CN109397458A - A kind of straw mat insect-proof agent - Google Patents
A kind of straw mat insect-proof agent Download PDFInfo
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- CN109397458A CN109397458A CN201710713771.9A CN201710713771A CN109397458A CN 109397458 A CN109397458 A CN 109397458A CN 201710713771 A CN201710713771 A CN 201710713771A CN 109397458 A CN109397458 A CN 109397458A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27M—WORKING OF WOOD NOT PROVIDED FOR IN SUBCLASSES B27B - B27L; MANUFACTURE OF SPECIFIC WOODEN ARTICLES
- B27M3/00—Manufacture or reconditioning of specific semi-finished or finished articles
- B27M3/24—Manufacture or reconditioning of specific semi-finished or finished articles of household utensils, e.g. spoons, clothes hangers, clothes pegs
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
- A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/16—Heavy metals; Compounds thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N61/00—Biocides, pest repellants or attractants, or plant growth regulators containing substances of unknown or undetermined composition, e.g. substances characterised only by the mode of action
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/007—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process employing compositions comprising nanoparticles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/52—Impregnating agents containing mixtures of inorganic and organic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K2200/00—Wooden materials to be treated
- B27K2200/10—Articles made of particles or fibres consisting of wood or other lignocellulosic material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K2240/00—Purpose of the treatment
- B27K2240/20—Removing fungi, molds or insects
Abstract
The invention discloses a kind of straw mat insect-proof agents; it is related to straw mat hygienic protection technical field, there are following raw material components to be made: nitrocellulose particle, carboxymethyl chitosan, epoxidized soybean oil, sodium alginate, plant extraction liquid, polyglyceryl fatty acid ester, castor oil hydrogenated mixture, glycerin monostearate, polymer alumina, terpene resin, zeolite powder, straw powder, lysozyme, nano silver-zinc oxide composites, potassium sorbate, glycerol, corn syrup, deionized water；It is safe and non-toxic to prepare straw mat insect-proof agent the selection of material, no pollution to the environment, to the corrosion-free effect of straw mat, when straw mat when not in use rolls straw mat folding, straw mat insect-proof agent is placed among interlayer, can be placed into next season before use, cleaning straw mat once using preceding, straw mat insect-proof agent is long-lasting use, can prevent acarid, damp worm etc..
Description
Technical field:
The present invention relates to straw mat hygienic protection technical fields, and in particular to a kind of straw mat insect-proof agent.
Background technique:
Straw mat refers to the mat woven with flexible grass blade, and general straw mat is not foldable, can only roll.But by improvement
Straw plaited summer sleeping mat, storage can be folded.
Straw mat water absorbing capacity is stronger, and after a used season, dishes served at a feast color is easy to turn yellow.Using rush, the stem or leaf of cattail, Malan Straw
The straw mat of braiding is mostly liked by old man.But straw mat has easily infested weakness.New straw mat is before use, preferably in the sun according to one
According to, pat several times repeatedly, then wipe dust away with warm water, be placed on shady place sunning.Second year reuses straw mat, uses disinfectant
Wiping one time, or mildew is washed away with suds, it is filtered dry with warm water, is then placed on shady place sunning；Daily used straw mat is stained with
There are sweat mark or dust, should all be wiped one time with warm water using preceding.
Acarid is easy to colonize in the gap of straw mat, leads to " summer sleeping mat dermatitis ".Therefore the maintenance of straw mat is most important.New grass
Seat preferably shines (time controlled within half an hour) in the sun, pats several times, then wipe dust away with warm water, is placed on repeatedly
Shady place sunning.The straw mat that second year is reused is wiped one time, or wash away mildew with suds with disinfectant, uses warm water
It is filtered dry, is then placed on shady place sunning；If it is possible that, daily used straw mat speckles with sweat mark or dust, is all answered using preceding
It is wiped one time when with warm water.
Summary of the invention:
Technical problem to be solved by the present invention lies in provide a kind of straw mat insect-proof agent, safe and non-toxic, best in quality, use
Persistence does not corrode straw mat, long-acting to prevent straw mat infested.
