CN109346757A - A kind of fuel cell pile - Google Patents

A kind of fuel cell pile Download PDF

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Publication number
CN109346757A
CN109346757A CN201811336448.5A CN201811336448A CN109346757A CN 109346757 A CN109346757 A CN 109346757A CN 201811336448 A CN201811336448 A CN 201811336448A CN 109346757 A CN109346757 A CN 109346757A
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China
Prior art keywords
plate
flow field
membrane electrode
fuel
fuel cell
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CN201811336448.5A
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Chinese (zh)
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CN109346757B (en
Inventor
陈莉
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Nanjing Sai'ao Peak Energy Technology Co Ltd
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Nanjing Sai'ao Peak Energy Technology Co Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/24Grouping of fuel cells, e.g. stacking of fuel cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/24Grouping of fuel cells, e.g. stacking of fuel cells
    • H01M8/2465Details of groupings of fuel cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/24Grouping of fuel cells, e.g. stacking of fuel cells
    • H01M8/2465Details of groupings of fuel cells
    • H01M8/247Arrangements for tightening a stack, for accommodation of a stack in a tank or for assembling different tanks
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/24Grouping of fuel cells, e.g. stacking of fuel cells
    • H01M8/249Grouping of fuel cells, e.g. stacking of fuel cells comprising two or more groupings of fuel cells, e.g. modular assemblies
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Abstract

The present invention provides a kind of fuel cell pile, belongs to field of fuel cell technology.Include the battery pack being laminated by multi-disc monocell, is respectively equipped with front end-plate and end plate in the upper and lower ends of battery pack, front end collector plate is set between the upper end and front end-plate of battery pack, sets rear end collector plate between the lower end and end plate of battery pack;Wherein, the monocell includes: anode plate, cathode plate and membrane electrode, and membrane electrode is sandwiched between anode plate and cathode plate;Anode plate is surrounded by the first positive stop lug boss towards membrane electrode one side, for fixing the position of membrane electrode;Anode plate is towards offering fuel flow field in membrane electrode one side;Cathode plate is towards offering the second positive stop lug boss in membrane electrode one side, and cathode plate is towards offering oxidant flow field in membrane electrode one side.Pile can accurately control the decrement of the gas diffusion layers per a piece of membrane electrode, and the performance uniformity of each monocell is preferable in pile, improve the service life of pile.

