CN109395543A - Soaking type exhaust gas separating treatment system and method - Google Patents

Soaking type exhaust gas separating treatment system and method Download PDF

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Publication number
CN109395543A
CN109395543A CN201811651726.6A CN201811651726A CN109395543A CN 109395543 A CN109395543 A CN 109395543A CN 201811651726 A CN201811651726 A CN 201811651726A CN 109395543 A CN109395543 A CN 109395543A
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China
Prior art keywords
exhaust gas
water
micro
sink
nozzle
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CN201811651726.6A
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Chinese (zh)
Inventor
吴正新
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Guangdong Wate Soil Remediation Research Center Co Ltd
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Guangdong Wate Soil Remediation Research Center Co Ltd
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Priority to CN201811651726.6A priority Critical patent/CN109395543A/en
Publication of CN109395543A publication Critical patent/CN109395543A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/18Absorbing units; Liquid distributors therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1487Removing organic compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/78Treatment of water, waste water, or sewage by oxidation with ozone
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/18Nature of the water, waste water, sewage or sludge to be treated from the purification of gaseous effluents

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Treating Waste Gases (AREA)

Abstract

The present invention provides a kind of soaking type exhaust gas separating treatment system and methods, wherein the system comprises sink, air-introduced machine, connecting tube, air hose, being located on air hose and the outwardly extending branch pipe with nozzle and the micro-nano ozone devices being arranged in outside sink.Soaking type exhaust gas separating treatment system and method for the present invention, by by exhaust gas diffusion into water in such a way that immersion form and nozzle are broadcasted, the exhaust gas bubble to differ in size is diffused into water, again with micro-nano bubble formation bubble layer ozoniferous by exhaust gas bubble residence in water, enable the organic solvent in ozone and exhaust gas mutually adsorb and react decomposition after discharge.It realizes and processing is efficiently separated to exhaust gas.It is at low cost, it is suitable for large-scale, small-scale workshops.

