CN109393607A - A kind of antibacterial sweat-absorbing medical rubber glove and preparation method thereof - Google Patents
A kind of antibacterial sweat-absorbing medical rubber glove and preparation method thereof Download PDFInfo
- Publication number
- CN109393607A CN109393607A CN201811483757.5A CN201811483757A CN109393607A CN 109393607 A CN109393607 A CN 109393607A CN 201811483757 A CN201811483757 A CN 201811483757A CN 109393607 A CN109393607 A CN 109393607A
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- China
- Prior art keywords
- parts
- housing
- inner sleeve
- rubber
- absorbing medical
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D19/00—Gloves
- A41D19/0055—Plastic or rubber gloves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C39/00—Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor
- B29C39/02—Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor for making articles of definite length, i.e. discrete articles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L15/00—Compositions of rubber derivatives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/48—Wearing apparel
- B29L2031/4842—Outerwear
- B29L2031/4864—Gloves
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Gloves (AREA)
Abstract
The invention discloses a kind of antibacterial sweat-absorbing medical rubber gloves, including inner sleeve, the coat of the housing and housing outer surface that are set on the outside of inner sleeve, the inner sleeve is absorbent polymer material layer or tapetum, the coat is that nano layered silicate is made to nano layered silicate dispersion liquid, it is added in natural emulsion, and silane coupling agent is added and mixes together, antibacterial sweat-absorbing medical rubber glove of the invention includes inner sleeve, the coat of the housing and housing outer surface that are set on the outside of inner sleeve, its inner sleeve can quickly absorb sweat, keep hand dry and comfortable, no matter hand is dry or moist, all it is easy to dress, maintain the comfort level of gloves, it is more convenient to use, safety;Housing has good inhibition or killing effect to common bacteria;Coat makes gloves have good ductility.
Description
Technical field
The present invention relates to medical rubber glove technical field more particularly to a kind of antibacterial sweat-absorbing medical rubber glove and its systems
Preparation Method.
Background technique
Medical rubber glove is easy to dress when hand is dry, but the not easy donning when hand is moist or has water mark;
Especially through wearing after a period of time, hand is perspired, and gloves glue hand, will affect the wearing comfort of medical personnel.
Gloves since its own substance is the nutrition of bacterium, so easily cause bacterium or microorganism growth and
Procreation.Simultaneously because hand is perspired, the breeding of bacterium also will increase, increase the danger of doctor and patient's infectious disease.
Summary of the invention
The purpose of the present invention is to solve disadvantages existing in the prior art, and the medical rubber of a kind of antibacterial sweat-absorbing proposed
Rubber gloves and preparation method thereof.
To achieve the goals above, present invention employs following technical solutions:
A kind of antibacterial sweat-absorbing medical rubber glove, the painting including inner sleeve, the housing being set on the outside of inner sleeve and housing outer surface
Coating, the inner sleeve are absorbent polymer material layer or tapetum, and the coat is made of by nano layered silicate
Nano layered silicate dispersion liquid, is added in natural emulsion, and silane coupling agent is added and mixes together, the housing
Raw material poidometer by weight is as follows: de- 78-90 parts of albumen epoxy natural rubber, Carboxylation SBR styrene butadiene rubbers
5-10 parts, 7-15 parts of butadiene rubber, 4-10 parts of modified polyurethane resin, 0.5-0.8 parts of sulphur, 2-5 parts of zinc oxide, N- ethyl-
0.5-1.2 parts of N- phenyl zinc dithiocarbamate, 0.3-0.6 parts of hydroquinone dibenzyl ether, 2-5 parts of superfine silica gel powder, crystallite are fine
Tie up 2-5 parts of element, 0.4-1.2 parts of double decyl dimethyl ammonium bromides, 0.2-0.8 parts of dandelion water extract, Rheum palmatum 0.2-0.8
Part and adjuvant 5-9 parts.
Preferably, insulation layer of cloth, heat-insulated layer of cloth and heat absorption cloth are disposed between the inner sleeve and housing from outside to inside
Layer.
