CN109346781A - A kind of small-sized AGM boosting battery - Google Patents

A kind of small-sized AGM boosting battery Download PDF

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Publication number
CN109346781A
CN109346781A CN201811075201.2A CN201811075201A CN109346781A CN 109346781 A CN109346781 A CN 109346781A CN 201811075201 A CN201811075201 A CN 201811075201A CN 109346781 A CN109346781 A CN 109346781A
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CN
China
Prior art keywords
battery
agm
pole
small
sized
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811075201.2A
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Chinese (zh)
Inventor
李朋
胡晓敏
鲁义铭
孟刚
徐建刚
高国兴
刘长来
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Camel Group Storage Battery Research Institute Co Ltd
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Camel Group Storage Battery Research Institute Co Ltd
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Publication date
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Priority to CN201811075201.2A priority Critical patent/CN109346781A/en
Publication of CN109346781A publication Critical patent/CN109346781A/en
Pending legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/06Lead-acid accumulators
    • H01M10/12Construction or manufacture
    • H01M10/121Valve regulated lead acid batteries [VRLA]
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/64Carriers or collectors
    • H01M4/66Selection of materials
    • H01M4/68Selection of materials for use in lead-acid accumulators
    • H01M4/685Lead alloys
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/64Carriers or collectors
    • H01M4/70Carriers or collectors characterised by shape or form
    • H01M4/72Grids
    • H01M4/73Grids for lead-acid accumulators, e.g. frame plates
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/30Arrangements for facilitating escape of gases
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Secondary Cells (AREA)

Abstract

Entitled a kind of small-sized AGM boosting battery of the invention.Belong to Lead-acid Battery Technology field.It mainly solves the problems, such as that existing one piece of start-stop battery has dimmed, air-conditioning of room light etc. in use and can not work normally.Being mainly characterized by comprising: for it includes battery groove body, battery big cover and pole group, the pole group includes AGM partition, pole plate, inclined part and straight pole, the battery big cover is equipped with positive and negative electrode terminal, further includes with the battery tegillum for concentrating gas vent, battery tegillum is loaded on battery big cover;The battery groove body includes 6 single lattices;The pole group is 6, corresponding with 6 single lattices respectively;The battery big cover is equipped with 6 acid filling holes corresponding with 6 single lattices;The acid filling hole is mounted on safety valve.The present invention has the characteristics that small in size, light-weight, output power is high, battery is easy to connect, deep discharge and service life are excellent, can be widely used for parking, hybrid electric vehicle and pure electric automobile.

