CN109393607A - A kind of antibacterial sweat-absorbing medical rubber glove and preparation method thereof - Google Patents
A kind of antibacterial sweat-absorbing medical rubber glove and preparation method thereof Download PDFInfo
- Publication number
- CN109393607A CN109393607A CN201811483757.5A CN201811483757A CN109393607A CN 109393607 A CN109393607 A CN 109393607A CN 201811483757 A CN201811483757 A CN 201811483757A CN 109393607 A CN109393607 A CN 109393607A
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- parts
- housing
- inner sleeve
- rubber
- absorbing medical
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- Pending
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- 229920001971 elastomer Polymers 0.000 title claims abstract description 27
- 239000005060 rubber Substances 0.000 title claims abstract description 27
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 24
- 238000002360 preparation method Methods 0.000 title claims description 9
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 8
- 239000006185 dispersion Substances 0.000 claims abstract description 7
- 239000000839 emulsion Substances 0.000 claims abstract description 7
- 239000007788 liquid Substances 0.000 claims abstract description 7
- 239000002250 absorbent Substances 0.000 claims abstract description 4
- 230000002745 absorbent Effects 0.000 claims abstract description 4
- 239000002861 polymer material Substances 0.000 claims abstract description 4
- 239000000203 mixture Substances 0.000 claims description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- 239000004744 fabric Substances 0.000 claims description 15
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 12
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 11
- 239000005864 Sulphur Substances 0.000 claims description 11
- 244000043261 Hevea brasiliensis Species 0.000 claims description 9
- 239000002671 adjuvant Substances 0.000 claims description 9
- 229920003052 natural elastomer Polymers 0.000 claims description 9
- 229920001194 natural rubber Polymers 0.000 claims description 9
- 239000004593 Epoxy Substances 0.000 claims description 8
- 239000005062 Polybutadiene Substances 0.000 claims description 7
- 229920002857 polybutadiene Polymers 0.000 claims description 7
- DYULYMCXVSRUPB-UHFFFAOYSA-N 1,4-bis(phenylmethoxy)benzene Chemical compound C=1C=CC=CC=1COC(C=C1)=CC=C1OCC1=CC=CC=C1 DYULYMCXVSRUPB-UHFFFAOYSA-N 0.000 claims description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- 241000245665 Taraxacum Species 0.000 claims description 6
- 235000005187 Taraxacum officinale ssp. officinale Nutrition 0.000 claims description 6
- 230000021523 carboxylation Effects 0.000 claims description 6
- 238000006473 carboxylation reaction Methods 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 238000009413 insulation Methods 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- SRESKMPUIWAGML-UHFFFAOYSA-N n,n-dimethyldecan-1-amine;hydrobromide Chemical class Br.CCCCCCCCCCN(C)C SRESKMPUIWAGML-UHFFFAOYSA-N 0.000 claims description 6
- 238000005554 pickling Methods 0.000 claims description 6
- 229920005749 polyurethane resin Polymers 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 238000003825 pressing Methods 0.000 claims description 6
- 239000002994 raw material Substances 0.000 claims description 6
- 239000000741 silica gel Substances 0.000 claims description 6
- 229910002027 silica gel Inorganic materials 0.000 claims description 6
- 239000011787 zinc oxide Substances 0.000 claims description 6
- 229920000168 Microcrystalline cellulose Polymers 0.000 claims description 5
- 240000001745 Rheum palmatum Species 0.000 claims description 5
- 235000008090 Rheum palmatum Nutrition 0.000 claims description 5
- 239000011248 coating agent Substances 0.000 claims description 5
- 235000019813 microcrystalline cellulose Nutrition 0.000 claims description 5
- 239000008108 microcrystalline cellulose Substances 0.000 claims description 5
- 229940016286 microcrystalline cellulose Drugs 0.000 claims description 5
- 238000006735 epoxidation reaction Methods 0.000 claims description 4
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 3
- 235000021355 Stearic acid Nutrition 0.000 claims description 3
- 238000010521 absorption reaction Methods 0.000 claims description 3
- 230000003213 activating effect Effects 0.000 claims description 3