Preferably, the insulation layer of cloth is made of glass fibre and organic silicon rubber pressing, and the heat-insulated layer of cloth is by asbestos
Fiber and carbon fiber pressing composition.
Preferably, poidometer is as follows by weight: 10-13 parts of nano layered silicate dispersion liquid, natural emulsion 20-23
Part, 5-13 parts of silane coupling agent, the silane coupling agent is 3- TSL 8330.
Preferably, the nitrogen content of the de- albumen epoxy natural rubber is less than 1.0ppm, and epoxidation degree is 60%.
Preferably, the adjuvant includes dodecyl sodium sulfate, stearic acid, activating agent, antibacterial agent.
A kind of preparation method of antibacterial sweat-absorbing medical rubber glove, includes the following steps:
S1: being weighed by formula each component of the raw material of housing, by de- albumen epoxy natural rubber, Carboxylation styrene-fourth
After diene rubber, butadiene rubber, mixing, it is put into progress colloidal sol processing in colloidal sol kettle, obtains mixture A;
S2: mixture A obtained in step S1 is put into kneader and is mediated, modified polyurethane resin, sulphur are then sequentially added
It is sulphur, zinc oxide, N- ethyl, N-phenyl zinc dithiocarbamate, hydroquinone dibenzyl ether, superfine silica gel powder, microcrystalline cellulose, double
Decyl dimethyl ammonium bromide, dandelion water extract, Rheum palmatum and adjuvant, obtain mixture B after mixing;
S3: mixture B is put into digester, and by electrically heated mode, digester is heated to 100-120 DEG C, de-
Vapor (steam) temperature keeps 1.5h to be reacted, obtains mixture C at this temperature at 165-175 DEG C in sulphur tank;
S4: carrying out dip pickling 10-15 seconds to glove mould with hydrochloric acid, and clear water rushes the glove mould after pickling at room temperature
It washes, it is then clean with 80-90 DEG C of hot water injection again, 55-65 DEG C of coagulator is impregnated into after mold clean, glove mould is solidifying
Gu time 1-2 minute of agent dipping, then 3-5 minutes dry under the conditions of 120 ± 5 DEG C;
S5: mixture C obtained in step S3 is injected into glove mould, then with clean water to outer on glove mould
Set embryo is rinsed demoulding, and housing is made;
S6: carrying out leaching coating agent for housing, vulcanizes into baking oven and dries, 65-85 DEG C of time 30- of cryogenic vulcanization drying temperature
Antibacterial sweat-absorbing doctor is made then by inner sleeve sewing in housing in 45min, 100-120 DEG C of time 60-90min of high temperature vulcanized temperature
Use rubber gloves.
Compared with prior art, the beneficial effects of the present invention are: a kind of antibacterial sweat-absorbing medical grade rubber hand provided by the invention
Set and preparation method thereof, antibacterial sweat-absorbing medical rubber glove of the invention include inner sleeve, the housing being set on the outside of inner sleeve and outer
The coat of outer surface is covered, inner sleeve can quickly absorb sweat, keep hand dry and comfortable, and no matter hand is dry or humidity, all
It is easy to dress, maintains the comfort level of gloves, more convenient to use, safety;Housing to common bacteria have it is good inhibition or
Killing effect;Coat makes gloves have good ductility.
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, below in conjunction with specific embodiment, to this
Invention is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, not
For limiting the present invention.
Embodiment 1
A kind of antibacterial sweat-absorbing medical rubber glove, the painting including inner sleeve, the housing being set on the outside of inner sleeve and housing outer surface
Coating, the inner sleeve are absorbent polymer material layer or tapetum, and the coat is made of by nano layered silicate
Nano layered silicate dispersion liquid, is added in natural emulsion, and silane coupling agent is added and mixes together, the housing
Raw material poidometer by weight is as follows: de- 78 parts of albumen epoxy natural rubber, 8 parts Carboxylation of SBR styrene butadiene rubbers,
12 parts of butadiene rubber, 10 parts of modified polyurethane resin, 0.5 part of sulphur, 2 parts of zinc oxide, N- ethyl, N-phenyl dithiocarbamates first
0.5 part of sour zinc, 0.3 part of hydroquinone dibenzyl ether, 2 parts of superfine silica gel powder, 2 parts of microcrystalline cellulose, double decyl dimethyl ammonium bromides 0.4
Part, 0.8 part of dandelion water extract, 0.8 part of Rheum palmatum and 9 parts of adjuvant.