The following technical solution is employed for the technical problems to be solved by the invention to realize:
A kind of straw mat insect-proof agent, has the raw material components of following parts by weight to be made:
3-56 parts of nitrocellulose particle, 5-15 parts of carboxymethyl chitosan, 15-30 parts of epoxidized soybean oil, sodium alginate 15-
30 parts, 5-40 parts of plant extraction liquid, 2-10 parts of polyglyceryl fatty acid ester, 2-31 parts of castor oil hydrogenated mixture, monostearate it is sweet
2-10 parts of grease, 2-10 parts of polymer alumina, 5-20 parts of terpene resin, 2-10 parts of zeolite powder, 2-10 parts of straw powder, lysozyme 5-
20 parts, nano silver -3-45 parts of zinc oxide composites, 2-10 parts of potassium sorbate, 2-8 parts of glycerol, 2-10 parts of corn syrup, deionization
10-100 parts of water.
Wherein the castor oil hydrogenated mixture is formed by castor oil modified, method of modifying are as follows: to 15-20 parts of castor oil
3-5 parts of turpentine oil of middle addition, 2-3 parts of cationic polyacrylamide and 0.5-1 parts of polydimethyl diallyl ammonium chloride, it is sufficiently mixed
After conjunction under microwave frequency 2450MHz, power 700W microwave treatment 5min, add 1-2 parts of rilanit specials, 0.5-1 parts it is poly-
Sodium styrene sulfonate and 0.5-1 parts of N methyldiethanol amines continue microwave treatment 5min, after microwave treatment after mixing
It is transferred to sealing and standing 3h in 10-100 DEG C of biochemical reaction device immediately, is then heated to 50-130 DEG C of heat preservation mixing 15min, pressurization
Keep 1-10h more than 10 atmospheric pressure, after be depressurized to normal pressure, into gained mixture be added 6-30 parts of 0-5 DEG C of cold water, sufficiently
1h is stood after mixing, is then heated to reflux state heat preservation mixing 30min, and cooled to room temperature, gained is after cooling
Castor oil hydrogenated mixture.
The nano silver-zinc oxide composites preparation method, preparation method method are as follows: take 1-5 parts of 1mol/LAgCl10-
Solution I is obtained in 50ml and 2-6 parts of polyvinyl alcohol and reaction unit；2mol/LNaOH 5-20ml is measured to be added in solution I, it is old
Change 1-6h, which sufficiently reacts, obtains precursor；Preceding step precursor mixture solution is filtered, precipitating is used distilled water flushing 2-6 times, is sunk
Shallow lake, which is washed, is placed on 40-80 DEG C of baking 2-6h in baking oven；Weigh 2-4 parts of oxalic acid again and 2-5 parts of zinc chloride be each configured to be saturated it is molten
The aqueous solution of oxalic acid and zinc chloride is mixed, 30-60min is sufficiently stirred by liquid, after mixture stood into 30-80min, then
Deionized water sufficiently wash to no chloride ion exist, after be placed in 100-120 DEG C of baking oven dry 2-4h obtain zinc chloride product；It will
Precursor mixture and zinc chloride product after drying are placed in reactor 1-4 parts of sulfuric acid of addition and sufficiently react, and take out product cleaning afterwards
Sufficiently be placed in dismembyator and grind, be placed in Muffle furnace 600 DEG C and process the 2-4h that burns, after toast burnt obtain without taking out cooling, grinding
Obtain nano silver-zinc oxide composites preparation method.
