CN109370750A - Environment-friendly pure oil cold rolling oil - Google Patents
Environment-friendly pure oil cold rolling oil Download PDFInfo
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- CN109370750A CN109370750A CN201811597731.3A CN201811597731A CN109370750A CN 109370750 A CN109370750 A CN 109370750A CN 201811597731 A CN201811597731 A CN 201811597731A CN 109370750 A CN109370750 A CN 109370750A
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- oil
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- 239000010731 rolling oil Substances 0.000 title claims abstract description 40
- 239000003921 oil Substances 0.000 title claims abstract description 29
- 238000005097 cold rolling Methods 0.000 title claims abstract description 20
- 239000002253 acid Substances 0.000 claims abstract description 14
- 229910052788 barium Inorganic materials 0.000 claims abstract description 14
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims abstract description 14
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000012964 benzotriazole Substances 0.000 claims abstract description 14
- 235000010290 biphenyl Nutrition 0.000 claims abstract description 14
- 239000004305 biphenyl Substances 0.000 claims abstract description 14
- OEIWPNWSDYFMIL-UHFFFAOYSA-N dioctyl benzene-1,4-dicarboxylate Chemical compound CCCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCCC)C=C1 OEIWPNWSDYFMIL-UHFFFAOYSA-N 0.000 claims abstract description 14
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims abstract description 14
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims abstract description 14
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 claims abstract description 10
- 235000010354 butylated hydroxytoluene Nutrition 0.000 claims abstract description 10
- -1 phosphate toluene diphenyl ester Chemical class 0.000 claims description 17
- 239000002994 raw material Substances 0.000 claims description 13
- 229920000570 polyether Polymers 0.000 claims description 12
- 241000158728 Meliaceae Species 0.000 claims description 11
- 239000004094 surface-active agent Substances 0.000 claims description 11
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 9
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 9
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 9
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 9
- 229910052710 silicon Inorganic materials 0.000 claims description 9
- 239000010703 silicon Substances 0.000 claims description 9
- 239000004593 Epoxy Substances 0.000 claims description 5
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 5
- 229920001296 polysiloxane Polymers 0.000 claims 3
- 239000004575 stone Substances 0.000 claims 2
- 238000005096 rolling process Methods 0.000 abstract description 12
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 abstract description 7
- 150000002148 esters Chemical class 0.000 abstract description 6
- 238000000137 annealing Methods 0.000 abstract description 5
- 239000003183 carcinogenic agent Substances 0.000 abstract description 5
- 238000001514 detection method Methods 0.000 abstract description 4
- 238000007127 saponification reaction Methods 0.000 abstract description 4
- 235000019198 oils Nutrition 0.000 abstract 2
- 229910019142 PO4 Inorganic materials 0.000 abstract 1
- 125000006267 biphenyl group Chemical group 0.000 abstract 1
- 231100000357 carcinogen Toxicity 0.000 abstract 1
- 235000019864 coconut oil Nutrition 0.000 abstract 1
- 239000003240 coconut oil Substances 0.000 abstract 1
- 230000001050 lubricating effect Effects 0.000 abstract 1
- 231100001081 no carcinogenicity Toxicity 0.000 abstract 1
- LPNBBFKOUUSUDB-UHFFFAOYSA-N p-toluic acid Chemical compound CC1=CC=C(C(O)=O)C=C1 LPNBBFKOUUSUDB-UHFFFAOYSA-N 0.000 abstract 1
- 239000003208 petroleum Substances 0.000 abstract 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract 1
- 239000010452 phosphate Substances 0.000 abstract 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 12
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 4
- 239000003595 mist Substances 0.000 description 4
- 238000001816 cooling Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 208000005623 Carcinogenesis Diseases 0.000 description 2
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 2
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Natural products CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 2
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 2
- 230000036952 cancer formation Effects 0.000 description 2
- 231100000504 carcinogenesis Toxicity 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000005461 lubrication Methods 0.000 description 2
- 238000003801 milling Methods 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 241000282412 Homo Species 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 230000003026 anti-oxygenic effect Effects 0.000 description 1
- 239000007866 anti-wear additive Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000013556 antirust agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- IWDCLRJOBJJRNH-UHFFFAOYSA-N p-cresol Chemical compound CC1=CC=C(O)C=C1 IWDCLRJOBJJRNH-UHFFFAOYSA-N 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/044—Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/04—Detergent property or dispersant property
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/64—Environmental friendly compositions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/243—Cold working
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
The invention discloses environment-friendly pure oil cold rolling oil which comprises, by weight, 69.2-92 parts of white oil, 0.05-1 part of 2, 6-di-tert-butyl-p-cresol, 0.01-0.5 part of benzotriazole, 0.5-3 parts of coconut oil acid, 0.5-3 parts of barium petroleum sulfonate, 5-20 parts of dioctyl terephthalate and 0.5-3 parts of diphenyl toluate phosphate. The dioctyl terephthalate is adopted, does not contain phthalate (16P) through SGS detection, has no carcinogenicity, is an environment-friendly colorless low-viscosity synthetic ester, has low volatility, can avoid human body inhalation in the high-speed rolling process, has a high saponification value, meets the lubricating performance required by a rolling mill unit, has good annealing detergency and no residue after rolling, and solves the technical problem that the existing rolling oil contains carcinogens and can cause harm to human bodies and the environment.
