CN109402597A - Vacuum coating system is directly electroplated in a kind of semidry method processing plastic cement - Google Patents

Vacuum coating system is directly electroplated in a kind of semidry method processing plastic cement Download PDF

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Publication number
CN109402597A
CN109402597A CN201811272348.0A CN201811272348A CN109402597A CN 109402597 A CN109402597 A CN 109402597A CN 201811272348 A CN201811272348 A CN 201811272348A CN 109402597 A CN109402597 A CN 109402597A
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China
Prior art keywords
vacuum
plastic cement
vacuum cavity
cavity
coating system
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Pending
Application number
CN201811272348.0A
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Chinese (zh)
Inventor
张绍璞
范刚
庞亮
杨继洪
黄兴盛
何志聪
蒋义锋
林志敏
胡征宇
侯章辉
黄贤明
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XIAMEN APISI INTELLIGENT MANUFACTURING SYSTEM Co.,Ltd.
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Runner Xiamen Corp
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Priority to CN201811272348.0A priority Critical patent/CN109402597A/en
Publication of CN109402597A publication Critical patent/CN109402597A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/56Apparatus specially adapted for continuous coating; Arrangements for maintaining the vacuum, e.g. vacuum locks
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/14Metallic material, boron or silicon
    • C23C14/20Metallic material, boron or silicon on organic substrates
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/34Sputtering

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physical Vapour Deposition (AREA)

Abstract

The invention discloses a kind of semidry method processing plastic cement, and vacuum coating system is directly electroplated, including feeding vacuum cavity, aura modified vacuum cavity, hard Cr coating bottoming vacuum cavity, Cr is to alloy layer plated film vacuum cavity, alloy layer plated film vacuum cavity and discharging cavity;The coating system can make film layer bulky grain diameter drop to 30 μm or less;Producing line beat is no more than 8min;It directly forms resistance to stress conductive layer in plastic rubber member surface, the pre-electroplating treatment process before sour copper to replace wet process plating, the film of preparation is semidry method processing mode, is a kind of plated film mode of environmental protection, to replace the heavily contaminateds medicaments such as Cr VI used in wet process plated film.