Preferably, the preparation method is as follows:
(1) first by 3-56 parts of nitrocellulose particle, 50-150 parts of carboxymethyl chitosan, 15-30 parts of epoxidized soybean oil, sea
40-80 DEG C of heating is heated in 15-30 parts of addition deionized waters of mosanom to be sufficiently mixed, and polyglycereol is added in backward mixture suspension
2-10 parts of aliphatic ester, 2-31 parts of castor oil hydrogenated mixture, 2-10 parts of glycerin monostearate, are first heated to 80-180 DEG C,
Object to be mixed, which dissolves and is cooled to room temperature to grind in the grinding machine that revolving speed is 100-500rpm/min, to stir evenly, rear to take out
1-12h is distilled in 50-120 DEG C of boiler obtains mixture I；
(2) by step 1 gained mixture I with polymer alumina 2-10 parts, 5-20 parts of terpene resin, 2-10 parts of zeolite powder,
2-10 parts of straw powder, 5-20 parts of lysozyme, nano silver -3-45 parts of zinc oxide composites addition mixed at high speed are opened in mixing machine,
1000-3000rpm/min is uniformly mixed；
It is (3) rear to be added in refiner by material is added in fluid-flywheel clutch and mixes after mixing in step 2,
Refine repeatedly refines material, to obtain mould inhibitor matrix；
(4) by 5-40 parts of mould inhibitor matrix obtained in step 3 and plant extraction liquid, 2-10 parts of potassium sorbate in 30-50
It dissolves and is uniformly mixed under DEG C high-speed stirred, be microwave treatment 10-30min under 2450MHz, power 800w in microwave frequency, mix
Up to material II after closing uniformly；
(5) 2-8 parts of glycerol, 2-10 parts of corn syrup are added in 5 times of 0.1-0.5% sodium bicarbonate solutions, room temperature is quiet
Set 1-24h make it dissolve uniformly, 30-50 DEG C of condition high-speed stirred be uniformly mixed, in microwave frequency be 2450MHz, power
Microwave treatment 10-30min under 800w, after mixing up to material II；
(6) material I and material II are mixed, is warming up to 40-60 DEG C and 15-60min is sufficiently stirred, add acid or alkaloid substance
PH value is adjusted to 5.5-7.5, then 100-500rpm/min 20-40 DEG C insulated and stirred 20-40min, the rear room temperature that stands is cooling, obtains
To mixed solution；Mixing 10-30min in mixer is added in mixed material, system after the material after mixing is put into granulator
It is standby at various shape straw mat insect-proof agent, after straw mat insect-proof agent is packaged into non-woven fabrics, used to mat.
The beneficial effects of the present invention are: straw mat insect-proof agent the selection of material prepared by the present invention is safe and non-toxic, to environment without dirt
Dye, to the corrosion-free effect of straw mat, when straw mat when not in use rolls straw mat folding, straw mat insect-proof agent is placed among interlayer, can
To be placed into next season before use, being cleaned straw mat once using preceding, straw mat insect-proof agent is long-lasting use, can prevent acarid, tide
Worm etc..
Specific embodiment:
For the technical method for realizing the present invention, creation characteristic is reached purpose and is easy to understand with effect, ties below
Specific embodiment is closed, the present invention is further explained.
Embodiment 1
A kind of straw mat insect-proof agent, has the raw material components of following parts by weight to be made:
36 parts of nitrocellulose particle, 7 parts of carboxymethyl chitosan, 15 parts of epoxidized soybean oil, 15 parts of sodium alginate, plant mention
Take 11 parts of liquid, 9 parts of polyglyceryl fatty acid ester, 21 parts of castor oil hydrogenated mixture, 8 parts of glycerin monostearate, polymer alumina
8.5 parts, 14 parts of terpene resin, 10 parts of zeolite powder, 7 parts of straw powder, 11 parts of lysozyme, 35 parts of nano silver-zinc oxide composites, mountain
7.5 parts of potassium sorbate, 6.5 parts of glycerol, 5.5 parts of corn syrup, 15 parts of deionized water.
