CN109370348A - A kind of aqueous ecological, environmental protective paint of pencil rod and preparation method thereof - Google Patents
A kind of aqueous ecological, environmental protective paint of pencil rod and preparation method thereof Download PDFInfo
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- CN109370348A CN109370348A CN201811141751.XA CN201811141751A CN109370348A CN 109370348 A CN109370348 A CN 109370348A CN 201811141751 A CN201811141751 A CN 201811141751A CN 109370348 A CN109370348 A CN 109370348A
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- parts
- aqueous
- environmental protective
- ecological
- pencil rod
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- 230000007613 environmental effect Effects 0.000 title claims abstract description 40
- 239000002519 antifouling agent Substances 0.000 title claims abstract description 27
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical group O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 38
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 31
- 239000003973 paint Substances 0.000 claims abstract description 27
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 25
- 239000002608 ionic liquid Substances 0.000 claims abstract description 23
- 235000010215 titanium dioxide Nutrition 0.000 claims abstract description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000000843 powder Substances 0.000 claims abstract description 21
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 claims abstract description 21
- 235000019731 tricalcium phosphate Nutrition 0.000 claims abstract description 21
- 102000015636 Oligopeptides Human genes 0.000 claims abstract description 19
- 108010038807 Oligopeptides Proteins 0.000 claims abstract description 19
- 240000008042 Zea mays Species 0.000 claims abstract description 19
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 claims abstract description 19
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims abstract description 19
- 235000005822 corn Nutrition 0.000 claims abstract description 19
- 239000002270 dispersing agent Substances 0.000 claims abstract description 19
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 18
- 235000019441 ethanol Nutrition 0.000 claims abstract description 18
- 239000002562 thickening agent Substances 0.000 claims abstract description 17
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 16
- -1 1- ethyl form Chemical group 0.000 claims abstract description 15
- 239000001506 calcium phosphate Substances 0.000 claims abstract description 15
- 229940078499 tricalcium phosphate Drugs 0.000 claims abstract description 15
- 229910000391 tricalcium phosphate Inorganic materials 0.000 claims abstract description 15
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000006210 lotion Substances 0.000 claims abstract description 11
- 239000008367 deionised water Substances 0.000 claims abstract description 10
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 10
- HGGLDADJQQPKKC-UHFFFAOYSA-N 2-butyl-1-methylimidazole Chemical compound CCCCC1=NC=CN1C HGGLDADJQQPKKC-UHFFFAOYSA-N 0.000 claims abstract description 9
- 238000005660 chlorination reaction Methods 0.000 claims abstract description 8
- 238000013329 compounding Methods 0.000 claims abstract description 8
- 239000003381 stabilizer Substances 0.000 claims abstract description 8
- 239000004615 ingredient Substances 0.000 claims abstract description 7
- 150000001875 compounds Chemical class 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 15
- 239000002253 acid Substances 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- 239000002994 raw material Substances 0.000 claims description 10
- 229940008099 dimethicone Drugs 0.000 claims description 7
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 7
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 7
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 7
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000011347 resin Substances 0.000 claims description 6
- 229920005989 resin Polymers 0.000 claims description 6
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 5
- 229920000642 polymer Polymers 0.000 claims description 5
- 238000010792 warming Methods 0.000 claims description 5
- 239000003643 water by type Substances 0.000 claims description 5
- 229920002367 Polyisobutene Polymers 0.000 claims description 4
- 239000000839 emulsion Substances 0.000 claims description 4
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 4
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 3
- 239000003595 mist Substances 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 229920000058 polyacrylate Polymers 0.000 claims description 3
- 229920000570 polyether Polymers 0.000 claims description 3
- 229910052710 silicon Inorganic materials 0.000 claims description 3
- 239000010703 silicon Substances 0.000 claims description 3
