CN109397803A - 新型透气除臭抗菌垫 - Google Patents
新型透气除臭抗菌垫 Download PDFInfo
- Publication number
- CN109397803A CN109397803A CN201811052285.8A CN201811052285A CN109397803A CN 109397803 A CN109397803 A CN 109397803A CN 201811052285 A CN201811052285 A CN 201811052285A CN 109397803 A CN109397803 A CN 109397803A
- Authority
- CN
- China
- Prior art keywords
- layer
- parts
- silver
- zirconium phosphate
- anion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 230000003115 biocidal effect Effects 0.000 title claims abstract description 18
- 230000001877 deodorizing effect Effects 0.000 title claims abstract description 17
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 60
- 239000000843 powder Substances 0.000 claims abstract description 43
- 150000001450 anions Chemical class 0.000 claims abstract description 28
- 239000000835 fiber Substances 0.000 claims abstract description 26
- 239000011162 core material Substances 0.000 claims abstract description 21
- 125000000129 anionic group Chemical group 0.000 claims abstract description 20
- 239000003094 microcapsule Substances 0.000 claims abstract description 20
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 19
- 230000006870 function Effects 0.000 claims abstract description 17
- 229920000079 Memory foam Polymers 0.000 claims abstract description 13
- 239000008210 memory foam Substances 0.000 claims abstract description 13
- 239000004744 fabric Substances 0.000 claims abstract description 10
- 239000000463 material Substances 0.000 claims abstract description 10
- 229920002101 Chitin Polymers 0.000 claims abstract description 9
- 229910000166 zirconium phosphate Inorganic materials 0.000 claims description 40
- LEHFSLREWWMLPU-UHFFFAOYSA-B zirconium(4+);tetraphosphate Chemical compound [Zr+4].[Zr+4].[Zr+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LEHFSLREWWMLPU-UHFFFAOYSA-B 0.000 claims description 40
- 239000004952 Polyamide Substances 0.000 claims description 25
- 229920002647 polyamide Polymers 0.000 claims description 25
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 20
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 20
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims description 20
- 239000000839 emulsion Substances 0.000 claims description 19
- 239000000243 solution Substances 0.000 claims description 17
- 239000004594 Masterbatch (MB) Substances 0.000 claims description 15
- 229920001807 Urea-formaldehyde Polymers 0.000 claims description 15
- 230000000845 anti-microbial effect Effects 0.000 claims description 14
- RZTYEUCBTNJJIW-UHFFFAOYSA-K silver;zirconium(4+);phosphate Chemical compound [Zr+4].[Ag+].[O-]P([O-])([O-])=O RZTYEUCBTNJJIW-UHFFFAOYSA-K 0.000 claims description 14