Description

Vacuum coating system is directly electroplated in a kind of semidry method processing plastic cement
Technical field
The present invention relates to coating technique fields, are specially related to a kind of semidry method processing plastic cement and Vacuum Deposition membrane system is directly electroplated System.
Background technique
Column target power output used in prior art plated film is low, and cooling effect is poor, film deposition low efficiency, and Cu sputters bulky grain Obviously, producing line productive temp is too long causes production efficiency low;Problem to be solved: using high-power shielding power supply, increases column Cu target is changed to alloys target by target volume and amount of cooling water, and reducing bulky grain influences, and film deposition efficiency is promoted, by productive temp 8min is fallen to from 45min.
Summary of the invention
In order to solve the above-mentioned technical problem, the purpose of the present invention is to provide a kind of semidry method processing plastic cement to be directly electroplated very Empty coating system.
The present invention is achieved through the following technical solutions: vacuum coating system, which is directly electroplated, in semidry method processing plastic cement has Continuous six cavitys, respectively 1- feeds vacuum cavity in sequence;2- aura modified vacuum cavity;3- hard Cr coating is beaten Bottom vacuum cavity;4-Cr is to alloy layer plated film vacuum cavity;5- alloy layer plated film vacuum cavity;6- discharging cavity;
Wherein charging vacuum cavity 1 reaches purer brightness by vacuumizing isolation atmosphere and aura modified vacuum cavity 2 Light gas component improves binding force and its uniformity;Aura modified vacuum cavity 2 passes through 2500V/50% high-frequency ac aura electricity Source oxygen build-up of luminance is realized that plastic rubber member surface is modified;Hard Cr coating bottoming vacuum cavity 3 uses 60KW, 40KHz mid frequency sputtering Power supply forms bottoming Cr layers in substrate surface and the Cr tunic thickness is made to be 0.1-0.2 μm;In Cr to alloy layer plated film vacuum chamber 30KW DC sputtering power is used in body 4, forms transition zone in Cr layer surface, the film thickness of the transition zone is 0.1-0.2 μm;Alloy Coating plated film vacuum cavity 5 uses 30KW DC sputtering power, forms pure alloy-layer in transition layer surface, the alloy layer thickness It is 0.1-0.2 μm;Discharging cavity 6, which is crossed, vacuumizes isolation atmosphere and alloy layer plated film vacuum cavity 5, reaches purer sputtering Gas component improves binding force and its uniformity.Product is 480s, total thicknesses of layers by the design section bat time of all cavitys It is 0.3-0.6 μm.
The invention has the following beneficial effects: film layer bulky grain diameters to drop to 30 μm or less;Producing line beat is no more than 8min;It directly forms resistance to stress conductive layer in plastic rubber member surface, before the plating before sour copper to replace wet process plating Process is managed, it is a kind of plated film mode of environmental protection that the film of preparation, which is semidry method processing mode, is used in wet process plated film to replace The heavily contaminateds medicament such as Cr VI.
Detailed description of the invention
It, below will be to required in embodiment or description of the prior art in order to illustrate more clearly of technical solution of the present invention The attached drawing used is briefly described, it should be apparent that, drawings in the following description are only some embodiments of the invention, right For those of ordinary skill in the art, without creative efforts, it can also be obtained according to these attached drawings Its attached drawing.
Fig. 1 is top view of the invention.
Fig. 2 is main view of the invention.
In figure: 1- feeds vacuum cavity;2- aura modified vacuum cavity;3- hard Cr coating bottoming vacuum cavity;4-Cr To alloy layer plated film vacuum cavity;5- alloy layer plated film vacuum cavity;6- discharging cavity;7- transmits rectangle gate valve;8- Manual operation door;9- observation window;10- equips support frame;11- heavy type lower margin;12- heavy type castor;Roughing pump in 13- dry type Unit;14- ultrahigh vacuum gate valve;15- high-vacuum molecular pump;16- low vacuum pump-line;17-KF25 interface;18-DN connects Mouthful;19- medium-high frequency high-voltage glow electrode;20- mid frequency sputtering device;21- throttle valve;22- intermediate frequency and d.c. sputtering transition apparatus; 23- DC sputtering device;24- pivoted frame transmission system.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, carries out to the technical solution in inventive embodiments clear, complete Ground description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based on this The embodiment of invention, those of ordinary skill in the art's every other reality obtained without making creative work Example is applied, shall fall within the protection scope of the present invention.