Description
Technical field
The embodiment of the present invention belongs to ROLLING OIL technical field more particularly to a kind of pure oiliness cold rolling oil of environment-friendly type.
Background technique
Cold rolling is that rotary roller gives rolled piece pressure under certain condition, and the one kind for making rolled piece generate plastic deformation adds
Work mode.In the case where being under pressure, section is reduced rolled piece, and shape changes, and length extends, and with broadening, at this moment rolled piece
It is produced relative sliding with roller surface, generates friction, and with frictional heat and deformation heat.During the rolling process, in deformed area pressure
Under the action of power, roll can generate flexible deformation, and band can generate plastic deformation.ROLLING OIL is entered by the wedge of band
Deformed area is attached on steel plate and roll, to meet lubrication and cooling needs.
The characteristics of for pure oiliness cold-rolling process, Surface Quality has higher requirement, usually requires that cold-rolled lubricating oil should have
Following performance: (1) stronger extreme pressure anti-wear；(2) good annealing cleanness；(3) outstanding antioxygenic property；(4) moderate fortune
Kinematic viscosity is to ensure its cooling performance；(5) higher flash-point is to guarantee safety when high-speed rolling；It is (6) non-toxic to humans,
It has no irritating odor.
Existing ROLLING OIL has good lubricity, cooling and annealing cleanness, but due to having used oneself in system two
Dioctyl phthalate, which is identified as 3 class carcinogenic substances, harmful to environment, can be to human body and ring especially to the pollution of water body
Bring harm in border.
Summary of the invention
The purpose of the embodiment of the present invention is that a kind of pure oiliness cold rolling oil of environment-friendly type is provided, in order to solve at present because existing
ROLLING OIL contains carcinogenic substance, can bring the technical issues of endangering to human body and environment.
To achieve the goals above, present invention employs following technical solutions:
The embodiment of the invention discloses a kind of pure oiliness cold rolling oil of environment-friendly type, which includes following parts by weight
Raw material: 69.2-92 parts of white oil, 0.05-1 parts of 2,6-di-tert-butyl p-cresol, 0.01-0.5 parts of benzotriazole, cocinic acid
0.5-3 parts, 0.5-3 parts of barium mahogany sulfonate, 5-20 parts of dioctyl terephthalate, 0.5-3 parts of phosphate toluene diphenyl ester.
The embodiment of the invention also discloses the raw materials that the ROLLING OIL includes following parts by weight: 77-85 parts of white oil, 2,6- bis- uncles
It is 0.2-0.8 parts of butyl paracresol, 0.08-0.3 parts of benzotriazole, 1-2.5 parts of cocinic acid, 1-2.5 parts of barium mahogany sulfonate, right
9-16 parts of dioctyl phthalate, 1-2 parts of phosphate toluene diphenyl ester.