- 238000003756 stirring Methods 0.000 claims description 13
- 125000003396 thiol group Chemical group [H]S* 0.000 claims description 12
- 238000002360 preparation method Methods 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 10
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 10
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 10
- 229960000583 acetic acid Drugs 0.000 claims description 10
- 239000004202 carbamide Substances 0.000 claims description 10
- 239000012362 glacial acetic acid Substances 0.000 claims description 10
- 229910052757 nitrogen Inorganic materials 0.000 claims description 10
- 239000004332 silver Substances 0.000 claims description 10
- 229910052709 silver Inorganic materials 0.000 claims description 10
- 229910001961 silver nitrate Inorganic materials 0.000 claims description 10
- 239000003960 organic solvent Substances 0.000 claims description 9
- 241000894006 Bacteria Species 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims description 5
- 235000017491 Bambusa tulda Nutrition 0.000 claims description 5
- 241001330002 Bambuseae Species 0.000 claims description 5
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 5
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 5
- 239000011425 bamboo Substances 0.000 claims description 5
- 230000015572 biosynthetic process Effects 0.000 claims description 5
- 238000001354 calcination Methods 0.000 claims description 5
- 239000003610 charcoal Substances 0.000 claims description 5
- 239000006185 dispersion Substances 0.000 claims description 5
- 230000001804 emulsifying effect Effects 0.000 claims description 5
- 238000002074 melt spinning Methods 0.000 claims description 5
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims description 5
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims description 5
- 239000013049 sediment Substances 0.000 claims description 5
- 238000010008 shearing Methods 0.000 claims description 5
- 238000001694 spray drying Methods 0.000 claims description 5
- 238000013517 stratification Methods 0.000 claims description 5
- 238000000967 suction filtration Methods 0.000 claims description 5
- 238000003786 synthesis reaction Methods 0.000 claims description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 4
- 239000007864 aqueous solution Substances 0.000 claims description 4
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 4
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 4
- 235000019441 ethanol Nutrition 0.000 claims description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 3