- WZZBNLYBHUDSHF-DHLKQENFSA-N 1-[(3s,4s)-4-[8-(2-chloro-4-pyrimidin-2-yloxyphenyl)-7-fluoro-2-methylimidazo[4,5-c]quinolin-1-yl]-3-fluoropiperidin-1-yl]-2-hydroxyethanone Chemical group CC1=NC2=CN=C3C=C(F)C(C=4C(=CC(OC=5N=CC=CN=5)=CC=4)Cl)=CC3=C2N1[C@H]1CCN(C(=O)CO)C[C@@H]1F WZZBNLYBHUDSHF-DHLKQENFSA-N 0.000 claims description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 1
- 125000005396 acrylic acid ester group Chemical group 0.000 claims 1
- 229910052698 phosphorus Inorganic materials 0.000 claims 1
- 239000011574 phosphorus Substances 0.000 claims 1
- 239000002002 slurry Substances 0.000 claims 1
- 230000001681 protective effect Effects 0.000 abstract description 8
- 239000000853 adhesive Substances 0.000 abstract description 4
- 230000001070 adhesive effect Effects 0.000 abstract description 4
- 238000005516 engineering process Methods 0.000 description 11
- 239000011248 coating agent Substances 0.000 description 9
- 238000000576 coating method Methods 0.000 description 9
- 239000004925 Acrylic resin Substances 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 229920000178 Acrylic resin Polymers 0.000 description 5
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 4
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 239000002966 varnish Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 239000004922 lacquer Substances 0.000 description 3
- 230000037452 priming Effects 0.000 description 3
- 229920001800 Shellac Polymers 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- 239000004208 shellac Substances 0.000 description 2
- ZLGIYFNHBLSMPS-ATJNOEHPSA-N shellac Chemical compound OCCCCCC(O)C(O)CCCCCCCC(O)=O.C1C23[C@H](C(O)=O)CCC2[C@](C)(CO)[C@@H]1C(C(O)=O)=C[C@@H]3O ZLGIYFNHBLSMPS-ATJNOEHPSA-N 0.000 description 2
- 229940113147 shellac Drugs 0.000 description 2
- 235000013874 shellac Nutrition 0.000 description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 150000001555 benzenes Chemical class 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000006184 cosolvent Substances 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000001802 infusion Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 235000021419 vinegar Nutrition 0.000 description 1
- 239000000052 vinegar Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/325—Calcium, strontium or barium phosphate
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses aqueous ecological, environmental protective paints of a kind of pencil rod and preparation method thereof, it includes aqueous color paste that aqueous its ingredient of ecological, environmental protective paint of the pencil rod, which includes its ingredient, waterborne acrylic paint lotion, compound ionic liquid, stabilizer, dispersing agent, levelling agent, defoaming agent, thickener, ethyl alcohol；The aqueous color paste is titanium dioxide, tricalcium phosphate, corn oligopeptide powder and deionized water；The compounding ionic liquid is that chlorination 1- alkene butyl -3- methylimidazole and -3 methylimidazole acetate of 1- ethyl form, mixed proportion 4-6:2-4.The aqueous ecological, environmental protective paint of pencil rod of the invention, environmental safety is high, adhesive force is stronger, water resistance is more preferable.
Description
Technical field
The invention belongs to coating producing process fields, and in particular to a kind of aqueous ecological, environmental protective paint of pencil rod and its
Preparation method.
Background technique
The Coating technologies such as existing wooden furniture varnish write group a volume, light industry publishing house nineteen eighty-three at " furniture finishing technology "
Detailed narration is made in December the first edition " furniture finishing technology " book, the varnish Coating technology of the description of page 138~172 is general
It is divided into 5 stages, i.e. surface treatment, basic coloring, coat colorization, varnish Lacquer finish, paint film finishing, has again in each stage several
Process is covered with paint, lacquer, colour wash, etc. the difference of requirement and processing technology by general grade, middle rank, advanced three classes furniture, there is 10~23 procedures, process respectively
It is more.Since the price of natural products shellac, solvent alcohol is more and more expensive, keep traditional covering with paint cost higher and higher, and uses
It is thermo-labile that shellac varnish makees priming paint, and the high-grade paint such as coating polyurethane can also reduce adhesive force on this face；The improved aqueous dye of blade coating
Color putty and erasing resin mill base technique, haves the shortcomings that fill out it is greasy it is uneven, show signs of anger it is bad, and due to resin mill base use it is organic
Solvent, at high cost, volatility is big, and contamination is serious, and popularization and application are restricted.