The embodiment of the invention also discloses the raw materials that the ROLLING OIL includes following parts by weight: 69.2 parts of white oil, 2,6- bis- uncles
0.05 part of butyl paracresol, 0.01 part of benzotriazole, 0.5 part of cocinic acid, 0.5 part of barium mahogany sulfonate, terephthalic acid (TPA) two
5 parts of monooctyl ester, 0.5 part of phosphate toluene diphenyl ester.
The embodiment of the invention also discloses the raw materials that the ROLLING OIL includes following parts by weight: 92 parts of white oil, 2,6- bis- tertiary fourths
1 part of base paracresol, 0.5 part of benzotriazole, 3 parts of cocinic acid, 3 parts of barium mahogany sulfonate, 20 parts of dioctyl terephthalate, phosphorus
3 parts of sour toluene diphenyl ester.
The embodiment of the invention also discloses the raw materials that the ROLLING OIL includes following parts by weight: 80.6 parts of white oil, 2,6- bis- uncles
0.53 part of butyl paracresol, 0.26 part of benzotriazole, 1.75 parts of cocinic acid, 1.75 parts of barium mahogany sulfonate, terephthalic acid (TPA)
12.5 parts of dioctyl ester, 1.75 parts of phosphate toluene diphenyl ester.
It further include containing fluoro- organic silicon modified by polyether surfactant the embodiment of the invention also discloses the ROLLING OIL.
The embodiment of the invention also discloses the parts by weight containing fluoro- organic silicon modified by polyether surfactant base to be
0.05-0.3 parts.
Contain fluoro- organic silicon modified by polyether surfactant structure general formula the embodiment of the invention also discloses described are as follows:
R1R2Me2SiO(Me(R2R1)SiO)(Me2SiO)aSiMe2R2R1
Wherein, Me is methyl, and a is the integer of 1-20, R1For-C4F9, R2For-(CH2)3O (EO) p (PO) q, EO is epoxy
Ethane, PO are propylene oxide, the integer that p is 0~150, the integer that q is 0~150.
Contain fluoro- organic silicon modified by polyether surfactant structure general formula the embodiment of the invention also discloses described are as follows:
R1R2Me2SiO(Me(R2R1)SiO)(Me2SiO)aSiMe2R2R1
Wherein, Me is methyl, and a is the integer of 5-20, R1For-C4F9, R2For-(CH2)3O (EO) p (PO) q, EO is epoxy
Ethane, PO are propylene oxide, and p is the integer of 5-15；Q is the integer of 0-10.
Wherein, the optional 7# white oil of oil based on white oil, plays the role of base grease；
2,6-di-tert-butyl p-cresol can guarantee the problem of oxidation that changes colour during oil product Reusability as antioxidant；
Benzotriazole can mitigate the corrosion to plate as corrosion inhibiter；
Cocinic acid played as oiliness improver make oil product more preferable be adsorbed on substrate surface；
Barium mahogany sulfonate mainly improves the rust-proof effect of oil product as antirust agent；
It can inhibit mist of oil output, safeguard protection use environment containing fluoro- organic silicon modified by polyether surfactant；
Lubricant effect can be improved in dioctyl terephthalate, while can be adjusted and be used according to different technological lubrication conditions
Amount, environment friendly and pollution-free, low volatility；
Phosphate toluene diphenyl ester is as extreme pressure anti-wear additives primarily to the wear resistence of raising oil product, prevents in the operation of rolling
Middle appearance scratch scratches, and improves the surface quality of plate.
In the present invention, unless otherwise defined, being related to the " include " or " contain " that composition limits both contains opening
"include", "comprise" of formula etc. and its similar meaning also contain enclosed " Consists of " etc. and its similar meaning.
One or more technical solutions provided in the embodiments of the present application at least have the following beneficial effects:
The present embodiments relate to a kind of pure oiliness cold rolling oil of environment-friendly type, it is pungent that this product uses terephthalic acid (TPA) two
Ester is free of phthalate (16P) by " SGS " detection, and non-carcinogenesis is a kind of colourless low viscosity synthetic ester of environment-friendly type,
With low volatility, it can avoid human body sucking during high-speed rolling, while there is high saponification value, meet needed for milling train unit
The greasy property wanted, while annealing cleanness is good, rolls rear noresidue, solves at present because existing ROLLING OIL contains carcinogenic substance, meeting
The technical issues of endangering, is brought to human body and environment.