The castor oil hydrogenated mixture is formed by castor oil modified, method of modifying are as follows: is added 3 into 15 parts of castor oil
Part turpentine oil, 2 parts of cationic polyacrylamide and 0.5 part of polydimethyl diallyl ammonium chloride, in Microwave Frequency after being sufficiently mixed
Microwave treatment 5min under rate 2450MHz, power 700W adds 1 part of rilanit special, 0.5 part of kayexalate and 0.6
Part N methyldiethanol amine, continues microwave treatment 5min after mixing, and it is anti-to be transferred to 50 DEG C of biochemistry immediately after microwave treatment
Sealing and standing 3h in device to be answered, 40 DEG C of heat preservation mixing 15min are then heated to, pressurization keeps 2h more than 10 atmospheric pressure, after
It is depressurized to normal pressure, 6 parts of 0-5 DEG C of cold water are added into gained mixture, 1h is stood after being sufficiently mixed, is then heated to reflux state
Heat preservation mixing 30min, and cooled to room temperature, gained is castor oil hydrogenated mixture after cooling.
The nano silver-zinc oxide composites preparation method, preparation method method are as follows: take 5 parts of 1mol/LAgCl 20ml
Solution I is obtained in 6 parts of polyvinyl alcohol and reaction unit；It measures 2mol/LNaOH10ml to be added in solution I, ageing 2h is sufficiently anti-
It should obtain precursor；Preceding step precursor mixture solution is filtered, precipitating is used distilled water flushing 3 times, and precipitating, which is washed, is placed on baking oven
In 40 DEG C of baking 2h；3 parts of oxalic acid are weighed again and 2 parts of zinc chloride are each configured to saturated solution, by the water-soluble of oxalic acid and zinc chloride
Liquid is mixed, and 30min is sufficiently stirred, after mixture stood into 35min, then deionized water is sufficiently washed to no chloride ion and is deposited
, after be placed in 100 DEG C of baking ovens dry 2.5h obtain zinc chloride product；By after drying precursor mixture and zinc chloride product set
2 parts of sulfuric acid are added in reactor sufficiently to react, rear taking-up product cleaning, which is sufficiently placed in dismembyator, grinds, and is placed on Muffle furnace
In 600 DEG C process the 2h that burns, after toast burnt obtain nano silver-zinc oxide composites preparation method without taking out cooling, grinding.
Preferably, the preparation method is as follows:
(1) first by 36 parts of nitrocellulose particle, 7 parts of carboxymethyl chitosan, 15 parts of epoxidized soybean oil, 15 parts of sodium alginate
40 DEG C of heating of heating in deionized water are added to be sufficiently mixed, 9 parts of polyglyceryl fatty acid ester, castor-oil plant are added in backward mixture suspension
21 parts of oily hydrogenated mixture, 8 parts of glycerin monostearate are first heated to 80 DEG C, and object to be mixed, which is dissolved and is cooled to room temperature, to be turned
It grinds and stirs evenly in the grinding machine that speed is 500rpm/min, rear taking-up distills 1.5h in 70 DEG C of boilers and obtains mixture I；
(2) by step 1 gained mixture I and 8.5 parts of polymer alumina, 14 parts of terpene resin, 10 parts of zeolite powder, straw powder
7 parts, 35 parts of 11 parts of lysozyme, nano silver-zinc oxide composites addition mixed at high speed open in mixing machine, 1000rpm/min stirring
It is uniformly mixed；
It is (3) rear to be added in refiner by material is added in fluid-flywheel clutch and mixes after mixing in step 2,
Refine repeatedly refines material, to obtain insect-proof agent matrix；
(4) by 11 parts of insect-proof agent matrix obtained in step 3 and plant extraction liquid, 7.5 parts of potassium sorbate in 30 DEG C of high speeds
It dissolves and is uniformly mixed under stirring, be microwave treatment 15min under 2450MHz, power 800w in microwave frequency, be after mixing
Obtain material II；
(5) 6.5 parts of glycerol, 5.5 parts of corn syrup are added in 5 times of 0.1-0.5% sodium bicarbonate solutions, are stored at room temperature
2h make it dissolve uniformly, 50 DEG C of condition high-speed stirreds be uniformly mixed, in microwave frequency be 2450MHz, power 800w under microwave
10min is handled, after mixing up to material II；
(6) material I and material II are mixed, is warming up to 40 DEG C and 15min is sufficiently stirred, added acid or alkaloid substance adjusts PH
For value to 7.5, then 20 DEG C of insulated and stirred 25min of 500rpm/min, the rear room temperature that stands is cooling, obtains mixed solution；By mixed material
Mixing 15min in mixer is added, various shape straw mat insect-proof agent is prepared into after the material after mixing is put into granulator, after
Straw mat insect-proof agent is packaged into non-woven fabrics, is used to mat.
