CN109401864A - A kind of outdoor wear washing-free agent - Google Patents

A kind of outdoor wear washing-free agent Download PDF

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Publication number
CN109401864A
CN109401864A CN201811499600.1A CN201811499600A CN109401864A CN 109401864 A CN109401864 A CN 109401864A CN 201811499600 A CN201811499600 A CN 201811499600A CN 109401864 A CN109401864 A CN 109401864A
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China
Prior art keywords
parts
weight
chitosan
water soluble
free agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811499600.1A
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Chinese (zh)
Inventor
刘战鹰
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Hefei Yingshibo Outdoor Technology Co Ltd
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Hefei Yingshibo Outdoor Technology Co Ltd
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Priority to CN201811499600.1A priority Critical patent/CN109401864A/en
Publication of CN109401864A publication Critical patent/CN109401864A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/40Products in which the composition is not well defined
    • C11D7/44Vegetable products
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/26Organic compounds containing oxygen
    • C11D7/261Alcohols; Phenols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/26Organic compounds containing oxygen
    • C11D7/265Carboxylic acids or salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/26Organic compounds containing oxygen
    • C11D7/266Esters or carbonates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/26Organic compounds containing oxygen
    • C11D7/268Carbohydrates or derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/28Organic compounds containing halogen
    • C11D7/30Halogenated hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/32Organic compounds containing nitrogen
    • C11D7/329Carbohydrate or derivatives thereof

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Molecular Biology (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Detergent Compositions (AREA)

Abstract

A kind of outdoor wear washing-free agent, is made of the raw material of following parts by weight: 1~3 part of water soluble chitosan, 1~2 part of chitin, 2~4 parts of butanediol, 0.8~1.2 part of carbomer, 0.6~1 part of Nanocrystalline Cellulose Colloid, 2~4 parts of fluorocarbons copolymer, 6~8 parts of fatty glyceride, 1~3 part of lemon, 120~150 parts of deionized water.The invention has the benefit that being rinsed after present invention exclusive use or use with a small amount of water, relatively it is suitble to use outdoors, convenience is brought to outdoor user, avoids directly cleaning bring inconvenience with clear water;The present invention does not have peculiar smell, harmless, while antibacterial effect is also played to clothing surface.

