CN109371478B - 3D stacked electrospinning fiber spraying method for experiment and application - Google Patents
3D stacked electrospinning fiber spraying method for experiment and application Download PDFInfo
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- CN109371478B CN109371478B CN201811259086.4A CN201811259086A CN109371478B CN 109371478 B CN109371478 B CN 109371478B CN 201811259086 A CN201811259086 A CN 201811259086A CN 109371478 B CN109371478 B CN 109371478B
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/0007—Electro-spinning
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/0007—Electro-spinning
- D01D5/0061—Electro-spinning characterised by the electro-spinning apparatus
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/0007—Electro-spinning
- D01D5/0061—Electro-spinning characterised by the electro-spinning apparatus
- D01D5/0076—Electro-spinning characterised by the electro-spinning apparatus characterised by the collecting device, e.g. drum, wheel, endless belt, plate or grid
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Abstract
In order to solve the problem of forming a plurality of electrospun fiber layers, the 3D stacked electrospun fiber jet forming device carries out custom jet on the material and the shape of electrospun fibers according to experimental requirements, and the effect is to realize the multilayer of the fibers.
Description
Technical Field
The invention belongs to the field of electrospinning, and relates to a device and a method for spraying and collecting electrospun fibers.
Background
The electrospinning fiber material has wide application fields and development prospects due to excellent physical and chemical properties, and various countries are tightening to improve the existing electrospinning fiber technology or develop novel electrospinning fiber equipment. In the production process of the electrospinning fiber, the charged polymer solution is sprayed, stretched, split, volatilized and solidified in a high-voltage electrostatic field, and finally the fibrous characteristic is formed. With the progress of material synthesis technology and the continuous expansion of the application field of electrospun fibers, the application field of experiments and engineering needs to more efficiently test and research the physical and chemical properties of multiple layers of different materials after the superposition of electrospun fibers. Due to the complex proportion, multiple types, long spraying time and complex environmental parameters of the electrospinning solution, the manual realization of the multi-layer electrospinning fiber 3D stacking experiment usually needs to overcome a plurality of difficulties, such as layered spraying, spraying template definition, spraying time setting, spraying angle measurement, spraying area control and the like. Moreover, the randomness of manual operation is large, the experimental steps are complex, and experimental data often has large-degree deviation.
Disclosure of Invention
In order to solve the problem of forming a plurality of electrospun fiber layers, the invention provides the following technical scheme: A3D stacked electrospinning fiber spraying method for experiments is characterized in that a 3D stacked electrospinning fiber spraying forming device carries out self-defined spraying on the electrospinning fiber material and shape according to experiment requirements.
Further, before the device is used, the proportion of electrospinning solutions is carried out according to the material requirements of each layer of electrospinning fibers, the electrospinning solutions with different proportions are respectively filled into electrospinning containers, and the rotary table rotates to drive the motor to rotate, so that the injection needle head is aligned with the center of the rotary collecting tray; selecting different templates according to the shape requirements of the electrospun fibers of each layer, sequentially installing the templates on a supporting arm of a model turntable, and adjusting the height of a height adjusting ring of a supporting rod of the model turntable to enable the distance between the model turntable and a rotary collecting tray to be 2-5 cm; when the supporting arm of the model turntable is positioned at the initial position, the model turntable drives the motor to rotate in the forward direction, so that the first plane supporting plate rotates to the rotary collecting tray, and the center of the plane supporting plate is superposed and vertical to the rotary collecting tray and the center of the injection needle; the downward pressing motion platform moves horizontally and longitudinally for adjustment, so that the pressure plate applies pressure to the rotating collection tray, and the electrospinning limit, the fixed pressure and the fixed temperature on the rotating collection tray are heated; the single-layer electrospun fiber is heated at constant pressure and constant temperature, firstly two transverse motion driving motors drive a transverse rod, a downward-pressing motion platform is transversely moved to the upper part of a rotary collecting tray, a longitudinal motion driving motor drives a longitudinal rod to enable a plane pressure regulator to be pressed downward, a pressure film of a pressure plate connected to the lower part of the pressure regulator is used for constant pressure, and the electrospun fiber is heated at constant temperature by a heating film.