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 3
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 3
- -1 Thioacetic acid glycol ester Chemical class 0.000 claims description 2
- 239000004599 antimicrobial Substances 0.000 claims description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- ZJLMKPKYJBQJNH-UHFFFAOYSA-N propane-1,3-dithiol Chemical compound SCCCS ZJLMKPKYJBQJNH-UHFFFAOYSA-N 0.000 claims description 2
- 229940070527 tourmaline Drugs 0.000 claims description 2
- 229910052613 tourmaline Inorganic materials 0.000 claims description 2
- 239000011032 tourmaline Substances 0.000 claims description 2
- SDKTUKJXHDZWMB-UHFFFAOYSA-N phosphoric acid zirconium Chemical compound [Zr].P(O)(O)(O)=O SDKTUKJXHDZWMB-UHFFFAOYSA-N 0.000 claims 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- 150000001408 amides Chemical class 0.000 claims 1
- 239000003599 detergent Substances 0.000 claims 1
- 239000002612 dispersion medium Substances 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims 1
- CWERGRDVMFNCDR-UHFFFAOYSA-M thioglycolate(1-) Chemical compound [O-]C(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-M 0.000 claims 1
- 230000035699 permeability Effects 0.000 abstract description 6
- 238000004332 deodorization Methods 0.000 abstract description 5
- 230000003385 bacteriostatic effect Effects 0.000 abstract description 3
- 206010040880 Skin irritation Diseases 0.000 abstract description 2
- 230000002045 lasting effect Effects 0.000 abstract description 2
- 230000036556 skin irritation Effects 0.000 abstract description 2
- 231100000475 skin irritation Toxicity 0.000 abstract description 2
- 239000007789 gas Substances 0.000 description 10
- 238000004090 dissolution Methods 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 239000002068 microbial inoculum Substances 0.000 description 4
- 239000006228 supernatant Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000005611 electricity Effects 0.000 description 3
- 235000013312 flour Nutrition 0.000 description 3
- 239000003242 anti bacterial agent Substances 0.000 description 2
- 230000002924 anti-infective effect Effects 0.000 description 2
- 238000013016 damping Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- 238000009738 saturating Methods 0.000 description 2
- DFOGGJMYYQUURK-UHFFFAOYSA-N 2,2-bis(sulfanyl)acetic acid Chemical compound OC(=O)C(S)S DFOGGJMYYQUURK-UHFFFAOYSA-N 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 229940070748 dimercaptosuccinate Drugs 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002168 ethanoic acid esters Chemical class 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 230000017525 heat dissipation Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- ACTRVOBWPAIOHC-UHFFFAOYSA-N succimer Chemical compound OC(=O)C(S)C(S)C(O)=O ACTRVOBWPAIOHC-UHFFFAOYSA-N 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- B01J13/06—Making microcapsules or microballoons by phase separation