Embodiment 2
A kind of straw mat insect-proof agent, has the raw material components of following parts by weight to be made:
46 parts of nitrocellulose particle, 5 parts of carboxymethyl chitosan, 15 parts of epoxidized soybean oil, 16 parts of sodium alginate, plant mention
Take 6 parts of liquid, 7.5 parts of polyglyceryl fatty acid ester, 11 parts of castor oil hydrogenated mixture, 10 parts of glycerin monostearate, polymerization oxidation
7 parts of aluminium, 12 parts of terpene resin, 6 parts of zeolite powder, 7 parts of straw powder, 13 parts of lysozyme, 15 parts of nano silver-zinc oxide composites, mountain
8 parts of potassium sorbate, 8.5 parts of glycerol, 9 parts of corn syrup, 16 parts of deionized water.
Wherein the castor oil hydrogenated mixture is formed by castor oil modified, method of modifying are as follows: into 15 parts of castor oil
3.5 parts of turpentine oil, 2.2 parts of cationic polyacrylamide and 0.5 part of polydimethyl diallyl ammonium chloride is added, after being sufficiently mixed
The microwave treatment 5min under microwave frequency 2450MHz, power 700W adds 2 parts of rilanit specials, 1 part of polystyrolsulfon acid
Sodium and 0.5 part of N methyldiethanol amine continue microwave treatment 5min after mixing, are transferred to 30 DEG C immediately after microwave treatment
Sealing and standing 3h in biochemical reaction device, is then heated to 50 DEG C of heat preservation mixing 15min, and pressurization is kept more than 10 atmospheric pressure
1.5h, after be depressurized to normal pressure, into gained mixture be added 6 parts of 0-5 DEG C of cold water, 1h is stood after being sufficiently mixed, is then heated to
Reflux state heat preservation mixing 30min, and cooled to room temperature, gained is castor oil hydrogenated mixture after cooling.
The nano silver-zinc oxide composites preparation method, preparation method method are as follows: take 3 parts of 1mol/LAgCl 15ml
Solution I is obtained in 2 parts of polyvinyl alcohol and reaction unit；It measures 2mol/LNaOH15ml to be added in solution I, ageing 2h is sufficiently anti-
It should obtain precursor；Preceding step precursor mixture solution is filtered, precipitating is used distilled water flushing 3 times, and precipitating, which is washed, is placed on baking oven
In 50 DEG C of baking 2h；2.5 parts of oxalic acid are weighed again and 3.5 parts of zinc chloride are each configured to saturated solution, by oxalic acid and zinc chloride
Aqueous solution is mixed, and 30min is sufficiently stirred, after mixture stood into 40min, then deionized water is sufficiently washed to no chloride ion
In the presence of, after be placed in 120 DEG C of baking ovens dry 2-4h obtain zinc chloride product；By the precursor mixture and zinc chloride product after drying
It is placed in reactor 4 parts of sulfuric acid of addition sufficiently to react, rear taking-up product cleaning, which is sufficiently placed in dismembyator, grinds, and is placed on Muffle
Process the 2h that burns for 600 DEG C in furnace, after toast burnt obtain nano silver-zinc oxide composites preparation method without taking out cooling, grinding.