- 239000003242 anti bacterial agent Substances 0.000 claims description 3
- 239000010425 asbestos Substances 0.000 claims description 3
- 239000004917 carbon fiber Substances 0.000 claims description 3
- 229920003244 diene elastomer Polymers 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 239000000835 fiber Substances 0.000 claims description 3
- 239000003365 glass fiber Substances 0.000 claims description 3
- 238000002347 injection Methods 0.000 claims description 3
- 239000007924 injection Substances 0.000 claims description 3
- 238000002386 leaching Methods 0.000 claims description 3
- 210000001161 mammalian embryo Anatomy 0.000 claims description 3
- 230000001404 mediated effect Effects 0.000 claims description 3
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 3
- 229910052895 riebeckite Inorganic materials 0.000 claims description 3
- 238000009958 sewing Methods 0.000 claims description 3
- 229920002379 silicone rubber Polymers 0.000 claims description 3
- 239000008117 stearic acid Substances 0.000 claims description 3
- 238000004073 vulcanization Methods 0.000 claims description 3
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 2
- 238000007598 dipping method Methods 0.000 claims description 2
- 229910000077 silane Inorganic materials 0.000 claims description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims 3
- 240000004980 Rheum officinale Species 0.000 claims 1
- 235000008081 Rheum officinale Nutrition 0.000 claims 1
- 150000001336 alkenes Chemical class 0.000 claims 1
- 239000011521 glass Substances 0.000 claims 1
- 150000003871 sulfonates Chemical class 0.000 claims 1
- 241000894006 Bacteria Species 0.000 abstract description 6
- 230000005764 inhibitory process Effects 0.000 abstract description 3
- 230000002147 killing effect Effects 0.000 abstract description 3
- 210000004243 sweat Anatomy 0.000 abstract description 3
- 229920003048 styrene butadiene rubber Polymers 0.000 description 4
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 2
- 239000002174 Styrene-butadiene Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 208000035473 Communicable disease Diseases 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 239000012990 dithiocarbamate Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 208000015181 infectious disease Diseases 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D19/00—Gloves
- A41D19/0055—Plastic or rubber gloves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C39/00—Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor
- B29C39/02—Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor for making articles of definite length, i.e. discrete articles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L15/00—Compositions of rubber derivatives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/48—Wearing apparel
- B29L2031/4842—Outerwear
- B29L2031/4864—Gloves
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Gloves (AREA)
Abstract
The invention discloses a kind of antibacterial sweat-absorbing medical rubber gloves, including inner sleeve, the coat of the housing and housing outer surface that are set on the outside of inner sleeve, the inner sleeve is absorbent polymer material layer or tapetum, the coat is that nano layered silicate is made to nano layered silicate dispersion liquid, it is added in natural emulsion, and silane coupling agent is added and mixes together, antibacterial sweat-absorbing medical rubber glove of the invention includes inner sleeve, the coat of the housing and housing outer surface that are set on the outside of inner sleeve, its inner sleeve can quickly absorb sweat, keep hand dry and comfortable, no matter hand is dry or moist, all it is easy to dress, maintain the comfort level of gloves, it is more convenient to use, safety；Housing has good inhibition or killing effect to common bacteria；Coat makes gloves have good ductility.
Description
Technical field
The present invention relates to medical rubber glove technical field more particularly to a kind of antibacterial sweat-absorbing medical rubber glove and its systems
Preparation Method.
Background technique
Medical rubber glove is easy to dress when hand is dry, but the not easy donning when hand is moist or has water mark；
Especially through wearing after a period of time, hand is perspired, and gloves glue hand, will affect the wearing comfort of medical personnel.
