CN208130835U - Micro-nano bubble cooperates with photoelectrocatalysis exhaust treatment system - Google Patents
Micro-nano bubble cooperates with photoelectrocatalysis exhaust treatment system Download PDFInfo
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- CN208130835U CN208130835U CN201820117366.0U CN201820117366U CN208130835U CN 208130835 U CN208130835 U CN 208130835U CN 201820117366 U CN201820117366 U CN 201820117366U CN 208130835 U CN208130835 U CN 208130835U
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- 238000006243 chemical reaction Methods 0.000 claims abstract description 16
- 230000000740 bleeding effect Effects 0.000 claims abstract description 12
- 238000010992 reflux Methods 0.000 claims abstract description 8
- 239000000945 filler Substances 0.000 claims abstract description 5
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- 238000009287 sand filtration Methods 0.000 claims description 12
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- 239000001301 oxygen Substances 0.000 description 3
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- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 2
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Abstract
A kind of micro-nano bubble collaboration photoelectrocatalysis exhaust treatment system, including:Tangential air inlet cyclone, has ejection air port, refluxing opening and tangent air inlet;Air hose;The bottom interface connects the ejection air port;Micro-nano bubble reaction unit tower has lower air inlet, filler demisting layer and upper air outlet;First shell is connected between the top interface and the lower air inlet;Anion generation system connects the anion inlet of the air hose side wall;Micro-nano bubble generation system connects the micro-nano bubble inlet of the air hose side wall;Extract system connects the bleeding point of the air hose side wall;Electric light-catalyzed reaction and ion manipulation arrangement have side air inlet and side air-out mouth;Second shell connects the upper air outlet and the side air inlet.The micro-nano bubble collaboration photoelectrocatalysis exhaust treatment system can be improved treatment effect, and reduce processing cost.
Description
Technical field
The utility model relates to environment protection fields more particularly to a kind of micro-nano bubble to cooperate with photoelectrocatalysis exhaust-gas treatment system
System.
Background technique
Industrial waste gas has been always the important pollution sources since industrializing, and there are different journeys in many field of industrial production
The industrial gas emission amount of degree, such as oil plant, rubber plant, chemical plant, pharmaceutical factory, caused by air pollution at present
Paid attention to extensively, discharge becomes research hotspot after how purifying to industrial waste gas.
In industrial waste gas, the improvement of organic exhaust gas is to administer one of problem.The case where traditional VOCs treatment, technique are multiple
It is miscellaneous.If corresponding purification efficiency is not high, and treatment effect is bad using technique at low cost;If high using purification efficiency
Technique, corresponding operating cost is high, and early investment cost is also relatively high, cannot meet the demand of enterprise well.
Utility model content
The utility model solves the problems, such as to be to provide a kind of micro-nano bubble collaboration photoelectrocatalysis exhaust treatment system, so as to
More high-quality and high-efficiency organic exhaust gas can be handled.
To solve the above problems, the utility model provides a kind of micro-nano bubble collaboration photoelectrocatalysis exhaust-gas treatment system
System, including:Tangential air inlet cyclone, has ejection air port, refluxing opening and tangent air inlet;Air hose has bottom interface, top
Interface, anion inlet, micro-nano bubble inlet and bleeding point;The bottom interface connects the ejection air port;Micro-nano
Rice bubble reaction unit tower, has lower air inlet, filler demisting layer and upper air outlet;First shell is connected to the top and connects
Between mouth and the lower air inlet;Anion generation system connects the anion inlet of the air hose side wall;It is micro-nano
Bubble generation system connects the micro-nano bubble inlet of the air hose side wall;Extract system connects the air hose side wall
The bleeding point;Electric light-catalyzed reaction and ion manipulation arrangement have side air inlet and side air-out mouth;Second shell, connection
The upper air outlet and the side air inlet.
Optionally, the electric light-catalyzed reaction and ion manipulation arrangement include filter, electric light catalysis region and ion dress
It sets.
Optionally, there is barrier net between the electric light catalysis region and the ion unit.
Optionally, on the air hose side wall, the position of the micro-nano bubble inlet is injected higher than the anion
The position of mouth.
Optionally, on the air hose side wall, the position of the bleeding point is higher than the position of the micro-nano bubble inlet
It sets.
