CN109370759A - Water base lubricant and preparation method thereof for titanium alloy machining - Google Patents
Water base lubricant and preparation method thereof for titanium alloy machining Download PDFInfo
- Publication number
- CN109370759A CN109370759A CN201811307988.0A CN201811307988A CN109370759A CN 109370759 A CN109370759 A CN 109370759A CN 201811307988 A CN201811307988 A CN 201811307988A CN 109370759 A CN109370759 A CN 109370759A
- Authority
- CN
- China
- Prior art keywords
- titanium alloy
- water base
- range
- base lubricant
- alloy machining
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
- C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/06—Metal compounds
- C10M2201/062—Oxides; Hydroxides; Carbonates or bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/022—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least two hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/02—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2217/024—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an amido or imido group
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/042—Sulfate esters
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/02—Unspecified siloxanes; Silicones
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/04—Detergent property or dispersant property
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/64—Environmental friendly compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
The invention discloses a kind of water base lubricants and preparation method thereof for titanium alloy machining, including following substance: Titanium dioxide nanoparticle, dispersing agent, defoaming agent and auxiliary agent, remaining is deionized water, wherein the concentration of Titanium dioxide nanoparticle is in the range of 15 ~ 30g/L, for the concentration of dispersing agent in the range of 10 ~ 25g/L, the concentration of defoaming agent is in the range of 2 ~ 10g/L.From said components it is found that a kind of water base lubricant and preparation method thereof for titanium alloy machining of the invention, raw material materials convenience, preparation process and method are simple, it is easy to laboratory and industrialized production；Water base lubricant for titanium alloy machining good cooling results, easy to clean, no pollution to the environment, is harmful to human health based on water, belongs to environmentally friendly lubricant.
Description
Technical field
The present invention relates to a kind of technical fields of lubricant for titanium alloy machining, and in particular to one kind is used for titanium
The water base lubricant and preparation method thereof of alloy mechanical processing.
Background technique
Titanium alloy specific strength with higher, excellent corrosion resisting property and be widely used in medical treatment, automobile, aerospace,
The industrial circles such as ocean.But titanium alloy has very poor friction and wear behavior, and metal-metal directly connects under the conditions of dry-charged plates
Touching be easy to cause titanium alloy member surface to be seriously worn and fail.The tradition such as coating lubricating oil, rouge profit on titanium alloy member surface
Lubrication prescription is a kind of cheap, quick, effective processing mode.Traditional lubricant is usually with mineral oil, vegetable and animals oils or it is mixed
Based on closing object, it is added what various additives were prepared.Since this series lubricant agent contains a large amount of oily substance, thus pole is not easy
Cleaning, and biological degradability is poor, environmental pollution is also more serious.Therefore, developing environmentally friendly lubricant becomes new
Epoch problem in the urgent need to address, and it is badly in need of the direction greatly developed.
Water base lubricant is usually the lubricant formed by the way that some additives are added based on water, this kind of lubrication
Agent is low in cost, low in the pollution of the environment, good cooling results, easy cleaning, it is nonflammable, be harmful to human health.Thus, water base lubricant
It is a kind of environmentally friendly and can realizes " with water generation oil " and be used for the lubricant that titanium alloy component surface is machined.
The present invention is not easy to clean, seriously for the very poor friction and wear behavior of titanium alloy surface and traditional oil lubricant
The problems such as environmental pollution, proposes a kind of environmentally friendly titanium oxide contained nanometer particle water base lubricant.
Summary of the invention
It is an object of the invention to: it overcomes the deficiencies of the prior art and provide a kind of for the water base of titanium alloy machining
Lubricant and preparation method thereof, raw material materials convenience, preparation process and method are simple, are easy to laboratory and industrialized production；With
In titanium alloy machining water base lubricant based on water, thus good cooling results, easy to clean, no pollution to the environment,
It is harmful to human health, belongs to environmentally friendly lubricant；Titanium dioxide nanoparticle in water base lubricant can be in titanium alloy
Surface forms transfer membrane, so that isolating metal-metal, reduces friction, improves abrasion；Ultrasonic cavitation process promotes dispersing agent pair
Effective package of titanium oxide nanoparticles, thus the oxidation in the water base lubricant for preventing particle agglomeration agent from settling, thus preparing
The dispersibility of titanium nano particle is very well.
