404940A CN201811222432.1A CN201811222432A CN109404940A CN 109404940 A CN109404940 A CN 109404940A CN 201811222432 A CN201811222432 A CN 201811222432A CN 109404940 A CN109404940 A CN 109404940A
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CN
China
Prior art keywords
heating wire
channel
carrier
catalyst
exhaust gas
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811222432.1A
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Chinese (zh)
Inventor
卢晗锋
汪月
王宁
周瑛
刘硕
朱秋莲
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hangzhou Runxin Technology Co ltd
Zhejiang University of Technology ZJUT
Original Assignee
Hangzhou Runxin Technology Co ltd
Zhejiang University of Technology ZJUT
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hangzhou Runxin Technology Co ltd, Zhejiang University of Technology ZJUT filed Critical Hangzhou Runxin Technology Co ltd
Priority to CN201811222432.1A priority Critical patent/CN109404940A/en
Publication of CN109404940A publication Critical patent/CN109404940A/en
Pending legal-status Critical Current

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G7/00Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
    • F23G7/06Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases
    • F23G7/07Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases in which combustion takes place in the presence of catalytic material
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/08Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating
    • F23G5/10Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating electric
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/44Details; Accessories

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Catalysts (AREA)

Abstract

A kind of catalyst converter of quick start organic exhaust gas degradation, the bed includes carrier, several channels is equipped at intervals on the carrier, and the channel is penetrated through along the short transverse of the carrier;The bed further includes the heating wire with catalysis, and the heating wire sequentially passes through each channel with each channel of connecting;And it is located at the heating wire in channel along the short transverse spiral in the channel into spring like;The both ends of the heating wire are respectively positioned on outside the carrier, and the both ends of the heating wire are connected with the positive and negative anodes of power supply respectively, and to form series circuit, and the series circuit is equipped with switch.The present invention combines heating wire catalyst with honeycomb catalyst, by on heating wire making alive make heating wire heating power and pass to entire bed, the process for reducing air blast circulation with air transmitted to preheat, with this reach reduce catalytic bed from room temperature be heated to catalytic temperature needed for the time.