Description

A kind of small-sized AGM boosting battery
Technical field
The invention belongs to Lead-acid Battery Technology fields.Lead-acid accumulator is assisted more particularly to a kind of small-sized AGM of 12V.
Background technique
Under standard of fuel increasingly harsh main trend, domestic and international major automaker constantly researches and develops new energy-saving ring Guarantor's technology, to adapt to local environmental requirement.And in various energy conservation and environmental protection technologies, start stop system, plug-in hybrid electric vehicle it is general And constantly heat up with use, it from high-end vehicles such as earliest BMW benz Audi, has covered rapidly economic section Energy vehicle, it is contemplated that before the year two thousand twenty, the new car that Chinese market there will be over 40% is equipped with start stop system, hybrid electric vehicle or plug-in Formula hybrid electric vehicle.
Start stop system is to increase to play power failure machine automatically on the basis of orthodox car, it is desirable that automobile is automatic in the idling state Close engine, start battery independent bearing vehicle load, when starting can automatic ignition, oil-saving effect is 5% or so, traffic congestion When frequent start-stop, depth of discharge will be deeper.It is interior auxiliary when each engine misses due to starting the increase of battery discharge depth Help influence of the power consumption of equipment to battery maximum, if only with one piece of start-stop battery, battery soon can not be normal Work.In addition the electric appliance of vehicle can undergo primary voltage rapid drawdown in starting process, air-conditioning dimmed so as to cause room light etc. It can not work normally.In order to guarantee the stability of the functions such as room light, air-conditioning, sound equipment, vehicle solution can be used at present Dual battery system design solves the problems, such as this, that is, to be further added by the small-sized AGM boosting battery of one piece of 12V auxiliary for equipment during start-stop Power supply is helped, this dual battery system can also greatly improve the comfort level of parking.
In plug-in hybrid electric vehicle and pure electric automobile system, since power battery is all made of high-voltage battery system, And the electrical equipments such as vehicle light, wiper, entire car controller, high voltage electric equipment controller still use traditional 12V low pressure It is low pressure system that system power supply, plug-in hybrid electric vehicle and pure electric automobile, which are also required to the additional a small-sized AGM boosting battery of 12V, System power supply.
In the above Full Vehicle System, AGM boosting battery small-sized for 12V usually requires that as follows:
1, battery size is small, light-weight;Meet vehicle light-weight design principle;
2, battery has excellent deep discharge performance, can satisfy vehicle power demand;
3, battery transient high power exports, battery discharge platform stable, and supply network is stablized;
4, installing and dismounting is simple;
5, non-maintaining, battery bubbing is few, can also concentrate outside discharge vehicle even if the sour gas being precipitated;
In addition environmental requirement in storage battery production manufacturing process (such as Battery formation, pole plate are cut) is considered, for small-sized auxiliary Battery request;
6, small-sized AGM boosting battery is using even punching grid, and pole plate continuously fills continuous parting-cut, rather than cutting causes greatly after solidifying The dust of amount;
7, Battery formation is assembled using being internalized into using green plate.
Summary of the invention
A kind of small-sized AGM boosting battery is provided the purpose of the present invention is to above-mentioned shortcoming, such battery tool Have the characteristics that small in size, light-weight, output power is high, battery is easy to connect, deep discharge and service life are excellent, can be widely used for Parking, hybrid electric vehicle and pure electric automobile.
The technical solution of the invention is as follows: a kind of small-sized AGM boosting battery, including battery groove body, battery big cover and pole Group, the pole group include AGM partition, pole plate, inclined part and straight pole, and the battery big cover is equipped with positive and negative electrode terminal, It is characterized in that: further including with the battery tegillum for concentrating gas vent, battery tegillum is loaded on battery big cover;The battery groove body includes 6 single lattices;The pole group is 6, corresponding with 6 single lattices respectively;The battery big cover is equipped with 6 and 6 single lattices pair The acid filling hole answered;The acid filling hole is mounted on safety valve.