Gloves since its own substance is the nutrition of bacterium, so easily cause bacterium or microorganism growth and
Procreation.Simultaneously because hand is perspired, the breeding of bacterium also will increase, increase the danger of doctor and patient's infectious disease.
Summary of the invention
The purpose of the present invention is to solve disadvantages existing in the prior art, and the medical rubber of a kind of antibacterial sweat-absorbing proposed
Rubber gloves and preparation method thereof.
To achieve the goals above, present invention employs following technical solutions:
A kind of antibacterial sweat-absorbing medical rubber glove, the painting including inner sleeve, the housing being set on the outside of inner sleeve and housing outer surface
Coating, the inner sleeve are absorbent polymer material layer or tapetum, and the coat is made of by nano layered silicate
Nano layered silicate dispersion liquid, is added in natural emulsion, and silane coupling agent is added and mixes together, the housing
Raw material poidometer by weight is as follows: de- 78-90 parts of albumen epoxy natural rubber, Carboxylation SBR styrene butadiene rubbers
5-10 parts, 7-15 parts of butadiene rubber, 4-10 parts of modified polyurethane resin, 0.5-0.8 parts of sulphur, 2-5 parts of zinc oxide, N- ethyl-
0.5-1.2 parts of N- phenyl zinc dithiocarbamate, 0.3-0.6 parts of hydroquinone dibenzyl ether, 2-5 parts of superfine silica gel powder, crystallite are fine
Tie up 2-5 parts of element, 0.4-1.2 parts of double decyl dimethyl ammonium bromides, 0.2-0.8 parts of dandelion water extract, Rheum palmatum 0.2-0.8
Part and adjuvant 5-9 parts.
Preferably, insulation layer of cloth, heat-insulated layer of cloth and heat absorption cloth are disposed between the inner sleeve and housing from outside to inside
Layer.
Preferably, the insulation layer of cloth is made of glass fibre and organic silicon rubber pressing, and the heat-insulated layer of cloth is by asbestos
Fiber and carbon fiber pressing composition.
Preferably, poidometer is as follows by weight: 10-13 parts of nano layered silicate dispersion liquid, natural emulsion 20-23
Part, 5-13 parts of silane coupling agent, the silane coupling agent is 3- TSL 8330.
Preferably, the nitrogen content of the de- albumen epoxy natural rubber is less than 1.0ppm, and epoxidation degree is 60%.
Preferably, the adjuvant includes dodecyl sodium sulfate, stearic acid, activating agent, antibacterial agent.
A kind of preparation method of antibacterial sweat-absorbing medical rubber glove, includes the following steps:
S1: being weighed by formula each component of the raw material of housing, by de- albumen epoxy natural rubber, Carboxylation styrene-fourth
After diene rubber, butadiene rubber, mixing, it is put into progress colloidal sol processing in colloidal sol kettle, obtains mixture A；
S2: mixture A obtained in step S1 is put into kneader and is mediated, modified polyurethane resin, sulphur are then sequentially added
It is sulphur, zinc oxide, N- ethyl, N-phenyl zinc dithiocarbamate, hydroquinone dibenzyl ether, superfine silica gel powder, microcrystalline cellulose, double
Decyl dimethyl ammonium bromide, dandelion water extract, Rheum palmatum and adjuvant, obtain mixture B after mixing；
S3: mixture B is put into digester, and by electrically heated mode, digester is heated to 100-120 DEG C, de-
Vapor (steam) temperature keeps 1.5h to be reacted, obtains mixture C at this temperature at 165-175 DEG C in sulphur tank；
S4: carrying out dip pickling 10-15 seconds to glove mould with hydrochloric acid, and clear water rushes the glove mould after pickling at room temperature
It washes, it is then clean with 80-90 DEG C of hot water injection again, 55-65 DEG C of coagulator is impregnated into after mold clean, glove mould is solidifying
Gu time 1-2 minute of agent dipping, then 3-5 minutes dry under the conditions of 120 ± 5 DEG C；
S5: mixture C obtained in step S3 is injected into glove mould, then with clean water to outer on glove mould
Set embryo is rinsed demoulding, and housing is made；
S6: carrying out leaching coating agent for housing, vulcanizes into baking oven and dries, 65-85 DEG C of time 30- of cryogenic vulcanization drying temperature
Antibacterial sweat-absorbing doctor is made then by inner sleeve sewing in housing in 45min, 100-120 DEG C of time 60-90min of high temperature vulcanized temperature
Use rubber gloves.