Vacuum coating system is directly electroplated with continuous six in reference book attached drawing 1-2, semidry method processing plastic cement Cavity, respectively 1- feeds vacuum cavity in sequence;2- aura modified vacuum cavity;3- hard Cr coating bottoming vacuum chamber Body;4-Cr is to alloy layer plated film vacuum cavity;5- alloy layer plated film vacuum cavity;6- discharging cavity;
Wherein charging vacuum cavity 1 reaches purer brightness by vacuumizing isolation atmosphere and aura modified vacuum cavity 2 Light gas component improves binding force and its uniformity;Aura modified vacuum cavity 2 passes through 2500V/50% high-frequency ac aura electricity Source oxygen build-up of luminance is realized that plastic rubber member surface is modified;Hard Cr coating bottoming vacuum cavity 3 uses 60KW, 40KHz mid frequency sputtering Power supply forms bottoming Cr layers in substrate surface and the Cr tunic thickness is made to be 0.1-0.2 μm;In Cr to alloy layer plated film vacuum chamber 30KW DC sputtering power is used in body 4, forms transition zone in Cr layer surface, the film thickness of the transition zone is 0.1-0.2 μm;Alloy Coating plated film vacuum cavity 5 uses 30KW DC sputtering power, forms pure alloy-layer in transition layer surface, the alloy layer thickness It is 0.1-0.2 μm;Discharging cavity 6, which is crossed, vacuumizes isolation atmosphere and alloy layer plated film vacuum cavity 5, reaches purer sputtering Gas component improves binding force and its uniformity.Workpiece is 480s, total thicknesses of layers by the design pitch time of all cavitys It is 0.3-0.6 μm.
Wherein feed the course of work of vacuum cavity 1 are as follows: step 1 is to be evacuated down to 5.0E-3Pa;Step 2 is to fill band mistake The atmosphere 150s of filter;
The course of work of aura modified vacuum cavity 2 are as follows: step 1 is to restore vacuum, air pressure 2.0E-3Pa, when process Between be 30s;Step 2 is aura preparation, and being filled with gas ratio is Ar:O2=1:3, pressure are 3~5Pa, process time 15s; Step 3 is modified for aura, and being filled with gas ratio is Ar:O2=1:3, pressure are 3~5Pa, 15s, auxiliary voltage 2500V/ 50%, process time 300s;Step 4 is ending protection, and being filled with gas ratio is Ar:O2=1:3, pressure are 3~5Pa, mistake The journey time is 10s;
3 course of work of hard Cr coating bottoming vacuum cavity are as follows: step 1 is to restore vacuum, air pressure 2.0E-3Pa, mistake The journey time is 30s;Step 2 is pre-aeration, adjusts Ar pressure to 3.5E-1~5.5E-1Pa, process time 15s;Step 3 To carry out Cr bottoming (thicknesses of layers >=100nm), Ar pressure is 3.5E-1~5.5E-1Pa, power 40KW, and frequency is 40KHz, process time 330s;Step 4 is ending protection, and Ar pressure is 3.5E-1~5.5E-1Pa;
Cr is to 4 course of work of alloy layer plated film vacuum cavity are as follows: step 1 restores vacuum, air pressure 2.0E-3Pa, mistake The journey time is 30s;Step 2 is pre-aeration, adjusts Ar pressure to 3.5E-1~5.5E-1Pa, process time 15s;Step 3 For alloy plating transition zone (thicknesses of layers >=100nm), Ar pressure is 3.5E-1~5.5E-1Pa, Cr: being first decremented to 40Kw 10Kw plates alloy: power is incremented to 30Kw, process time 330s by 10Kw;Step 4 is ending protection, and Ar pressure is 3.5E-1~5.5E-1Pa;
5 course of work of alloy layer plated film vacuum cavity is that step 1 restores vacuum, air pressure 2.0E-3Pa, process time For 30s;Step 2 is pre-aeration, adjusts Ar pressure to 3.5E-1~5.5E-1Pa, process time 15s;Step 3 is that plating is closed The pure layer (thicknesses of layers >=100nm) of gold, Ar pressure are 3.5E-1~5.5E-1Pa, power 30Kw, process time 330s; Step 4 is ending protection, and Ar pressure is 3.5E-1~5.5E-1Pa;
Discharging 6 course of work of cavity is that step 1 fills the atmosphere by filtering, process time 180s;Step 2 is taken out true Sky, air pressure 5.0E-3Pa.
Vacuum coating system is directly electroplated with pivoted frame transmission system (24) in the semidry method processing plastic cement, and the pivoted frame passes Dynamic system (24) have pivoted frame drive bearing, and the pivoted frame drive bearing uses magnet fluid sealing, so that leak rate is lower than 10E-8Pa Rank.
Vacuum coating system, which is directly electroplated, in the semidry method processing plastic cement also has travel switch, advances for detecting workpiece Position.
Directly vacuum coating system is electroplated also in the semidry method processing plastic cement, and there is high vacuum rectangle to transmit gate valve, energy Shorten the gap between pivoted frame while guaranteeing that leak rate is stablized.
The preferred embodiment of the present invention has shown and described in above description, as previously described, it should be understood that the present invention is not office Be limited to form disclosed herein, should not be regarded as an exclusion of other examples, and can be used for various other combinations, modification and Environment, and can be changed within that scope of the inventive concept describe herein by the above teachings or related fields of technology or knowledge It is dynamic.And changes and modifications made by those skilled in the art do not depart from the spirit and scope of the present invention, then it all should be appended by the present invention In scope of protection of the claims.