Pole plate described in technical solution of the invention is green plate;Grid in pole plate is to connect punching grid;Grid Using the lead calcium Pb alloy containing Ca 0.03%~0.2%, Sn 0.1%~5%, with a thickness of 0.6~1.2mm, 50~128mm of width, Highly 50~146mm.
Pole plate described in technical solution of the invention is ripe pole plate;Slab lattice thickness in pole plate is 0.6~ 1.2mm, 50~128mm of width, 50~146mm of height.
The diameter that gas vent is concentrated described in technical solution of the invention is 5.7-5.9mm, depth >=10mm.
Anode and cathode terminals described in technical solution of the invention use the die casting lead terminal with copper core internal screw thread.
Each component is relative to lead powder quality in anode diachylon in pole plate described in technical solution of the invention It is 10~20wt% that content, which is respectively as follows: red lead additional amount, and the net additional amount of sulfuric acid is 1~6wt%, apparent density of lead paste control 4.1~ 4.3g/cm³;It is 0.2 that each component, which is respectively as follows: acetylene black additional amount relative to the content of lead powder quality, in cathode lead plaster in pole plate ~2.0wt%, lignin additional amount are 0.2~0.5wt%, and humic acid additional amount is 0.3~0.5wt%, and short fibre additional amount is dimension 0.1 ~0.8wt%, the net additional amount of sulfuric acid are 1~6wt%, and apparent density of lead paste is controlled in 4.0~4.3g/cm3.
Pole group's welding in pole group described in technical solution of the invention forms busbar connector, inclined part by cast welding With straight pole butt welding;Welding uses cross wall welding between the group of pole, and straight pole and anode and cathode terminals freeze connection.
The encapsulating width that AGM partition described in technical solution of the invention encapsulates pole plate is 5~6mm, and encapsulating is high Degree is 5~8mm.
Battery groove body described in technical solution of the invention, battery big cover and battery tegillum are all made of PP material, Battery groove body is sealed with battery big cover and battery tegillum respectively.
The present invention is due to using two-piece lid construction, and each single lattice designs individual safety valve, and tegillum design has standard deliveries The gas of precipitation can be concentrated and is discharged to outside vehicle by hole, and anode and cathode terminals are designed as copper core internal screw thread terminal and facilitate battery installation and connect It connecing, partition uses AGM partition, and grid is using even punching grid, and pole group's welding uses cast welding, and welding uses through-wall welding between the group of pole, because And have the characteristics that small in size, light-weight, output power is high, battery is easy to connect, deep discharge and service life are excellent, it can use extensively Parking, hybrid electric vehicle and pure electric automobile in.
Detailed description of the invention
Fig. 1 is general assembly drawing of the invention.
Fig. 2 is the schematic diagram of the section structure of the invention.
Fig. 3 is battery tegillum schematic diagram of the present invention.
Fig. 4 is battery big cover structure of the present invention and safety valve scheme of installation.
In figure, 1. battery groove bodies;2. battery big cover;3. battery tegillum;4. concentrating gas vent;5. acid filling hole;6. Anode and cathode terminals;7. safety valve;8. the die casting lead terminal with copper core internal screw thread;9. pole group;10. pair being partially welded part;11. Straight pole;12. AGM partition;13. pole plate;14. grid.
Specific embodiment
The invention will be further described with reference to the accompanying drawing.