Description

A kind of fuel cell pile
Technical field
The present invention provides a kind of fuel cell pile, belongs to field of fuel cell technology.
Background technique
Proton Exchange Membrane Fuel Cells (proton exchange membrane fuel cell, PEMFC) is a kind of clear The electrochemical generating unit of clean environmental protection, since its is small in size, light weight, operating condition is mild, energy conversion rate is high, structure is simple And the response advantages such as rapidly, can be widely applied to the vehicles, stationary power generation, material carry, backup power source and portable All various aspects such as power supply.Hydrogen Energy provides a new approach with fuel cell technology for the utilization of clean energy resource system.Hydrogen It is from a wealth of sources, both include renewable energy, also includes non-renewable energy resources resource.Hydrogen Energy can become the energy complementary with electric power Carrier, so that the carbon emission of current energy resource system be effectively reduced.Therefore, PEMFC be considered as 21 century first choice cleaning, efficiently Power generator.
For vehicle fuel battery engine, the service life must reach with the comparable level of conventional engines, be possible to Realize industrialization.The plan of U.S. Department of Energy Hydrogen Energy, Japanese new energy and industrial technology develop the committee and European Hydrogen Energy and fuel Battery technology forum thinks, for vehicle fuel battery engine service life at least 5000h(passenger car) and 10000h(commercialization Vehicle) just with the possibility of industrialization.Compared to static application environment (such as power station or mobile power source), vehicle environment and work item Part seems more severe, the durability of PEMFC engine and contemplates that a certain distance at present.Wherein, the service life of pemfc stack One of an important factor for being the durability of influence PEMFC engine.
Traditional pile is to be pressed pressing molding after membrane electrode, the superposition of bipolar plates interval by adjusting in the process Power or pile total length control the total compression amounts of gas diffusion layers, due to the pretightning force distribution in compaction process, inside pile Unevenly, cause the decrement of the gas diffusion layers of each monocell in pile not of uniform size, i.e., the gas of part monocell expands Dissipate layer decrement gas diffusion layers bigger than normal, part monocell decrement it is less than normal, then pile in the process of running, especially After long-play, the performance gap between each monocell becomes increasing, generates " short -board effect ", influences pile Service life.
For traditional pile, when pile performing leak test is unqualified or pile breaks down in the process of running, very Heapcheck may be torn open, due to repeated disassembled and assembled pile, gas diffusion layers are repeatedly extruded, cause the structure of gas diffusion layers by Irreversible damage hinders the transmission of reaction gas and water, to influence the service life of pile.
In addition, the sealing performance of pile is also to influence one of the key factor in pile service life, the gas of traditional pile is close Envelope is compressed by using five in one as anode plate/anode-side gasket/membrane electrode frame/cathode side gasket/cathode plate Structure realizes that this is higher to anode-side gasket and the required precision of the height of cathode side gasket, and this structure Dislocation between pole plate easily occurs in the environment of vibration and impact for pile, is easy for that leakage problem can be generated in this way, leads to electricity Heap cannot be run, and influence the service life of pile.
Therefore, it is badly in need of finding a kind of novel pile, can accurately controls the pressure of the gas diffusion layers per a piece of membrane electrode Contracting amount, and be avoided that since the gas diffusion layers that disassembly pile causes when pile sealing problem or pile break down are by repeatedly Irreversible damage caused by squeezing, moreover it is possible to reduce the requirement to gas side gasket, improve the service life of pile.
Summary of the invention
The purpose of the present invention is to provide the fuel cell packs of long-life a kind of, and the fuel cell pack is by front end-plate, front end The novel monocell of collector plate, N group, rear end plate, rear end collector plate, end plate, strapping and sealing ring composition;Described is new The monocell of type is pressed by novel anode plate, membrane electrode, highway gasket seal, novel cathode plate, until film The positive positive stop lug boss of electrode border and anode plate, the front of cathode plate are completely overlapped, form " sandwich " structure, are used in combination Upper and lower cleat insulator is locked, and novel fuel-cell single-cell is formed.
Technical solution is:
A kind of fuel cell pile includes the battery pack being laminated by multi-disc monocell, in the upper and lower ends point of battery pack Not She You front end-plate and end plate, front end collector plate, the lower end and rear end of battery pack are set between the upper end and front end-plate of battery pack Rear end collector plate is set between plate;