Specifically, insulation layer of cloth, heat-insulated layer of cloth and heat absorption cloth are disposed between the inner sleeve and housing from outside to inside
Layer.
Specifically, the insulation layer of cloth is made of glass fibre and organic silicon rubber pressing, the heat-insulated layer of cloth is by asbestos
Fiber and carbon fiber pressing composition.
Specifically, poidometer is as follows by weight: 13 parts of nano layered silicate dispersion liquid, 23 parts of natural emulsion, silane
13 parts of coupling agent, the silane coupling agent is 3- TSL 8330.
Specifically, the nitrogen content of the de- albumen epoxy natural rubber is less than 1.0ppm, epoxidation degree is 60%.
Specifically, the adjuvant includes dodecyl sodium sulfate, stearic acid, activating agent, antibacterial agent.
A kind of preparation method of antibacterial sweat-absorbing medical rubber glove, includes the following steps:
S1: being weighed by formula each component of the raw material of housing, by de- albumen epoxy natural rubber, Carboxylation styrene-fourth
After diene rubber, butadiene rubber, mixing, it is put into progress colloidal sol processing in colloidal sol kettle, obtains mixture A;
S2: mixture A obtained in step S1 is put into kneader and is mediated, modified polyurethane resin, sulphur are then sequentially added
It is sulphur, zinc oxide, N- ethyl, N-phenyl zinc dithiocarbamate, hydroquinone dibenzyl ether, superfine silica gel powder, microcrystalline cellulose, double
Decyl dimethyl ammonium bromide, dandelion water extract, Rheum palmatum and adjuvant, obtain mixture B after mixing;
S3: mixture B is put into digester, by electrically heated mode, digester is heated to 100 DEG C, in digester
Interior vapor (steam) temperature keeps 1.5h to be reacted, obtains mixture C at this temperature at 165 DEG C;
S4: carrying out dip pickling 10 seconds to glove mould with hydrochloric acid, and clear water rinses the glove mould after pickling at room temperature,
Hot water injection then again with 80 DEG C is clean, and 55 DEG C of coagulator is impregnated into after mold clean, and glove mould is impregnated in coagulator
Time 1 minute, then dry 3 minutes under the conditions of 120 DEG C;
S5: mixture C obtained in step S3 is injected into glove mould, then with clean water to outer on glove mould
Set embryo is rinsed demoulding, and housing is made;
S6: carrying out leaching coating agent for housing, vulcanizes into baking oven and dries, 65 DEG C of time 30min of cryogenic vulcanization drying temperature, high temperature
Then antibacterial sweat-absorbing medical rubber glove is made in housing in inner sleeve sewing by 120 DEG C of time 60min of curing temperature.
A kind of antibacterial sweat-absorbing medical rubber glove provided by the invention and preparation method thereof, antibacterial sweat-absorbing of the invention is medical
Rubber gloves includes the coat of inner sleeve, the housing being set on the outside of inner sleeve and housing outer surface, and inner sleeve can quickly absorb
Sweat keeps hand dry and comfortable, and no matter hand is dry or humidity, is all easy to dress, the comfort level of gloves is maintained, using more
Convenient, safety;Housing has good inhibition or killing effect to common bacteria;Coat makes gloves have good extension
Performance.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (7)
1. a kind of antibacterial sweat-absorbing medical rubber glove, including inner sleeve, the housing being set on the outside of inner sleeve and housing outer surface
Coat, it is characterised in that: the inner sleeve is absorbent polymer material layer or tapetum, and the coat is by nanometer layer
Nano layered silicate dispersion liquid is made in shape silicate, is added in natural emulsion, and be added silane coupling agent be mixed and
At the raw material of housing poidometer by weight is as follows: de- 78-90 parts of albumen epoxy natural rubber, Carboxylation benzene second
Alkene -5-10 parts of butadiene rubber, 7-15 parts of butadiene rubber, 4-10 parts of modified polyurethane resin, 0.5-0.8 parts of sulphur, zinc oxide
2-5 parts, 0.5-1.2 parts of N- ethyl, N-phenyl zinc dithiocarbamate, 0.3-0.6 parts of hydroquinone dibenzyl ether, superfine silica gel powder
2-5 parts, 2-5 parts of microcrystalline cellulose, 0.4-1.2 parts of double decyl dimethyl ammonium bromides, 0.2-0.8 parts of dandelion water extract, rheum officinale
0.2-0.8 parts and adjuvant 5-9 parts of water extract.