Specific embodiment
The embodiment of the present application solves at present by providing a kind of pure oiliness cold rolling oil of environment-friendly type because of existing ROLLING OIL
Containing carcinogenic substance, the technical issues of endangering can be brought to human body and environment.ROLLING OIL of the embodiment of the present invention is realized to human body, ring
The harmless technical effect in border.
In order to solve the above technical problems, the general thought that the embodiment of the present application provides technical solution is as follows:
The application provides a kind of pure oiliness cold rolling oil of environment-friendly type, which includes the raw material of following parts by weight: white
It is 69.2-92 parts oily, 0.05-1 parts of 2,6-di-tert-butyl p-cresol, 0.01-0.5 parts of benzotriazole, 0.5-3 parts of cocinic acid,
0.5-3 parts of barium mahogany sulfonate, 5-20 parts of dioctyl terephthalate, 0.5-3 parts of phosphate toluene diphenyl ester.
This product uses dioctyl terephthalate, is free of phthalate (16P) by " SGS " detection, no cause
It is carcinous, it is a kind of colourless low viscosity synthetic ester of environment-friendly type, there is low volatility, can avoid human body during high-speed rolling and inhale
Enter, roll rear noresidue, solve at present because existing ROLLING OIL contains carcinogenic substance, the technology of harm can be brought to ask human body and environment
Topic.
In order to better understand the above technical scheme, being carried out below by specific embodiment to above-mentioned technical proposal detailed
Describe in detail bright, it should be understood that the specific features in the embodiment of the present invention and embodiment be to technical scheme specifically
It is bright, rather than the restriction to technical scheme, in the absence of conflict, the skill in the embodiment of the present application and embodiment
Art feature can be combined with each other.
ROLLING OIL preparation method:
1, white oil is first added in container or reaction kettle, heating temperature is to 80 DEG C；
2,2,6-di-tert-butyl p-cresol, benzotriazole are added, stirring until completely dissolved, stops heating；
3, dioctyl terephthalate is added, stirring at normal temperature is transparent to solution.
4, barium mahogany sulfonate is sequentially added, phosphate toluene diphenyl ester and contains fluoro- organic silicon modified by polyether surface at cocinic acid
It is transparent to solution to continue stirring at normal temperature for activating agent.Product is colourless or light yellow transparent liquid.
ROLLING OIL each embodiment raw material injected volume (parts by weight) such as the following table 1 are prepared in aforementioned manners:
Contain fluoro- organic silicon modified by polyether surfactant structure general formula in above-mentioned 1 embodiment of table:
R1R2Me2SiO(Me(R2R1)SiO)(Me2SiO)aSiMe2R2R1
Wherein, Me is methyl, a 1, R in embodiment 61For-C4F9, R2For-(CH2)3O (EO) p (PO) q, EO is epoxy
Ethane, PO are propylene oxide, p 0, q 0；
Me is methyl, a 20, R in embodiment 71For-C4F9, R2For-(CH2)3O (EO) p (PO) q, EO are epoxy second
Alkane, PO are propylene oxide, p 150, q 150；
Me is methyl, a 5, R in embodiment 81For-C4F9, R2For-(CH2)3O (EO) p (PO) q, EO is ethylene oxide,
PO is propylene oxide, p 5, q 2；
Me is methyl, a 15, R in embodiment 91For-C4F9, R2For-(CH2)3O (EO) p (PO) q, EO are epoxy second
Alkane, PO are propylene oxide, p 15, q 10；
Me is methyl, a 10, R in embodiment 101For-C4F9, R2For-(CH2)3O (EO) p (PO) q, EO are epoxy second
Alkane, PO are propylene oxide, p 12, q 5.
