CN109371334A - A kind of high abrasion coating material for lithium battery cutting machine - Google Patents

A kind of high abrasion coating material for lithium battery cutting machine Download PDF

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Publication number
CN109371334A
CN109371334A CN201811351917.0A CN201811351917A CN109371334A CN 109371334 A CN109371334 A CN 109371334A CN 201811351917 A CN201811351917 A CN 201811351917A CN 109371334 A CN109371334 A CN 109371334A
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CN
China
Prior art keywords
parts
coating material
cutting machine
high abrasion
lithium battery
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201811351917.0A
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Chinese (zh)
Inventor
徐林
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Jiangsu Wanda New Energy Polytron Technologies Inc
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Jiangsu Wanda New Energy Polytron Technologies Inc
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Priority to CN201811351917.0A priority Critical patent/CN109371334A/en
Publication of CN109371334A publication Critical patent/CN109371334A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/10Ferrous alloys, e.g. steel alloys containing cobalt
    • C22C38/105Ferrous alloys, e.g. steel alloys containing cobalt containing Co and Ni
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C32/00Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ
    • C22C32/0094Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with organic materials as the main non-metallic constituent, e.g. resin
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/005Ferrous alloys, e.g. steel alloys containing rare earths, i.e. Sc, Y, Lanthanides
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/008Ferrous alloys, e.g. steel alloys containing tin
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/12Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/14Ferrous alloys, e.g. steel alloys containing titanium or zirconium
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C30/00Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Powder Metallurgy (AREA)
  • Cutting Tools, Boring Holders, And Turrets (AREA)

Abstract

A kind of high abrasion coating material for lithium battery cutting machine provided by the invention, the component of at least following parts by weight are made: 40-50 parts of Ni-Ti-Nb-Fe based alloy, the Si of 20-40 parts by weight3B0.5C1.5N0.5AlxParticle, 8-12 parts of graphite are 4-6 parts of nano titanium carbide, 4-6 parts of Nano titanium nitride, niobium 1-2 parts nano oxidized.The high abrasion coating material intensity with higher and toughness, wearability is good, has certain anti-oxidant and corrosion resistance.