Claims (12)

1. vacuum coating system, including charging vacuum cavity (1), aura modified vacuum is directly electroplated in a kind of semidry method processing plastic cement Cavity (2), hard Cr coating bottoming vacuum cavity (3), for Cr to alloy layer plated film vacuum cavity (4), alloy layer plated film is true Cavity body (5) and discharging cavity (6);
It is characterized in that, by by the continuous connection vacuum cavity (1), aura modified vacuum cavity (2), hard Cr coating bottoming Vacuum cavity (3), Cr to alloy layer plated film vacuum cavity (4), alloy layer plated film vacuum cavity (5) and discharging cavity (6) It forms semidry method processing plastic cement and vacuum coating system is directly electroplated.
2. vacuum coating system is directly electroplated in semidry method according to claim 1 processing plastic cement, which is characterized in that it is described into Material vacuum cavity (1) reaches purer glow gases group by vacuumizing isolation atmosphere and aura modified vacuum cavity (2) Point, improve binding force and its uniformity;
The aura modified vacuum cavity (2), by oxygen build-up of luminance, realizes plastic cement by 2500V/50% high-frequency ac aura power supply Part surface is modified;
The hard Cr coating bottoming vacuum cavity (3) uses 60KW, 40KHz mid frequency sputtering power supply, beats in substrate surface formation Bottom Cr layers makes the Cr tunic thickness be 0.1-0.2 μm;
30KW DC sputtering power is used in the Cr to alloy layer plated film vacuum cavity (4), is formed in Cr layer surface Layer is crossed, the film thickness of the transition zone is 0.1-0.2 μm;
The alloy layer plated film vacuum cavity (5) uses 30KW DC sputtering power, forms pure alloy in transition layer surface Layer, the alloy layer thickness are 0.1-0.2 μm;
The discharging cavity (6), which is crossed, vacuumizes isolation atmosphere and the alloy layer plated film vacuum cavity (5), reaches purer Sputter gas component improves binding force and its uniformity.
3. vacuum coating system is directly electroplated in semidry method according to claim 1 processing plastic cement, which is characterized in that it is described into Expect the course of work of vacuum cavity (1) are as follows: step 1 is to be evacuated down to 5.0E-3Pa;Step 2 is to fill the atmosphere with filtering 150s。
4. vacuum coating system is directly electroplated in semidry method processing plastic cement according to claim 1, which is characterized in that the brightness The course of work of light modified vacuum cavity (2) are as follows: step 1 is to restore vacuum, air pressure 2.0E-3Pa, process time 30s; Step 2 is aura preparation, and being filled with gas ratio is Ar:O2=1:3, pressure are 3~5Pa, process time 15s;Step 3 is Aura is modified, and being filled with gas ratio is Ar:O2=1:3, pressure is 3~5Pa, 15s, auxiliary voltage 2500V/50%, when process Between be 300s;Step 4 is ending protection, and being filled with gas ratio is Ar:O2=1:3, pressure are 3~5Pa, and process time is 10s。
5. vacuum coating system is directly electroplated in semidry method processing plastic cement according to claim 1, which is characterized in that described hard Matter Cr coating bottoming vacuum cavity (3) course of work are as follows: step 1 is to restore vacuum, air pressure 2.0E-3Pa, and process time is 30s;Step 2 is pre-aeration, adjusts Ar pressure to 3.5E-1~5.5E-1Pa, process time 15s;Step 3 is to carry out Cr Bottoming, thicknesses of layers >=100nm, Ar pressure are 3.5E-1~5.5E-1Pa, power 40KW, frequency 40KHz, process time For 330s;Step 4 is ending protection, and Ar pressure is 3.5E-1~5.5E-1Pa.
6. vacuum coating system is directly electroplated in semidry method processing plastic cement according to claim 1, which is characterized in that the Cr To alloy layer plated film vacuum cavity (4) course of work are as follows: step 1 restores vacuum, air pressure 2.0E-3Pa, and process time is 30s;Step 2 is pre-aeration, adjusts Ar pressure to 3.5E-1~5.5E-1Pa, process time 15s;Step 3 is alloy plating Transition zone, thicknesses of layers >=100nm, Ar pressure are 3.5E-1~5.5E-1Pa, Cr: 40Kw being decremented to 10Kw first, is plated Alloy: power is incremented to 30Kw, process time 330s by 10Kw;Step 4 be ending protection, Ar pressure be 3.5E-1~ 5.5E-1Pa。
7. vacuum coating system is directly electroplated in semidry method processing plastic cement according to claim 1, which is characterized in that the conjunction 5 course of work of gold plate plated film vacuum cavity is that step 1 restores vacuum, air pressure 2.0E-3Pa, process time 30s;Step Two be pre-aeration, adjusts Ar pressure to 3.5E-1~5.5E-1Pa, process time 15s;Step 3 is the pure layer of alloy plating, film Thickness degree >=100nm, Ar pressure are 3.5E-1~5.5E-1Pa, power 30Kw, process time 330s;Step 4 is ending Protection, Ar pressure are 3.5E-1~5.5E-1Pa.
8. vacuum coating system is directly electroplated in semidry method processing plastic cement according to claim 1, which is characterized in that discharging chamber Body (6) course of work is that step 1 fills the atmosphere by filtering, process time 180s;Step 2 vacuumizes, air pressure 5.0E- 3Pa。
9. vacuum coating system is directly electroplated in semidry method processing plastic cement according to claim 1, which is characterized in that described half Vacuum coating system is directly electroplated with pivoted frame transmission system (24) in dry process plastic cement, and the pivoted frame transmission system (24) has Pivoted frame drive bearing, the pivoted frame drive bearing use magnet fluid sealing, so that leak rate is lower than 10E-8Pa rank.
10. vacuum coating system is directly electroplated in semidry method processing plastic cement according to claim 1, which is characterized in that described Vacuum coating system, which is directly electroplated, in semidry method processing plastic cement also has travel switch, for detecting workpiece advanced positions.
11. vacuum coating system is directly electroplated in semidry method processing plastic cement according to claim 1, it is characterised in that described half Directly vacuum coating system is electroplated also in dry process plastic cement, and there is high vacuum rectangle to transmit gate valve, can stablize guaranteeing leak rate While shorten pivoted frame between gap.
12. vacuum coating system is directly electroplated in semidry method processing plastic cement according to claim 1, it is characterised in that workpiece warp The design pitch time for crossing all cavitys is 480s, and total thicknesses of layers is 0.3-0.6 μm.
CN201811272348.0A 2018-10-30 2018-10-30 Vacuum coating system is directly electroplated in a kind of semidry method processing plastic cement Pending CN109402597A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110055501A (en) * 2019-04-17 2019-07-26 厦门阿匹斯智能制造系统有限公司 A kind of method of semidry method continuous type PVD plated film plastic metal temperature control