As shown in Figures 1 to 4.A kind of small-sized AGM boosting battery of the present invention, including battery groove body 1, battery big cover 2, battery Tegillum 3 and pole group 9.Wherein, battery groove body 1 includes 6 single lattices.Battery big cover 2 be equipped with anode and cathode terminals 6 and 6 with The corresponding acid filling hole 5 of 6 single lattices, acid filling hole 5 are mounted on safety valve 7, and anode and cathode terminals 6 use the die casting with copper core internal screw thread Lead terminal 8.Battery tegillum 3, which is equipped with, concentrates gas vent 4, and concentrating the diameter of gas vent 4 is 5.7-5.9mm, depth >=10mm, electricity Pond tegillum 3 is loaded on battery big cover 2.Battery groove body 1, battery big cover 2 and battery tegillum 3 are all made of PP material, and battery groove body 1 divides It is not sealed with battery big cover 2 and battery tegillum 3.Pole group 9 is 6, corresponding with 6 single lattices respectively.Pole group 9 includes AGM partition 12, pole plate 13, inclined part 10 and straight pole 11.Pole plate 13 can be green plate, and the grid 14 in pole plate 13 is to connect punching Grid, grid 14 uses the lead calcium Pb alloy containing Ca 0.03%~0.2%, Sn 0.1%~5%, with a thickness of 0.6~1.2mm, width 50 ~128mm, 50~146mm of height.Pole plate 13 can also be ripe pole plate, and the grid 14 in pole plate 13 is wide with a thickness of 0.6~1.2mm Spend 50~128mm, 50~146mm of height.Each component is distinguished relative to the content of lead powder quality in anode diachylon in pole plate 13 Are as follows: red lead additional amount is 10~20wt%, and the net additional amount of sulfuric acid is 1~6wt%, and apparent density of lead paste is controlled in 4.1~4.3g/cm3. In cathode lead plaster in pole plate 13 each component relative to the content of lead powder quality be respectively as follows: acetylene black additional amount be 0.2~ 2.0wt%, lignin additional amount be 0.2~0.5wt%, humic acid additional amount be 0.3~0.5wt%, it is short fibre additional amount be dimension 0.1~ 0.8wt%, the net additional amount of sulfuric acid are 1~6wt%, and apparent density of lead paste is controlled in 4.0~4.3g/cm3.AGM partition 12 encapsulates pole plate 13 encapsulating width is 5~6mm, and encapsulating height is 5~8mm.Pole group's welding in pole group 9 forms busbar connector by cast welding, Inclined 11 butt welding of part 10 and straight pole, welding uses cross wall welding between pole group 9, and straight pole 11 and anode and cathode terminals 6 freeze connection.
Small-sized AGM boosting battery design of the invention is as follows.
The production of first stage grid: battery grid 14 is using technique is even rushed, and using lead calcium, ((Ca contains Pb alloy grid material Amount is 0.03%~0.2%;Sn content range is 0.1%~5%), with a thickness of 0.6~1.3mm, 50~128mm of width, height 50~ 146mm。
Second stage lead plaster and system: each component is respectively as follows: red lead additional amount relative to the content of lead powder and is in anode diachylon 10~20wt%, the net additional amount of sulfuric acid are 1~6wt% of lead powder quality;Apparent density of lead paste is controlled in 4.1~4.3g/cm3.
Each component is respectively as follows: 0.2~2.0wt% of acetylene black relative to the content of lead powder in cathode lead plaster, and lignin 0.2~ 0.5wt%, 0.3~0.5wt% of humic acid, 0.1~0.8wt% of staple fiber, the net additional amount of sulfuric acid are 1~6wt% of lead powder quality, lead Cream apparent density is controlled in 4.0~4.3g/cm3.
Phase III pole plate fills growth plate curing: filling mode using machinery, that lead plaster is continuously coated in plate railings of anode and cathode is right Positive plate and negative plate are formed by continuous mechanical cutting afterwards.Then pole plate carries out curing and drying respectively.
The assembly of fourth stage battery: partition uses AGM partition 12, the U-shaped encapsulating positive plate of partition or negative plate, and encapsulating is wide 5~6mm, encapsulating 5~8mm of height are spent, the welding of pole group uses cast welding, and cast-on strap thickness control is in 3~5mm;Partition arrives 5~8mm of busbar connector gap;Pole group enters after slot between the group of pole welding using butt welding;Big lid, using heat-sealing, then will with groove body sealing Copper core terminal and straight pole carry out processing of freezing on battery case.
5th stage Battery formation: small-sized AGM boosting battery uses vacuum acid feeding, and vacuum degree control is on the left side -0.08Mpa The right side, acid adding acid density domination is in 1.26~1.29g/ml;It is melted into 24~48h of time.
The post-processing of 6th stage battery: installing safety valve after Battery formation is offline, then will be with concentration 4 structure of gas vent Battery tegillum 3 sealed with battery big cover 2, after heat-sealing pack delivery.