The technical solution used in the present invention is:
For the water base lubricant of titanium alloy machining, including following substance: Titanium dioxide nanoparticle, dispersing agent, defoaming agent
And auxiliary agent, remaining is deionized water, and wherein the concentration of Titanium dioxide nanoparticle is in the range of 15 ~ 30g/L, the concentration of dispersing agent
In the range of 10 ~ 25g/L, the concentration of defoaming agent is in the range of 2 ~ 10g/L.
The present invention is further improved scheme, and the shape of the Titanium dioxide nanoparticle is spherical or close spherical.
The further improvement project of the present invention is that the partial size of the Titanium dioxide nanoparticle is in the range of 50 ~ 500 nm.
The further improvement project of the present invention is that the dispersing agent is by NaLS, polyethyleneimine, poly alkyl alcohol
One of ethylene oxide ether, neopelex, dodecyl sodium sulfate or a variety of compositions.
The further improvement project of the present invention is that the defoaming agent is by silicone emulsion, dimethyl silicone polymer, fluorosilicone
One of or a variety of compositions.
The further improvement project of the present invention is, the auxiliary agent is by one of glycerine, polyethylene glycol or a variety of forms.
The further improvement project of the present invention is that the molecular weight of the polyethylene glycol is in the range of 400 ~ 3000.
The method for the water base lubricant that preparation is machined for titanium alloy as described above, comprising the following steps:
1) it will be stood after deionized water, Titanium dioxide nanoparticle in proportion abundant mechanical mixture；
2) above-mentioned solution is subjected to low-speed centrifugal processing, after filtering out bulky grain precipitating, collects upper solution；
3) substances such as dispersing agent, defoaming agent, auxiliary agent are then put into, and carry out ultrasonic cavitation under water-bath state；
4) it can be prepared by lubricant after standing.
The further improvement project of the present invention is, in the step 1), mechanical mixture is carried out by way of stirring, stirring
Time is in the range of 1 ~ 5h.
The further improvement project of the present invention is, in affiliated step 2, in low-speed centrifugal treatment process, centrifuge speed exists
In the range of 300 ~ 2000 rpm.
The further improvement project of the present invention is, in the step 3), the temperature of water-bath surpasses in the range of 20 ~ 75 DEG C
The time of acoustic cavitation is in the range of 1 ~ 5h.
The beneficial effects of the present invention are:
The first, the water base lubricant for titanium alloy machining of the invention, raw material materials are convenient, preparation process and method letter
It is single, it is easy to laboratory and industrialized production.
The second, the water base lubricant for titanium alloy machining of the invention, for the water base of titanium alloy machining
Lubricant good cooling results, easy to clean, no pollution to the environment, is harmful to human health based on water, belongs to environment
The lubricant of friendly.
Third, the water base lubricant for titanium alloy machining of the invention, the TiOx nano in water base lubricant
Particle can form transfer membrane in titanium alloy surface, so that isolating metal-metal, reduces friction, improves abrasion.
4th, the preparation method of the water base lubricant for titanium alloy machining of the invention, ultrasonic cavitation process promote
Into dispersing agent to effective package of titanium oxide nanoparticles, thus the water base profit for preventing particle agglomeration agent from settling, thus preparing
The dispersibility of Titanium dioxide nanoparticle in lubrication prescription is very well.
Detailed description of the invention:
When Fig. 1 is load 50N, under the water base lubricant state of dry-charged plates and the Titanium dioxide nanoparticle containing embodiment 2, GCr15
Steel/TC4 alloy friction coefficient curve.