Description

Soaking type exhaust gas separating treatment system and method
Technical field
The present invention relates to water-treatment technology field more particularly to a kind of soaking type exhaust gas separating treatment system and methods.
Background technique
A variety of different waste organic solvent gas can be often generated in many industrial production links.These organic exhaust gas need into It just can be with normal discharge after the processing such as row absorption, filtering, purification.
However, the benzene series organic exhaust gas such as huge number of organic exhaust gas, such as formaldehyde organic exhaust gas, benzene toluene dimethylbenzene, Acetone butanone organic exhaust gas, ethyl acetate organic exhaust gas, mist of oil organic exhaust gas, furfural, resin, coating cloud organic exhaust gas etc..It is above-mentioned The treatment process of these exhaust gas, largely use eluting column concept, i.e., in washing water acid adding or add alkali it is organic molten to reduce The exhaust gas of agent discharges.
But as waste gas emission standard is higher and higher, chemical component, solvent, dust in exhaust gas, even heavy metal from Son reuses traditional eluting column spray mode, and especially small-sized eluting column, it is impossible to meet needs, in addition, traditional Eluting column spray mode also need huger volumetric spaces, and its purification efficiency has been approached the limit to a certain extent, because This traditional eluting column processing mode has no longer adapted to current exhaust-gas treatment needs.
Summary of the invention
For this purpose, the technical problems to be solved by the present invention are: provide a kind of soaking type exhaust gas separating treatment system and method, Realization efficiently separates processing to exhaust gas.It is at low cost, it is suitable for large-scale, small-scale workshops.
Then, the present invention provides a kind of soaking type exhaust gas separating treatment systems, comprising: sink, air-introduced machine, connecting tube, The air hose for being located at sink underwater that connect with connecting tube is located on air hose and the outwardly extending branch pipe with nozzle, Yi Jishe The micro-nano ozone devices outside sink are set, air-introduced machine introduces exhaust gas into air hose by connecting tube, and air hose passes through again on its branch pipe For the nozzle of connection by exhaust gas diffusion into water, sink bottom portion is equipped with an aqueduct, the water in sink is introduced into micro-nano smelly Micro-nano ozone bubbles are injected in oxygen equipment and into the water being introduced into, and the water containing micro-nano ozone bubbles is drawn by water pipe again It returns in sink, and is diffused into water by the nozzle on water pipe.
Wherein, the nozzle is spiral nozzle.
The sink has chimney, and air-introduced machine is located at the other side of sink chimney, and air hose extends to chimney side, branch pipe with Air hose is at obtuse angle.
The aqueduct is arranged in sink chimney side bottom end.
It is additionally provided with a skirt in the micro-nano ozone devices, the exhaust gas which spreads in the sink water surface towards sink Direction of travel sprays the water containing micro-nano ozone bubbles in micro-nano ozone devices.
The present invention also provides a kind of soaking type exhaust gas method for separating and processing, comprising:
Exhaust gas is passed sequentially through into air-introduced machine, the air hose for being located at sink underwater connecting with air-introduced machine, is located on air hose and is outside The branch pipe with nozzle extended is by exhaust gas diffusion into water;
Water in sink is introduced into micro-nano ozone devices by the aqueduct that sink bottom portion is equipped with, and to the water of introducing The middle micro-nano ozone bubbles of injection;
The water of the micro-nano ozone bubbles contained in micro-nano ozone devices is led back in screw clamp using water pipe, and passes through water Nozzle on pipe is diffused into water.
Wherein, the nozzle is spiral nozzle.
The sink has chimney, and air-introduced machine is located at the other side of sink chimney, and air hose extends to chimney side, branch pipe with Air hose is at obtuse angle.
The aqueduct is arranged in sink chimney side bottom end.
The above method further include: by the water of the micro-nano ozone bubbles contained in the micro-nano ozone devices by being located at After a skirt in micro-nano ozone devices is drawn, the exhaust gas direction of travel injection towards the diffusion of the sink water surface.
Soaking type exhaust gas separating treatment system and method for the present invention, by by exhaust gas diffusion into water in the form of soaking Mode is broadcasted with nozzle, diffuses into the exhaust gas bubble to differ in size, then in water with micro-nano bubble formation bubble ozoniferous Layer in water, discharges exhaust gas bubble residence after so that the organic solvent in ozone and exhaust gas is mutually adsorbed and reacting decomposition. It realizes and processing is efficiently separated to exhaust gas.It is at low cost, it is suitable for large-scale, small-scale workshops.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of soaking type exhaust gas separating treatment system described in the embodiment of the present invention.
Specific embodiment
In the following, in conjunction with attached drawing, the present invention will be described in detail.
As shown in Figure 1, present embodiments providing a kind of soaking type exhaust gas separating treatment system 10.Positioned at the useless of arrow 12 Gas introduces sink 16 by air-introduced machine 14 through connecting tube 15.16 preliminary infusion of sink is to scheduled water level line 18.In sink 16 Air hose 20 extends below out multiple branch pipes in water level line 18, and the branch pipe 22 of example as shown in figure 1 is one of branch pipe.Each branch pipe On have one or more nozzles, such as nozzle 24 is located at one end of branch pipe 22.