- B01J13/14—Polymerisation; cross-linking
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
- B32B3/02—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions
- B32B3/08—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions characterised by added members at particular parts
- B32B3/085—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions characterised by added members at particular parts spaced apart pieces on the surface of a layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
- B32B3/26—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
- B32B3/266—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by an apertured layer, the apertures going through the whole thickness of the layer, e.g. expanded metal, perforated layer, slit layer regular cells B32B3/12
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/024—Woven fabric
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/18—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
- B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
- B32B5/245—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it being a foam layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
- B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
- B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G12/00—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08G12/02—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes
- C08G12/04—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds
- C08G12/10—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds with acyclic compounds having the moiety X=C(—N<)2 in which X is O, S or —N
- C08G12/12—Ureas; Thioureas
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
- D01F1/103—Agents inhibiting growth of microorganisms
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/12—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyamide as constituent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
- B32B2262/0261—Polyamide fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2266/00—Composition of foam
- B32B2266/02—Organic
- B32B2266/0214—Materials belonging to B32B27/00
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/554—Wear resistance
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/56—Damping, energy absorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
- B32B2307/7145—Rot proof, resistant to bacteria, mildew, mould, fungi
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/724—Permeability to gases, adsorption
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Textile Engineering (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Dispersion Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Artificial Filaments (AREA)
Abstract
本发明属于防菌垫领域，具体涉及一种新型透气除臭抗菌垫，自下而上包括基布层、记忆海绵层、气孔层、记忆海绵层、负离子层、以及甲壳素纤维层；所述的负离子层由经线、纬线制造而成，所述经线、纬线相交处的凹陷面内设有负离子微胶囊；所述的负离子微胶囊包括下述重量份组份：芯材：抗菌负离子粉50‑45份，乳化剂25‑50份；壁材：脲醛树脂35‑45份。本发明提供的新型透气除臭抗菌垫具有良好的透气性、散热性、持久的抗菌抑菌功能以及除臭功能，同时，该垫的制作材料也应对人体无害、对皮肤无刺激性。
Description
技术领域
本发明属于除菌垫领域，具体涉及一种新型透气除臭抗菌垫。
背景技术
近年来，随着人们对美好生活的需要与技术的不断提升，出现了抗静电垫、增高垫、防水垫等功能垫。但目前市场上的常规垫大多数存在透气性不佳等缺点。如果垫子的透气性能与散热性能较差，容易导致滋生大量的细菌。因此，为了使使用者提供更加舒适的体验，需要使垫子具有良好的透气性、散热性、持久的抗菌抑菌功能以及除臭功能，同时，垫子的制作材料也应对人体无害、对皮肤无刺激性。
发明内容
本发明的目的在于提供一种新型透气除臭抗菌垫。
本发明为实现上述目的，采用以下技术方案：
一种新型透气除臭抗菌垫,自下而上包括基布层、记忆海绵层、气孔层、记忆海绵层、负离子层、以及甲壳素纤维层；
所述的负离子层由经线、纬线制造而成，所述经线、纬线相交处的凹陷面内设有负离子微胶囊；所述的负离子微胶囊包括下述重量份组份：
芯材：抗菌负离子粉45-50份，乳化剂25-50份；
壁材：脲醛树脂35-45份。
所述的抗菌负离子粉包括下述重量份组份：纳米级二氧化钛3份、硅藻土16份、电气石粉10份、竹炭粉5份。
所述的负离子微胶囊采用下述方式制备：
1)所述脲醛树脂由尿素和甲醛按摩尔比1:2合成；将尿素和甲醛溶液混合，按搅拌溶解后，调节pH至8，在65度下反应1h得到透明粘稠的脲醛树脂预聚体；
2)囊芯乳化液的合成：将抗菌负离子粉加入到乳化剂水溶液中，加热至45℃度搅拌，并用高剪切分散乳化机在5000-15000r/min的转速下进行乳化，得到囊芯乳化液；各组分质量比例为5份抗菌负离子粉、30份水、0.5份乳化剂；
3)将制成的脲醛树脂预聚体与囊芯乳化液混合：使脲醛树脂预聚体溶解于乳化液的分散介质水中保持温度50-60℃，搅拌，滴加冰醋酸溶液溶液调节PH＝4时，在氮气保护下，开始加热升温；当pH达到2.8-3.0时温度同时上升到70度，在氮气保护下，保温0.5-1h；再滴加冰醋酸溶液至pH为2.0，保温1h，用三乙醇胺调节pH到6-8；自然降温，静置分层，去掉上层清液，将沉淀物抽滤干燥得到可得负离子微胶囊。
所述乳化剂为十二烷基苯磺酸钠、聚乙烯醇、或者聚丙烯酸钠中的一种。
所述的基布层为纳米磷酸锆载银抗菌纤维层。
所述的纳米磷酸锆载银抗菌纤维层采用下述方式制备：
1)纳米磷酸锆载银抗菌剂的制备：a)将磷酸锆粉体与多巯基化合物分散于有机溶剂中，在室温下密闭超声分散0.5～2小时；b)加入硝酸银，500r/min搅拌12-15小时；其中，所述的磷酸锆粉体、多巯基化合物和硝酸银的质量比为100∶1～6∶8～20；c)利用喷雾干燥的方式去除有机溶剂；d)将获得的粉体置于800℃-1000℃温度煅烧3-4个小时，得到纳米磷酸锆载银抗菌剂；
2)纳米磷酸锆载银抗菌纤维层的制备：a)：按照上述步骤获得纳米磷酸锆载银抗菌剂后，将纳米磷酸锆载银抗菌剂与聚酰胺树脂经双螺杆造粒机造粒，获得具有抗菌功能的聚酰胺母粒，所述的抗菌功能聚酰胺母粒中载银磷酸锆的质量百分比为10％～20％；b)将抗菌聚酰胺母粒和聚酰胺树脂按质量比50∶100经熔融纺丝制备出纳米磷酸锆载银抗菌纤维层。
所述的多巯基化合物为二巯基乙酸乙二醇酯、1，3-二巯基丙烷、季戊四醇四巯基乙酸酯和季戊四醇四-3-巯基丙酸酯等的一种或几种；所述的有机溶剂为乙醇、丙酮的一种。
所述的气孔层上开设多个直径为1.5mm的小气孔，用于空气流通。
与现有技术相比，本发明的有益效果是：
(1)抗菌、抑菌性：基布层所含纳米磷酸锆载银抗菌剂具有抗菌抑菌的作用，可对多类细菌进行高效广谱的杀灭和去除；负离子层中的微胶囊慢慢释放负离子，起到有效杀菌的作用；与使用者直接接触的甲壳素纤维层，具有抗感染、抗菌功能，有效抑制细菌的滋生。
(2)透气性：记忆海绵层-气孔层-记忆海绵层的“三明治结构”有效提高了垫的透气性能。记忆海绵的通透泡孔结构，保证了人体皮肤需要的透气性，同时记忆海绵层(2)为气孔层提供了排气通道，保证了垫子的空气流通。
(3)散热性：由于甲壳素具有很强的吸湿性，汗液被甲壳素纤维层吸收并通过记忆海绵层、透气层向外层扩散、蒸发。
(4)除臭性：微胶囊释放出的负离子，起到杀菌、除臭、净化空气的作用；位于负离子层上方的甲壳素纤维层也具有抗感染、抗菌、除臭的功能。
(5)亲肤性：与皮肤直接接触的甲壳素纤维对人体无毒无刺激，可被人体内的溶菌酶分解而吸收，与人体组织有良好的生物相容性。同时，本申请的新型垫采用的材料对皮肤无刺激性。
(6)减震性：本申请的新型垫采用的记忆海绵层不仅具有良好的透气性还具有吸收冲击力、减少震动、低反弹力释放的作用，因而有效提高了垫的减震性能。
(7)耐磨性：特别是纳米磷酸锆载银抗菌剂能持久地与高分子材料相结合，化学稳定性好，在较宽的PH范围内化学稳定，能经受表面活性剂多次洗涤，其抗菌力不下降。聚酰胺具有无毒、质轻、耐磨等特性，提高了垫的耐磨性。
附图说明