Description

A kind of outdoor wear washing-free agent
Technical field
The invention belongs to outdoor wear fields, and in particular to a kind of outdoor wear washing-free agent.
Background technique
Outdoor environment is complicated and changeable, to resist injury of the adverse circumstances to human body, protect body heat do not scattered and disappeared and Quickly generated sweat when discharge movement, in mountain-climbing, rock-climbing and other outdoor sports, it should accomplish to be layered dressing.
So-called layering dressing refers to the clothes that unlike material is worn in movement outdoors, is become with adapting to the various weather in field Changing influences on brought by human body, such as clothing of charging, fleece clothing, thermal-insulating garment, sun-proof clothing, rapid-curing cutback clothing etc..
Frequent activity outdoors will lead to clothing surface and the spots such as mud stain, grease stain, sweat stain occurs, if simple uses clear water If cleaning, cleaning effect is bad, while if cleaned with clear water, to will lead to cloth drying speed slow, influences to wear.
Summary of the invention
Technical problem to be solved by the present invention lies in: frequent activity outdoors will lead to clothing surface and mud stain, oil occurs The spots such as stain, sweat stain, if it is simple cleaned with clear water if, cleaning effect is bad, and is cleaned with clear water and will lead to clothing Slow drying speed influences to wear.For this purpose, providing a kind of outdoor wear washing-free agent.
In order to solve the above technical problems, the technical solution of the present invention is as follows:
A kind of outdoor wear washing-free agent, is made of the raw material of following parts by weight: 1~3 part of water soluble chitosan, chitin 1 ~2 parts, 2~4 parts of butanediol, 0.8~1.2 part of carbomer, 0.6~1 part of Nanocrystalline Cellulose Colloid, fluorocarbons copolymerization 2~4 parts of object, 6~8 parts of fatty glyceride, 1~3 part of lemon, 120~150 parts of deionized water.
Preferably, be made of the raw material of following parts by weight: 1 part of water soluble chitosan, 1 part of chitin, 2 parts of butanediol, 0.8 part of carbomer, 0.6 part of Nanocrystalline Cellulose Colloid, 2 parts of fluorocarbons copolymer, 6 parts of fatty glyceride, lemon 1 part of essential oil, 120 parts of deionized water.
Preferably, be made of the raw material of following parts by weight: 3 parts of water soluble chitosan, 2 parts of chitin, 4 parts of butanediol, 1.2 parts of carbomer, 1 part of Nanocrystalline Cellulose Colloid, 4 parts of fluorocarbons copolymer, 8 parts of fatty glyceride, lemon extract 3 parts, 150 parts of deionized water of oil.
Preferably, it is made of the raw material of following parts by weight: 2 parts of water soluble chitosan, 1.5 parts of chitin, butanediol 3 Part, 1.0 parts of carbomer, 0.8 part of Nanocrystalline Cellulose Colloid, 3 parts of fluorocarbons copolymer, 7 parts of fatty glyceride, lemon 2 parts of lemon essential oil, 135 parts of deionized water.
Preferably, the water soluble chitosan is water soluble chitosan hydrochloride, water soluble chitosan nitrate, water solubility Chitosan citrate is according to parts by weight than the mixture for 1:1:1.
Preferably, the deacetylation of the water soluble chitosan is 92%~94%.
Preferably, above-mentioned outdoor wear washing-free agent the preparation method comprises the following steps: (1) is fine by the nano microcrystallines of above-mentioned parts by weight It ties up plain colloid, fluorocarbons copolymer, fatty glyceride to be placed in 90~95 parts of deionized waters, ultrasound is sufficiently mixed, and is obtained Mixed liquor A;(2) deionized water that add weight number is 10~20 parts in the water soluble chitosan of Xiang Shangshu parts by weight, mixing It stirs and chitosan colloid is made;(3) butanediol of above-mentioned parts by weight is added in the chitosan colloid in step (2), is stirred, It stands, obtains chitosan-butanediol mixed liquor;(4) chitosan-butanediol mixed liquor is decolourized to colourless using filter It is bright, collect transparent mixed liquor;(5) lemon of remaining deionized water and above-mentioned parts by weight is added into above-mentioned transparent mixed liquor Essential oil, chitin are uniformly mixed to obtain mixed liquid B;(6) by the carbomer of above-mentioned parts by weight and above-mentioned mixed liquor A and mixed liquid B Mixing after being completely dissolved, stands to get the outdoor wear washing-free agent.