The air force of air-introduced machine 14 is depended primarily in the quantity of underwater placement nozzle, to overcome hydraulic pressure, air inducing Machine 14 generallys use medium-pressure or high pressure blower.So importing the exhaust gas in sink 16 by air-introduced machine 14, it is distributed to through air hose 20 more A branch pipe, then by the nozzle of each branch pipe in exhaust gas diffusion to water, and is not dissolved in the exhaust gas of water section, via the expansion of nozzle 24 It dissipates, with the exhaust gas bubble form to differ in size, is distributed to the water surface or less.
The tail end of sink 16 connects an aqueduct 26 and injects micro-nano ozone after water is guided to micro-nano ozone devices 28 Bubble.Micro-nano bubble refers to bubble diameter in 100 microns of micro-bubbles below.Bubble includes ozone, oxygen and other gas Body.After equipment 28 adds the water of micro-nano ozone bubbles, by the other end of the reflux screw clamp 16 of water inlet pipe 30, then via nozzle 32 are diffused into water containing micro-nano ozone gas is soaked.
The micro-nano ozone bubbles generated by micro-nano ozone devices 28, spread in water via nozzle 32, if micro-nano The size of bubble is close to a hundred nano-scale, and the bubble of a large scale will be gradually reduced volume, and finally be dissolved in water.If micro- The size of nano bubble is near or above micron-sized, it will slowly float under the action of buoyancy, then close to the water surface Place forms one layer of bubble layer 34 by many micro-bubbles.Because of the surface polarized of ozone gas vacuolar membrane, between each bubble or gas Mutual absorption between bubble and water surface forms one layer of stable bubble layer 34.
Water surface makes the pollutant in water due to the formation of bubble layer 34, particular for not being hydrophilic pollutant, compared with Not readily disengage from water body.When organic pollutant touches bubble layer 34, more increase and ozone contact chance, via and ozone Reaction carrys out decomposing organic pollutant.
For example, it in domestic waste, other than food waste, more or less also has in some industrial production links often The waste seen.During garbage harmless heating, drying, other than generating general food waste hydrocarbon and steam, also Various different degrees of industrial organic exhaust gas ingredients may be generated.However the huge number of organic exhaust gas, such as: construction waste Aldehydes residue-formaldehyde organic exhaust gas, the organic exhaust gas such as benzene class remanent-benzene toluene dimethylbenzene, ketone remanent-acetone fourth Ketone organic exhaust gas, esters of gallic acid residue-ethyl acetate organic exhaust gas, other are also possible to mist of oil organic exhaust gas, furfural, resin, paint Mist organic exhaust gas etc..These above-mentioned organic exhaust gas, although the few traditional eluting column processing of amount is difficult, because many organic molten The exhaust gas of agent is hydrophobicity.
Immersion form and nozzle 24 diffusion that exhaust gas is conveyed in sink by blower 14 are broadcasted, and size is diffused into water Not equal exhaust gas bubble.The water circulation in sink 16 each outer is filled by what micro-nano ozone devices 28 made in entire sink simultaneously Full micro-nano bubble.
The water surface of the micro-nano bubble in sink based on ozone forms bubble layer 34, and the various compositions of exhaust gas are detained In water.If the organic principle in exhaust gas is hydrophilic, it will be apparent that it can be soluble in water, and have an opportunity with it is smelly in water Oxygen or hydroxyl and gradually decompose.If the organic principle in exhaust gas be it is hydrophobic, herein at separating before water and bubble layer 34 It meets, because of micro-nano ozone bubbles polarized, via the attracting characteristic of electrostatic, hydrophobic organic principle is attracted to bubble layer On, then just have an opportunity in multiple times with ozone or hydroxyl reaction and gradually decompose.
In Fig. 1, exhaust gas enters sink 16 via air hose 20, is diffused into water through nozzle.When exhaust gas contact water, part is molten Aqueous or hydrophilic substance is dissolved in water, remaining exhaust gas forms bubble not of uniform size in water, most formation Centimeter Level is to millimetre-sized bubble.However the size of one millimeter of bubble and 100 micron bubbles differs about 10 times, one centimetre of bubble About 100 times are differed with the size of 100 micron bubbles.And the size of exhaust gas bubble, largely, depending on setting for nozzle 24 Meter.The design of good nozzle 24 size difference of exhaust gas bubble and microbubble can be maintained tens of to hundreds times it Between, preferred range is between 10 to 500 times.
The design of nozzle 24 can be the general nozzle for using pin, but pin hole is easy to be blocked, and preferred nozzle is Spiral nozzle.Spiral nozzle has spiral helicine structure at water out, so when water leaves from nozzle exit, it can lasing Strike in sped structure and four dissipate, this makes any bubble after leaving exit, and lasing strike is in sped structure, after four dissipate Minute bubbles are formed, a part forms Centimeter Level bubble, and a part forms grade bubble.
When exhaust gas bubble 36 buoyancy promotion thus float, and with bubble layer 34 contact.Because of the pole on ozone bubbles surface Property act on 36 surface of exhaust gas bubble, be easy to make exhaust gas bubble 36 to rupture ahead of time, the floating of exhaust gas bubble 36 can be reduced in this way Power, and reduce the disengaging of the organic substance in exhaust gas or heavy metal.