Pencil is main writing implement in modern people's culture life, and Wood-bar pencil the most traditional writes spy due to it
Point is still main tool in fields such as sketch, drawing, examination, color make-ups, there is the status that do not replace.In order to rod lead
Pen carries out protection and beauty, it is necessary to carry out coating, and to reach ideal painting effect and first have to priming.I.e. in the table of rod
Face is coated with the priming paint of white with painting machine, is then coated coloured finishing coat.The purpose of coating white primer is to cover rod
The lines on surface and the primary colors of timber, improve the flatness on surface, convenient for pigmented top coat reach due smoothness, glossiness,
Color.
What the coating prime lacquer used of Wood-bar pencil production at present used is entirely solvent based coating, and wherein base-material is nitrification
Cotton, alkyd resin, acrylic resin etc. generally also need to add the increasing such as dibutyl phthalate, dioctyl ester, blown castor oil
Mould agent.Solvent mainly has a true solvent such as esters, ketone, alcohol ethers, the diluents such as the cosolvents such as alcohols and benzene class, wherein benzene
The organic solvents such as class, toxicity smell is big, inflammable and explosive, is unfavorable for keeping the safety in production and improve working conditions, easily causes dirt to environment
Dye.
Summary of the invention
The object of the present invention is to provide aqueous ecological, environmental protective paints of a kind of pencil rod and preparation method thereof, provide one kind
The high ecological, environmental protective paint of environmental safety, and adhesive force is stronger, water resistance is more preferable.
In order to solve the above technical problems, the invention adopts the following technical scheme:
A kind of aqueous ecological, environmental protective paint of pencil rod, which is characterized in that its ingredient includes aqueous color paste, aqueous acrylamide
Acid ester resin lotion compounds ionic liquid, stabilizer, dispersing agent, levelling agent, defoaming agent, thickener, ethyl alcohol；Described is aqueous
Mill base is titanium dioxide, tricalcium phosphate, corn oligopeptide powder and deionized water；The compounding ionic liquid is chlorination 1- alkene butyl-
3- methylimidazole and -3 methylimidazole acetate of 1- ethyl composition, mixed proportion 4-6:2-4.
Further, the acid value of the water soluble acrylic resin is 300-400mgKOH/g, molecular weight 30000-
50000g/mol。
Further, the aqueous ecological, environmental protective paint of the pencil rod is as unit of parts by weight, including following raw material: water
Property 48-60 parts of mill base, 20-30 parts of waterborne acrylic paint lotion, compound ionic liquid 20-40 parts, 0.5-2 parts of dispersing agent,
0.1-1 parts of levelling agent, 0.2-0.5 parts of defoaming agent, 0.5-2 parts of thickener, 15-25 parts of ethyl alcohol；The aqueous color paste is 25-30
Part titanium dioxide, 10-15 parts of tricalcium phosphates, 5-10 parts of corn oligopeptide powders and 5-10 parts of deionized waters.
Further, the aqueous ecological, environmental protective paint of the pencil rod is as unit of parts by weight, including following raw material: water
Property 55 parts of mill base, 25 parts of waterborne acrylic paint lotion, compound 30 parts of ionic liquid, 1 part of dispersing agent, 0.5 part of levelling agent, disappear
0.3 part of infusion, 1 part of thickener, 20 parts of ethyl alcohol；The aqueous color paste is 27.5 parts of titanium dioxides, 12.5 parts of tricalcium phosphates, 7.5
Part corn oligopeptide powder and 7.5 parts of deionized waters.
Further, the defoaming agent is high molecular weight dimethicone, and molecular weight is 50,000-10 ten thousand.
Further, the thickener is hydroxyethyl cellulose.
Further, the levelling agent is at least one in organic silicon modified by polyether oxygen alkane or fluorin modified crylic acid polymer
Kind；The dispersing agent is at least one of polyacrylate and polyisobutene maleate.
Further, the titanium dioxide, the micro mist that tricalcium phosphate is 200 mesh or more.
A kind of preparation method of the aqueous ecological, environmental protective paint of above-mentioned pencil rod, which is characterized in that including following step
Rapid: (1), by titanium dioxide, tricalcium phosphate, corn oligopeptide powder and deionized water, number is contained in mixing machine according to the proportion, stirring
It is uniformly mixed and obtains aqueous color paste；(2), by waterborne acrylic paint lotion, ionic liquid, stabilizer, dispersing agent, stream are compounded
Flat agent, defoaming agent, thickener, ethyl alcohol mixing stir evenly and stir 20-30min after mixture is warming up to 60-70 DEG C, finally
Cooling mixed liquor；(3), the step 1 is added in the mixed liquor of step 2 and is stirred evenly.