Description

A kind of catalyst converter of quick start organic exhaust gas degradation
Technical field
The invention belongs to environment protection catalytic fields, and in particular to a kind of catalyst converter of quick start organic exhaust gas degradation.
Background technique
Volatile organic waste gas (VOCs) is one of the main arch-criminal that atmosphere pollution is got worse, mainly by petroleum The production discharge of the chemical industries such as work, pharmacy, spray painting, coating generates, and a large amount of discharges of VOCs are strong to ecological environment and people's life The serious harm that health causes is the target of current environmental protection industry (epi) solution in need of immediate treatment.Catalytic combustion technology is purified treatment One of high-efficiency environment friendly method of VOCs, organic exhaust gas by be catalyzed burning can thoroughly destroy generate non-hazardous carbon dioxide and Water, but catalytic combustion process needs to consume the mass energy for maintaining catalysis reaction required temperature, and goes into operation the stage in technique The warm-up phase for making catalytic bed reach required temperature needs to consume a large amount of time, is not able to satisfy discontinuous job factory discharge The complicated conditions of discharge in source, the important limiting factor that the two factors become catalytic combustion technology application and promote.
Currently, the improvement project in industry is mainly the catalyst of research more efficient stable to reduce the item of process operation Part, the technical solution as disclosed in Chinese patent CN200810062849.6, CN201310181538.2, CN201410089699.3 Using cordierite as matrix, and after the coatings such as surface coating A12O3, CeY, CuCeY and La-Al-Si, in coating surface electrostatic Precious metals pt or Pd are adsorbed, the integral honeycomb ceramic catalyst of high activity is prepared, significantly reduces the temperature of catalysis reaction Degree.Chinese patent CN201410730988.7 has studied the Metal Substrate integral honeycomb catalyst of carried noble metal, passes through carrier material The change of material improves the mechanical performance and heat transfer efficiency of catalytic bed.
Although the mode of these linguistic terms reduce energy consumption, mention high activity and stability in terms of make moderate progress, its The problems such as catalytic combustion process runs warm-up phase overlong time, and reaction starting rate is slow aspect is solved without essence.
Summary of the invention
It is slow to solve existing catalytic combustion technology catalytic combustion process operation warm-up phase overlong time, reaction starting rate The shortcomings that, the present invention provides a kind of catalyst converter of quick start organic exhaust gas degradation.The present invention passes through in catalytic combustion device Portion carries out local flow improvement to promote catalysis burning working efficiency, reaches the different industrial discharge conditions that can be applicable in, and start faster, Plug and play.
The technical solution adopted by the present invention is that:
The embodiment of the present application provides a kind of catalyst converter of quick start organic exhaust gas degradation, and the bed includes carrier, institute It states and is equipped at intervals with several channels on carrier, and the channel is penetrated through along the short transverse of the carrier;
The bed further includes heating wire, and the heating wire sequentially passes through each channel with each channel of connecting;And position In the heating wire in channel along the short transverse spiral in the channel at spring like;
The both ends of the heating wire are respectively positioned on outside the carrier, and the both ends of the heating wire respectively with the positive and negative anodes of power supply It is connected, to form series circuit, and the series circuit is equipped with switch.
Further, the channel is arranged in arrays on the carrier.
Further, the heating wire is nichrome, Aludirome or chromium aluminium molybdenum alloys
Further, the carrier is cordierite honeycomb ceramic, mullite ceramic honey comb or cellular alumina ceramics.
Further, the carrier in a rectangular parallelepiped shape, square or cylindrical shape.
Further, the channel is square hole, i.e., the cross-sectional shape in the described channel is square, and the square Side length is 1~10mm.
Further, the channel is circular hole, i.e., the cross-sectional shape in the described channel is round, and the circular diameter For 1~10mm.
Further, the first catalyst coat is coated on the heating wire, and first catalyst coat load has First active component;First catalyst coat be Al2O3, first active component be Pt, Pd, Ag, Au, Cu, Mn, The combination of one or more of Ce, Ti, and load capacity of first active component on first catalyst coat is 0.1wt%~1wt%.
Further, the second catalyst coat, and second catalyst coat are coated on the outer surface of the carrier Load has the second active component;Second catalyst coat be Al, Ti, Si, Ni, Co, Mn, Cr, Ce, La, Zn, Cu, Ba, The combination of one or more of Mg, Zr, Y, second active component are one in Pt, Pd, Ag, Au, Cu, Mn, Ce, Ti Kind or several combinations, and load capacity of second active component on second catalyst coat be 0.1wt%~ 1wt%.
The embodiment of the present application provides a kind of catalyst converter bed of more scientific and reasonable quick start organic exhaust gas degradation, will Heating wire and honeycomb catalyst, which are combined, constitutes an entirety as catalytic bed, which is used for catalyst converter.It is logical It crosses on heating wire plus certain voltage makes heating wire heating power and passes to entire bed, pass through direct electro heating and thermo-contact The process that the mode of conduction reduces air blast circulation with air transmitted to preheat is reached with this and reduces catalytic bed from room temperature heating Time needed for catalytic temperature makes whole device technique start more quick purpose.
The beneficial effects of the present invention are embodied in:
(1) present invention can be used for the various volatile organic compounds of purified treatment comprising benzene,toluene,xylene, just oneself Alkane, hexamethylene, ethyl acetate, acetaldehyde, acetone, pyridine, DMF etc. a kind of or arbitrarily a variety of mixture.
(2) working method of the invention is simple and convenient, will be on the positive and negative anodes of two end Jie D.C. regulated power supplies of heating wire Or on the firewire and zero curve of alternating current transformer, the voltage control of electric current or alternating current transformer by adjusting D.C. regulated power supply The power loaded on catalyst processed, all self-heating obtains heat needed for catalysis reaction from catalyst, does not need additional Add heat generating device.
(3) present invention convenience flexible in application, processing waste gas reaction is rapid, that is, opens and close, discontinuous especially suitable for exhaust gas Formula discharge, exhaust gas component is complicated, the biggish operating condition of fluctuation of concentration.