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CN101299910A (en) * 2007-04-04 2008-11-05 应用材料公司 Apparatus and method for coating of a plastic substrate
TW201104006A (en) * 2009-07-30 2011-02-01 Jin Xing Electrooptic Co Ltd Method for forming antifouling layer of workpiece utilizing continuous type vacuum sputtering equipment
CN102127764A (en) * 2011-01-28 2011-07-20 厦门建霖工业有限公司 Method for implementing semi-dry plating on surface of plastic substrate
US20120024695A1 (en) * 2011-03-14 2012-02-02 Primestar Solar, Inc. Systems and methods for high-rate deposition of thin film layers on photovoltaic module substrates
CN107338420A (en) * 2017-07-25 2017-11-10 北京实力源科技开发有限责任公司 A kind of vacuum coating method and equipment

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101299910A (en) * 2007-04-04 2008-11-05 应用材料公司 Apparatus and method for coating of a plastic substrate
TW201104006A (en) * 2009-07-30 2011-02-01 Jin Xing Electrooptic Co Ltd Method for forming antifouling layer of workpiece utilizing continuous type vacuum sputtering equipment
CN102127764A (en) * 2011-01-28 2011-07-20 厦门建霖工业有限公司 Method for implementing semi-dry plating on surface of plastic substrate
US20120024695A1 (en) * 2011-03-14 2012-02-02 Primestar Solar, Inc. Systems and methods for high-rate deposition of thin film layers on photovoltaic module substrates
CN107338420A (en) * 2017-07-25 2017-11-10 北京实力源科技开发有限责任公司 A kind of vacuum coating method and equipment

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110055501A (en) * 2019-04-17 2019-07-26 厦门阿匹斯智能制造系统有限公司 A kind of method of semidry method continuous type PVD plated film plastic metal temperature control

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Application publication date: 20190301