2. a kind of antibacterial sweat-absorbing medical rubber glove according to claim 1, it is characterised in that: the inner sleeve and housing it
Between be disposed with from outside to inside insulation layer of cloth, heat-insulated layer of cloth and heat absorption layer of cloth.
3. a kind of antibacterial sweat-absorbing medical rubber glove according to claim 1, it is characterised in that: the insulation layer of cloth is by glass
Glass fiber and organic silicon rubber pressing composition, the heat-insulated layer of cloth are made of asbestos fibre and carbon fiber pressing.
4. a kind of antibacterial sweat-absorbing medical rubber glove according to claim 1, it is characterised in that: poidometer is such as by weight
Under: it is 10-13 parts of nano layered silicate dispersion liquid, 20-23 parts of natural emulsion, 5-13 parts of silane coupling agent, described silane coupled
Agent is 3- TSL 8330.
5. a kind of antibacterial sweat-absorbing medical rubber glove according to claim 1, it is characterised in that: the de- albumen epoxidation
The nitrogen content of natural rubber is less than 1.0ppm, and epoxidation degree is 60%.
6. a kind of antibacterial sweat-absorbing medical rubber glove according to claim 1, it is characterised in that: the adjuvant includes ten
Dialkyl sulfonates, stearic acid, activating agent, antibacterial agent.
7. a kind of preparation method of antibacterial sweat-absorbing medical rubber glove described in claim 1, it is characterised in that: including walking as follows
It is rapid:
S1: being weighed by formula each component of the raw material of housing, by de- albumen epoxy natural rubber, Carboxylation styrene-fourth
After diene rubber, butadiene rubber, mixing, it is put into progress colloidal sol processing in colloidal sol kettle, obtains mixture A;
S2: mixture A obtained in step S1 is put into kneader and is mediated, modified polyurethane resin, sulphur are then sequentially added
It is sulphur, zinc oxide, N- ethyl, N-phenyl zinc dithiocarbamate, hydroquinone dibenzyl ether, superfine silica gel powder, microcrystalline cellulose, double
Decyl dimethyl ammonium bromide, dandelion water extract, Rheum palmatum and adjuvant, obtain mixture B after mixing;
S3: mixture B is put into digester, and by electrically heated mode, digester is heated to 100-120 DEG C, de-
Vapor (steam) temperature keeps 1.5h to be reacted, obtains mixture C at this temperature at 165-175 DEG C in sulphur tank;
S4: carrying out dip pickling 10-15 seconds to glove mould with hydrochloric acid, and clear water rushes the glove mould after pickling at room temperature
It washes, it is then clean with 80-90 DEG C of hot water injection again, 55-65 DEG C of coagulator is impregnated into after mold clean, glove mould is solidifying
Gu time 1-2 minute of agent dipping, then 3-5 minutes dry under the conditions of 120 ± 5 DEG C;
S5: mixture C obtained in step S3 is injected into glove mould, then with clean water to outer on glove mould
Set embryo is rinsed demoulding, and housing is made;
S6: carrying out leaching coating agent for housing, vulcanizes into baking oven and dries, 65-85 DEG C of time 30- of cryogenic vulcanization drying temperature
Antibacterial sweat-absorbing doctor is made then by inner sleeve sewing in housing in 45min, 100-120 DEG C of time 60-90min of high temperature vulcanized temperature
Use rubber gloves.