The ROLLING OIL that 1 embodiment of table is obtained carries out index test, and test result see the table below 2:
| It distinguishes | Flash-point (DEG C) | Saponification number (mgKOH/g) |
| Embodiment 1 | 152 | 16 |
| Embodiment 2 | 162 | 67 |
| Embodiment 3 | 154 | 29 |
| Embodiment 4 | 158 | 54 |
| Embodiment 5 | 158 | 42 |
| Embodiment 6 | 164 | 16 |
| Embodiment 7 | 184 | 67 |
| Embodiment 8 | 168 | 29 |
| Embodiment 9 | 178 | 54 |
| Embodiment 10 | 176 | 42 |
Test method used in table 2:
The measurement of GB/T3536-2008 Flash Point for Petroleum Products and burning point
GB/T8021-2003 oil product soap value test method
2 embodiment 1-10 of table uses dioctyl terephthalate, is free of phthalate by " SGS " detection
(16P), non-carcinogenesis are a kind of colourless low viscosity synthetic esters of environment-friendly type, have low volatility, can keep away during high-speed rolling
Exempt from human body sucking, while there is high saponification value, meets greasy property required for milling train unit, while annealing cleanness is good, rolls
Noresidue afterwards.
In addition, can be seen that introducing containing fluoro- organic silicon modified by polyether surfactant, can be improved flash-point from embodiment 6-10
Ensure safety, which can form layer protecting film on oil reservoir surface, reduce oil evaporation, improve oil flash point, drop
The formation of mist of oil during low high-speed rolling reduces a possibility that fire occurs, ensure that the safety of operator.
Product safety environmental protection, operation of rolling generation mist of oil is few, is recycled Reusability, reduces equipment cost, keeps simultaneously
Good lubricity, wear resistence, resistance to marring guarantee fire safety issue in the quality and production process of rolled plate.
Therefore, it is harmless to have developed a kind of pair of environment human-body safety, and the low pure oiliness ROLLING OIL of mist of oil during high-speed rolling.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (9)
1. a kind of pure oiliness cold rolling oil of environment-friendly type, which is characterized in that the ROLLING OIL includes the raw material of following parts by weight: white oil
69.2-92 parts, 0.05-1 parts of 2,6-di-tert-butyl p-cresol, 0.01-0.5 parts of benzotriazole, 0.5-3 parts of cocinic acid, stone
Oily barium sulfonate 0.5-3 parts, 5-20 parts of dioctyl terephthalate, 0.5-3 parts of phosphate toluene diphenyl ester.
2. the pure oiliness cold rolling oil of a kind of environment-friendly type according to claim 1, which is characterized in that under the ROLLING OIL includes
The raw material of column parts by weight: 77-85 parts of white oil, 0.2-0.8 parts of 2,6-di-tert-butyl p-cresol, 0.08-0.3 parts of benzotriazole,
1-2.5 parts of cocinic acid, 1-2.5 parts of barium mahogany sulfonate, 9-16 parts of dioctyl terephthalate, 1-2 parts of phosphate toluene diphenyl ester.
3. the pure oiliness cold rolling oil of a kind of environment-friendly type according to claim 1, which is characterized in that under the ROLLING OIL includes
The raw material of column parts by weight: 69.2 parts of white oil, 0.05 part of 2,6-di-tert-butyl p-cresol, 0.01 part of benzotriazole, cocinic acid
0.5 part, 0.5 part of barium mahogany sulfonate, 5 parts of dioctyl terephthalate, 0.5 part of phosphate toluene diphenyl ester.
4. the pure oiliness cold rolling oil of a kind of environment-friendly type according to claim 1, which is characterized in that under the ROLLING OIL includes
The raw material of column parts by weight: 92 parts of white oil, 1 part of 2,6-di-tert-butyl p-cresol, 0.5 part of benzotriazole, 3 parts of cocinic acid, stone
3 parts of oily barium sulfonate, 20 parts of dioctyl terephthalate, 3 parts of phosphate toluene diphenyl ester.
5. the pure oiliness cold rolling oil of a kind of environment-friendly type according to claim 1, which is characterized in that under the ROLLING OIL includes
The raw material of column parts by weight: 80.6 parts of white oil, 0.53 part of 2,6-di-tert-butyl p-cresol, 0.26 part of benzotriazole, cocinic acid
1.75 parts, 1.75 parts of barium mahogany sulfonate, 12.5 parts of dioctyl terephthalate, 1.75 parts of phosphate toluene diphenyl ester.