Furthermore, the pressure regulator comprises two support columns and a plurality of pressure regulating columns, the support columns play a supporting role on two sides, the pressure regulating columns can turn over by taking a transverse shaft as a center, the pressure of multiple levels is regulated through the working quantity of the support columns, and the working columns are in vertical positions.
Further, the lower pressing motion platform 33 is located at the initial position, a suitable pressure film material is selected according to the type of the first electrospinning solution, the pressure film is installed on the pressure plate, the silicone rubber heating film heats the pressure film to a specified temperature, and the number of the pressure adjusting columns of the planar pressure regulator in the vertical direction is adjusted, so that the pressure of the pressure plate pressing the rotary collecting tray is consistent with the plan.
Furthermore, in the process of spraying the electrospun fiber, the width and the direction of the air outlet strips of the four air outlets are adjusted, an external constant-temperature and constant-humidity air source is started, a constant-temperature and constant-humidity air field is formed around the rotary collecting tray by the four adjustable air outlets, the first electrospun solution is sprayed out from the needle head under the action of an electric field and pressure and is formed on the rotary collecting tray according to the shape of the first template, and the model rotary table drives the motor to rotate in the forward direction after the first electrospun solution is sprayed for a specified time.
The invention also relates to application of the electrospinning fiber jet forming device in forming multilayer electrospinning fibers of various materials and shapes.
Has the advantages that: according to the invention, the automatic alternate spraying of the material and the shape of the electrospun fiber is realized in a rotating mode through the rotatable electrospinning spraying rotary table and the model rotary table, and the transverse and vertical movement of the collection table is realized through the pressing motion platform below the collection table, so that the electrospun fiber can be compacted layer by layer as required to form a 3D layered structure.
Drawings
FIG. 1 is a schematic view of the structure of an ejection forming apparatus according to the present invention;
FIG. 2 is a graph of the effect of a 3D stacked electrospun fiber jet;
FIG. 3 is a schematic diagram of a planar pressure regulator.
10. The model turntable comprises a model turntable, 11 driving motors, 12 supporting arms, 13 plane supporting plates, 14 supporting rods and 15 supporting rod height adjusting rings;
20. an electrospinning jet turntable, 21. a driving motor, 22. a supporting arm, 23. an electrospinning container, 24. a jet needle head, 25. a supporting rod, 26. a supporting rod height adjusting ring;
30. the air conditioner comprises a collecting table, 31, an adjustable air outlet, 32, a rotary collecting tray, 33, a downward pressing motion platform, 331, a transverse motion driving motor, 332, a supporting frame, 333, a longitudinal motion driving motor, 334, a supporting column, 335, a pressure adjusting column, 336, a transverse shaft, 337, a connector, 34, a plane pressure regulator, 35, a control knob, 36, a pressure plate, 37, a pressure film, 38, a heating film and 39, and an external air source port;
40. electrospinning fibers;
51. first layer of electrospun fibers, 52. second layer of electrospun fibers, 53. third layer of electrospun fibers, 54. fourth layer of electrospun fibers
Detailed Description
In order to more clearly illustrate the embodiments or prior art solutions of the present invention, the drawings used in the description of the embodiments or prior art will be described in detail below.
Example 1: as shown in fig. 1, a 3D stacked electrospinning fiber spray forming device for experiments is composed of an electrospinning spray turntable, a model turntable, and a collection table, wherein the electrospinning spray turntable comprises a spraying turntable rotation driving motor 21, a spraying turntable supporting arm 22, an electrospinning container 23, a spraying needle 24, a spraying turntable supporting rod 25, and a spraying turntable supporting rod height adjusting ring 26; the model rotary table comprises a model rotary table driving motor 11, a model rotary table supporting arm 12, a plane supporting plate 13, a model rotary table supporting rod 14 and a model rotary table supporting rod height adjusting ring 15; the collecting table comprises an adjustable air outlet 31, a rotary collecting tray 32, a downward-pressing moving platform 33, a plane pressure regulator 34, a control knob 35, a pressure plate 36, a pressure film 37, a heating film 38 and an external air source port 39. In order to conveniently and clearly show the structure of the device, the position of the model rotary table in the schematic diagram is intentionally increased upwards, but in actual use, the position of the model rotary table is only 2-5 cm higher than the tray.