Detailed description of the invention
Fig. 1 is overall structure diagram of the invention in an embodiment;
Fig. 2 is cross-sectional view of the invention in an embodiment.
Specific embodiment
It is clearly and completely described below in conjunction with technical solution of the attached drawing to the invention patent, it is clear that described Embodiment is a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common Technical staff's every other embodiment obtained without making creative work belongs to the model that the present invention protects It encloses.
In the description of the present invention, it should be noted that such as occur term " center ", "upper", "lower", "left", "right", The orientation or positional relationship of the instructions such as "vertical", "horizontal", "inner", "outside" is to be based on the orientation or positional relationship shown in the drawings, Be merely for convenience of description of the present invention and simplification of the description, rather than the device or element of indication or suggestion meaning must have it is specific Orientation, be constructed and operated in a specific orientation, therefore be not considered as limiting the invention.In addition, such as there is term " One ", " second ", " third " are used for descriptive purposes only and cannot be understood as indicating or suggesting relative importance.
In the description of the present invention, it should be noted that unless otherwise clearly defined and limited, term " peace such as occur Dress ", " connected ", " connection " shall be understood in a broad sense, for example, it may be being fixedly connected, may be a detachable connection, or integrally Connection;It can be mechanical connection, be also possible to be electrically connected;Can be directly connected, can also indirectly connected through an intermediary, It can be the connection inside two elements.For the ordinary skill in the art, above-mentioned art can be understood with concrete condition The concrete meaning of language in the present invention.
Referring to attached drawing, the present embodiment provides a kind of catalyst converter of quick start organic exhaust gas degradation, the bed includes carrying Body 2 is equipped at intervals with several channels 3 on the carrier 2, and short transverse of the channel 3 along the carrier 2 is (i.e. in Fig. 1 Z-axis direction, and x-axis direction be carrier 2 length direction, y-axis direction be carrier 2 width direction) perforation;
The bed further includes heating wire 1, and the heating wire 1 sequentially passes through each channel 3 with each channel 3 of connecting; And it is located at the heating wire 1 in channel 3 along the short transverse spiral in the channel into spring like;
The both ends of the heating wire 1 are respectively positioned on outside the carrier 2, and the both ends of the heating wire 1 respectively with power supply just Cathode is connected, and to form series circuit, and the series circuit is equipped with switch.
Specifically, the voltage regulator for adjusting electric power output voltage is additionally provided on the series circuit, with control The heat generation rate of heating wire 1 processed.
It is penetrated specifically, heating wire 1 is turned to strip-spiral since the one end in some channel 3 on the carrier 2, and Be pierced by from the other end in the channel 3, then penetrated in adjacency channel 3 again, and so on, until heating wire 1 be inserted through it is all Channel 3, finally with connect external power supply series connection.
Further, the heating wire 1 is wire.
Further, the channel 3 is arranged in arrays on the carrier 2.
Specifically, channel 3 is spaced on the carrier 2 is arranged and is arranged in m row n column, and 3 spaced set of each channel is simultaneously It is mutually aligned.Further, the heating wire 2 is that nichrome, Aludirome or chromium aluminium molybdenum alloys etc. have certain structure The heater of intensity.
Specifically, the heating wire 2 preferably uses Aludirome;The diameter of the heating wire 2 is 0.1~5mm, and institute It states heating wire 2 and turns to the cylindrical spiral shape that diameter is 5mm.Further, the carrier 2 is cordierite honeycomb ceramic, not Come stone ceramic honey comb or cellular alumina ceramics.
Further, the carrier 2 in a rectangular parallelepiped shape, square or cylindrical shape.
Further, the channel 3 is square hole, i.e., the cross-sectional shape in the described channel 3 is square, and the square Side length be 1~10mm.
Further, the channel 3 is circular hole, i.e., the cross-sectional shape in the described channel 3 is circle, and described circular straight Diameter is 1~10mm.
Further, the first catalyst coat is coated on the heating wire 1, and first catalyst coat load has First active component;First catalyst coat be Al2O3 layers, and first active component be Pt, Pd, Ag, Au, The combination of one or more of Cu, Mn, Ce, Ti, and first active component is negative on first catalyst coat Carrying capacity is 0.1wt%~1wt%.
Specifically, the heating wire 1 can be used directly, it can also be prepared into chaff seeding agent use, if being prepared into Chaff seeding agent coats the first catalyst coat on the heating wire 1;First catalyst coat is by metal Silk (Al) is placed in tube furnace after soda acid washes pretreatment and is passed through oxygen high-temperature calcination generation, the ingredient of coating is prepared in situ It is Al2O3.
Further, the second catalyst coat, and second catalyst coat are coated on the outer surface of the carrier 2 Load has the second active component;Second catalyst coat be Al, Ti, Si, Ni, Co, Mn, Cr, Ce, La, Zn, Cu, Ba, The combination of one or more of Mg, Zr, Y, second active component are one in Pt, Pd, Ag, Au, Cu, Mn, Ce, Ti Kind or several combinations;And load capacity of second active component on second catalyst coat be 0.1wt%~ 1wt%.
Specifically, the present invention is used on catalyst converter.When work, before being passed through organic exhaust gas, turn on the switch, heating wire 1, which is powered, generates heat rapidly and heat is conducted to the carrier 2 that surrounding is surrounded, and carrier 2 absorbs heat and is rapidly reached catalytic temperature;At this time It is passed through exhaust gas again, by the second catalyst coat on the first catalyst coat and carrier 2 on heating wire 1, decomposition and inversion is Non-hazardous carbon dioxide and water.Catalyst heat supply is given in the energization of heating wire 1, and the time for making bed heat up is greatly decreased, to reach Rapidly to starting, that is, it opens and closes, the purpose of operation readiness.
Content described in this specification embodiment is only enumerating to the way of realization of inventive concept, protection of the invention Range is not construed as being only limitted to the concrete form of embodiment statement, and protection scope of the present invention is also and in those skilled in the art Member according to the present invention design it is conceivable that equivalent technologies mean.