6. the pure oiliness cold rolling oil of a kind of environment-friendly type according to claim 1-5, which is characterized in that the rolling
Oil further includes containing fluoro- organic silicon modified by polyether surfactant.
7. the pure oiliness cold rolling oil of a kind of environment-friendly type according to claim 6, which is characterized in that described to contain fluoro- polyethers
The parts by weight of modified silicone surfactants raw material are 0.05-0.3 parts.
8. the pure oiliness cold rolling oil of a kind of environment-friendly type according to claim 7, which is characterized in that described to contain fluoro- polyethers
Modified silicone surfactants general structure are as follows:
R1R2Me2SiO(Me(R2R1)SiO) (Me2SiO)aSiMe2R2R1
Wherein, Me is methyl, and a is the integer of 1-20, R1For-C4F9, R2For-(CH2)3O (EO) p (PO) q, E0 are epoxy second
Alkane, PO are propylene oxide, the integer that p is 0~150, the integer that q is 0~150.
9. the pure oiliness cold rolling oil of a kind of environment-friendly type according to claim 8, which is characterized in that described to contain fluoro- polyethers
Modified silicone surfactants general structure are as follows:
R1R2Me2SiO(Me(R2R1)SiO) (Me2SiO)aSiMe2R2R1
Wherein, Me is methyl, and a is the integer of 5-20, R1For-C4F9, R2For-(CH2)3O (EO) p (PO) q, EO are epoxy second
Alkane, PO are propylene oxide, p 5-15；Q is the integer of 0-10.
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| CN201811597731.3A CN109370750A (en) | 2018-12-26 | 2018-12-26 | Environment-friendly pure oil cold rolling oil |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110452756A (en) * | 2019-08-07 | 2019-11-15 | 黄河三角洲京博化工研究院有限公司 | A kind of diesel injection pump school pump oil and its manufacturing method |
| CN113621427A (en) * | 2021-08-16 | 2021-11-09 | 富兰克科技（深圳）股份有限公司 | Low-carbon footprint environment-friendly biodegradable stainless steel and titanium alloy cutting oil and preparation method thereof |
| CN114058427A (en) * | 2021-08-11 | 2022-02-18 | 富兰克润滑科技（太仓）有限公司 | Biodegradable aluminum alloy hot rolling liquid and preparation method thereof |
Citations (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005095556A1 (en) * | 2004-03-31 | 2005-10-13 | Nippon Oil Corporation | Metalworking fluid |
| CN1831092A (en) * | 2006-04-19 | 2006-09-13 | 上海工程技术大学 | Fluorine-silicon contd. linkage polyether demulsification agent and its prepn. method |
| CA2609652A1 (en) * | 2005-04-26 | 2006-11-02 | Renewable Lubricants, Inc. | High temperature biobased lubricant compositions comprising boron nitride |
| CN101501046A (en) * | 2006-08-28 | 2009-08-05 | 3M创新有限公司 | Perfluoropolyether silanes and use thereof |
| CN102002418A (en) * | 2009-09-01 | 2011-04-06 | 中国石油化工集团公司 | Cold rolled silicon steel rolled oil composition |
| CN102046847A (en) * | 2008-05-27 | 2011-05-04 | 吉坤日矿日石能源株式会社 | Rust-preventive oil composition |
| CN102149720A (en) * | 2008-07-18 | 2011-08-10 | 3M创新有限公司 | Fluorinated ether silanes and methods of using the same |
| CN102504919A (en) * | 2011-12-12 | 2012-06-20 | 彭美东 | Rolling oil for stainless steel |
| CN103044687A (en) * | 2012-12-21 | 2013-04-17 | 江苏美思德化学股份有限公司 | Fluorine contained organosilicon-polyether copolymer and preparation method thereof |
| CN103450988A (en) * | 2013-09-12 | 2013-12-18 | 广西大学 | Cold rolling lubricating agent for tantalum and tantalum alloy foils |