The spraying turntable rotation driving motor 21 is responsible for driving the spraying turntable to rotate, and when a certain layer needs to spray certain electrospinning solution, the spraying turntable rotation driving motor can rotate the corresponding solution to be right above the spraying model. The spraying turntable supporting arm 22 is responsible for connecting the spraying turntable rotation driving motor and the electrospinning container, and plays a role in supporting the electrospinning container. The electrospinning vessel 23 is responsible for holding various electrospinning solutions. And a spraying needle 24, from which the electrospinning solution is sprayed under the action of pressure and an electric field, and the diameter of the needle can be changed according to the requirements of the experiment. The injection turntable support rod 25 is responsible for supporting the injection turntable, one end of the support rod is fixed on the extension surface on the right side of the collection table, and the support rod can move transversely along the collection table to adjust the coordinate of the injection needle. The height adjusting ring 26 for the supporting rod of the spraying rotary table is used for adjusting the height of the supporting rod of the spraying rotary table so as to match different spraying experiment requirements. The turntable drive motor 11 is responsible for driving the model turntable support arm to rotate so that the corresponding model is directly above the collection tray. The model turntable supporting arm 12 is responsible for connecting a turntable driving motor and a plane supporting plate and plays a supporting role for the plane supporting plate. The plane supporting plate 13 can be selected in various types (the middle of the plane supporting plate is hollowed into a circle, a rectangle, a semicircle, a triangle and the like), and before an experiment, an operator can select the supporting plate according to the experiment requirement and fix the supporting plate on the model turntable supporting arm 12 respectively. The model turntable support rod 14 is responsible for supporting the model turntable, the bottom end of the model turntable support rod is fixed on the extension surface on the left side of the collecting table, and the support rod can extend to the transverse movement of the collecting table to adjust the coordinate of the center of the plane supporting plate, so that the center of the plane supporting plate, the center of the injection needle head and the center of the rotary collecting tray form a vertical straight line. The model turret support height adjustment ring 15 is responsible for adjusting the height of the model turret support to control the size of the spun fiber shape on the rotating collection tray 32. The adjustable air outlet 31 has important influence on the injection and formation of the electrospun fibers due to the environment temperature and humidity, the stable environment temperature and humidity is maintained, the experiment precision is improved, the 4 adjustable air outlets vertically upwards exhaust air, and the size and the direction of the 4 air outlets can be manually adjusted. The tray 32 is collected in the rotation, has the recess that can be used for fixed aluminium foil on the tray, and the tray is used for collecting the electrospinning fibre that falls from the plane layer board, and the tray can be according to the demand by the motor control corotation of the below at a slow speed or reversal, and rotatory collection tray 32 can extend x axle and y axle and move on the collection platform to the position of regulation tray.
The pressure plate 36 is responsible for compacting a layer of electrospun fiber material on the rotary collecting tray, and the middle of the pressure plate is hollowed out and can be provided with pressure films made of different materials. The pressure film 37 has 2 layers to play the role of elastic compaction, pressure films of different materials are selected according to different electrospinning materials, the pyromellitic polyimide film has good heat-conducting property, chemical corrosion resistance, stretch resistance and insulation, and common electrospinning materials can be selected as the upper layer and the lower layer of the pressure film. The side length of the square pressure film is larger than the diameter of the tray so as to ensure that the tray is completely covered when the pressure film falls down. The pressure membrane 37 can flatten the single/multi-layer electrospun fiber material on the rotating collection tray. The heating film 38 is arranged between the 2 layers of pressure films, the controllable silicon rubber heating films are arranged between the two layers of pressure films 37 in a wave mode, and the temperature of the silicon rubber heating films is adjusted through the control knob 35.
The downward-pressing motion platform 33 is a transverse and longitudinal motion system consisting of three motors and aluminum alloy support rods. The pressure plate is used for heating the electrospinning fibers on the tray at a constant pressure and a constant temperature under the pressure action of the pressure plate on the tray. The downward-pressing moving platform 33 is composed of 2 lateral moving driving motors 331, a supporting frame 332, a longitudinal moving driving motor 333, a supporting column 334, a pressure adjusting column 335, a transverse shaft 336 and a connector 337, wherein the supporting column 334, the pressure adjusting column 335, the transverse shaft 336 and the connector 337 are used in cooperation to function as a pressure regulator. When the single-layer electrospun fiber needs to be heated at constant pressure and constant temperature, firstly, the 2 transverse movement driving motors 331 push the moving platform 33 to the upper part of the rotary collecting tray 32, the longitudinal movement driving motor 333 rotates to press the pressure regulator, and the pressure film 37 connected to the pressure plate 36 below the pressure regulator heats the electrospun fiber.