The invention has the following advantages:
Aqueous color paste is titanium dioxide, tricalcium phosphate, corn oligopeptide powder and deionized water；The aqueous color paste is not applicable logical
Alkene acid ester resin uses corn oligopeptide powder instead, improves aqueous color paste in the dispersibility of environmental protection paint, and improve and rod surface
Adhesiveness, while there is stable whole system, have the effect of environment-friendly high-efficiency.Titanium dioxide, tricalcium phosphate micro powder end can disperse
In environmental protection paint, and by cooperating with high molecular weight dimethicone, mechanical property is improved.The compounding ionic liquid is chlorine
Change 1- alkene butyl -3- methylimidazole and -3 methylimidazole acetate of 1- ethyl composition, mixed proportion 4-6:2-4.Compound ion
Liquid has certain solvability to noncrystalline or low crystalline material, and plays destruction to the hydrogen bond structure of cellulosic sections
Effect, the adhesion strength of enhancing and rod surface.The aqueous ecological, environmental protective paint of pencil rod of the invention, environmental safety height,
Adhesive force is stronger, water resistance is more preferable.
Specific embodiment
To facilitate a better understanding of the present invention, it is illustrated by the following examples, these examples belong to protection of the invention
Range, but do not limit the scope of the invention.
Embodiment 1
A kind of aqueous ecological, environmental protective paint of pencil rod, which is characterized in that its ingredient includes 55 parts of aqueous color paste, aqueous
25 parts of acrylate resin emulsion, 30 parts of ionic liquid are compounded, 1 part of dispersing agent, 0.5 part of levelling agent, 0.3 part of defoaming agent, is thickened
1 part of agent, 20 parts of ethyl alcohol；The aqueous color paste is 27.5 parts of titanium dioxides, 12.5 parts of tricalcium phosphates, 7.5 parts of corn oligopeptide powders
With 7.5 parts of deionized waters；The compounding ionic liquid is -3 methylimidazole vinegar of chlorination 1- alkene butyl -3- methylimidazole and 1- ethyl
Hydrochlorate composition, mixed proportion 5:3.The acid value of the water soluble acrylic resin is 350mgKOH/g, molecular weight 40000g/
mol.The defoaming agent is high molecular weight dimethicone, and molecular weight is 7.5 ten thousand.The thickener is hydroxyethyl cellulose.Institute
Stating levelling agent is organic silicon modified by polyether oxygen alkane polymer；The dispersing agent is polyacrylate.The titanium dioxide, tricalcium phosphate
For micro mists more than 200 mesh.
A kind of preparation method of the aqueous ecological, environmental protective paint of above-mentioned pencil rod, which is characterized in that including following step
Rapid: (1), by titanium dioxide, tricalcium phosphate, corn oligopeptide powder and deionized water, number is contained in mixing machine according to the proportion, stirring
It is uniformly mixed and obtains aqueous color paste；(2), by waterborne acrylic paint lotion, ionic liquid, stabilizer, dispersing agent, stream are compounded
Flat agent, defoaming agent, thickener, ethyl alcohol mixing stir evenly and stir 20-30min after mixture is warming up to 60-70 DEG C, finally
Cooling mixed liquor；(3), the step 1 is added in the mixed liquor of step 2 and is stirred evenly.
Embodiment 2
A kind of aqueous ecological, environmental protective paint of pencil rod, which is characterized in that its ingredient includes 48 parts of aqueous color paste, aqueous
30 parts of acrylate resin emulsion, 20 parts of ionic liquid are compounded, 2 parts of dispersing agent, 0.1 part of levelling agent, 0.5 part of defoaming agent, is thickened
2 parts of agent, 15 parts of ethyl alcohol；The aqueous color paste is 30 parts of titanium dioxides, 10 parts of tricalcium phosphates, 10 parts of corn oligopeptide powders and 5 parts
Deionized water；The compounding ionic liquid is -3 methylimidazole acetate group of chlorination 1- alkene butyl -3- methylimidazole and 1- ethyl
At mixed proportion 6:2.The acid value of the water soluble acrylic resin is 400mgKOH/g, molecular weight 30000g/mol.Institute
Stating defoaming agent is high molecular weight dimethicone, and molecular weight is 100,000.The thickener is hydroxyethyl cellulose.The levelling agent
For fluorin modified crylic acid polymer；The dispersing agent is at least one of polyisobutene maleate.The titanium dioxide,
Tricalcium phosphate is the micro mist of 200 mesh or more.