Claims (9)

1. a kind of small-sized AGM boosting battery, including battery groove body (1), battery big cover (2) and pole group (9), the pole group It (9) include AGM partition (12), pole plate (13), inclined part (10) and straight pole (11), the battery big cover (2) is equipped with positive and negative anodes Terminal (6), it is characterised in that: further include with the battery tegillum (3) for concentrating gas vent (4), battery tegillum (3) is loaded on battery big cover (2) on;The battery groove body (1) includes 6 single lattices;The pole group (9) is 6, corresponding with 6 single lattices respectively;It is described Battery big cover (2) is equipped with 6 acid filling holes (5) corresponding with 6 single lattices;The acid filling hole (5) is mounted on safety valve (7).
2. a kind of small-sized AGM boosting battery according to claim 1, it is characterised in that: the pole plate (13) is made a living pole Plate;Grid (14) in pole plate (13) is to connect punching grid;Grid (14) is using containing Ca 0.03%~0.2%, Sn 0.1%~5% Lead calcium Pb alloy, with a thickness of 0.6~1.2mm, 50~128mm of width, 50~146mm of height.
3. a kind of small-sized AGM boosting battery according to claim 1, it is characterised in that: the plate in the pole plate (13) Grid (14) are with a thickness of 0.6~1.2mm, 50~128mm of width, 50~146mm of height.
4. a kind of small-sized AGM boosting battery according to claim 1,2 or 3, it is characterised in that: the concentration gas vent (4) diameter is 5.7-5.9mm, depth >=10mm.
5. a kind of small-sized AGM boosting battery according to claim 1,2 or 3, it is characterised in that: the anode and cathode terminals (6) the die casting lead terminal (8) with copper core internal screw thread is used.
6. a kind of small-sized AGM boosting battery according to claim 1,2 or 3, it is characterised in that: in the pole plate (13) Anode diachylon in each component to be respectively as follows: red lead additional amount relative to the content of lead powder quality be 10~20wt%, sulfuric acid is added only Amount is 1~6wt%, and apparent density of lead paste is controlled in 4.1~4.3g/cm3;In cathode lead plaster in pole plate (13) each component relative to It is 0.2~2.0wt% that the content of lead powder quality, which is respectively as follows: acetylene black additional amount, and lignin additional amount is 0.2~0.5wt%, humic acid Additional amount is 0.3~0.5wt%, and short fibre additional amount is 0.1~0.8wt% of dimension, and the net additional amount of sulfuric acid is 1~6wt%, and lead plaster view is close Degree control is in 4.0~4.3g/cm3.
7. a kind of small-sized AGM boosting battery according to claim 1,2 or 3, it is characterised in that: the pole group (9) In pole group's welding pass through cast welding formation busbar connector, inclined part (10) and straight pole (11) butt welding;Welding is used and is worn between pole group (9) Wall welding, straight pole (11) and anode and cathode terminals (6) freeze connection.
8. a kind of small-sized AGM boosting battery according to claim 1,2 or 3, it is characterised in that: the AGM partition (12) the encapsulating width for encapsulating pole plate (13) is 5~6mm, and encapsulating height is 5~8mm.
9. a kind of small-sized AGM boosting battery according to claim 1,2 or 3, it is characterised in that: the battery groove body (1), battery big cover (2) and battery tegillum (3) are all made of PP material, and battery groove body (1) is small with battery big cover (2) and battery respectively Lid (3) is sealed.
CN201811075201.2A 2018-09-14 2018-09-14 A kind of small-sized AGM boosting battery Pending CN109346781A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112885988A (en) * 2021-01-07 2021-06-01 浙江南都电源动力股份有限公司 12V low-voltage electrical system AGM manufacturing process for BEV automobile and battery
CN114243201A (en) * 2021-12-20 2022-03-25 风帆(扬州)有限责任公司 High valve accuse non-maintaining battery of security

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN203398235U (en) * 2013-08-29 2014-01-15 福建一洲动力科技有限公司 12-V and 30-Ah lead-acid storage battery
CN107359354A (en) * 2017-07-31 2017-11-17 山东久力工贸集团有限公司 A kind of tubular type maintenance-free battery
CN206864510U (en) * 2017-06-28 2018-01-09 重庆万里新能源股份有限公司 Lead-acid battery lid
CN207009593U (en) * 2017-06-16 2018-02-13 江苏海宝电池科技有限公司 High-performance lead-acid accumulator
CN207097878U (en) * 2017-07-26 2018-03-13 漳州市华威电源科技有限公司 A kind of modified top cover for lead-acid accumulator

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN203398235U (en) * 2013-08-29 2014-01-15 福建一洲动力科技有限公司 12-V and 30-Ah lead-acid storage battery
CN207009593U (en) * 2017-06-16 2018-02-13 江苏海宝电池科技有限公司 High-performance lead-acid accumulator
CN206864510U (en) * 2017-06-28 2018-01-09 重庆万里新能源股份有限公司 Lead-acid battery lid
CN207097878U (en) * 2017-07-26 2018-03-13 漳州市华威电源科技有限公司 A kind of modified top cover for lead-acid accumulator
CN107359354A (en) * 2017-07-31 2017-11-17 山东久力工贸集团有限公司 A kind of tubular type maintenance-free battery

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112885988A (en) * 2021-01-07 2021-06-01 浙江南都电源动力股份有限公司 12V low-voltage electrical system AGM manufacturing process for BEV automobile and battery
CN114243201A (en) * 2021-12-20 2022-03-25 风帆(扬州)有限责任公司 High valve accuse non-maintaining battery of security
CN114243201B (en) * 2021-12-20 2023-11-17 风帆(扬州)有限责任公司 High valve accuse maintenance-free battery of security

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Application publication date: 20190215

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