The pressure regulator consists of 2 support columns 334 and 5 pressure regulating columns 335. The support column 334 supports on side 2 and the pressure adjustment column 335 is 360 degrees reversible centered on the horizontal axis 336 to adjust 6 levels of pressure by the number of support column operations (since the single longitudinal motion drive motor 333 will push the pressure regulator to a given position and if the number of pressure adjustment columns 335 operated is large, a greater downward pressure will be generated). The structure and operation of which is shown in fig. 3, wherein only 3 pressure regulating columns 335 are operating (providing fourth gear pressure) in fig. 3.
The control knob 35 consists of 6 right control buttons, and one control button is responsible for controlling the injection turntable to rotate the driving motor 21; the second is responsible for controlling the turntable driving motor 11; the third is responsible for controlling the drive motor of the rotary collecting tray 32; the fourth and fifth are responsible for controlling the transverse and longitudinal movement of the pressing movement platform 33; six of them are responsible for controlling the temperature of the heated film. The external air source port 39 is responsible for connecting an external constant temperature and humidity air source to provide constant temperature and humidity air to the 4 air outlets 31.
The experimental 3D heap electrospun fiber sprays forming device of this embodiment through succinct, practical mechanical structure to lower cost has realized that can self-defined automatic many materials of 3D heap and the multilayer electrospun fiber successive layer of shape sprays, and does not need artifical interference, has improved the efficiency that electrospun fiber sprayed the experiment and the stability of experiment. The device has small floor area and low requirement on the use environment; the device has rich fittings, can realize the electrospinning injection of various shapes, and is quick to disassemble, combine and package, thereby being convenient to transport; when the device is operated, the non-seal scattering of fiber impurities can be effectively controlled, and the influence on the surrounding environment is avoided. The device can realize the automatic 3D stacking type multilayer electrospun fiber injection with the customizable electrospun fiber at lower cost, and has the advantages of simple operation, stable operation and the like. Is very suitable for being popularized in units such as universities and colleges, research institutes and the like.
Example 2: as shown in fig. 1, a 3D stacked electrospinning fiber spray forming device for experiments is composed of an electrospinning spray turntable, a model turntable, and a collection table, wherein the electrospinning spray turntable comprises a spraying turntable rotation driving motor 21, a spraying turntable supporting arm 22, an electrospinning container 23, a spraying needle 24, a spraying turntable supporting rod 25, and a spraying turntable supporting rod height adjusting ring 26; the model rotary table comprises a model rotary table driving motor 11, a model rotary table supporting arm 12, a plane supporting plate 13, a model rotary table supporting rod 14 and a model rotary table supporting rod height adjusting ring 15; the collecting table comprises an adjustable air outlet 31, a rotary collecting tray 32, a downward-pressing moving platform 33, a plane pressure regulator 34, a control knob 35, a pressure plate 36, a pressure film 37, a heating film 38 and an external air source port 39.
The 3D stacked electrospinning fiber spraying forming device can perform self-defined spraying on electrospinning fiber materials layer by layer according to experimental requirements. Before the device is used, experimenters carry out the proportioning of the electrospinning solution according to the material requirements of each layer of electrospinning fiber and then respectively put the electrospinning solution into the electrospinning container 23. The turntable rotation driving motor 21 rotates 90 degrees to make the spraying needle 24 align with the center of the rotation collection tray 32, and the height of the height adjusting ring 26 of the supporting rod of the turntable is sprayed according to the experimental requirement, so that the distance between the bottommost end of the spraying needle 24 and the center of the rotation collection tray 32 just meets the experimental requirement. Different templates are selected according to the shape requirement of the electro-spun fiber of each layer and are sequentially arranged on the model rotary table supporting arm 12. The height of the model turntable support height adjustment ring 15 is adjusted to a distance of 322-5 cm from the rotating collection tray. However, in the first schematic diagram, the model turret position in the schematic diagram is intentionally raised in order to facilitate visual and clear representation of the apparatus structure. When the model turntable supporting arm 12 is located at the initial position, the model turntable driving motor 11 rotates forward 90 degrees to rotate the first plane supporting plate 13 to the rotary collecting tray 32, and the center of the plane supporting plate 13 is coincident with and perpendicular to the rotary collecting tray 32 and the center of the injection needle 24.