A kind of preparation method of the aqueous ecological, environmental protective paint of above-mentioned pencil rod, which is characterized in that including following step
Rapid: (1), by titanium dioxide, tricalcium phosphate, corn oligopeptide powder and deionized water, number is contained in mixing machine according to the proportion, stirring
It is uniformly mixed and obtains aqueous color paste；(2), by waterborne acrylic paint lotion, ionic liquid, stabilizer, dispersing agent, stream are compounded
Flat agent, defoaming agent, thickener, ethyl alcohol mixing stir evenly and stir 20-30min after mixture is warming up to 60-70 DEG C, finally
Cooling mixed liquor；(3), the step 1 is added in the mixed liquor of step 2 and is stirred evenly.
Embodiment 3
A kind of aqueous ecological, environmental protective paint of pencil rod, which is characterized in that its ingredient includes 60 parts of aqueous color paste, aqueous
20 parts of acrylate resin emulsion, 40 parts of ionic liquid are compounded, 0.5 part of dispersing agent, 1 part of levelling agent, 0.2 part of defoaming agent, is thickened
0.5 part of agent, 25 parts of ethyl alcohol；The aqueous color paste is 25 parts of titanium dioxides, 15 parts of tricalcium phosphates, 5 parts of corn oligopeptide powders and 10
Part deionized water；The compounding ionic liquid is -3 methylimidazole acetate of chlorination 1- alkene butyl -3- methylimidazole and 1- ethyl
Composition, mixed proportion 4:4.The acid value of the water soluble acrylic resin is 300mgKOH/g, molecular weight 50000g/mol.
The defoaming agent is high molecular weight dimethicone, and molecular weight is 50,000.The thickener is hydroxyethyl cellulose.The levelling
Agent is fluorin modified crylic acid polymer；The dispersing agent is polyisobutene maleate.The titanium dioxide, tricalcium phosphate are
Micro mists more than 200 mesh.
A kind of preparation method of the aqueous ecological, environmental protective paint of above-mentioned pencil rod, which is characterized in that including following step
Rapid: (1), by titanium dioxide, tricalcium phosphate, corn oligopeptide powder and deionized water, number is contained in mixing machine according to the proportion, stirring
It is uniformly mixed and obtains aqueous color paste；(2), by waterborne acrylic paint lotion, ionic liquid, stabilizer, dispersing agent, stream are compounded
Flat agent, defoaming agent, thickener, ethyl alcohol mixing stir evenly and stir 20-30min after mixture is warming up to 60-70 DEG C, finally
Cooling mixed liquor；(3), the step 1 is added in the mixed liquor of step 2 and is stirred evenly.
Comparative example 1
It is essentially identical with the production technology of embodiment 1, it has only the difference is that preparing the aqueous ecological, environmental protective of pencil rod
Corn oligopeptide powder is substituted for waterborne acrylic paint in the raw material of paint.
Comparative example 2
It is essentially identical with the production technology of embodiment 1, it has only the difference is that preparing the aqueous ecological, environmental protective of pencil rod
Corn oligopeptide powder is not included in the raw material of paint.
Comparative example 3
It is essentially identical with the production technology of embodiment 1, it has only the difference is that preparing the aqueous ecological, environmental protective of pencil rod
Lack compounding ionic liquid in the raw material of paint.
Comparative example 4
It is essentially identical with the production technology of embodiment 1, it has only the difference is that preparing the aqueous ecological, environmental protective of pencil rod
Lack high molecular weight dimethicone in the raw material of paint.
Comparative example 5
It is essentially identical with the production technology of embodiment 1, it has only the difference is that preparing the aqueous ecological, environmental protective of pencil rod
- 3 methylimidazole acetate of chlorination 1- alkene butyl -3- methylimidazole and 1- ethyl, mixed proportion 2:6 in the raw material of paint.
Comparative example 6
It is essentially identical with the production technology of embodiment 1, it has only the difference is that preparing the aqueous ecological, environmental protective of pencil rod
- 3 methylimidazole acetate of chlorination 1- alkene butyl -3- methylimidazole and 1- ethyl, mixed proportion 8:1 in the raw material of paint.