Wherein, the monocell includes: anode plate, cathode plate and membrane electrode, and membrane electrode is sandwiched between anode plate and cathode plate; Anode plate is surrounded by the first positive stop lug boss towards membrane electrode one side, for fixing the position of membrane electrode;Anode plate direction Fuel flow field is offered in membrane electrode one side;Cathode plate is surrounded by the second positive stop lug boss towards membrane electrode one side, and being used for will The position of membrane electrode is fixed, and cathode plate is towards offering oxidant flow field in membrane electrode one side.
In one embodiment, membrane electrode is located inside the first positive stop lug boss and the second positive stop lug boss of rectangle.
In one embodiment, the quantity of the monocell in battery pack is 1~500.
In one embodiment, an entirety is fixed as by strapping between battery pack, front end-plate and end plate.
In one embodiment, fuel inlet, fuel outlet, cooling liquid inlet are additionally provided on front end-plate;Coolant liquid Outlet, oxidant inlet, oxidant outlet;Fuel inlet, fuel outlet are connected to fuel flow field;Cooling liquid inlet, coolant liquid Outlet is connected to coolant liquid flow field;Oxidant inlet, oxidant outlet are connected to oxidant flow field.
In one embodiment, cathode plate sets coolant liquid flow field in membrane electrode one side;The surrounding in coolant liquid flow field If coolant liquid seal gasket;The depth of the coolant liquid seal gasket is 0.2~0.5mm, and width is 2~5mm;Described is cold But liquid stream field is parallel flow field, and the groove depth in flow field is 0.3~1.0mm, and the groove width in flow field is 0.4~1.0mm, ridge width is 0.4~ 1.0mm。
In one embodiment, rear end plate is set between rear end collector plate and battery pack.
In one embodiment, the runner between anode plate and cathode plate is carried out close by highway gasket seal Envelope.
In one embodiment, the edge of the upper end of anode plate is socketed with cleat insulator, the lower edge of cathode plate It is socketed with lower cleat insulator;Locking mode between the upper cleat insulator and lower cleat insulator is that bolt fastening or glue are viscous Connect fastening.
In one embodiment, the material of the strapping is stainless steel or titanium, and the number of the strapping is 3 ~8, it is non-crossing arrangement between the strapping.
In one embodiment, the material of the upper cleat insulator and lower cleat insulator be glass fibre, polyformaldehyde, The nylon material of ABS engineering plastics or fiberglass reinforced.
In one embodiment, the fuel flow field is parallel flow field, and the groove depth in flow field is 0.3~1.0mm, flow field Groove width be 0.4~1.0mm, ridge width be 0.5~1.2mm.
In one embodiment, the oxidant flow field is parallel flow field, and the groove depth in flow field is 0.3~1.0mm, stream The groove width of field is 0.4~1.0mm, and ridge width is 0.4~1.2mm.
In one embodiment, the front end-plate is invented is glass fibre, gathers with the material of end plate invention invention The nylon material of formaldehyde, ABS engineering plastics or fiberglass reinforced.
In one embodiment, the main material of front end collector plate invention and the invention of rear end collector plate is Huang Copper, red copper, nickel, stainless steel or titanium.
In one embodiment, anode plate invention invention, cathode plate invention invention and end plate invention invention Material be graphite, metal, metal-base composites or C-base composte material.
Beneficial effect
First, pile of the invention, due to using anode plate, cathode plate with positive stop lug boss, so can accurately control every The decrement of the gas diffusion layers of a piece of membrane electrode, the performance uniformity of each monocell is preferable in pile, improves pile Service life.
Second, meanwhile, pile of the invention is clamped anode plate, membrane electrode, cathode plate using upper and lower cleat insulator The fixed monocell for forming " sandwich " structure, is avoided that in this way due to dismounting when pile sealing problem or pile break down The gas diffusion layers that pile causes are repeatedly extruded caused irreversible damage, improve the service life of pile.
Third, and the pile of this structure is not susceptible to the dislocation between pole plate in the environment of vibration and impact, guarantees The air-tightness of pile, improves the service life of pile.
4th, in addition, also eliminating the gasket of oxidant side in the electric pile structure, simplify pile production technology stream Journey improves the production efficiency of pile, meanwhile, reduce the cost of pile.
5th, pile is integrally fixed using the tired band of elasticity, so that the application distribution between each cell piece is equal One, it solves in the prior art since in compaction process, the pretightning force inside pile is unevenly distributed, leads to each list in pile The decrement of the gas diffusion layers of battery problem not of uniform size.