The downward-pressing motion platform 33 is a transverse and longitudinal motion system consisting of three motors and aluminum alloy support rods. The pressure plate is used for heating the electrospinning fibers on the tray at a constant pressure and a constant temperature under the pressure action of the pressure plate on the tray. When the single-layer electrospun fiber needs to be heated at constant pressure and constant temperature, firstly, the 2 transverse movement driving motors 331 push the moving platform 33 to the upper part of the rotary collecting tray 32, the longitudinal movement driving motor 333 rotates to press the pressure regulator, and the pressure film 37 connected to the pressure plate 36 below the pressure regulator heats the electrospun fiber.
The pressure regulator consists of 2 support columns 334 and 5 pressure regulating columns 335. The support column 334 supports on side 2 and the pressure adjustment columns 335 are 360 degrees reversible centered on the horizontal axis 336 to adjust 6 levels of pressure by the number of support column operations (since the longitudinal motion drive motor 333 will push the pressure regulator to a given position and if the number of pressure adjustment columns 335 operated is large, a greater downward pressure will be generated). The structure and operation of which is shown in fig. 3, wherein only 3 pressure regulating columns 335 are operating (providing fourth gear pressure) in fig. 3.
The lower pressure moving platform 33 is located at the initial position (right side), a suitable pressure film 37 material is selected according to the type of the first electrospinning solution (ensuring that the pressure film is not sticky with the electrospun fiber filaments after being sprayed, and a pyromellitic polyimide film is generally selected), the pressure film 37 is installed on the pressure plate 36, the silicone rubber heating film 38 heats the pressure film 37 to a specified temperature, and the number of pressure adjusting columns 342 on the planar pressure regulator 34 is adjusted, so that the pressure of the pressure plate pressing the rotary collecting tray conforms to the experimental plan.
Adjust the strip width and the direction of giving vent to anger of 4 air outlets 31, start outside constant temperature and humidity air supply, 4 adjustable air outlets 31 form the constant temperature and humidity's air field around rotatory collection tray 32. The first electrospinning solution is ejected from the needle under the influence of the electric field and pressure and shaped in the shape of the first template on the rotating collection tray 32, and the model turntable driving motor 11 rotates forward 45 degrees after a specified time of ejection of the first electrospinning solution.
The platform is driven to move rightwards by 2 transverse motion driving motors 331 on the downward-pressing motion platform 33, the longitudinal motion driving motor 333 drives a pressure regulator to drive a pressure film 37 to completely cover the rotary collecting tray 32 and compact the pressure (the pressure is controlled by the plane pressure regulator, the film temperature is controlled by a heating film 38, the downward-pressing time is regulated by a control knob 35), then the longitudinal motion driving motor drives a retraction pressure regulator, and the transverse motion driving motor 331 drives the downward-pressing motion platform to return to the initial position. And finishing the spray forming and temperature control compaction of the first layer of the electro-spinning material. The injection turret rotation drive motor 21 rotates 90 degrees to align the second electrospinning vessel 23 with the center of the rotating collection tray 32 and the mold turret drive motor 11 rotates 90 degrees to position the second planar support plate 13 above the rotating collection tray 32 and begin the formation injection of the second layer of electrospun fibrous material. Similarly, one-time spraying and stacking of each layer of electrospun fibers are completed according to the experimental plan, and the final effect diagram is shown in fig. 2, wherein 51 is the first layer of electrospun fibers, 52 is the second layer of electrospun fibers, 53 is the third layer of electrospun fibers, and 54 is the fourth layer of electrospun fibers.