When Fig. 2 is 2 load 50 of embodiment, the water base lubricant shape of dry-charged plates and the Titanium dioxide nanoparticle containing embodiment 2
Under state, GCr15 steel/TC4 alloy wear volume.
Specific embodiment:
Embodiment 1
Weigh Titanium dioxide nanoparticle 20g, NaLS 12g, silicone emulsion 2g, glycerine 10mL, deionized water 1L.It will
After deionized water, Titanium dioxide nanoparticle mixing, mechanical stirring 2h after standing 1h, takes upper solution to carry out centrifugal treating, revolving speed
For 500rpm, after filtering out bulky grain, upper solution is collected；By lauryl sodium sulfate, dimethyl silicone polymer, glycerine etc.
Above-mentioned solution is put into, and after being sufficiently stirred, heating water bath then can be obtained required lubrication to 50 DEG C and ultrasonic cavitation 5h
Agent.
Embodiment 2
Weigh Titanium dioxide nanoparticle 15g, polyethyleneimine 5g, neopelex 15g, silicone emulsion 2g, poly- second two
Alcohol 15mL, deionized water 1L.After deionized water, Titanium dioxide nanoparticle are mixed, mechanical stirring 2h takes upper layer after standing 1h
Solution carries out centrifugal treating, and revolving speed 500rpm after filtering out bulky grain, collects upper solution；By dodecyl sodium sulfate, the moon
Osmanthus base sodium sulphate, emulsification silicon, polyethylene glycol etc. put into above-mentioned solution, and after being sufficiently stirred, and heating water bath is to 50 DEG C and ultrasound
Cavitation 5h then can be obtained required lubricant.
Embodiment 3
Weigh Titanium dioxide nanoparticle 20g, polyethyleneimine 6g, NaLS 6g, neopelex 8g, emulsification
Silicone oil 2g, glycerine 10mL, deionized water 1L.After deionized water, Titanium dioxide nanoparticle are mixed, mechanical stirring 2h is stood
After 1h, upper solution is taken to carry out centrifugal treating, revolving speed 500rpm after filtering out bulky grain, collects upper solution；By polyethylene
Imines, neopelex, dimethyl silicone polymer, glycerine etc. put into above-mentioned solution, and after being sufficiently stirred, water-bath
50 DEG C and ultrasonic cavitation 5h are heated to, then can be obtained required lubricant.
Above three embodiments are prepared into resulting lubricant, UMT-2 frictional testing machine is respectively adopted in TC4 titanium alloy table
The friction-reducing and antiwear action in face is evaluated, and compared the friction and wear behavior under the conditions of dry-charged plates.Opposite grinding pair selects GCr15
Steel ball, hardness 50HRC, slideably to be reciprocating, amplitude 4Hz, load 20N, sliding distance 28m.Before sliding starts,
In the water base lubricant of unit test specimen surface addition 1mL/mm2, without any addition in subsequent sliding process.
It was found that the data of lubricant prepared by embodiment 2 are worst in three embodiments, therefore to prepared by embodiment 2
Lubricant analyzed.
The coefficient of friction and wear volume result of the titanium alloy of lubricant prepared by embodiment 2 are as shown in figure 1 and 2.
In Fig. 1, when load 50N, the coefficient of friction of water base lubricant is added significantly lower than the friction system under dry-charged plates state
Number, especially since 400 seconds, in 1700 seconds or so time ranges, the stable friction factor for adding water base lubricant exists
In the range of 0.15；And the coefficient of friction under dry-charged plates state is then to be stepped up over time.
In Fig. 2, when load 50N, the wear volume for adding water base lubricant is significantly less than abrasion body under dry-charged plates state
Product and the wear volume for adding water base lubricant are less than the half of the wear volume under dry-charged plates state, so addition water dispenser
The abrasion of lubricant is significantly less than the abrasion under dry-charged plates state.
Obviously, the water base lubricant of titanium oxide contained nanometer particle has excellent friction and wear behavior.