Detailed description of the invention
Fig. 1 stack structure for fuel battery effect picture
Fig. 2 stack structure for fuel battery explosive view
Fig. 3 monocell positive effect figure
Fig. 4 monocell adverse side effects figure
Fig. 5 single-cell structure explosive view
Fig. 6 cathode plate positive effect figure
Fig. 7 cathode plate adverse side effects figure
Fig. 8 anode plate positive effect figure
Fig. 9 anode plate adverse side effects figure
The constant current life test operating condition schematic diagram that Figure 10 operating condition is formulated
1, fuel inlet;2, fuel outlet;3, cooling liquid inlet;4, cooling liquid outlet;5, oxidant inlet;6, oxidant goes out Mouthful;7, front end collector plate;8, rear end collector plate;9, front end-plate;10, end plate;11, strapping;12, monocell;13, hold level with both hands after Plate;14, anode plate;15, cathode plate;16, membrane electrode;17, upper cleat insulator;18, lower cleat insulator;19, highway seals Gasket;20, positive stop lug boss;21, oxidant flow field;22, coolant liquid flow field;23, coolant liquid seal gasket;24, fuel encapsulation glue Pad;25, fuel flow field;26, the second positive stop lug boss;27, rear end plate;28, sealing ring.
Specific embodiment
Embodiment 1
This example assembles one by 200 monocells 12, and 12 active area of monocell is 250cm2Pile.
As depicted in figs. 1 and 2, fuel cell pile includes the battery pack being laminated by multi-disc monocell 12, in electricity The upper and lower ends of pond group are respectively equipped with front end-plate 9 and end plate 10, set front end collector plate between the upper end and front end-plate 9 of battery pack 7, rear end collector plate 8 is set between the lower end and end plate 10 of battery pack;Pass through bundle between battery pack, front end-plate 9 and end plate 10 Band 11 is fixed as an entirety, and the material of the strapping 11 is stainless steel or titanium, and the number of the strapping 11 is 3 ~8, it is non-crossing arrangement between the strapping 11, rear end plate 27, anode plate is set between rear end collector plate 8 and battery pack Runner between 14 and cathode plate 15 is sealed by highway gasket seal 19.Be additionally provided on front end-plate 9 fuel into Mouth 1, fuel outlet 2, cooling liquid inlet 3;Cooling liquid outlet 4, oxidant inlet 5, oxidant outlet 6;Fuel inlet 1, fuel Outlet 2 is connected to fuel flow field 25;Cooling liquid inlet 3, cooling liquid outlet 4 are connected to coolant liquid flow field 22;Oxidant inlet 5, Oxidant outlet 6 is connected to oxidant flow field 21.
Monocell 12 includes: anode plate 14, cathode plate 15 and membrane electrode 16.The front and back sides structure of monocell 12 is respectively as schemed Shown in 3- Fig. 5, in addition, the structure of anode plate 15, as shown in Fig. 8 and Fig. 9 gas, the structure of cathode plate is as shown in Figure 6 and Figure 7.Film electricity Pole 16 is sandwiched between anode plate 14 and cathode plate 15;Anode plate 14 is surrounded by the first positive stop lug boss towards 16 one side of membrane electrode 20, for the position of membrane electrode 16 to be fixed;Anode plate 14 is towards offering fuel flow field 25 in 16 one side of membrane electrode;Cathode plate 15 towards offering the second positive stop lug boss 26 in 16 one side of membrane electrode, and cathode plate 15 is towards offering oxidation in 16 one side of membrane electrode Agent flow field 21, the runner between anode plate 14 and cathode plate 15 are sealed by highway gasket seal 19.Front end-plate 9 with It is sealed between monocell 12 by sealing ring 28.
The front of anode plate 14 has fuel encapsulation rubber mat 24, fuel flow field 25, and reverse side is plane, and fuel flow field 25 is Parallel flow field, the groove depth in flow field are 0.4mm, and the groove width in flow field is 0.8mm, and ridge width is 0.6mm.The front of cathode plate 15 is oxidation Agent flow field 21 and be equipped with the second positive stop lug boss 26, reverse side have coolant liquid seal gasket 23 and coolant liquid flow field 22, oxidant Flow field is parallel flow field, and the groove depth in flow field is 0.4mm, and the groove width in flow field is 0.5mm, and ridge width is 0.5mm;Coolant liquid flow field 22 is Parallel flow field, the groove depth in flow field are 0.5mm, and the groove width in flow field is 0.6mm, and ridge width is 0.6mm.
The edge of the upper end of anode plate 15 is socketed with cleat insulator 17, and the lower edge of cathode plate 15 is socketed with lower insulation Clamping plate 18;Locking mode between the upper cleat insulator 17 and lower cleat insulator 18 is that bolt fastening or glue bonding are tight Gu.
Highway gasket seal 19, sealing ring 28, fuel encapsulation rubber mat 24 and the coolant liquid seal gasket 23 Material is silicon rubber, butyl rubber, nitrile rubber, fluorine silicone rubber, ethylene propylene diene rubber or neoprene.
Rack life test is carried out under operating condition as shown in Figure 10, test result is learnt, when pile is on rack After running 5000h, the output voltage of pile has decayed about 5.92%, then the service life of pile is greater than 8500h(according to pile Output voltage decaying 10% defines the pile service life).