Example 3: A3D stacked electrospinning fiber spraying forming device for experiments mainly comprises an electrospinning spraying rotary table 20, a model rotary table 10 and a collecting table 30, wherein the collecting table 30 collects electrospinning fibers layer by layer, the electrospinning spraying rotary table 20 is provided with a plurality of rotatable electrospinning containers 23, the model rotary table 10 is provided with a plurality of plane supporting plates 13, the electrospinning fibers on a certain layer of the collecting table 30 are formed by rotating the electrospinning containers 23 with corresponding types of electrospinning fiber solutions to the corresponding positions above the corresponding plane supporting plates 13 and spraying, and the corresponding plane supporting plates 13 rotate to the corresponding positions above the collecting table 30 for forming the electrospinning fibers with the required shapes on the certain layer.
The electrospinning jet rotary table 20 comprises a rotary driving motor 21, a supporting arm 22, an electrospinning container 23, a jet needle 24 and a supporting rod 25; the support rod 25 is installed at one end of the fixed support base, the top end of the support rod 25 is provided with a rotating shaft, the rotating drive motor drives the rotating shaft to rotate, the rotating shaft can be rotatably connected to the top end of the support rod 25 by taking the support rod 25 as a rotating center, a plurality of support walls are connected to the rotating shaft to rotate along with the rotating shaft, the terminal ends of the support walls are connected with the electrospinning container 23, and the electrospinning container 23 is provided with the spraying needle 24. The electrospinning spraying turntable 20 further includes a support rod height adjusting ring 26 for height adjustment of the support rod 25, the support rod height adjusting ring 26 being mounted on the support rod 25.
The model rotary table 10 comprises a driving motor 11, a supporting arm 12, a plane supporting plate 13 and a supporting rod 14; the supporting rod 14 is installed at one end of the fixed supporting base and is the end opposite to the electrospinning spraying rotary table 20, a rotating shaft is arranged at the top end of the supporting rod 14, the driving motor drives the rotating shaft to rotate, the rotating shaft is rotatably connected to the top end of the supporting rod 14 by taking the supporting rod 14 as a rotation center, a plurality of supporting walls are connected to the rotating shaft to rotate along with the rotating shaft, the terminal ends of the supporting walls are connected with the plane supporting plate 13, and the plane supporting plate 13 is provided with openings with different shapes for forming electrospinning limiting shapes with different shapes.
The collection station 30 comprises a rotating collection tray 32, a pressure plate 36, a downward pressure motion platform 33, a planar pressure regulator 337, a connector 337, and a pressure plate 36; the rotary collecting tray 32 is positioned at one side of the collecting platform 30 close to the supporting rod 14 of the model rotary table 10, the pressure plate 36 is positioned at one side of the collecting platform 30 close to the electrospinning spraying rotary table 20, the rotary collecting tray 32 is positioned at a spraying position, a stopping position for forming a plane supporting plate 13 with a corresponding shape is above the spraying position, and a stopping position for forming an electrospinning container 23 with a corresponding electrospinning solution type is above the plane supporting plate 13; the downward-pressing motion platform 33 is a transverse and longitudinal motion system composed of three motors and aluminum alloy support rods 14, and comprises a transverse motion driving motor 331, a transverse rod, a longitudinal rod, a support frame 332 and a longitudinal motion driving motor 333, wherein the transverse rod is connected with the longitudinal rod through the support frame 332, the transverse rod is connected with the longitudinal rod through the support frame 332 to form a triangular support, the transverse rod is movably connected with the collection table 30, the transverse motion driving motor 331 drives the transverse rod to move transversely along the collection table 30, the longitudinal motion driving motor 333 drives the longitudinal rod to move longitudinally, the longitudinal rod is connected with a plane pressure regulator 337, the lower end surface of the plane pressure regulator 337 is connected with a connector 337, the lower end surface of the connector 337 is connected with a pressure plate 36, the transverse motion driving the downward-pressing motion platform 33 to move transversely through the transverse motion of the transverse rod, so that the pressure plate 36 is moved above the rotary collection tray 3232, the longitudinal rod drives the planar pressure regulator 337 to move longitudinally so that the distance of the pressure plate 36 from the rotating collection tray 32 is adjusted and the pressure plate 36 is pressed against the rotating collection tray 32. The pressure plate 36 is hollow in the middle to mount a pressure film 37 and a heating film 38, the pressure film 37 comprises two layers, and the heating film 38 is arranged between the two layers of pressure films 37.