The above content is it cannot be assumed that present invention specific implementation is only limited to these instructions, for the technical field of the invention
Those of ordinary skill for, under the premise of not departing from present inventive concept, a number of simple deductions or replacements can also be made, all answers
When being considered as belonging to present invention scope of patent protection determined by the appended claims.
Claims (8)
1. a kind of aqueous ecological, environmental protective paint of pencil rod, which is characterized in that its ingredient includes aqueous color paste, water soluble acrylic acid
Ester resin emulsion compounds ionic liquid, stabilizer, dispersing agent, levelling agent, defoaming agent, thickener, ethyl alcohol；The aqueous color
Slurry is titanium dioxide, tricalcium phosphate, corn oligopeptide powder and deionized water；The compounding ionic liquid is chlorination 1- alkene butyl -3-
Methylimidazole and -3 methylimidazole acetate of 1- ethyl composition, mixed proportion 4-6:2-4.
2. the aqueous ecological, environmental protective paint of pencil rod according to claim 1, which is characterized in that the water soluble propene
The acid value of acid resin is 300-400mgKOH/g, molecular weight 30000-50000g/mol.
3. the aqueous ecological, environmental protective paint of pencil rod according to claim 1, which is characterized in that the pencil rod is used
Aqueous ecological, environmental protective paint as unit of parts by weight, including following raw material: 48-60 parts of aqueous color paste, waterborne acrylic paint
20-30 parts of lotion, ionic liquid 20-40 parts is compounded, 0.5-2 parts of dispersing agent, 0.1-1 parts of levelling agent, is defoamed
0.2-0.5 parts of agent, 0.5-2 parts of thickener, 15-25 parts of ethyl alcohol；The aqueous color paste is 25-30 parts of titanium dioxides, 10-15
Part tricalcium phosphate, 5-10 parts of corn oligopeptide powders and 5-10 parts of deionized waters.
4. the aqueous ecological, environmental protective paint of pencil rod according to claim 1, which is characterized in that the pencil rod is used
Aqueous ecological, environmental protective paint as unit of parts by weight, including following raw material: 55 parts of aqueous color paste, waterborne acrylic paint lotion
25 parts, compound 30 parts of ionic liquid, 1 part of dispersing agent, 0.5 part of levelling agent, 0.3 part of defoaming agent, 1 part of thickener, 20 parts of ethyl alcohol；Institute
The aqueous color paste stated is 27.5 parts of titanium dioxides, 12.5 parts of tricalcium phosphates, 7.5 parts of corn oligopeptide powders and 7.5 parts of deionized waters.
5. the aqueous ecological, environmental protective paint of pencil rod according to claim 1, which is characterized in that the defoaming agent is height
Molecular weight dimethicone, molecular weight are 50,000-10 ten thousand.
6. the aqueous ecological, environmental protective paint of pencil rod according to claim 1, which is characterized in that the thickener is hydroxyl
Ethyl cellulose；Levelling agent is at least one of organic silicon modified by polyether oxygen alkane or fluorin modified crylic acid polymer；Described point
Powder is at least one of polyacrylate and polyisobutene maleate.
7. the aqueous ecological, environmental protective paint of pencil rod according to claim 1, which is characterized in that the titanium dioxide, phosphorus
Sour tricalcium is the micro mist of 200 mesh or more.
8. a kind of preparation method of the aqueous ecological, environmental protective paint of pencil rod according to claim 1-7,
It is characterized in that, comprising the following steps: (1), by titanium dioxide, tricalcium phosphate, corn oligopeptide powder and deionized water part according to the proportion
Number is contained in mixing machine, is uniformly mixed to obtain aqueous color paste；(2), by waterborne acrylic paint lotion, ionic liquid is compounded
Body, stabilizer, dispersing agent, levelling agent, defoaming agent, thickener, ethyl alcohol mixing stir evenly mixture being warming up to 60-70 DEG C
After stir 20-30min, finally cooling mixed liquor；(3), the aqueous color paste of the step 1 is added to the mixed liquor of step 2
In stir evenly.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201811141751.XA CN109370348A (en) | 2018-09-28 | 2018-09-28 | A kind of aqueous ecological, environmental protective paint of pencil rod and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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Application publication date: 20190222 |