Chitosan is that the chitin (chitin) being widely present by nature is obtained by deacetylation, chemical name Referred to as Chitosan (1-4) -2- amino-B-D glucose.Chitosan can be used for textile finishing, health care underwear, paper making additive Deng.The film forming agent of fragrance, dyestuff and active agent capsules is also acted as, nucleic acid scavenger reduces gallbladder alcohol formulations, antibacterial agent, plant Seed coats bonding agent, and is used as synthesis in solid state and enzyme immobilization carrier.Chitosan is added in the present invention can be effective Increase the antibiotic property of fabric.
Chitin, chitin are of wide application general, can industrially make cloth, clothing, dyestuff, paper and water process Deng.Insecticide, plant antiviral agent can agriculturally done.It breeds fish in fishery feed.It is a kind of macromolecule polysaccharide of line style, I.e. natural neutral mucopolysacchauide removes acetyl group if handling through concentrated base up to chitosan.Torpescence on chitin chemistry, It does not change with body fluid, it is nontoxic to can not organizing foreign body reaction, have the characteristics that antithrombotic, high temperature-resistant disinfected.Chitin Water absorption rate is up to 1300%, and 1 gram of chitin can achieve 13 grams after being saturated with water, and chitin has effects that natural bacteriostatic, wide spectrum are anti- Bacterium rate is very high, and 90% or more common bacteria cannot survive on chitin fiber;Therefore chitin fiber and color cotton goods pure cotton Fabric made of equal fibers is particularly suitable for doing infant clothing and men and women's high-grade underwear.
Nano micro crystal cellulose is in club shaped structure, has good adsorption function, can be with fluorocarbons copolymer and rouge Fatty acid glyceride combines, and fluorocarbons copolymer has excellent waterproof and oilproof effect.
Carbomer, as acrylic resin, alias are emulsion acrylic resin.Acrylic resin color is shallow, water-white transparent.It applies Film properties are excellent, fast light, weatherability is good, heat-resisting, and resistance to paint baking over, chemical-resistant and the performances such as corrosion-resistant are all fabulous.
Lemon not only has good fungistatic effect, while assisting in removing the peculiar smell on clothing, and smelling makes one Body and mind is comfortable.
The invention has the benefit that the present invention is used alone or use is rinsed with a small amount of water later, it is relatively more suitable Conjunction uses outdoors, brings conveniently to outdoor user, avoids directly cleaning bring inconvenience with clear water;The present invention is not different Taste, it is harmless, while antibacterial effect is also played to clothing surface.
Specific embodiment
The effect of to make to structure feature of the invention and being reached, has a better understanding and awareness, to preferable Embodiment cooperation detailed description, is described as follows:
Embodiment 1
A kind of outdoor wear washing-free agent, is made of the raw material of following parts by weight: 1 part of water soluble chitosan, 1 part of chitin, 2 parts of butanediol, 0.8 part of carbomer, 0.6 part of Nanocrystalline Cellulose Colloid, 2 parts of fluorocarbons copolymer, fatty acid glycerine 6 parts of ester, 1 part of lemon, 120 parts of deionized water.
Wherein, the water soluble chitosan is water soluble chitosan hydrochloride, water soluble chitosan nitrate, water soluble shells For glycan citrate according to parts by weight than the mixture for 1:1:1, the deacetylation of the water soluble chitosan is 92%.
Above-mentioned outdoor wear washing-free agent the preparation method comprises the following steps: (1) by the nano micro crystal cellulose glue of above-mentioned parts by weight Body, fluorocarbons copolymer, fatty glyceride are placed in 90 parts of deionized waters, and ultrasound is sufficiently mixed, and obtains mixed liquor A;(2) The deionized water that add weight number is 10 parts into the water soluble chitosan of above-mentioned parts by weight is mixed and chitosan gum is made Body;(3) butanediol of above-mentioned parts by weight is added in the chitosan colloid in step (2), is stirred, stood, obtain chitosan- Butanediol mixed liquor;(4) chitosan-butanediol mixed liquor is decolourized to colorless and transparent using filter, collects transparent mixed liquor; (5) lemon, the chitin of remaining deionized water and above-mentioned parts by weight are added into above-mentioned transparent mixed liquor, mixing is equal It is even to obtain mixed liquid B;(6) carbomer of above-mentioned parts by weight and above-mentioned mixed liquor A and mixed liquid B are mixed, it is quiet after being completely dissolved It sets to get the outdoor wear washing-free agent.
Embodiment 2
A kind of outdoor wear washing-free agent, is made of the raw material of following parts by weight: 3 parts of water soluble chitosan, 2 parts of chitin, 4 parts of butanediol, 1.2 parts of carbomer, 1 part of Nanocrystalline Cellulose Colloid, 4 parts of fluorocarbons copolymer, fatty glyceride 8 Part, 3 parts of lemon, 150 parts of deionized water.