Optionally, the micro-nano bubble inlet includes the first inlet and the second inlet;In the air hose side wall
On, the position of second inlet is higher than the position of first inlet;The micro-nano bubble generation system includes the
One micro-nano air Bubble generating apparatus and the second micro-nano air Bubble generating apparatus;The first micro-nano air Bubble generating apparatus connects institute
The first inlet is stated, the second micro-nano air Bubble generating apparatus connects second inlet.
Optionally, the micro-nano bubble collaboration photoelectrocatalysis exhaust treatment system further include water circulating pump, sandfiltration pot and
Cyclic water tank, the refluxing opening connect the water inlet of the water circulating pump, and the water outlet of the water circulating pump connects the sand filtration
The water inlet of tank, the water outlet of the sandfiltration pot connect the water inlet of the cyclic water tank, and the water outlet of the cyclic water tank is same
When connect the water inlet of the anion generation system and the water inlet of the micro-nano bubble generation system.
Optionally, the air hose includes multiple pipelines arranged side by side.
Optionally, the bleeding point is set to the top side wall of the pipeline, and the extract system is axial flow blower.
Optionally, the first shell includes first level shell section, the second horizontal shell section and upright shell section;First water
Flat shell section connects the top interface;The second horizontal shell section connects the lower air inlet;Described in the upright shell section connection
First level shell section and the second horizontal shell section;There is the flow-stopping plate being obliquely installed, the flow-stopping plate in the first shell
Between the upright shell section and the second horizontal shell section, it is horizontal that the flow-stopping plate lower edge is located at described second for top edge
In shell section.
In the technical solution of the utility model, by the design of system, so that cooperateing with photoelectrocatalysis using micro-nano bubble
When exhaust treatment system, almost problem without secondary pollution, resource consumption is small, and greenhouse effects are low, and facility operation is reliable and stable, failure
Rate is extremely low, and maintenance is easy, and operating cost is low, and the waste disposal come out derived from treatment process is simple, and can handle a variety of has
Machine exhaust gas, thus the problem of having taken into account treatment effect and cost.
Detailed description of the invention
Fig. 1 is micro-nano bubble collaboration photoelectrocatalysis exhaust treatment system schematic diagram provided by the embodiment of the utility model.
Specific embodiment
Existing organic waste gas treatment system can not take into account the problem of cost and treatment effect well.
For this purpose, the utility model provides a kind of new micro-nano bubble collaboration photoelectrocatalysis exhaust treatment system, to improve
The clean-up effect of organic exhaust gas, while reducing corresponding processing cost.
More clearly to indicate, the utility model is described in detail with reference to the accompanying drawing.
The utility model embodiment provides a kind of micro-nano bubble collaboration photoelectrocatalysis exhaust treatment system, please refers to Fig. 1.
The micro-nano bubble collaboration photoelectrocatalysis exhaust treatment system include tangential air inlet cyclone 110, air hose 120,
Extract system 130, first shell 140, micro-nano bubble reaction unit tower 150, anion generation system 160, micro-nano bubble
Generation system (not marking), second shell 104 and electric light-catalyzed reaction and ion manipulation arrangement 190.
Tangential air inlet cyclone 110 has ejection air port (not shown), refluxing opening (not marking) and tangent air inlet 111.
Air hose 120 has bottom interface (not shown), top interface (not shown), anion inlet (not marking), micro-
Nano bubble inlet (not marking) and bleeding point (not shown).
The ejection air port of the tangential air inlet cyclone 110 of bottom interface connection of air hose 120, so that air hose
120 are located at tangential 110 top of air inlet cyclone, as shown in Figure 1.
Micro-nano bubble reaction unit tower 150 has lower air inlet (not shown), filler demisting layer 151 and upper air outlet
(not marking).
First shell 140 is connected to the top interface of air hose 120 and the lower air inlet of micro-nano bubble reaction unit tower 150
Between.
The anion inlet of connection 120 side wall of air hose of anion generation system 160.
The micro-nano bubble inlet of micro-nano bubble generation system (not marking) connection 120 side wall of air hose.
The bleeding point of connection 120 side wall of air hose of extract system 130.