Compared with prior art, the beneficial effects of the present invention are: a kind of antibacterial sweat-absorbing medical grade rubber hand provided by the invention
Set and preparation method thereof, antibacterial sweat-absorbing medical rubber glove of the invention include inner sleeve, the housing being set on the outside of inner sleeve and outer
The coat of outer surface is covered, inner sleeve can quickly absorb sweat, keep hand dry and comfortable, and no matter hand is dry or humidity, all
It is easy to dress, maintains the comfort level of gloves, more convenient to use, safety；Housing to common bacteria have it is good inhibition or
Killing effect；Coat makes gloves have good ductility.
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, below in conjunction with specific embodiment, to this
Invention is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, not
For limiting the present invention.
Embodiment 1
A kind of antibacterial sweat-absorbing medical rubber glove, the painting including inner sleeve, the housing being set on the outside of inner sleeve and housing outer surface
Coating, the inner sleeve are absorbent polymer material layer or tapetum, and the coat is made of by nano layered silicate
Nano layered silicate dispersion liquid, is added in natural emulsion, and silane coupling agent is added and mixes together, the housing
Raw material poidometer by weight is as follows: de- 78 parts of albumen epoxy natural rubber, 8 parts Carboxylation of SBR styrene butadiene rubbers,
12 parts of butadiene rubber, 10 parts of modified polyurethane resin, 0.5 part of sulphur, 2 parts of zinc oxide, N- ethyl, N-phenyl dithiocarbamates first
0.5 part of sour zinc, 0.3 part of hydroquinone dibenzyl ether, 2 parts of superfine silica gel powder, 2 parts of microcrystalline cellulose, double decyl dimethyl ammonium bromides 0.4
Part, 0.8 part of dandelion water extract, 0.8 part of Rheum palmatum and 9 parts of adjuvant.
Specifically, insulation layer of cloth, heat-insulated layer of cloth and heat absorption cloth are disposed between the inner sleeve and housing from outside to inside
Layer.
Specifically, the insulation layer of cloth is made of glass fibre and organic silicon rubber pressing, the heat-insulated layer of cloth is by asbestos
Fiber and carbon fiber pressing composition.
Specifically, poidometer is as follows by weight: 13 parts of nano layered silicate dispersion liquid, 23 parts of natural emulsion, silane
13 parts of coupling agent, the silane coupling agent is 3- TSL 8330.
Specifically, the nitrogen content of the de- albumen epoxy natural rubber is less than 1.0ppm, epoxidation degree is 60%.
Specifically, the adjuvant includes dodecyl sodium sulfate, stearic acid, activating agent, antibacterial agent.