In organic pollutant in exhaust gas bubble 36, if containing hydrophilic composition can very quickly with ozone or hydroxyl Reaction.And these organic pollutants are in the path of floating and ozone or hydroxyl contact can accelerate the oxidation of pollutant It decomposes.If containing benzene in organic pollutant, due to the hydrophobicity of benzene, benzene is easily separated from the water surface, and bubble layer 34 can stop benzene The surface deviation of class.Some benzene classes are immersed in water, some benzene classes may adhere to the micro-bubble surface in bubble layer 34.This Sample just allows benzene class to have an opportunity between ozone or hydroxyl, multiple impacts, and then stable benzene ring structure is disassembled.
In Fig. 1, it is detached from the exhaust gas of the sink water surface, is advanced according to direction indicated by arrow 40, nozzle 42 advances in exhaust gas Path on opposite direction spray droplet 44.Nozzle 42 is soaked with the micro-nano ozone gas from micro-nano ozone devices 28.Droplet 44 because of the polarity containing ozone bubbles, so advantageous in the former pollutant being detached from water surface exhaust gas of absorption.Droplet 44 falls back to Ozone bubbles, which can help, when water surface bubble layer 34, in bubble layer 34 decomposes the pollutant of the absorption of droplet 44.
So exhaust gas after the immersion mode of leading portion is handled, is adsorbed in gas phase in a manner of elution again when being detached from the water surface Pollutant, and decomposing pollutant is helped when eluting droplet and dropping back into the water surface, then with the ozone bubbles of water surface arrangement.
Exhaust gas enters folded plate area 48 after the elution operation of nozzle 42, by channel, is to make exhaust gas with tortuous side Formula is advanced, through arrow 50,52,54.In the process of advance, excluded on spacing board droplet is adhered in exhaust gas.Finally give up Gas is discharged into the atmosphere of surrounding via chimney 56.
Exhaust gas is contained in folded plate area 48 with the cost of air loss by tortuous channel to reduce steam therein It measures, the spacing board in extra droplet and folded plate area 48 contacts and is detained, and remaining exhaust gas continues to move ahead to the direction of chimney 56.
It is to sum up sayed, the exhaust gas containing organic solvent, via the push of the air-introduced machine 14 of medium-pressure or high pressure, immerses sink 16 After the water surface, exhaust gas bubble 36 is formed in a manner of lasing strike via preferred spiral nozzle 24, a part forms Centimeter Level Bubble, a part form grade bubble, diffusion profile Yu Shuili.Water a part of in sink 16 is set through micro-nano ozone simultaneously After standby 28, micro-nano ozone bubbles are injected, are flowed back in screw clamp 16.This makes to be filled with micro-nano ozone bubbles in sink 16, special It is not to be formed about a bubble layer 34 in water surface.Bubble layer 34 can prevent the disengaging water surface of organic pollutant, and one Determine in degree, the ozone on bubble layer 34 can help the oxygenolysis of organic pollutant.
This immersion mode, can collect in sink 16 aldehydes, esters, alcohols and the heavy metal etc. in pollutant. Benzene class can rest on benzene class in the bubble layer 34 of the water surface containing ozone bubbles smelly although benzene class has hydrophobicity On oxygen bubbles, allow in this way it is organic between ozone and benzene class will do it collision, and benzene ring structure is opened.
It is detached from the exhaust gas of the water surface, is eluted using the droplet containing micro-nano ozone, the former dirt being detached from water surface exhaust gas is adsorbed Object is contaminated, falls back to and carries out oxygenolysis in the bubble layer 34 of the water surface again, the exhaust gas being then detached from through the mode of tortuous passageway, subtracts again Droplet in few remainder of exhaust gas, is discharged into atmosphere.
Using above-mentioned soaking type exhaust gas separating treatment system 10, the present embodiment is additionally provided at a kind of soaking type exhaust gas separation Reason method, comprising:
Exhaust gas is passed sequentially through into air-introduced machine, the air hose for being located at sink underwater connecting with air-introduced machine, is located on air hose and is outside The branch pipe with nozzle extended is by exhaust gas diffusion into water;
Water in sink is introduced into micro-nano ozone devices by the aqueduct that sink bottom portion is equipped with, and to the water of introducing The middle micro-nano ozone bubbles of injection;
The water of the micro-nano ozone bubbles contained in micro-nano ozone devices is led back in screw clamp using water pipe, and passes through water Nozzle on pipe is diffused into water.
And the above method further include: lead to the water of the micro-nano ozone bubbles contained in the micro-nano ozone devices After crossing the skirt extraction being located in micro-nano ozone devices, the exhaust gas direction of travel injection towards the diffusion of the sink water surface.
In conclusion soaking type exhaust gas separating treatment system and method described in the present embodiment, by by exhaust gas diffusion to water In in such a way that immersion form and nozzle are broadcasted, diffuse into the exhaust gas bubble to differ in size, then in water with ozoniferous micro-nano Exhaust gas bubble residence in water, is enable the organic solvent in ozone and exhaust gas mutually to adsorb and react by bubble formation bubble layer It is discharged after decomposition.It realizes and processing is efficiently separated to exhaust gas.It is at low cost, it is suitable for large-scale, small-scale workshops.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention Within mind and principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.