Preferably, the preparation method is as follows:
(1) first by 46 parts of nitrocellulose particle, 5 parts of carboxymethyl chitosan, 15 parts of epoxidized soybean oil, 16 parts of sodium alginate
70 DEG C of heating of heating in deionized water are added to be sufficiently mixed, 7.5 parts of polyglyceryl fatty acid ester, castor are added in backward mixture suspension
11 parts of sesame oil hydrogenated mixture, 10 parts of glycerin monostearate, are first heated to 90 DEG C, object to be mixed is dissolved and is cooled to room temperature
It grinds and stirs evenly in the grinding machine that revolving speed is 500rpm/min, rear taking-up distills 2h in 80 DEG C of boilers and obtains mixture I；
(2) by step 1 gained mixture I and 7 parts of polymer alumina, 12 parts of terpene resin, 6 parts of zeolite powder, straw powder 7
15 parts of part, 13 parts of lysozyme, nano silver-zinc oxide composites addition mixed at high speed are opened in mixing machine, and 2000rpm/min stirring is mixed
It closes uniform；
It is (3) rear to be added in refiner by material is added in fluid-flywheel clutch and mixes after mixing in step 2,
Refine repeatedly refines material, to obtain insect-proof agent matrix；
(4) by 6 parts of insect-proof agent matrix obtained in step 3 and plant extraction liquid, 8 parts of potassium sorbate in 50 DEG C of high-speed stirreds
Lower dissolution is simultaneously uniformly mixed, in microwave frequency be microwave treatment 15min under 2450MHz, power 800w, after mixing up to object
Material II；
(5) 8.5 parts of glycerol, 9 parts of corn syrup are added in 5 times of 0.1-0.5% sodium bicarbonate solutions, are stored at room temperature 4h
It makes it dissolve uniformly, is uniformly mixed in 50 DEG C of condition high-speed stirreds, at microwave frequency is microwave under 2450MHz, power 800w
15min is managed, after mixing up to material II；
(6) material I and material II are mixed, is warming up to 50 DEG C and 15min is sufficiently stirred, added acid or alkaloid substance adjusts PH
For value to 7.0, then 30 DEG C of insulated and stirred 25min of 500rpm/min, the rear room temperature that stands is cooling, obtains mixed solution；By mixed material
Mixing 15min in mixer is added, various shape straw mat insect-proof agent is prepared into after the material after mixing is put into granulator, after
Straw mat insect-proof agent is packaged into non-woven fabrics, is used to mat.
To experiment investigation is carried out respectively in embodiment provided by the invention, by embodiment 1 and the made straw mat insect prevention of embodiment 2
Agent is investigated, and is investigated as shown in table 1, is detected according to LYT2062-2012；
1 straw mat insect-proof agent of table investigates result
From the above detection method and testing result: the present invention prepares straw mat insect-proof agent and does not sell on the market, and
Straw mat is frequently encountered in life to place the summer, there is mould, worm etc. when in use, so raw using insect-proof agent prevention straw mat when placing
Worm reduces harm；Straw mat insect-proof agent the selection of material prepared by the present invention is safe and non-toxic, and no pollution to the environment is corrosion-free to straw mat
Effect, when straw mat when not in use rolls straw mat folding, straw mat insect-proof agent is placed among interlayer, and can be placed into makes in next season
With preceding, straw mat cleaned primary using preceding, straw mat insect-proof agent is long-lasting use, can prevent acarid, damp worm etc..
The above shows and describes the basic principles and main features of the present invention and the advantages of the present invention.The technology of the industry
Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the above embodiments and description only describe this
The principle of invention, without departing from the spirit and scope of the present invention, various changes and improvements may be made to the invention, these changes
Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its
Equivalent thereof.
Claims (4)
1. a kind of straw mat insect-proof agent, which is characterized in that there is the raw material of following parts by weight to be made:
3-56 parts of nitrocellulose particle, 5-15 parts of carboxymethyl chitosan, 15-30 parts of epoxidized soybean oil, sodium alginate 15-30
Part, 5-40 parts of plant extraction liquid, 2-10 parts of polyglyceryl fatty acid ester, 2-31 parts of castor oil hydrogenated mixture, glycerol monostearate
2-10 parts of ester, 2-10 parts of polymer alumina, 5-20 parts of terpene resin, 2-10 parts of zeolite powder, 2-10 parts of straw powder, lysozyme 5-20
Part, nano silver -3-45 parts of zinc oxide composites, 2-10 parts of potassium sorbate, 2-8 parts of glycerol, 2-10 parts of corn syrup, deionized water
10-100 parts.