A kind of preparation method of antibacterial sweat-absorbing medical rubber glove, includes the following steps:
S1: being weighed by formula each component of the raw material of housing, by de- albumen epoxy natural rubber, Carboxylation styrene-fourth
After diene rubber, butadiene rubber, mixing, it is put into progress colloidal sol processing in colloidal sol kettle, obtains mixture A；
S2: mixture A obtained in step S1 is put into kneader and is mediated, modified polyurethane resin, sulphur are then sequentially added
It is sulphur, zinc oxide, N- ethyl, N-phenyl zinc dithiocarbamate, hydroquinone dibenzyl ether, superfine silica gel powder, microcrystalline cellulose, double
Decyl dimethyl ammonium bromide, dandelion water extract, Rheum palmatum and adjuvant, obtain mixture B after mixing；
S3: mixture B is put into digester, by electrically heated mode, digester is heated to 100 DEG C, in digester
Interior vapor (steam) temperature keeps 1.5h to be reacted, obtains mixture C at this temperature at 165 DEG C；
S4: carrying out dip pickling 10 seconds to glove mould with hydrochloric acid, and clear water rinses the glove mould after pickling at room temperature,
Hot water injection then again with 80 DEG C is clean, and 55 DEG C of coagulator is impregnated into after mold clean, and glove mould is impregnated in coagulator
Time 1 minute, then dry 3 minutes under the conditions of 120 DEG C；
S5: mixture C obtained in step S3 is injected into glove mould, then with clean water to outer on glove mould
Set embryo is rinsed demoulding, and housing is made；
S6: carrying out leaching coating agent for housing, vulcanizes into baking oven and dries, 65 DEG C of time 30min of cryogenic vulcanization drying temperature, high temperature
Then antibacterial sweat-absorbing medical rubber glove is made in housing in inner sleeve sewing by 120 DEG C of time 60min of curing temperature.
A kind of antibacterial sweat-absorbing medical rubber glove provided by the invention and preparation method thereof, antibacterial sweat-absorbing of the invention is medical
Rubber gloves includes the coat of inner sleeve, the housing being set on the outside of inner sleeve and housing outer surface, and inner sleeve can quickly absorb
Sweat keeps hand dry and comfortable, and no matter hand is dry or humidity, is all easy to dress, the comfort level of gloves is maintained, using more
Convenient, safety；Housing has good inhibition or killing effect to common bacteria；Coat makes gloves have good extension
Performance.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (7)
1. a kind of antibacterial sweat-absorbing medical rubber glove, including inner sleeve, the housing being set on the outside of inner sleeve and housing outer surface
Coat, it is characterised in that: the inner sleeve is absorbent polymer material layer or tapetum, and the coat is by nanometer layer
Nano layered silicate dispersion liquid is made in shape silicate, is added in natural emulsion, and be added silane coupling agent be mixed and
At the raw material of housing poidometer by weight is as follows: de- 78-90 parts of albumen epoxy natural rubber, Carboxylation benzene second
Alkene -5-10 parts of butadiene rubber, 7-15 parts of butadiene rubber, 4-10 parts of modified polyurethane resin, 0.5-0.8 parts of sulphur, zinc oxide
2-5 parts, 0.5-1.2 parts of N- ethyl, N-phenyl zinc dithiocarbamate, 0.3-0.6 parts of hydroquinone dibenzyl ether, superfine silica gel powder
2-5 parts, 2-5 parts of microcrystalline cellulose, 0.4-1.2 parts of double decyl dimethyl ammonium bromides, 0.2-0.8 parts of dandelion water extract, rheum officinale
0.2-0.8 parts and adjuvant 5-9 parts of water extract.
2. a kind of antibacterial sweat-absorbing medical rubber glove according to claim 1, it is characterised in that: the inner sleeve and housing it
Between be disposed with from outside to inside insulation layer of cloth, heat-insulated layer of cloth and heat absorption layer of cloth.
3. a kind of antibacterial sweat-absorbing medical rubber glove according to claim 1, it is characterised in that: the insulation layer of cloth is by glass
Glass fiber and organic silicon rubber pressing composition, the heat-insulated layer of cloth are made of asbestos fibre and carbon fiber pressing.
4. a kind of antibacterial sweat-absorbing medical rubber glove according to claim 1, it is characterised in that: poidometer is such as by weight
Under: it is 10-13 parts of nano layered silicate dispersion liquid, 20-23 parts of natural emulsion, 5-13 parts of silane coupling agent, described silane coupled
Agent is 3- TSL 8330.