图1为本发明新型透气除臭抗菌垫的整体结构示意图。
具体实施方式
为了使本技术领域的技术人员更好地理解本发明的技术方案，下面结合附图和最佳实施例对本发明作进一步的详细说明。
图1示出一种新型透气除臭抗菌垫,自下而上包括基布层1、记忆海绵层2、气孔层3、记忆海绵层4、负离子层5、以及甲壳素纤维层6；所述的负离子层由经线、纬线制造而成，所述经线、纬线相交处的凹陷面内设有负离子微胶囊；所述的负离子微胶囊包括下述重量份组份：
实施例1：芯材：抗菌负离子粉48份，乳化剂35份；壁材：脲醛树脂40份。所述的抗菌负离子粉包括下述重量份组份：纳米级二氧化钛3份、硅藻土16份、电气石粉10份、竹炭粉5份。
所述的负离子微胶囊采用下述方式制备：
1)所述脲醛树脂由尿素和甲醛按摩尔比1:2合成；将尿素和甲醛溶液混合，按搅拌溶解后，调节pH至8，在65度下反应1h得到透明粘稠的脲醛树脂预聚体；
2)囊芯乳化液的合成：将抗菌负离子粉加入到乳化剂十二烷基苯磺酸钠的水溶液中，加热至45℃度搅拌，并用高剪切分散乳化机在5000-15000r/min的转速下进行乳化，得到囊芯乳化液；各组分质量比例为5份抗菌负离子粉、30份水、0.5份乳化剂；
3)将制成的脲醛树脂预聚体与囊芯乳化液混合：使脲醛树脂预聚体溶解于乳化液的分散介质水中保持温度50-60℃，搅拌，滴加冰醋酸溶液溶液调节PH＝4时，在氮气保护下，开始加热升温；当pH达到2.8-3.0时温度同时上升到70度，在氮气保护下，保温0.5-1h；再滴加冰醋酸溶液至pH为2.0，保温1h，用三乙醇胺调节pH到6-8；自然降温，静置分层，去掉上层清液，将沉淀物抽滤干燥得到可得负离子微胶囊。
所述的基布层为纳米磷酸锆载银抗菌纤维层。
所述的纳米磷酸锆载银抗菌纤维层采用下述方式制备：
1)纳米磷酸锆载银抗菌剂的制备：a)将磷酸锆粉体与多巯基化合物二巯基乙酸乙二醇酯分散于有机溶剂乙醇中，在室温下密闭超声分散0.5～2小时；b)加入硝酸银，500r/min搅拌12-15小时；其中，所述的磷酸锆粉体、多巯基化合物和硝酸银的质量比为100∶3∶15；c)利用喷雾干燥的方式去除有机溶剂；d)将获得的粉体置于800℃-1000℃温度煅烧3-4个小时，得到纳米磷酸锆载银抗菌剂；
2)纳米磷酸锆载银抗菌纤维层的制备：a)：按照上述步骤获得纳米磷酸锆载银抗菌剂后，将纳米磷酸锆载银抗菌剂与聚酰胺树脂经双螺杆造粒机造粒，获得具有抗菌功能的聚酰胺母粒，所述的抗菌功能聚酰胺母粒中载银磷酸锆的质量百分比为15％；b)将抗菌聚酰胺母粒和聚酰胺树脂按质量比50∶100经熔融纺丝制备出纳米磷酸锆载银抗菌纤维层。
所述的气孔层上开设多个直径为1.5mm的小气孔，用于空气流通。
实施例2：芯材：抗菌负离子粉45份，乳化剂25份；壁材：脲醛树脂35份。
所述的抗菌负离子粉包括下述重量份组份：纳米级二氧化钛3份、硅藻土16份、电气石粉10份、竹炭粉5份。
所述的负离子微胶囊采用下述方式制备：
1)所述脲醛树脂由尿素和甲醛按摩尔比1:2合成；将尿素和甲醛溶液混合，按搅拌溶解后，调节pH至8，在65度下反应1h得到透明粘稠的脲醛树脂预聚体；
2)囊芯乳化液的合成：将抗菌负离子粉加入到乳化剂聚乙烯醇水溶液中，加热至45℃度搅拌，并用高剪切分散乳化机在5000-15000r/min的转速下进行乳化，得到囊芯乳化液；各组分质量比例为5份抗菌负离子粉、30份水、0.5份乳化剂；
3)将制成的脲醛树脂预聚体与囊芯乳化液混合：使脲醛树脂预聚体溶解于乳化液的分散介质水中保持温度50-60℃，搅拌，滴加冰醋酸溶液溶液调节PH＝4时，在氮气保护下，开始加热升温；当pH达到2.8-3.0时温度同时上升到70度，在氮气保护下，保温0.5-1h；再滴加冰醋酸溶液至pH为2.0，保温1h，用三乙醇胺调节pH到6-8；自然降温，静置分层，去掉上层清液，将沉淀物抽滤干燥得到可得负离子微胶囊。
所述的基布层为纳米磷酸锆载银抗菌纤维层。
所述的纳米磷酸锆载银抗菌纤维层采用下述方式制备：
1)纳米磷酸锆载银抗菌剂的制备：a)将磷酸锆粉体与多巯基化合物分散于有机溶剂中，在室温下密闭超声分散0.5～2小时；b)加入硝酸银，500r/min搅拌12-15小时；其中，所述的磷酸锆粉体、多巯基化合物和硝酸银的质量比为100∶1∶8；c)利用喷雾干燥的方式去除有机溶剂；d)将获得的粉体置于800℃-1000℃温度煅烧3-4个小时，得到纳米磷酸锆载银抗菌剂；
2)纳米磷酸锆载银抗菌纤维层的制备：a)：按照上述步骤获得纳米磷酸锆载银抗菌剂后，将纳米磷酸锆载银抗菌剂与聚酰胺树脂经双螺杆造粒机造粒，获得具有抗菌功能的聚酰胺母粒，所述的抗菌功能聚酰胺母粒中载银磷酸锆的质量百分比为10％；b)将抗菌聚酰胺母粒和聚酰胺树脂按质量比50∶100经熔融纺丝制备出纳米磷酸锆载银抗菌纤维层。
实施例3：芯材：抗菌负离子粉50份，乳化剂50份；壁材：脲醛树脂45份。
所述的抗菌负离子粉包括下述重量份组份：纳米级二氧化钛3份、硅藻土16份、电气石粉10份、竹炭粉5份。
所述的负离子微胶囊采用下述方式制备：
1)所述脲醛树脂由尿素和甲醛按摩尔比1:2合成；将尿素和甲醛溶液混合，按搅拌溶解后，调节pH至8，在65度下反应1h得到透明粘稠的脲醛树脂预聚体；
2)囊芯乳化液的合成：将抗菌负离子粉加入到乳化剂水溶液中，加热至45℃度搅拌，并用高剪切分散乳化机在5000-15000r/min的转速下进行乳化，得到囊芯乳化液；各组分质量比例为5份抗菌负离子粉、30份水、0.5份乳化剂；
3)将制成的脲醛树脂预聚体与囊芯乳化液混合：使脲醛树脂预聚体溶解于乳化液的分散介质水中保持温度50-60℃，搅拌，滴加冰醋酸溶液溶液调节PH＝4时，在氮气保护下，开始加热升温；当pH达到2.8-3.0时温度同时上升到70度，在氮气保护下，保温0.5-1h；再滴加冰醋酸溶液至pH为2.0，保温1h，用三乙醇胺调节pH到6-8；自然降温，静置分层，去掉上层清液，将沉淀物抽滤干燥得到可得负离子微胶囊。
所述乳化剂为十二烷基苯磺酸钠、聚乙烯醇、或者聚丙烯酸钠中的一种。
所述的基布层为纳米磷酸锆载银抗菌纤维层。
所述的纳米磷酸锆载银抗菌纤维层采用下述方式制备：