Wherein, the water soluble chitosan is water soluble chitosan hydrochloride, water soluble chitosan nitrate, water soluble shells For glycan citrate according to parts by weight than the mixture for 1:1:1, the deacetylation of the water soluble chitosan is 94%.
Above-mentioned outdoor wear washing-free agent the preparation method comprises the following steps: (1) by the nano micro crystal cellulose glue of above-mentioned parts by weight Body, fluorocarbons copolymer, fatty glyceride are placed in 95 parts of deionized waters, and ultrasound is sufficiently mixed, and obtains mixed liquor A;(2) The deionized water that add weight number is 20 parts into the water soluble chitosan of above-mentioned parts by weight is mixed and chitosan gum is made Body;(3) butanediol of above-mentioned parts by weight is added in the chitosan colloid in step (2), is stirred, stood, obtain chitosan- Butanediol mixed liquor;(4) chitosan-butanediol mixed liquor is decolourized to colorless and transparent using filter, collects transparent mixed liquor; (5) lemon, the chitin of remaining deionized water and above-mentioned parts by weight are added into above-mentioned transparent mixed liquor, mixing is equal It is even to obtain mixed liquid B;(6) carbomer of above-mentioned parts by weight and above-mentioned mixed liquor A and mixed liquid B are mixed, it is quiet after being completely dissolved It sets to get the outdoor wear washing-free agent.
Embodiment 3
A kind of outdoor wear washing-free agent, is made of the raw material of following parts by weight: 2 parts of water soluble chitosan, chitin 1.5 Part, 3 parts of butanediol, 1.0 parts of carbomer, 0.8 part of Nanocrystalline Cellulose Colloid, 3 parts of fluorocarbons copolymer, fatty acid are sweet 7 parts of grease, 2 parts of lemon, 135 parts of deionized water.
Wherein, the water soluble chitosan is water soluble chitosan hydrochloride, water soluble chitosan nitrate, water soluble shells For glycan citrate according to parts by weight than the mixture for 1:1:1, the deacetylation of the water soluble chitosan is 93%.
Above-mentioned outdoor wear washing-free agent the preparation method comprises the following steps: (1) by the nano micro crystal cellulose glue of above-mentioned parts by weight Body, fluorocarbons copolymer, fatty glyceride are placed in 92 parts of deionized waters, and ultrasound is sufficiently mixed, and obtains mixed liquor A;(2) The deionized water that add weight number is 15 parts into the water soluble chitosan of above-mentioned parts by weight is mixed and chitosan gum is made Body;(3) butanediol of above-mentioned parts by weight is added in the chitosan colloid in step (2), is stirred, stood, obtain chitosan- Butanediol mixed liquor;(4) chitosan-butanediol mixed liquor is decolourized to colorless and transparent using filter, collects transparent mixed liquor; (5) lemon, the chitin of remaining deionized water and above-mentioned parts by weight are added into above-mentioned transparent mixed liquor, mixing is equal It is even to obtain mixed liquid B;(6) carbomer of above-mentioned parts by weight and above-mentioned mixed liquor A and mixed liquid B are mixed, it is quiet after being completely dissolved It sets to get the outdoor wear washing-free agent.
Using in above-described embodiment 1 to 3 gained outdoor wear with washing-free agent than the clean effect directly cleaned with clear water Good, that spot residual is cleaned than clear water after final cleaning few 90% or so.
In antibacterial test, clean and use clear water clear with washing-free agent using gained outdoor wear in above-described embodiment 1 to 3 It washes, detects fabric surface bacteria content, it is found that gained outdoor wear is cleaned more clear than clear water with washing-free agent in above-described embodiment 1 to 3 Clothing surface bacterial content wants low 92 to 94% after washing.The clothing cleaned simultaneously using outdoor wear with washing-free agent is than clear water The cloth drying speed fast 90% or so of cleaning.
The basic principles, main features and advantages of the present invention have been shown and described above.The technology of the industry Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and what is described in the above embodiment and the description is only the present invention Principle, various changes and improvements may be made to the invention without departing from the spirit and scope of the present invention, these variation and Improvement is both fallen in the range of claimed invention.The present invention claims protection scope by appended claims and its Equivalent defines.