Claims (10)
1. the water base lubricant for titanium alloy machining, it is characterised in that: including following substance: Titanium dioxide nanoparticle,
Dispersing agent, defoaming agent and auxiliary agent, remaining is deionized water, wherein range of the concentration of Titanium dioxide nanoparticle in 15 ~ 30g/L
Interior, for the concentration of dispersing agent in the range of 10 ~ 25g/L, the concentration of defoaming agent is in the range of 2 ~ 10g/L.
2. the water base lubricant for titanium alloy machining as described in claim 1, it is characterised in that: the titanium oxide
The shape of nano particle is spherical or close spherical；The partial size of the Titanium dioxide nanoparticle is in the range of 50 ~ 500 nm.
3. as described in claim 1 for titanium alloy machining water base lubricant, it is characterised in that: the dispersing agent by
NaLS, polyethyleneimine, fatty alcohol polyoxyethylene ether, neopelex, in dodecyl sodium sulfate
One or more compositions.
4. as described in claim 1 for titanium alloy machining water base lubricant, it is characterised in that: the defoaming agent by
One of silicone emulsion, dimethyl silicone polymer, fluorosilicone or a variety of compositions.
5. the water base lubricant for titanium alloy machining as described in claim 1, it is characterised in that: the auxiliary agent is by third
One of triol, polyethylene glycol or a variety of compositions.
6. the water base lubricant for titanium alloy machining as claimed in claim 5, it is characterised in that: the polyethylene glycol
Molecular weight in the range of 400 ~ 3000.
7. the side of water base lubricant for titanium alloy machining of the preparation as described in claim 1 ~ 6 wherein any one
Method, it is characterised in that the following steps are included:
1) it will be stood after deionized water, Titanium dioxide nanoparticle in proportion abundant mechanical mixture；
2) above-mentioned solution is subjected to low-speed centrifugal processing, after filtering out bulky grain precipitating, collects upper solution；
3) substances such as dispersing agent, defoaming agent, auxiliary agent are then put into, and carry out ultrasonic cavitation under water-bath state；
4) it can be prepared by lubricant after standing.
8. the preparation method for the water base lubricant of titanium alloy machining as claimed in claim 7, it is characterised in that: institute
It states in step 1), mechanical mixture is carried out by way of stirring, mixing time is in the range of 1 ~ 5h.
9. the preparation method for the water base lubricant of titanium alloy machining as claimed in claim 7, it is characterised in that:
In affiliated step 2, in low-speed centrifugal treatment process, centrifuge speed is in the range of 300 ~ 2000 rpm.
10. the preparation method for the water base lubricant of titanium alloy machining as claimed in claim 7, it is characterised in that:
In the step 3), for the temperature of water-bath in the range of 20 ~ 75 DEG C, the time of ultrasonic cavitation is in the range of 1 ~ 5h.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811307988.0A CN109370759A (en) | 2018-11-05 | 2018-11-05 | Water base lubricant and preparation method thereof for titanium alloy machining |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811307988.0A CN109370759A (en) | 2018-11-05 | 2018-11-05 | Water base lubricant and preparation method thereof for titanium alloy machining |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109370759A true CN109370759A (en) | 2019-02-22 |
Family
ID=65397749
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811307988.0A Pending CN109370759A (en) | 2018-11-05 | 2018-11-05 | Water base lubricant and preparation method thereof for titanium alloy machining |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109370759A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH1030097A (en) * | 1996-07-15 | 1998-02-03 | Sumitomo Metal Ind Ltd | Lubricant for hot rolling |
| US20130130951A1 (en) * | 2011-11-23 | 2013-05-23 | National University Of Singapore | Su-8 nano-composites with improved tribological and mechanical properties |