| CN106536693A (en) * | 2014-10-03 | 2017-03-22 | 捷客斯能源株式会社 | Lubricant base oil and refrigerator oil |
| CN107090333A (en) * | 2017-04-12 | 2017-08-25 | 苏州瀚固新材料科技有限公司 | Low abrasion and environmentally friendly tail seal grease of shield and preparation method thereof |
| CN107177401A (en) * | 2017-05-17 | 2017-09-19 | 东营市分众工贸有限公司 | A kind of tire banbury sealing ring special environment protection lubricating oil |
| CN107602866A (en) * | 2017-08-28 | 2018-01-19 | 无锡龙驰氟硅新材料有限公司 | A kind of fluoride silicon surfactant and preparation method thereof |
-
2018
- 2018-12-26 CN CN201811597731.3A patent/CN109370750A/en active Pending
Patent Citations (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005095556A1 (en) * | 2004-03-31 | 2005-10-13 | Nippon Oil Corporation | Metalworking fluid |
| CA2609652A1 (en) * | 2005-04-26 | 2006-11-02 | Renewable Lubricants, Inc. | High temperature biobased lubricant compositions comprising boron nitride |
| CN1831092A (en) * | 2006-04-19 | 2006-09-13 | 上海工程技术大学 | Fluorine-silicon contd. linkage polyether demulsification agent and its prepn. method |
| CN101501046A (en) * | 2006-08-28 | 2009-08-05 | 3M创新有限公司 | Perfluoropolyether silanes and use thereof |
| CN102046847A (en) * | 2008-05-27 | 2011-05-04 | 吉坤日矿日石能源株式会社 | Rust-preventive oil composition |
| CN102149720A (en) * | 2008-07-18 | 2011-08-10 | 3M创新有限公司 | Fluorinated ether silanes and methods of using the same |
| CN102002418A (en) * | 2009-09-01 | 2011-04-06 | 中国石油化工集团公司 | Cold rolled silicon steel rolled oil composition |
| CN102504919A (en) * | 2011-12-12 | 2012-06-20 | 彭美东 | Rolling oil for stainless steel |
| CN103044687A (en) * | 2012-12-21 | 2013-04-17 | 江苏美思德化学股份有限公司 | Fluorine contained organosilicon-polyether copolymer and preparation method thereof |
| CN103450988A (en) * | 2013-09-12 | 2013-12-18 | 广西大学 | Cold rolling lubricating agent for tantalum and tantalum alloy foils |
| CN106536693A (en) * | 2014-10-03 | 2017-03-22 | 捷客斯能源株式会社 | Lubricant base oil and refrigerator oil |
| CN107090333A (en) * | 2017-04-12 | 2017-08-25 | 苏州瀚固新材料科技有限公司 | Low abrasion and environmentally friendly tail seal grease of shield and preparation method thereof |
| CN107177401A (en) * | 2017-05-17 | 2017-09-19 | 东营市分众工贸有限公司 | A kind of tire banbury sealing ring special environment protection lubricating oil |
| CN107602866A (en) * | 2017-08-28 | 2018-01-19 | 无锡龙驰氟硅新材料有限公司 | A kind of fluoride silicon surfactant and preparation method thereof |
Non-Patent Citations (3)
| Title |
|---|
| 唐荻、蔡九菊、吴道洪主编: "《钢铁工业节能减排新技术5000问 下 轧钢系统分册》", 31 July 2009, 北京：中国科学技术出版社 * |
| 杨继生编著: "《表面活性剂原理与应用》", 31 December 2012, 南京：东南大学出版社 * |
| 洪仲苓主编: "《化工有机原料深加工》", 30 March 1997, 北京：化学工业出版社 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110452756A (en) * | 2019-08-07 | 2019-11-15 | 黄河三角洲京博化工研究院有限公司 | A kind of diesel injection pump school pump oil and its manufacturing method |
| CN114058427A (en) * | 2021-08-11 | 2022-02-18 | 富兰克润滑科技（太仓）有限公司 | Biodegradable aluminum alloy hot rolling liquid and preparation method thereof |
| CN113621427A (en) * | 2021-08-16 | 2021-11-09 | 富兰克科技（深圳）股份有限公司 | Low-carbon footprint environment-friendly biodegradable stainless steel and titanium alloy cutting oil and preparation method thereof |
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