Description

A kind of high abrasion coating material for lithium battery cutting machine
Technical field
The present invention relates to a kind of high abrasion coating materials for lithium battery cutting machine, belong to field of new materials.
Background technique
Tool in Cutting performance determines the working performance of lithium battery cutting machine, and cutter material is to determine Tool in Cutting performance Fundamental factor, for processing efficiency, processing quality, processing cost and tool life influence it is very big.The knife of function admirable Have material, is the primary condition for guaranteeing cutter efficient operation.Blades of cutting tools works under strong friction, high pressure, high temperature, answers Has following basic demand.
Coated cutting tool is a kind of nearly 20 years NEW TYPES OF TOOL MATERIALSs occurred, is the developing important breakthrough of cutter, is Solve hardness, a wear-resisting effective measures contradictory between intensity, toughness in cutter material.Coated cutting tool is in some toughness On preferable hard alloy or high-speed steel tool matrix, coats the high infusibilized metallic compound of one layer of wearability and obtain. Common coating material has TiC, TiN and Al2O3 etc..Coat one layer of carbon at the beginning of 1970's on hard alloy substrate for the first time After changing titanium (TiC), the cutting speed of ordinary rigid alloy is increased to 180m/min from 80m/min.There is carbon again within 1976 Change the double coated carbides of titanium-aluminium oxide, cutting speed is increased to 250m/min.There is titanium carbide-oxidation again within 1981 Aluminium-cobalt nitride Three coating hard alloy, makes cutting speed be increased to 300m/min.
Current each industrially developed country is very fast to the research and extension use aspect development of coated cutting tool.It is in a leading position The Sweden of status, has accounted for 70%-80% using coated cemented carbide insert in turning, had reached in terms of milling 50% with On.But coated cutting tool is not suitable for processing high temperature alloy, titanium alloy and nonmetallic materials, being also not suitable for roughing has burning into sand, hard The forging and casting of skin.
Summary of the invention
Technical problem: in order to solve the defects of prior art, the present invention provides a kind of height for lithium battery cutting machine Abrasion-resistant coating material.
Technical solution: a kind of high abrasion coating material for lithium battery cutting machine provided by the invention, it is at least following The component of parts by weight is made: 40-50 parts of Ni-Ti-Nb-Fe based alloy, the Si of 20-40 parts by weight3B0.5C1.5N0.5AlxParticle, 8-12 parts of graphite, it is 4-6 parts of nano titanium carbide, 4-6 parts of Nano titanium nitride, niobium 1-2 parts nano oxidized.
As an improvement, the Ni-Ti-Nb-Fe based alloy includes the component of following weight percent: Ni 26-33%, Ti 14-18%, Nb 8-12%, Co 4-6%, W 3-4%, Sn 4-6%, Y 0.2-0.8%, surplus Fe.
As an improvement, x is 0.05-0.3.
The present invention also provides the preparation methods of the high abrasion coating material for lithium battery cutting machine, including following step It is rapid:
(1)Si3B0.5C1.5N0.5AlxPreparation: use a cube silicon powder, hexagonal boron nitride powder, graphite powder, metallic aluminium powder for original Material, is placed in ball milling in planetary ball mill, obtains mixture;By mixture be placed in sintering equipment be sintered to get;
(2) preparation of high abrasion coating material: by nickel oxide, titanium oxide, niobium oxide, cobalt oxide, tungsten oxide, tin oxide, Yttrium oxide and iron oxide are placed in ball milling 8-12h in planetary ball mill, add Si3B0.5C1.5N0.5AlxContinue ball milling 8-12h, obtains Coating composition;
(3) utilize physical vaporous deposition by coating composition in cutting machine tool matrix surface.
The utility model has the advantages that provided by the present invention for the high abrasion coating material intensity with higher of lithium battery cutting machine, Wearability is good, has certain anti-oxidant and corrosion resistance, especially suitable for lithium battery cutting machine.
Specific embodiment
The present invention is further illustrated below.
Embodiment 1
For the high abrasion coating material of lithium battery cutting machine, the component of at least following parts by weight is made: 40 parts of Ni- Ti-Nb-Fe based alloy, the Si of 40 parts by weight3B0.5C1.5N0.5Al0.05Particle, 8 parts of graphite, 4 part, nanometer nitrogen of nano titanium carbide Change 6 parts of titanium, 1 part of nano oxidized niobium.
The Ni-Ti-Nb-Fe based alloy includes the component of following weight percent: Ni 26%, Ti 18%, Nb 8%, Co 6%, W 3%, Sn 6%, Y 0.2%, surplus Fe.
Preparation method, comprising the following steps:
(1)Si3B0.5C1.5N0.5AlxPreparation: use a cube silicon powder, hexagonal boron nitride powder, graphite powder, metallic aluminium powder for original Material, is placed in ball milling in planetary ball mill, obtains mixture;By mixture be placed in sintering equipment be sintered to get;
(2) preparation of high abrasion coating material: by nickel oxide, titanium oxide, niobium oxide, cobalt oxide, tungsten oxide, tin oxide, Yttrium oxide and iron oxide are placed in ball milling 8-12h in planetary ball mill, add Si3B0.5C1.5N0.5AlxContinue ball milling 8-12h, obtains Coating composition;
(3) utilize physical vaporous deposition by coating composition in cutting machine tool matrix surface.
Embodiment 2
For the high abrasion coating material of lithium battery cutting machine, the component of at least following parts by weight is made: 50 parts of Ni- Ti-Nb-Fe based alloy, the Si of 20 parts by weight3B0.5C1.5N0.5Al0.3Particle, 12 parts of graphite, 6 part, nanometer nitrogen of nano titanium carbide Change 4 parts of titanium, 2 parts of nano oxidized niobium.
The Ni-Ti-Nb-Fe based alloy includes the component of following weight percent: Ni 33%, Ti 14%, Nb 12%, Co 4%, W 4%, Sn 4%, Y 0.8%, surplus Fe.
Preparation method is substantially the same manner as Example 1.
Embodiment 3
For the high abrasion coating material of lithium battery cutting machine, the component of at least following parts by weight is made: 45 parts of Ni- Ti-Nb-Fe based alloy, the Si of 30 parts by weight3B0.5C1.5N0.5Al0.02Particle, 10 parts of graphite, 5 part, nanometer nitrogen of nano titanium carbide Change 5 parts of titanium, 1.5 parts of nano oxidized niobium.
The Ni-Ti-Nb-Fe based alloy includes the component of following weight percent: Ni 29%, Ti 16%, Nb 10%, Co 5%, W 3.5%, Sn 5%, Y 0.5%, surplus Fe.
Preparation method is substantially the same manner as Example 1.
The high abrasion coating material performance of testing example 1 to 3.
Project Hardness GPa Coefficient of friction Wear rate (m3/N·m)
Embodiment 1 38 0.3 6.4×10-16
Embodiment 2 39 0.4 4.4×10-16
Embodiment 3 42 0.3 2.9×10-16