5. a kind of antibacterial sweat-absorbing medical rubber glove according to claim 1, it is characterised in that: the de- albumen epoxidation
The nitrogen content of natural rubber is less than 1.0ppm, and epoxidation degree is 60%.
6. a kind of antibacterial sweat-absorbing medical rubber glove according to claim 1, it is characterised in that: the adjuvant includes ten
Dialkyl sulfonates, stearic acid, activating agent, antibacterial agent.
7. a kind of preparation method of antibacterial sweat-absorbing medical rubber glove described in claim 1, it is characterised in that: including walking as follows
It is rapid:
S1: being weighed by formula each component of the raw material of housing, by de- albumen epoxy natural rubber, Carboxylation styrene-fourth
After diene rubber, butadiene rubber, mixing, it is put into progress colloidal sol processing in colloidal sol kettle, obtains mixture A；
S2: mixture A obtained in step S1 is put into kneader and is mediated, modified polyurethane resin, sulphur are then sequentially added
It is sulphur, zinc oxide, N- ethyl, N-phenyl zinc dithiocarbamate, hydroquinone dibenzyl ether, superfine silica gel powder, microcrystalline cellulose, double
Decyl dimethyl ammonium bromide, dandelion water extract, Rheum palmatum and adjuvant, obtain mixture B after mixing；
S3: mixture B is put into digester, and by electrically heated mode, digester is heated to 100-120 DEG C, de-
Vapor (steam) temperature keeps 1.5h to be reacted, obtains mixture C at this temperature at 165-175 DEG C in sulphur tank；
S4: carrying out dip pickling 10-15 seconds to glove mould with hydrochloric acid, and clear water rushes the glove mould after pickling at room temperature
It washes, it is then clean with 80-90 DEG C of hot water injection again, 55-65 DEG C of coagulator is impregnated into after mold clean, glove mould is solidifying
Gu time 1-2 minute of agent dipping, then 3-5 minutes dry under the conditions of 120 ± 5 DEG C；
S5: mixture C obtained in step S3 is injected into glove mould, then with clean water to outer on glove mould
Set embryo is rinsed demoulding, and housing is made；
S6: carrying out leaching coating agent for housing, vulcanizes into baking oven and dries, 65-85 DEG C of time 30- of cryogenic vulcanization drying temperature
Antibacterial sweat-absorbing doctor is made then by inner sleeve sewing in housing in 45min, 100-120 DEG C of time 60-90min of high temperature vulcanized temperature
Use rubber gloves.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811483757.5A CN109393607A (en) | 2018-12-06 | 2018-12-06 | A kind of antibacterial sweat-absorbing medical rubber glove and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811483757.5A CN109393607A (en) | 2018-12-06 | 2018-12-06 | A kind of antibacterial sweat-absorbing medical rubber glove and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109393607A true CN109393607A (en) | 2019-03-01 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111000308A (en) * | 2019-12-18 | 2020-04-14 | 镇江苏惠乳胶制品有限公司 | A rubber glove for wet hands |
| CN111286093A (en) * | 2020-02-12 | 2020-06-16 | 江苏瑞京科技发展有限公司 | Composition for producing medical gloves and application thereof |
| CN112339196A (en) * | 2020-10-14 | 2021-02-09 | 上海那博新材料科技有限公司 | Preparation method of environment-friendly nano-copper latex gloves |
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| CN111000308A (en) * | 2019-12-18 | 2020-04-14 | 镇江苏惠乳胶制品有限公司 | A rubber glove for wet hands |
| CN111286093A (en) * | 2020-02-12 | 2020-06-16 | 江苏瑞京科技发展有限公司 | Composition for producing medical gloves and application thereof |
| CN112339196A (en) * | 2020-10-14 | 2021-02-09 | 上海那博新材料科技有限公司 | Preparation method of environment-friendly nano-copper latex gloves |
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Application publication date: 20190301 |