1)纳米磷酸锆载银抗菌剂的制备：a)将磷酸锆粉体与多巯基化合物分散于有机溶剂中，在室温下密闭超声分散0.5～2小时；b)加入硝酸银，500r/min搅拌12-15小时；其中，所述的磷酸锆粉体、多巯基化合物和硝酸银的质量比为100∶6∶20；c)利用喷雾干燥的方式去除有机溶剂；d)将获得的粉体置于800℃-1000℃温度煅烧3-4个小时，得到纳米磷酸锆载银抗菌剂；
2)纳米磷酸锆载银抗菌纤维层的制备：a)：按照上述步骤获得纳米磷酸锆载银抗菌剂后，将纳米磷酸锆载银抗菌剂与聚酰胺树脂经双螺杆造粒机造粒，获得具有抗菌功能的聚酰胺母粒，所述的抗菌功能聚酰胺母粒中载银磷酸锆的质量百分比为20％；b)将抗菌聚酰胺母粒和聚酰胺树脂按质量比50∶100经熔融纺丝制备出纳米磷酸锆载银抗菌纤维层。
以上所述仅是本发明的优选实施方式，应当指出，对于本技术领域的普通技术人员来说，在不脱离本发明原理的前提下，还可以做出若干改进和润饰，这些改进和润饰也应视为本发明的保护范围。
Claims (8)
1.一种新型透气除臭抗菌垫,其特征在于，自下而上包括基布层、记忆海绵层、气孔层、记忆海绵层、负离子层、以及甲壳素纤维层；
所述的负离子层由经线、纬线制造而成，所述经线、纬线相交处的凹陷面内设有负离子微胶囊；所述的负离子微胶囊包括下述重量份组份：
芯材：抗菌负离子粉45-50份，乳化剂25-50份；
壁材：脲醛树脂35-45份。
2.根据权利要求1所述的新型透气除臭抗菌垫,其特征在于，所述的抗菌负离子粉包括下述重量份组份：纳米级二氧化钛3份、硅藻土16份、电气石粉10份、竹炭粉5份。
3.根据权利要求1所述的新型透气除臭抗菌垫,其特征在于，所述的负离子微胶囊采用下述方式制备：
1)所述脲醛树脂由尿素和甲醛按摩尔比1:2合成；将尿素和甲醛溶液混合，按搅拌溶解后，调节pH至8，在65度下反应1h得到透明粘稠的脲醛树脂预聚体；
2)囊芯乳化液的合成：将抗菌负离子粉加入到乳化剂水溶液中，加热至45℃度搅拌，并用高剪切分散乳化机在5000-15000r/min的转速下进行乳化，得到囊芯乳化液；各组分质量比例为5份抗菌负离子粉、30份水、0.5份乳化剂；
3)将制成的脲醛树脂预聚体与囊芯乳化液混合：使脲醛树脂预聚体溶解于乳化液的分散介质水中保持温度50-60℃，搅拌，滴加冰醋酸溶液溶液调节PH＝4时，在氮气保护下，开始加热升温；当pH达到2.8-3.0时温度同时上升到70度，在氮气保护下，保温0.5-1h；再滴加冰醋酸溶液至pH为2.0，保温1h，用三乙醇胺调节pH到6-8；自然降温，静置分层，去掉上层清液，将沉淀物抽滤干燥得到可得负离子微胶囊。
4.根据权利要求3所述的新型透气除臭抗菌垫,其特征在于，所述乳化剂为十二烷基苯磺酸钠、聚乙烯醇、或者聚丙烯酸钠中的一种。
5.根据权利要求1所述的新型透气除臭抗菌垫,其特征在于，所述的基布层为纳米磷酸锆载银抗菌纤维层。
6.根据权利要求5所述的新型透气除臭抗菌垫,其特征在于，所述的纳米磷酸锆载银抗菌纤维层采用下述方式制备：
1)纳米磷酸锆载银抗菌剂的制备：a)将磷酸锆粉体与多巯基化合物分散于有机溶剂中，在室温下密闭超声分散0.5～2小时；b)加入硝酸银，500r/min搅拌12-15小时；其中，所述的磷酸锆粉体、多巯基化合物和硝酸银的质量比为100∶1～6∶8～20；c)利用喷雾干燥的方式去除有机溶剂；d)将获得的粉体置于800℃-1000℃温度煅烧3-4个小时，得到纳米磷酸锆载银抗菌剂；
2)纳米磷酸锆载银抗菌纤维层的制备：a)：按照上述步骤获得纳米磷酸锆载银抗菌剂后，将纳米磷酸锆载银抗菌剂与聚酰胺树脂经双螺杆造粒机造粒，获得具有抗菌功能的聚酰胺母粒，所述的抗菌功能聚酰胺母粒中载银磷酸锆的质量百分比为10％～20％；b)将抗菌聚酰胺母粒和聚酰胺树脂按质量比50∶100经熔融纺丝制备出纳米磷酸锆载银抗菌纤维层。
7.根据权利要求6所述的新型透气除臭抗菌垫,其特征在于，所述的多巯基化合物为二巯基乙酸乙二醇酯、1，3-二巯基丙烷、季戊四醇四巯基乙酸酯和季戊四醇四-3-巯基丙酸酯等的一种或几种；所述的有机溶剂为乙醇、丙酮的一种。
8.根据权利要求1所述的新型透气除臭抗菌垫,其特征在于，所述的气孔层上开设多个直径为1.5mm的小气孔，用于空气流通。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811052285.8A CN109397803A (zh) | 2018-09-10 | 2018-09-10 | 新型透气除臭抗菌垫 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811052285.8A CN109397803A (zh) | 2018-09-10 | 2018-09-10 | 新型透气除臭抗菌垫 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109397803A true CN109397803A (zh) | 2019-03-01 |
Family
ID=65464682
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811052285.8A Pending CN109397803A (zh) | 2018-09-10 | 2018-09-10 | 新型透气除臭抗菌垫 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109397803A (zh) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111286806A (zh) * | 2020-03-31 | 2020-06-16 | 王云甘 | 一种负离子保健功能纤维及其制备方法 |
| CN116082755A (zh) * | 2023-01-10 | 2023-05-09 | 武汉金牛经济发展有限公司 | 一种具有抗菌自修复功能的pp-r管材及其制备方法 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105332082A (zh) * | 2015-12-01 | 2016-02-17 | 东华大学 | 一种基于载银磷酸锆的抗菌聚酰胺纤维及其制备方法 |