The pressure membrane 37 is square with sides longer than the radius of the circular rotating collection tray 32. The planar pressure regulator 337 is composed of two side support columns 334 and a plurality of pressure regulating columns 335, wherein the support columns 334 are used for supporting at the sides, and the pressure regulating columns 335 are turnable around a horizontal axis 336. The collecting table around the rotary collecting tray 32 is provided with an adjustable air outlet 31, and the adjustable air outlet 31 is vertically upward for air outlet.
The fixed support base is a transversely fixed rectangular column, one end of the fixed support base is fixedly provided with a support rod 25, the other end of the fixed support base is fixedly provided with a support rod 14, the bottom of the collection table 30 is transversely provided with a sliding groove, the fixed support base and the collection table 30 are arranged through the sliding groove, and the fixed support base can transversely move to adapt to the position adjustment of the collection table.
The application of an electrospinning fiber jet forming device in the formation of multi-layer electrospinning fibers with various materials and shapes is as follows:
A3D stacked electrospinning fiber spraying method for experiments is characterized in that a 3D stacked electrospinning fiber spraying forming device carries out self-defined spraying on the electrospinning fiber material and shape according to experiment requirements. Or in order to realize the multi-layer electro-spinning fiber spraying of different materials and shapes, or simply carry out multi-layer spraying on the same material and shape, the 3D stacking multi-layer electro-spinning fiber layer-by-layer spraying method is characterized in that a 3D stacking electro-spinning fiber spraying forming device sprays layer by layer, two transverse movement driving motors of a downward pressing movement platform drive the downward pressing movement platform to move transversely, a longitudinal movement driving motor drives a plane pressure regulator to drive a pressure film of a pressure plate to completely cover a rotary collecting tray and compact the pressure film, then the longitudinal movement driving motor drives the pressure plate to withdraw the plane pressure regulator, a transverse movement driving motor drives the downward pressing movement platform to return to an initial position to complete the spraying forming of the first layer of electro-spinning fiber, a spraying turntable rotary driving motor rotates to align a second electro-spinning container to the center of the rotary collecting tray, and a model turntable driving motor rotates, and placing a second plane supporting plate above the rotary collecting tray, starting the forming and spraying of a second layer of the electrospun fibers, and circulating the spraying process to finish the forming and spraying of the multilayer electrospun fibers.
Before the device is used, the proportion of electrospinning solutions is carried out according to the material requirements of each layer of electrospinning fibers, the electrospinning solutions with different proportions are respectively filled into an electrospinning container, and a rotary table rotates to drive a motor to rotate, so that a spraying needle head is aligned with the center of a rotary collecting tray; selecting different templates according to the shape requirements of the electrospun fibers of each layer, sequentially installing the templates on a supporting arm of a model turntable, and adjusting the height of a height adjusting ring of a supporting rod of the model turntable to enable the distance between the model turntable and a rotary collecting tray to be 2-5 cm; when the supporting arm of the model turntable is positioned at the initial position, the model turntable drives the motor to rotate in the forward direction, so that the first plane supporting plate rotates to the rotary collecting tray, and the center of the plane supporting plate is superposed and vertical to the rotary collecting tray and the center of the injection needle; the downward pressing motion platform moves horizontally and longitudinally for adjustment, so that the pressure plate applies pressure to the rotating collection tray, and the electrospinning limit, the fixed pressure and the fixed temperature on the rotating collection tray are heated; the single-layer electrospun fiber is heated at constant pressure and constant temperature, firstly two transverse motion driving motors drive a transverse rod, a downward-pressing motion platform is transversely moved to the upper part of a rotary collecting tray, a longitudinal motion driving motor drives a longitudinal rod to enable a plane pressure regulator to be pressed downward, a pressure film of a pressure plate connected to the lower part of the pressure regulator is used for constant pressure, and the electrospun fiber is heated at constant temperature by a heating film.