Claims (9)

1. a kind of catalyst converter of quick start organic exhaust gas degradation, it is characterised in that: the bed includes carrier, on the carrier Several channels are equipped at intervals with, and the channel is penetrated through along the short transverse of the carrier;
The bed further includes heating wire, and the heating wire sequentially passes through each channel with each channel of connecting;And it is located at logical Heating wire in road is along the short transverse spiral in the channel at spring like;
The both ends of the heating wire are respectively positioned on outside the carrier, and the both ends of the heating wire respectively with the positive and negative anodes phase of power supply Even, to form series circuit, and the series circuit is equipped with switch.
2. a kind of catalyst converter of quick start organic exhaust gas degradation as described in claim 1, it is characterised in that: the channel exists It is arranged in arrays on the carrier.
3. a kind of catalyst converter of quick start organic exhaust gas degradation as described in claim 1, it is characterised in that: the heating wire It is nichrome, Aludirome or chromium aluminium molybdenum alloys.
4. a kind of catalyst converter of quick start organic exhaust gas degradation as described in claim 1, it is characterised in that: the carrier is Cordierite honeycomb ceramic, mullite ceramic honey comb or cellular alumina ceramics.
5. a kind of catalyst converter of quick start organic exhaust gas degradation as described in claim 1, it is characterised in that: the carrier is in Rectangular-shape, square or cylindrical shape.
6. a kind of catalyst converter of quick start organic exhaust gas degradation as described in claim 1, it is characterised in that: the channel is The cross-sectional shape of square hole, i.e., the described channel is square, and the side length of the square is 1~10mm.
7. a kind of catalyst converter of quick start organic exhaust gas degradation as described in claim 1, it is characterised in that: the channel is Circular hole, i.e., the cross-sectional shape in the described channel is circle, and the circular diameter is 1~10mm.
8. a kind of catalyst converter of quick start organic exhaust gas degradation as described in claim 1, it is characterised in that: the heating wire It is upper to be coated with the first catalyst coat, and first catalyst coat load has the first active component;First catalyst Coating is Al2O3, and first active component is the combination of one or more of Pt, Pd, Ag, Au, Cu, Mn, Ce, Ti, and Load capacity of first active component on first catalyst coat is 0.1wt%~1wt%.
9. a kind of catalyst converter of quick start organic exhaust gas degradation as described in claim 1, it is characterised in that: the carrier The second catalyst coat is coated on outer surface, and second catalyst coat load has the second active component;Described Two catalyst coats are the group of one or more of Al, Ti, Si, Ni, Co, Mn, Cr, Ce, La, Zn, Cu, Ba, Mg, Zr, Y It closes, second active component is the combination of one or more of Pt, Pd, Ag, Au, Cu, Mn, Ce, Ti, and described second Load capacity of the active component on second catalyst coat is 0.1wt%~1wt%.
CN201811222432.1A 2018-10-19 2018-10-19 A kind of catalyst converter of quick start organic exhaust gas degradation Pending CN109404940A (en)