2. straw mat insect-proof agent according to claim 1, it is characterised in that: wherein the castor oil hydrogenated mixture is by castor-oil plant
Oil modification forms, method of modifying are as follows: 3-5 parts of turpentine oil, 2-3 parts of cation polypropylene acyls are added into 15-20 parts of castor oil
Amine and 0.5-1 parts of polydimethyl diallyl ammonium chloride, after being sufficiently mixed under microwave frequency 2450MHz, power 700W microwave
5min is handled, 1-2 parts of rilanit specials, 0.5-1 parts of kayexalates and 0.5-1 parts of N methyldiethanol amines are added,
Continue microwave treatment 5min after mixing, be transferred in 10-100 DEG C of biochemical reaction device immediately after microwave treatment seal it is quiet
Set 3h, be then heated to 50-130 DEG C of heat preservation mixing 15min, pressurization keeps 1-10h more than 10 atmospheric pressure, after be depressurized to often
6-30 parts of 0-5 DEG C of cold water are added into gained mixture, 1h is stood after being sufficiently mixed for pressure, are then heated to reflux state heat preservation
30min, and cooled to room temperature are mixed, gained is castor oil hydrogenated mixture after cooling.
3. straw mat insect-proof agent according to claim 2, it is characterised in that: the nano silver-zinc oxide composites preparation side
Method, preparation method method are as follows: take obtained in 1-5 parts of 1mol/LAgCl10-50ml and 2-6 parts of polyvinyl alcohol and reaction unit it is molten
Liquid I；It measures 2mol/LNaOH 5-20ml to be added in solution I, ageing 1-6h, which sufficiently reacts, obtains precursor；By preceding step precursor
Mixture solution filtering, precipitating are used distilled water flushing 2-6 times, and precipitating, which is washed, is placed on 40-80 DEG C of baking 2-6h in baking oven；It weighs again
2-4 parts of oxalic acid and 2-5 parts of zinc chloride are each configured to saturated solution, the aqueous solution of oxalic acid and zinc chloride are mixed, sufficiently
Stir 30-60min, after mixture stood into 30-80min, then deionized water sufficiently wash to the presence of no chloride ion, after be placed in
2-4h is dried in 100-120 DEG C of baking oven obtains zinc chloride product；By after drying precursor mixture and zinc chloride product be placed in reaction
Device is added 1-4 parts of sulfuric acid and sufficiently reacts, and rear taking-up product cleaning, which is sufficiently placed in dismembyator, grinds, and is placed in Muffle furnace
600 DEG C are processed the 2-4h that burns, after toast burnt obtain nano silver-zinc oxide composites preparation method without taking out cooling, grinding.