The pressure regulator comprises two support columns and a plurality of pressure regulating columns, wherein the support columns play a supporting role on two sides, the pressure regulating columns can turn over by taking a transverse shaft as a center, the pressure of multiple grades is regulated through the working quantity of the support columns, and the working columns are in vertical positions. The lower pressing motion platform 33 is located at an initial position, a proper pressure film material is selected according to the type of the first electrospinning solution, the pressure film is installed on the pressure plate, the silicon rubber heating film heats the pressure film to a specified temperature, and the number of the pressure adjusting columns of the plane pressure regulator in the vertical direction is adjusted, so that the pressure of the pressure plate pressing the rotary collecting tray conforms to the plan. In the electrospinning fiber spraying process, the width and the direction of the air outlet strips of the four air outlets are adjusted, an external constant-temperature and constant-humidity air source is started, a constant-temperature and constant-humidity air field is formed around the rotary collecting tray by the four adjustable air outlets, a first electrospinning solution is sprayed out from the needle head under the action of an electric field and pressure and is formed on the rotary collecting tray according to the shape of a first template, and the model turntable drives the motor to rotate in the forward direction after the first electrospinning solution is sprayed for a specified time.
The above description is only for the purpose of creating a preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art can substitute or change the technical solution and the inventive concept of the present invention within the technical scope of the present invention.
Claims (5)
1. A3D stacked electrospinning fiber spraying method for experiments is characterized in that a 3D stacked electrospinning fiber spraying forming device carries out self-defined spraying on the electrospinning fiber material and shape according to experiment requirements; before the device is used, the proportion of electrospinning solutions is carried out according to the material requirements of each layer of electrospinning fibers, the electrospinning solutions with different proportions are respectively filled into an electrospinning container, and a rotary table rotates to drive a motor to rotate, so that a spraying needle head is aligned with the center of a rotary collecting tray; selecting different templates according to the shape requirements of the electrospun fibers of each layer, sequentially installing the templates on a supporting arm of a model turntable, and adjusting the height of a height adjusting ring of a supporting rod of the model turntable to enable the distance between the model turntable and a rotary collecting tray to be 2-5 cm; when the supporting arm of the model turntable is positioned at the initial position, the model turntable drives the motor to rotate in the forward direction, so that the first plane supporting plate rotates to the rotary collecting tray, and the center of the plane supporting plate is superposed and vertical to the rotary collecting tray and the center of the injection needle; the downward pressing motion platform moves horizontally and longitudinally for adjustment, so that the pressure plate applies pressure to the rotating collection tray, and the electrospinning limit, the fixed pressure and the fixed temperature on the rotating collection tray are heated; the single-layer electrospun fiber is heated at constant pressure and constant temperature, firstly two transverse motion driving motors drive a transverse rod, a downward-pressing motion platform is transversely moved to the upper part of a rotary collecting tray, a longitudinal motion driving motor drives a longitudinal rod to enable a plane pressure regulator to be pressed downward, a pressure film of a pressure plate connected to the lower part of the pressure regulator is used for constant pressure, and the electrospun fiber is heated at constant temperature by a heating film.
2. The experimental 3D stacked electrospinning fiber spraying method of claim 1, wherein the pressure regulator is composed of two support columns and a plurality of pressure regulating columns, the support columns support on both sides, the pressure regulating columns can be turned over centering on a horizontal axis, and the plurality of levels of pressure are regulated by the number of works of the support columns, which works so that the work columns are in a vertical position.
3. The experimental 3D stacked electrospinning fiber spraying method according to claim 1, wherein the downward moving platform (33) is located at an initial position, a suitable pressure membrane material is selected according to the type of the first electrospinning solution, the pressure membrane is mounted on a pressure plate, a silicone rubber heating membrane heats the pressure membrane to a specified temperature, and the number of pressure adjusting columns of a planar pressure regulator located in a vertical direction is adjusted so that the pressure of the pressure plate pressing against the rotating collecting tray is in accordance with a plan.
4. The method for spraying experimental 3D stacked electrospun fibers as claimed in claim 1, wherein in the process of spraying electrospun fibers, the width and direction of the air outlet strips of the four adjustable air outlets are adjusted, the external constant-temperature and constant-humidity air source is started, the four adjustable air outlets form a constant-temperature and constant-humidity air field around the rotating collection tray, the first electrospun solution is sprayed from the needle head under the action of the electric field and the pressure and is formed on the rotating collection tray according to the shape of the first template, and the model turntable drives the motor to rotate forward after the first electrospun solution is sprayed for a specified time.
5. An application of an electrospinning fiber jet forming device in the formation of multi-layer electrospinning fibers with various materials and shapes.
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