Claims (4)

1. a kind of high abrasion coating material for lithium battery cutting machine, it is characterised in that: at least by the component of following parts by weight It is made: 40-50 parts of Ni-Ti-Nb-Fe based alloy, the Si of 20-40 parts by weight3B0.5C1.5N0.5AlxParticle, 8-12 parts of graphite, It is 4-6 parts of nano titanium carbide, 4-6 parts of Nano titanium nitride, niobium 1-2 parts nano oxidized.
2. a kind of high abrasion coating material for lithium battery cutting machine according to claim 1, it is characterised in that: described Ni-Ti-Nb-Fe based alloy includes the component of following weight percent: Ni 26-33%, Ti 14-18%, Nb8-12%, Co 4-6%, W 3-4%, Sn 4-6%, Y 0.2-0.8%, surplus Fe.
3. a kind of high abrasion coating material for lithium battery cutting machine according to claim 1, it is characterised in that: x is 0.05-0.3。
4. a kind of preparation method of high abrasion coating material for lithium battery cutting machine described in claim 1, feature exist In: the following steps are included:
(1)Si3B0.5C1.5N0.5AlxPreparation: use a cube silicon powder, hexagonal boron nitride powder, graphite powder, metallic aluminium powder for raw material, It is placed in ball milling in planetary ball mill, obtains mixture;By mixture be placed in sintering equipment be sintered to get;
(2) preparation of high abrasion coating material: by nickel oxide, titanium oxide, niobium oxide, cobalt oxide, tungsten oxide, tin oxide, oxidation Yttrium and iron oxide are placed in ball milling 8-12h in planetary ball mill, add Si3B0.5C1.5N0.5AlxContinue ball milling 8-12h, obtains coating Composition;
(3) utilize physical vaporous deposition by coating composition in cutting machine tool matrix surface.
CN201811351917.0A 2018-11-14 2018-11-14 A kind of high abrasion coating material for lithium battery cutting machine Withdrawn CN109371334A (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2001000A1 (en) * 1968-01-30 1969-09-19 Int Nickel Ltd
US6245439B1 (en) * 1994-08-09 2001-06-12 Kabushiki Kaisha Toyoyta Chuo Kenkyusho composite material and method for the manufacture
CN101705410A (en) * 2009-10-16 2010-05-12 孙晓冰 Wear-resistant and thermal corrosion resistant multi-element aluminum-silicon-carbon nitride metal ceramic for laser cladding
CN102218857A (en) * 2011-05-27 2011-10-19 合肥金四达科技有限公司 Composite material coated with SiC-Fe based alloy layer and preparation method of composite material
CN105779996A (en) * 2016-03-17 2016-07-20 苏州范德雅特新材料科技有限公司 High-wear-resisting metal ceramic coating
CN206878047U (en) * 2017-06-09 2018-01-12 江苏万达新能源科技股份有限公司 A kind of band overcharges the lithium battery top cap plate of function

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2001000A1 (en) * 1968-01-30 1969-09-19 Int Nickel Ltd
US6245439B1 (en) * 1994-08-09 2001-06-12 Kabushiki Kaisha Toyoyta Chuo Kenkyusho composite material and method for the manufacture
CN101705410A (en) * 2009-10-16 2010-05-12 孙晓冰 Wear-resistant and thermal corrosion resistant multi-element aluminum-silicon-carbon nitride metal ceramic for laser cladding
CN102218857A (en) * 2011-05-27 2011-10-19 合肥金四达科技有限公司 Composite material coated with SiC-Fe based alloy layer and preparation method of composite material
CN105779996A (en) * 2016-03-17 2016-07-20 苏州范德雅特新材料科技有限公司 High-wear-resisting metal ceramic coating
CN206878047U (en) * 2017-06-09 2018-01-12 江苏万达新能源科技股份有限公司 A kind of band overcharges the lithium battery top cap plate of function

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Application publication date: 20190222

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