Electric light-catalyzed reaction and ion manipulation arrangement 190 have side air inlet (not marking) and side air-out mouth (not marking).
Second shell 104 connect micro-nano bubble reaction unit tower 150 the upper air outlet and electric light-catalyzed reaction and
The side air inlet of ion manipulation arrangement 190.
In the present embodiment, micro-nano bubble inlet includes that the first inlet (not marking) and the second inlet (are not marked
Note).On 120 side wall of air hose, the position of the second inlet is higher than the position of the first inlet.The micro-nano bubble generates system
System includes the first micro-nano air Bubble generating apparatus 170 and the second micro-nano air Bubble generating apparatus 180.First micro-nano bubble generates
Device 170 connects the first inlet, and the second micro-nano air Bubble generating apparatus 180 connects the second inlet.
In the present embodiment, setting air hose 120 stands on tangential 110 top of air inlet cyclone, i.e., air hose 120 is set up vertically.
In other embodiments, air hose can also have one tilt angle.
In the present embodiment, air hose 120 includes 4 pipelines arranged side by side, due to showing two pipelines therein in Fig. 1 (not
Distinguish mark), other two pipeline due to just being blocked by two pipelines shown in FIG. 1, do not show.Air hose 120 includes
Multiple pipelines, the sectional area for facilitating each pipeline reduces, and then is more advantageous to and handles exhaust gas therein.Other implementations
In example, air hose may include multiple pipelines of other numbers arranged side by side.
In the present embodiment, the bleeding point of air hose 120 is set to the top side wall of the pipeline, and extract system 130 is
Axial flow blower is arranged in 120 top side wall of air hose.
In the present embodiment, first shell 140 include first level shell section (not marking), the second horizontal shell section (not marking) and
Upright shell section (not marking).The top interface of the first level shell section connection air hose 120.The second horizontal shell section connection is micro-
The lower air inlet of nano bubble reaction unit tower 150.The upright shell section connects the first level shell section and second water
Flat shell section, at this point, " Z " type is presented in entire first shell 140.In other embodiments, first shell is also possible to other shapes.
In the present embodiment, there is the flow-stopping plate 141 being obliquely installed, 141 top edge of flow-stopping plate is located at institute in first shell 140
It states between upright shell section and the second horizontal shell section, also, 141 lower edge of flow-stopping plate is located in the described second horizontal shell section,
I.e. flow-stopping plate 141 is tilted to the described second horizontal shell section, as shown in fig. 1.The setting of flow-stopping plate 141 enables to, and has
Before entering micro-nano bubble reaction unit tower 150, corresponding steam condenses into the gas of steam because encountering flow-stopping plate 141
Liquid water, to drip back into first shell 140, to reduce steam into subsequent micro-nano bubble reaction unit tower 150
In.
In the present embodiment, electric light-catalyzed reaction and ion manipulation arrangement 190 include filter 191, electric light catalysis region 192
With ion unit 193.
In the present embodiment, filter 191 can be high efficiency particulate air filter.
In the present embodiment, ion unit 193 specifically can be energetic ion device.Energetic ion body (i.e. plasma) is
4th state of the substance after solid-state, liquid, gaseous state exists centainly in all gas of the absolute temperature greater than zero
Ionization phenomena, any subtle ray and other energy may all make the molecule in gas accelerated and obtain energy, when its energy
When amount is higher than the ionization energy of gas, the collision between electron and molecule will lead to the ionization of the gas, generate including electronics, it is various from
Mixture including son, atom and free radical, i.e. plasma.It is generated inside energetic ion body and is rich in high chemically active grain
Son, such as electronics, ion, free radical and excited state molecule.Energetic ion body degradation of contaminant is using these high energy electrons, certainly
It is reacted by the pollutant in base isoreactivity particle and exhaust gas, contaminant molecule is made to decompose in a very short period of time, and
Subsequent various reactions occur, are eventually converted into CO2And H2The substances such as O, to achieve the purpose that purify exhaust gas.
There is barrier net 194 in the present embodiment, between electric light catalysis region 192 and ion unit 193.It is same to obstruct net 194
Sample has filtration.
In the present embodiment, second shell 104 includes two sections (not marking respectively), all has in two sections and is bent in an arc shape part.
In other embodiments, second shell is also possible to other shapes.