Claims (8)

1. a kind of fuel cell pile, which is characterized in that include the battery pack being laminated by multi-disc monocell (12), in electricity The upper and lower ends of pond group are respectively equipped with front end-plate (9) and end plate (10), set front end between the upper end of battery pack and front end-plate (9) Collector plate (7) sets rear end collector plate (8) between the lower end of battery pack and end plate (10);
Wherein, the monocell (12) includes: anode plate (14), cathode plate (15) and membrane electrode (16), membrane electrode (16) folder Between anode plate (14) and cathode plate (15);Anode plate (14) is surrounded by the first limit convex towards membrane electrode (16) one side Platform (20), for fixing the position of membrane electrode (16);Anode plate (14) is towards offering fuel stream in membrane electrode (16) one side Field (25);Cathode plate (15) is towards offering the second positive stop lug boss (26) in membrane electrode (16) one side, and cathode plate (15) is towards film Oxidant flow field (21) are offered in electrode (16) one side.
2. fuel cell pile according to claim 1, which is characterized in that membrane electrode (16) is located at the first limit of rectangle Boss (20) and the second positive stop lug boss (26) are internal, and the quantity of the monocell (12) in battery pack is 1~500;Battery pack, front end An entirety is fixed as by strapping (11) between plate (9) and end plate (10).
3. fuel cell pile according to claim 1, which is characterized in that be additionally provided with fuel inlet on front end-plate (9) (1), fuel outlet (2), cooling liquid inlet (3);Cooling liquid outlet (4), oxidant inlet (5), oxidant outlet (6);Fuel Import (1), fuel outlet (2) are connected to fuel flow field (25);Cooling liquid inlet (3), cooling liquid outlet (4) and coolant liquid flow field (22) it is connected to;Oxidant inlet (5), oxidant outlet (6) are connected to oxidant flow field (21);Cathode plate (15) is backwards to membrane electrode (16) coolant liquid flow field (22) are set in one side;The surrounding in coolant liquid flow field (22) sets coolant liquid seal gasket (23);Described is cold But the depth of liquid seal gasket is 0.2~0.5mm, and width is 2~5mm;The coolant liquid flow field (22) is parallel flow field, stream The groove depth of field is 0.3~1.0mm, and the groove width in flow field is 0.4~1.0mm, and ridge width is 0.4~1.0mm.
4. fuel cell pile according to claim 1, which is characterized in that set between rear end collector plate (8) and battery pack Rear end plate (27);Runner between anode plate (14) and cathode plate (15) is carried out close by highway gasket seal (19) Envelope;The edge of the upper end of anode plate (15) is socketed with cleat insulator (17), and the lower edge of cathode plate (15) is socketed with lower exhausted Edge clamping plate (18);Locking mode between the upper cleat insulator (17) and lower cleat insulator (18) is bolt fastening or glue Fastening adhesion.
5. fuel cell pile according to claim 2, which is characterized in that the material of the strapping (11) is stainless Steel or titanium, the number of the strapping (11) are 3~8, are non-crossing arrangement between the strapping (11);Described is upper The material of cleat insulator (17) and lower cleat insulator (18) is the Buddhist nun of glass fibre, polyformaldehyde, ABS engineering plastics or fiberglass reinforced Imperial material;The fuel flow field (25) is parallel flow field, and the groove depth in flow field is 0.3~1.0mm, the groove width in flow field is 0.4~ 1.0mm, ridge width are 0.5~1.2mm.
6. fuel cell pile according to claim 1, which is characterized in that the oxidant flow field (21) is concurrent flow , the groove depth in flow field is 0.3~1.0mm, and the groove width in flow field is 0.4~1.0mm, and ridge width is 0.4~1.2mm;The oxidation Agent flow field (21) is parallel flow field, and the groove depth in flow field is 0.3~1.0mm, and the groove width in flow field is 0.4~1.0mm, and ridge width is 0.4 ~1.2mm.
7. fuel cell pile according to claim 1, which is characterized in that the front end collector plate (7) and rear end collection The main material of flowing plate (8) is brass, red copper, nickel, stainless steel or titanium.
8. fuel cell pile according to claim 1, which is characterized in that the anode plate (14), cathode plate (15) Material with end plate (10) is graphite, metal, metal-base composites or C-base composte material.
CN201811336448.5A 2018-11-12 2018-11-12 Fuel cell stack Active CN109346757B (en)

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CN113113626A (en) * 2021-03-25 2021-07-13 国家电投集团氢能科技发展有限公司 Single cell and fuel cell
CN114400346A (en) * 2021-12-03 2022-04-26 佛山仙湖实验室 Integrated membrane electrode unit structure and fuel cell stack

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CN113113626A (en) * 2021-03-25 2021-07-13 国家电投集团氢能科技发展有限公司 Single cell and fuel cell
CN114400346A (en) * 2021-12-03 2022-04-26 佛山仙湖实验室 Integrated membrane electrode unit structure and fuel cell stack

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CN109346757B (en) 2024-03-22

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