4. straw mat insect-proof agent according to claim 3, it is characterised in that: it is preferred, the preparation method is as follows:
(1) first by 3-56 parts of nitrocellulose particle, 50-150 parts of carboxymethyl chitosan, 15-30 parts of epoxidized soybean oil, alginic acid
40-80 DEG C of heating is heated in 15-30 parts of addition deionized waters of sodium to be sufficiently mixed, and polyglycereol fat is added in backward mixture suspension
2-10 parts of acid esters, 2-31 parts of castor oil hydrogenated mixture, 2-10 parts of glycerin monostearate, are first heated to 80-180 DEG C, to mixed
Conjunction object, which dissolves and is cooled to room temperature to grind in the grinding machine that revolving speed is 100-500rpm/min, to stir evenly, rear to take out in 50-120
Distillation 1-12h obtains mixture I in DEG C boiler；
(2) by step 1 gained mixture I and polymer alumina 2-10 parts, 5-20 parts of terpene resin, 2-10 parts of zeolite powder, stalk
2-10 parts of powder, 5-20 parts of lysozyme, nano silver -3-45 parts of zinc oxide composites addition mixed at high speed are opened in mixing machine, 1000-
3000rpm/min is uniformly mixed；
(3) rear to be added in refiner by material is added in fluid-flywheel clutch and mixes after mixing in step 2, it carries out
Refining repeatedly refines material, to obtain mould inhibitor matrix；
(4) by 5-40 parts of mould inhibitor matrix obtained in step 3 and plant extraction liquid, 2-10 parts of potassium sorbate in 30-50 DEG C of height
It dissolves and is uniformly mixed under speed stirring, be microwave treatment 10-30min under 2450MHz, power 800w in microwave frequency, mixing is equal
Up to material II after even；
(5) 2-8 parts of glycerol, 2-10 parts of corn syrup are added in 5 times of 0.1-0.5% sodium bicarbonate solutions, are stored at room temperature 1-
It makes it dissolve uniformly, is uniformly mixed in 30-50 DEG C of condition high-speed stirred for 24 hours, in microwave frequency under 2450MHz, power 800w
Microwave treatment 10-30min, after mixing up to material II；
(6) material I and material II are mixed, is warming up to 40-60 DEG C and 15-60min is sufficiently stirred, added acid or alkaloid substance is adjusted
For pH value to 5.5-7.5, then 100-500rpm/min 20-40 DEG C insulated and stirred 20-40min, the rear room temperature that stands is cooling, is mixed
Close solution；Mixing 10-30min in mixer is added in mixed material, is prepared into after the material after mixing is put into granulator
Various shape straw mat insect-proof agent, after straw mat insect-proof agent is packaged into non-woven fabrics, to mat use.
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| CN201710713771.9A CN109397458B (en) | 2017-08-18 | 2017-08-18 | Straw mat insect-resist agent |
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| CN201710713771.9A CN109397458B (en) | 2017-08-18 | 2017-08-18 | Straw mat insect-resist agent |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1772375A (en) * | 2005-10-27 | 2006-05-17 | 南京大学 | Nanometer doped zinc oxide and its prepn and application in photocatalysis to degrade organic matter and kill bacteria |
| CN104824059A (en) * | 2015-04-14 | 2015-08-12 | 柳培健 | Pest-preventing agricultural mulch plastic film additive |
| CN105836264A (en) * | 2016-04-29 | 2016-08-10 | 安徽巢湖南方膜业有限责任公司 | Inner-layer plastic film of instant noodle packaging bowl |
| CN105885166A (en) * | 2016-04-29 | 2016-08-24 | 安徽巢湖南方膜业有限责任公司 | Plastic inner film of rice packaging bag |
| CN106380936A (en) * | 2016-11-04 | 2017-02-08 | 南平博士达节能科技有限公司 | Water-based nanometer color paste for synthetic leather coating agent and preparation method thereof |
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2017
- 2017-08-18 CN CN201710713771.9A patent/CN109397458B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1772375A (en) * | 2005-10-27 | 2006-05-17 | 南京大学 | Nanometer doped zinc oxide and its prepn and application in photocatalysis to degrade organic matter and kill bacteria |
| CN104824059A (en) * | 2015-04-14 | 2015-08-12 | 柳培健 | Pest-preventing agricultural mulch plastic film additive |
| CN105836264A (en) * | 2016-04-29 | 2016-08-10 | 安徽巢湖南方膜业有限责任公司 | Inner-layer plastic film of instant noodle packaging bowl |
| CN105885166A (en) * | 2016-04-29 | 2016-08-24 | 安徽巢湖南方膜业有限责任公司 | Plastic inner film of rice packaging bag |
| CN106380936A (en) * | 2016-11-04 | 2017-02-08 | 南平博士达节能科技有限公司 | Water-based nanometer color paste for synthetic leather coating agent and preparation method thereof |
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Denomination of invention: A straw mat insect repellent Effective date of registration: 20210915 Granted publication date: 20210413 Pledgee: Funan SME financing Company limited by guarantee Pledgor: FUNAN RUNYANG HOME FURNISHING Co.,Ltd. Registration number: Y2021980009445 |