| CN103013642B (en) * | 2013-01-05 | 2014-02-12 | 北京科技大学 | Water-based hot rolling liquid containing nano TiO2 and preparation method thereof |
| CN108441312A (en) * | 2017-02-16 | 2018-08-24 | 宝山钢铁股份有限公司 | A kind of water base 2D/0D nanocomposites lubricant |
-
2018
- 2018-11-05 CN CN201811307988.0A patent/CN109370759A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH1030097A (en) * | 1996-07-15 | 1998-02-03 | Sumitomo Metal Ind Ltd | Lubricant for hot rolling |
| US20130130951A1 (en) * | 2011-11-23 | 2013-05-23 | National University Of Singapore | Su-8 nano-composites with improved tribological and mechanical properties |
| CN103013642B (en) * | 2013-01-05 | 2014-02-12 | 北京科技大学 | Water-based hot rolling liquid containing nano TiO2 and preparation method thereof |
| CN108441312A (en) * | 2017-02-16 | 2018-08-24 | 宝山钢铁股份有限公司 | A kind of water base 2D/0D nanocomposites lubricant |
Non-Patent Citations (3)
| Title |
|---|
| 丰华: "《石油加工助剂及石油产品添加剂加工配制与生产应用最新工艺技术操作手册》", 30 June 2006, 中国科技文化出版社 * |
| 孔令辉: "TiO_2纳米流体热传输及摩擦学行为研究", 《中国博士学位论文全文数据库 工程科技Ⅰ辑》 * |
| 朱作鑫: "水基纳米轧制液制备及润滑模型研究", 《中国博士学位论文全文数据库 工程科技Ⅰ辑》 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105316077B (en) | A kind of graphene/nitridation carbon quantum dot composite nano materials and lubricating oil friction modifier | |
| CN103160369B (en) | Self-repairing compound titanium-based grease and preparation method thereof | |
| CN105200433B (en) | Stainless steel liquid buffing wax and preparation method thereof | |
| CN108395657A (en) | A kind of self-repair type self-lubricating material and preparation method thereof | |
| CN106281630A (en) | A kind of micro emulsion cutting fluid and preparation technology thereof | |
| CN106318220A (en) | Polishing solution for stainless steel surface machining | |
| CN106590906A (en) | Graphene oxide-containing water-based metal cutting fluid and preparation method thereof | |
| JP3984159B2 (en) | Water-based lubricant for metal material plastic working and method for forming lubricating film | |
| CN101955844A (en) | Water-based dry film lubricant for chain conveyer belt and preparation method thereof | |
| CN110373246B (en) | Montmorillonite-titanium nitride-functional graphene composite lubricating oil additive | |
| CN108441312A (en) | A kind of water base 2D/0D nanocomposites lubricant | |
| CN102250673A (en) | Environment-friendly emulsion cutting oil with high lubricity and high permeability for metal working | |
| CN105950260B (en) | Obtain the friendly MoS containing lubrication2The method of nano particle lubricating oil | |
| CN108624389A (en) | A kind of graphene oxide water-based nano lubricant and preparation method thereof | |
| CN105950268A (en) | Metal processing multifunctional lubricating agent containing graphene additive and preparation method of metal processing multifunctional lubricating agent | |
| CN108865347A (en) | A kind of preparation method of lubricating fluid | |
| CN109233978A (en) | A method of antiwear and antifriction lubricating oil is prepared with additive filling plant oil base nano-fluid | |
| CN112410098B (en) | Preparation method and application of copper-doped polydopamine nanoparticles | |
| CN109370759A (en) | Water base lubricant and preparation method thereof for titanium alloy machining | |
| CN104818103A (en) | Cold extrusion forming lubricant for low carbon steel part used for automobile and preparation method thereof | |
| CN106701277A (en) | Micro-nano engine oil and preparation method thereof | |
| CN104962354B (en) | A kind of lubricating grease and preparation method thereof | |
| CN104498131A (en) | Method for preparing lithium-based (lithium-based calcium-based) lubricating grease by using waste vegetable oil and application | |
| CN102660366A (en) | Water-based synthetic cutting fluid lubricating agent, and preparation method and application thereof | |
| CN103695148B (en) | A kind of collocation method of bearing high-speed grinding liquid |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190222 |
|
| RJ01 | Rejection of invention patent application after publication |