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Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2217106Y (en) * 1994-01-08 1996-01-10 潘增合 Waste gas treatment apparatus for multi-function silencer
CN1554860A (en) * 2003-12-25 2004-12-15 上海交通大学 Wall flow exhaust particle filtering and electricalloy heating post-regeneration treating device for diesel engine
KR20070046437A (en) * 2005-10-31 2007-05-03 재단법인 포항산업과학연구원 Catalytic converter using electrothermal wire catalyst support
CN101276924A (en) * 2007-03-29 2008-10-01 三星Sdi株式会社 Reaction vessel and reaction device
CN203365192U (en) * 2013-07-09 2013-12-25 中国原子能科学研究院 Gas catalytic oxidation furnace for monitoring and sampling of <14>C of air
CN203783697U (en) * 2014-01-23 2014-08-20 南京劲鸿茂科技有限公司 Foam metal preheater for diesel engine
CN104990154A (en) * 2015-07-10 2015-10-21 深圳市海一电器有限公司 Air purification method and air purifier
CN104998542A (en) * 2015-08-10 2015-10-28 广东美的制冷设备有限公司 Electric heating device with catalytic coating and preparation method and application thereof
CN106640287A (en) * 2016-10-18 2017-05-10 南京依柯卡特排放技术股份有限公司 Electric heating carrier
CN108397782A (en) * 2018-03-02 2018-08-14 徐州燃烧控制研究院有限公司 A kind of volatile organic matter heatable catalytic combustion reactor and its method
CN209558373U (en) * 2018-10-19 2019-10-29 浙江工业大学 A kind of catalyst converter of quick start organic exhaust gas degradation

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2217106Y (en) * 1994-01-08 1996-01-10 潘增合 Waste gas treatment apparatus for multi-function silencer
CN1554860A (en) * 2003-12-25 2004-12-15 上海交通大学 Wall flow exhaust particle filtering and electricalloy heating post-regeneration treating device for diesel engine
KR20070046437A (en) * 2005-10-31 2007-05-03 재단법인 포항산업과학연구원 Catalytic converter using electrothermal wire catalyst support
CN101276924A (en) * 2007-03-29 2008-10-01 三星Sdi株式会社 Reaction vessel and reaction device
CN203365192U (en) * 2013-07-09 2013-12-25 中国原子能科学研究院 Gas catalytic oxidation furnace for monitoring and sampling of <14>C of air
CN203783697U (en) * 2014-01-23 2014-08-20 南京劲鸿茂科技有限公司 Foam metal preheater for diesel engine
CN104990154A (en) * 2015-07-10 2015-10-21 深圳市海一电器有限公司 Air purification method and air purifier
CN104998542A (en) * 2015-08-10 2015-10-28 广东美的制冷设备有限公司 Electric heating device with catalytic coating and preparation method and application thereof
CN106640287A (en) * 2016-10-18 2017-05-10 南京依柯卡特排放技术股份有限公司 Electric heating carrier
CN108397782A (en) * 2018-03-02 2018-08-14 徐州燃烧控制研究院有限公司 A kind of volatile organic matter heatable catalytic combustion reactor and its method
CN209558373U (en) * 2018-10-19 2019-10-29 浙江工业大学 A kind of catalyst converter of quick start organic exhaust gas degradation

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