Claims (7)

1. a kind of outdoor wear washing-free agent, it is characterised in that: be made of the raw material of following parts by weight: water soluble chitosan 1 ~3 parts, 1~2 part of chitin, 2~4 parts of butanediol, 0.8~1.2 part of carbomer, 0.6~1 part of Nanocrystalline Cellulose Colloid, 2~4 parts of fluorocarbons copolymer, 6~8 parts of fatty glyceride, 1~3 part of lemon, 120~150 parts of deionized water.
2. a kind of outdoor wear washing-free agent according to claim 1, it is characterised in that: by the raw material of following parts by weight Composition: 1 part of water soluble chitosan, 1 part of chitin, 2 parts of butanediol, 0.8 part of carbomer, 0.6 part of Nanocrystalline Cellulose Colloid, 2 parts of fluorocarbons copolymer, 6 parts of fatty glyceride, 1 part of lemon, 120 parts of deionized water.
3. a kind of outdoor wear washing-free agent according to claim 1, it is characterised in that: by the raw material of following parts by weight Composition: 3 parts of water soluble chitosan, 2 parts of chitin, 4 parts of butanediol, 1.2 parts of carbomer, 1 part of Nanocrystalline Cellulose Colloid, fluorine 4 parts of carbon compound copolymer, 8 parts of fatty glyceride, 3 parts of lemon, 150 parts of deionized water.
4. a kind of outdoor wear washing-free agent according to claim 1, it is characterised in that: by the raw material of following parts by weight Composition: 2 parts of water soluble chitosan, 1.5 parts of chitin, 3 parts of butanediol, 1.0 parts of carbomer, Nanocrystalline Cellulose Colloid 0.8 Part, 3 parts of fluorocarbons copolymer, 7 parts of fatty glyceride, 2 parts of lemon, 135 parts of deionized water.
5. a kind of outdoor wear washing-free agent according to any one of claim 1 to 4, it is characterised in that: described water-soluble Property chitosan be water soluble chitosan hydrochloride, water soluble chitosan nitrate, water soluble chitosan citrate is according to weight Portion rate is the mixture of 1:1:1.
6. a kind of outdoor wear washing-free agent according to claim 5, it is characterised in that: the water soluble chitosan takes off Acetyl degree is 92%~94%.
7. a kind of outdoor wear washing-free agent according to any one of claim 6, it is characterised in that: above-mentioned outdoor wear With washing-free agent the preparation method comprises the following steps: (1) by the Nanocrystalline Cellulose Colloid of above-mentioned parts by weight, fluorocarbons copolymer, Fatty glyceride is placed in 90~95 parts of deionized waters, and ultrasound is sufficiently mixed, and obtains mixed liquor A;(2) Xiang Shangshu parts by weight The deionized water that add weight number is 10~20 parts in water soluble chitosan is mixed and chitosan colloid is made;It (3) will be above-mentioned The butanediol of parts by weight adds in the chitosan colloid in step (2), stirs, and stands, and obtains chitosan-butanediol mixing Liquid;(4) chitosan-butanediol mixed liquor is decolourized to colorless and transparent using filter, collects transparent mixed liquor;(5) Xiang Shangshu Lemon, the chitin of remaining deionized water and above-mentioned parts by weight are added in transparent mixed liquor, is uniformly mixed to obtain mixing Liquid B;(6) carbomer of above-mentioned parts by weight and above-mentioned mixed liquor A and mixed liquid B are mixed, after being completely dissolved, stand to get The outdoor wear washing-free agent.
CN201811499600.1A 2018-12-09 2018-12-09 A kind of outdoor wear washing-free agent Pending CN109401864A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811499600.1A CN109401864A (en) 2018-12-09 2018-12-09 A kind of outdoor wear washing-free agent

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Application Number Priority Date Filing Date Title
CN201811499600.1A CN109401864A (en) 2018-12-09 2018-12-09 A kind of outdoor wear washing-free agent

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105908502A (en) * 2016-06-23 2016-08-31 杭州余杭兴隆绸厂 Wash-free agent and wash-free fabric treated by adopting same
CN108498372A (en) * 2018-05-10 2018-09-07 江苏金太阳纺织科技股份有限公司 A kind of disposable hand cleanser and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105908502A (en) * 2016-06-23 2016-08-31 杭州余杭兴隆绸厂 Wash-free agent and wash-free fabric treated by adopting same
CN108498372A (en) * 2018-05-10 2018-09-07 江苏金太阳纺织科技股份有限公司 A kind of disposable hand cleanser and preparation method thereof

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Application publication date: 20190301