Claims (10)

1. a kind of soaking type exhaust gas separating treatment system, which is characterized in that connect including sink, air-introduced machine, connecting tube and connecting tube The air hose for being located at sink underwater that connects is located on air hose and the outwardly extending branch pipe with nozzle and is arranged outside sink Micro-nano ozone devices, air-introduced machine introduces exhaust gas into air hose by connecting tube, and air hose passes through the nozzle connected on its branch pipe again By exhaust gas diffusion into water, sink bottom portion is equipped with an aqueduct, and the water in sink is introduced into micro-nano ozone devices simultaneously Micro-nano ozone bubbles are injected into the water being introduced into, and the water containing micro-nano ozone bubbles is passed through into water pipe again and leads back screw clamp In, and be diffused into water by the nozzle on water pipe.
2. soaking type exhaust gas separating treatment system according to claim 1, which is characterized in that the sink has chimney, Air-introduced machine is located at the other side of sink chimney, and air hose extends to chimney side, and branch pipe and air hose are at obtuse angle.
3. soaking type exhaust gas separating treatment system according to claim 2, which is characterized in that the aqueduct is arranged in water Slot chimney side bottom end.
4. soaking type exhaust gas separating treatment system according to claim 1, which is characterized in that the nozzle is spiral spray Mouth.
5. soaking type exhaust gas separating treatment system according to any one of claims 1 to 4, which is characterized in that described A skirt is additionally provided in micro-nano ozone devices, the skirt is micro- in the exhaust gas direction of travel injection that the sink water surface is spread towards sink The water containing micro-nano ozone bubbles in nanometer ozone devices.
6. a kind of soaking type exhaust gas method for separating and processing characterized by comprising
Exhaust gas is passed sequentially through into air-introduced machine, the air hose for being located at sink underwater connecting with air-introduced machine, is located on air hose and is outside The branch pipe with nozzle extended is by exhaust gas diffusion into water;
Water in sink is introduced into micro-nano ozone devices by the aqueduct that sink bottom portion is equipped with, and to the water of introducing The middle micro-nano ozone bubbles of injection;
The water of the micro-nano ozone bubbles contained in micro-nano ozone devices is led back in screw clamp using water pipe, and passes through water Nozzle on pipe is diffused into water.
7. soaking type exhaust gas method for separating and processing according to claim 6, which is characterized in that the nozzle is spiral spray Mouth.
8. soaking type exhaust gas method for separating and processing according to claim 6, which is characterized in that the sink has chimney, Air-introduced machine is located at the other side of sink chimney, and air hose extends to chimney side, and branch pipe and air hose are at obtuse angle.
9. soaking type exhaust gas method for separating and processing according to claim 6, which is characterized in that the aqueduct is arranged in water Slot chimney side bottom end.
10. according to soaking type exhaust gas method for separating and processing described in claim 6 to 9 any one, which is characterized in that will be described The water of the micro-nano ozone bubbles contained in micro-nano ozone devices is drawn by the skirt being located in micro-nano ozone devices Afterwards, towards the exhaust gas direction of travel injection of sink water surface diffusion.
CN201811651726.6A 2018-12-31 2018-12-31 Soaking type exhaust gas separating treatment system and method Pending CN109395543A (en)

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CN116899388A (en) * 2023-07-12 2023-10-20 湖南九九智能环保股份有限公司 Micro-nano ozone bubble treatment VOCs integrated reaction device and method

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Application publication date: 20190301