Priority Applications (1)
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CN201811483757.5A CN109393607A (en) | 2018-12-06 | 2018-12-06 | A kind of antibacterial sweat-absorbing medical rubber glove and preparation method thereof |
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CN201811483757.5A CN109393607A (en) | 2018-12-06 | 2018-12-06 | A kind of antibacterial sweat-absorbing medical rubber glove and preparation method thereof |
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CN201811483757.5A Pending CN109393607A (en) | 2018-12-06 | 2018-12-06 | A kind of antibacterial sweat-absorbing medical rubber glove and preparation method thereof |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111286093A (en) * | 2020-02-12 | 2020-06-16 | 江苏瑞京科技发展有限公司 | Composition for producing medical gloves and application thereof |
CN112339196A (en) * | 2020-10-14 | 2021-02-09 | 上海那博新材料科技有限公司 | Preparation method of environment-friendly nano-copper latex gloves |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103535936A (en) * | 2013-11-11 | 2014-01-29 | 镇江苏惠乳胶制品有限公司 | Medical rubber glove capable of preventing sweat |
CN205285104U (en) * | 2016-01-08 | 2016-06-08 | 辛集市汇富三合劳保用品有限公司 | Industrial glove with high temperature resistant function |
CN105931689A (en) * | 2016-05-31 | 2016-09-07 | 中国工程物理研究院材料研究所 | Variable-wall-thickness glove preparation method and gloves prepared with method |
CN106336536A (en) * | 2016-08-29 | 2017-01-18 | 樊之雄 | Antibacterial and sweat-absorbing medical rubber glove and preparing method thereof |
CN107266732A (en) * | 2017-07-20 | 2017-10-20 | 桂林紫竹乳胶制品有限公司 | A kind of nano layered silicate/Heveatex medical rubber glove and preparation method thereof |
CN108084512A (en) * | 2017-12-20 | 2018-05-29 | 王维维 | A kind of medical rubber glove for having antibacterial functions and preparation method thereof |
CN108299702A (en) * | 2018-01-30 | 2018-07-20 | 上海科邦医用乳胶器材有限公司 | A kind of medical rubber glove latex resin composition, preparation method and applications |
-
2018
- 2018-12-06 CN CN201811483757.5A patent/CN109393607A/en active Pending
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103535936A (en) * | 2013-11-11 | 2014-01-29 | 镇江苏惠乳胶制品有限公司 | Medical rubber glove capable of preventing sweat |
CN205285104U (en) * | 2016-01-08 | 2016-06-08 | 辛集市汇富三合劳保用品有限公司 | Industrial glove with high temperature resistant function |
CN105931689A (en) * | 2016-05-31 | 2016-09-07 | 中国工程物理研究院材料研究所 | Variable-wall-thickness glove preparation method and gloves prepared with method |
CN106336536A (en) * | 2016-08-29 | 2017-01-18 | 樊之雄 | Antibacterial and sweat-absorbing medical rubber glove and preparing method thereof |
CN107266732A (en) * | 2017-07-20 | 2017-10-20 | 桂林紫竹乳胶制品有限公司 | A kind of nano layered silicate/Heveatex medical rubber glove and preparation method thereof |
CN108084512A (en) * | 2017-12-20 | 2018-05-29 | 王维维 | A kind of medical rubber glove for having antibacterial functions and preparation method thereof |
CN108299702A (en) * | 2018-01-30 | 2018-07-20 | 上海科邦医用乳胶器材有限公司 | A kind of medical rubber glove latex resin composition, preparation method and applications |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111286093A (en) * | 2020-02-12 | 2020-06-16 | 江苏瑞京科技发展有限公司 | Composition for producing medical gloves and application thereof |
CN112339196A (en) * | 2020-10-14 | 2021-02-09 | 上海那博新材料科技有限公司 | Preparation method of environment-friendly nano-copper latex gloves |
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Application publication date: 20190301 |