In the present embodiment, on 120 side wall of air hose, be arranged the micro-nano bubble inlet position be higher than it is described bear from
The position of sub- inlet, the position that the bleeding point is arranged can be in conjunction with reference higher than the position of the micro-nano bubble inlet
Shown in Fig. 1.Such set-up mode is conducive to corresponding exhaust gas and first passes through anion processing, handles using micro-nano bubble,
To be conducive to preferably handle exhaust gas.
With continued reference to FIG. 1, micro-nano bubble collaboration photoelectrocatalysis exhaust treatment system provided by the present embodiment also wraps
Include water circulating pump 101, sandfiltration pot 102 and cyclic water tank 103.The refluxing opening of tangential air inlet cyclone 110 connects recirculated water
The water inlet (not marking) of pump 101, to be conducive to the water that will be generated in tangential air inlet cyclone 110 by water circulating pump 101
Extraction.The water inlet (not marking) of water outlet (not marking) the connection sandfiltration pot 102 of water circulating pump 101, sandfiltration pot 102 will be corresponding
Water be filtered.The water inlet (not marking) of water outlet (not marking) the connection cyclic water tank 103 of sandfiltration pot 102, recirculated water
The water outlet (not marking) of case 103 while water inlet (not marking) and the production of micro-nano bubble for connecting anion generation system 160
The water inlet (not marking) of raw system.As it can be seen that the present embodiment directly utilizes cyclic water tank 103, while being supplied to two systems
Water simplifies system.
In micro-nano bubble collaboration photoelectrocatalysis exhaust treatment system provided in this embodiment, when exhaust gas (organic exhaust gas) into
After entering tangential air inlet cyclone 110, due to tangentially entering the wind 111 section of tangent air inlet of cyclone 110 much smaller than internal chamber
And the open-topped section (again smaller than the total cross section of each pipeline of air hose 120), therefore, the flow section of exhaust gas sharply increases
Greatly, exhaust gas wind speed decreased.At this point, the exhaust gas containing big grit (particulate matter) can be settled under the effect of gravity, and containing smaller
The exhaust gas (can also claim dusty gas) of particulate matter enters air hose 120.
During dusty gas is walked in air hose 120, anion generation system 160 is passed through anion.Anion produces
Raw 160 mesohigh of system atomization promotes the movement (anion generation system 160 usually has high voltage functionality) of water, makes the micro- of electrification
Small water droplet is split into that surface layer is negatively charged and internal layer is positively charged.Electronegative water droplet surface layer and atom or molecule combination in air,
Form anion.Heavier water droplet internal layer then sinks under the effect of gravity, thus can obtain a large amount of anion in air.
After smaller particle object and part organic gas micel in exhaust gas are coated by anion, settle down.
The exhaust gas for continuing uplink can be in conjunction with the micro-nano bubble for continuing injection in air hose 120, and micro-nano bubble is immediately right
Part organic exhaust gas carries out oxygenolysis.These micro-nano bubbles generate (micro-nano bubble production by micro-nano bubble generation system
Raw system is generally also integrated with the action function of high-pressure hydraulic pump).Micro-nano bubble is that generation diameter is micro- 50 when bubble occurs
Rice (μm) micro-bubble below, can also be micron bubble or nano bubble according to its diameter range respectively.Micro-nano bubble
After generation, bubble oneself is shunk, and in this process because bubble becomes small so the rate of climb is slowed by, causes to melt efficiency
It is high.Thawing efficiency is higher, and the energy of generation is bigger, is better able to interrupt the macromolecular chain of organic matter, this i.e. corresponding super oxygen
Change effect.And the micro-nano air Bubble generating apparatus of two-stage is used in the present embodiment, so that organic matter in exhaust gas more be made to decompose
More thoroughly.
And in 120 side wall of air hose, it is arranged corresponding axial flow blower (extract system 130), axial flow blower can will purify
Gas afterwards is passed to micro-nano bubble reaction unit tower 150, and the filler demisting layer 151 into tower, to remove water mist, then is discharged into
In atmosphere.