| EP2992953A2 (en) * | 2013-01-25 | 2016-03-09 | Ecopol Tech, S.L. | Method for producing a microencapsulate and corresponding reactive amphiphilic compound, microencapsulate and composition. |
| CN206443518U (zh) * | 2016-09-26 | 2017-08-29 | 龙门多泰工业有限公司 | 多功能颈椎保健卷垫 |
| CN206983398U (zh) * | 2017-05-17 | 2018-02-09 | 杭州世佳布艺有限公司 | 一种透气沙发布 |
| CN107777905A (zh) * | 2017-11-06 | 2018-03-09 | 南京工程学院 | 一种环氧树脂微胶囊、制备及应用 |
-
2018
- 2018-09-10 CN CN201811052285.8A patent/CN109397803A/zh active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2992953A2 (en) * | 2013-01-25 | 2016-03-09 | Ecopol Tech, S.L. | Method for producing a microencapsulate and corresponding reactive amphiphilic compound, microencapsulate and composition. |
| CN105332082A (zh) * | 2015-12-01 | 2016-02-17 | 东华大学 | 一种基于载银磷酸锆的抗菌聚酰胺纤维及其制备方法 |
| CN206443518U (zh) * | 2016-09-26 | 2017-08-29 | 龙门多泰工业有限公司 | 多功能颈椎保健卷垫 |
| CN206983398U (zh) * | 2017-05-17 | 2018-02-09 | 杭州世佳布艺有限公司 | 一种透气沙发布 |
| CN107777905A (zh) * | 2017-11-06 | 2018-03-09 | 南京工程学院 | 一种环氧树脂微胶囊、制备及应用 |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111286806A (zh) * | 2020-03-31 | 2020-06-16 | 王云甘 | 一种负离子保健功能纤维及其制备方法 |
| CN116082755A (zh) * | 2023-01-10 | 2023-05-09 | 武汉金牛经济发展有限公司 | 一种具有抗菌自修复功能的pp-r管材及其制备方法 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108166157B (zh) | 一种吸湿抑菌的水刺无纺布美容面膜基布及其制备方法 | |
| JP2021526036A (ja) | 分子篩／繊維複合材料及びその製造方法 | |
| CN109554919A (zh) | 一种护肤抗菌微胶囊整理剂及其制备方法和应用 | |
| CN110042671A (zh) | 一种具有蓄热调温和抗菌功能的非织造布的制备方法 | |
| CN100529246C (zh) | 一种多元改性壳聚糖抗菌保湿整理剂的制备方法 | |
| CN102061625A (zh) | 一种艾叶油微胶囊抗菌防皱织物及其制备方法 | |
| CN109397803A (zh) | 新型透气除臭抗菌垫 | |
| CN108411402A (zh) | 一种基于一维纳米氧化锌聚酯抗菌母料的服装面料 | |
| CN108754653A (zh) | 一种具有抗菌保健功能纤维及其制备方法 | |
| CN106400199A (zh) | 一种相变调温微胶囊材料、其制备方法及其制备的敷料 | |
| CN113089316A (zh) | 一种金钱草纤维抗菌纺织面料及其制备方法 | |
| JP2010090523A (ja) | 繊維構造物の抗菌防臭・制菌加工方法 | |
| CN109847092A (zh) | 一种止血复合物及其制备方法 | |
| CN105709674A (zh) | 一种温控保健微胶囊及其制备方法 | |
| CN104562843A (zh) | 多功能改性棕榈蜡乳液、其制备方法和应用 | |
| CN103806279B (zh) | 一种用于卫生巾导流层的抑菌无纺布制备方法 | |
| CN107675292B (zh) | 一种纳米银竹炭纤维及其杀菌内衣制品 | |
| CN109056092A (zh) | 一种抗菌型粘胶短纤的制备方法 | |
| CN106012092A (zh) | 一种多功能蛋白纤维及其制备方法 | |
| CN113089151B (zh) | 一种含棉纤维的三维抗菌纱线及其制备方法和毛巾制品 | |
| CN107245887B (zh) | 一种面料的制备方法及面料、服装 | |
| CN113718522A (zh) | 一种长效抗菌组合物及其制备方法 | |
| Massella et al. | Manufacture techniques of chitosan-based microcapsules to enhance functional properties of textiles | |
| EP1736178B1 (en) | Multicomponent material comprising chitosan material and absorbent article containing the same | |
| CN105484052A (zh) | 一种蚕丝被整理用生态抗菌微胶囊的制备方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190301 |