In above process, in air hose 120, anion generation system 160 and micro-nano bubble generation system are being handled
In the process, liquid water is all generated, remains pollutant component in these liquid waters, after returning to tangential air inlet cyclone 110,
It is first extracted by water circulating pump 101, the refluxing opening by tangentially entering the wind cyclone 110 is passed through water circulating pump 101, then by recirculated water
The water outlet of pump 101 is sent into the water inlet of sandfiltration pot 102.It is filtered by sandfiltration pot 102, clean water after filtering is entered
Cyclic water tank 103, then via cyclic water tank 103, it is supplied to anion generation system 160 and micro-nano bubble generation system, i.e.,
Clean water is returned again in processing equipment system.Therefore, corresponding system usually only needs periodic cleaning water tank.
After micro-nano bubble reaction unit tower 150, corresponding exhaust gas enters electric light catalysis instead from second shell 104
It answers and ion manipulation arrangement 190.
In electric light-catalyzed reaction and ion manipulation arrangement 190, exhaust gas first passes through filter 191, to go in removing exhaust gas
Coating cloud, and further remove steam.
Later, exhaust gas (organic exhaust gas) enters electric light catalysis region 192, by set in electric light catalysis region 192
The effect of UV lamp pipe is broken the chain structure under action of ultraviolet radiation of the macromolecular organic gas in exhaust gas, and then makes organic gas
Substance is converted into the small molecule compound or permineralization of odorless.
Hereafter, exhaust gas is after through barrier net 194, into ion unit 193.The purification system of ion unit 193 is adopted
With positive negative bipolar ionization technique, under electric field action, the ion generator in ion unit 193 generates a large amount of ion unit
Oxygen molecule in α particle, α particle and air is collided and forms positive negative oxygen ion.Positive oxonium ion has very strong oxidisability,
Can pollution factors such as oxygenolysis methyl mercaptan, ammonia and hydrogen sulfide in a very short period of time, and with volatile organic matter
After (volatile organic compounds, VOCs) molecule is in contact, the chemistry of volatile organic matter (gas) can be opened
Key ultimately generates carbon dioxide and water etc. after a series of reaction and stablizes harmless small molecule.Oxonium ion can destroy simultaneously
The living environment of bacterium in exhaust gas reduces bacterial concentration in exhaust gas.Charged ion can adsorb more than tens times of own wt
Suspended particulate settles down by self weight, so that the suspension colloid in scavenging, achievees the purpose that further to purify exhaust gas.Only
Exhaust gas after change can be emitted from the side air-out mouth of electric light-catalyzed reaction and ion manipulation arrangement 190.
In micro-nano bubble collaboration photoelectrocatalysis exhaust treatment system provided in this embodiment, anion high-pressure atomization is utilized
System (anion generation system 160) is combined with micro-nano air bubble apparatus (micro-nano bubble generation system), will be generated peculiar
Superoxides (super oxide, wherein super oxygen indicates super oxidation, and the reaction for passing through micro-nano bubble generates super oxidation
Effect) and active hydroxy (hydroxyl radical), these substance diameters are at 50 microns hereinafter, the specific surface of its own
Product is greatly, the rate of climb is slow, itself pressurization dissolution, surface electrification, can generate a large amount of free radicals, and it is huge to show energy instantaneous relase
Energy has strong oxidizing property.Later, it filters and purifies using electric light-catalyzed reaction and 190 further progress of ion manipulation arrangement,
To further increase the treatment effect of exhaust gas.
The design scheme and country's tradition of micro-nano bubble collaboration photoelectrocatalysis exhaust treatment system provided in this embodiment
VOCs treatment scheme thinking it is different, almost problem without secondary pollution, resource consumption is small, and greenhouse effects are low, facility operation
Reliable and stable, failure rate is extremely low, and maintenance is easy, and operating cost is low, and the waste disposal come out derived from treatment process is simple,
A variety of organic exhaust gas can be handled.
Although the utility model discloses as above, the utility model is not limited to this.Anyone skilled in the art,
It does not depart from the spirit and scope of the utility model, can make various changes or modifications, therefore the protection scope of the utility model
It should be defined by the scope defined by the claims..
Claims (10)
1. a kind of micro-nano bubble cooperates with photoelectrocatalysis exhaust treatment system, which is characterized in that including:
Tangential air inlet cyclone, has ejection air port, refluxing opening and tangent air inlet;
Air hose has bottom interface, top interface, anion inlet, micro-nano bubble inlet and bleeding point;
The bottom interface connects the ejection air port;
Micro-nano bubble reaction unit tower has lower air inlet, filler demisting layer and upper air outlet;
First shell is connected between the top interface and the lower air inlet;
Anion generation system connects the anion inlet of the air hose side wall;
Micro-nano bubble generation system connects the micro-nano bubble inlet of the air hose side wall;
Extract system connects the bleeding point of the air hose side wall;
Electric light-catalyzed reaction and ion manipulation arrangement have side air inlet and side air-out mouth;
Second shell connects the upper air outlet and the side air inlet.
2. micro-nano bubble as described in claim 1 cooperates with photoelectrocatalysis exhaust treatment system, which is characterized in that the electric light
Catalysis reaction and ion manipulation arrangement include filter, electric light catalysis region and ion unit.
3. micro-nano bubble as described in claim 1 cooperates with photoelectrocatalysis exhaust treatment system, which is characterized in that the electric light
There is barrier net between catalysis region and the ion manipulation arrangement.
4. micro-nano bubble as described in claim 1 cooperates with photoelectrocatalysis exhaust treatment system, which is characterized in that in the wind
On pipe side wall, the position of the micro-nano bubble inlet is higher than the position of the anion inlet.
5. micro-nano bubble as claimed in claim 4 cooperates with photoelectrocatalysis exhaust treatment system, which is characterized in that in the wind
On pipe side wall, the position of the bleeding point is higher than the position of the micro-nano bubble inlet.
6. micro-nano bubble as claimed in claim 5 cooperates with photoelectrocatalysis exhaust treatment system, which is characterized in that the micro-nano
Rice bubble inlet includes the first inlet and the second inlet;On the air hose side wall, the position of second inlet
Higher than the position of first inlet;The micro-nano bubble generation system includes the first micro-nano air Bubble generating apparatus and the
Two micro-nano air Bubble generating apparatus;The first micro-nano air Bubble generating apparatus connects first inlet, and described second is micro-
Nano bubble generation device connects second inlet.
7. micro-nano bubble as described in claim 1 cooperates with photoelectrocatalysis exhaust treatment system, which is characterized in that further include following
Ring water pump, sandfiltration pot and cyclic water tank, the refluxing opening connect the water inlet of the water circulating pump, the water outlet of the water circulating pump
Mouth connects the water inlet of the sandfiltration pot, and the water outlet of the sandfiltration pot connects the water inlet of the cyclic water tank, the circulation
The water outlet of water tank connects the water inlet of the anion generation system and the water inlet of the micro-nano bubble generation system simultaneously
Mouthful.
8. micro-nano bubble as described in claim 1 cooperates with photoelectrocatalysis exhaust treatment system, which is characterized in that the air hose
Including multiple pipelines arranged side by side.
9. micro-nano bubble as claimed in claim 8 cooperates with photoelectrocatalysis exhaust treatment system, which is characterized in that the pumping
Mouth is set to the top side wall of the pipeline, and the extract system is axial flow blower.
10. micro-nano bubble as described in claim 1 cooperates with photoelectrocatalysis exhaust treatment system, which is characterized in that described the
One shell includes first level shell section, the second horizontal shell section and upright shell section;The first level shell section connects the top and connects
Mouthful;The second horizontal shell section connects the lower air inlet;The upright shell section connects the first level shell section and described the
Two horizontal shell sections;There is the flow-stopping plate being obliquely installed, the flow-stopping plate top edge is located at the upright shell in the first shell
Between section and the second horizontal shell section, the flow-stopping plate lower edge is located in the described second horizontal shell section.
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN114042369A (en) * | 2021-04-20 | 2022-02-15 | 云南华谱量子材料有限公司 | Organic pollutant co-processing method and intelligent integrated processing equipment |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN114042369A (en) * | 2021-04-20 | 2022-02-15 | 云南华谱量子材料有限公司 | Organic pollutant co-processing method and intelligent integrated processing equipment |
CN114042369B (en) * | 2021-04-20 | 2023-03-03 | 云南华谱量子材料有限公司 | Organic pollutant co-processing method and intelligent integrated processing equipment |
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