CN109337233A - A kind of zero shrinkage floor film - Google Patents
A kind of zero shrinkage floor film Download PDFInfo
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- CN109337233A CN109337233A CN201811018747.4A CN201811018747A CN109337233A CN 109337233 A CN109337233 A CN 109337233A CN 201811018747 A CN201811018747 A CN 201811018747A CN 109337233 A CN109337233 A CN 109337233A
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- floor film
- zero shrinkage
- zero
- plasticizer
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2327/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2427/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2427/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2427/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08J2427/18—Homopolymers or copolymers of tetrafluoroethylene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2491/00—Characterised by the use of oils, fats or waxes; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0893—Zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/221—Oxides; Hydroxides of metals of rare earth metal
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
- C08K3/042—Graphene or derivatives, e.g. graphene oxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K3/2279—Oxides; Hydroxides of metals of antimony
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
A kind of zero shrinkage floor film of the present invention, according to weight ratio, its raw material composition are as follows: 100 parts of PVC sizing material, 6-12 parts of zinc powder, 2-3 parts of epoxidized soybean oil, 40-60 parts of plasticizer, 4-8 parts of polytetrafluoroethylene (PTFE), 2~4 parts of stabilizer, 20-40 parts of processing aid, floor film zero is shunk, and cuts and long-time use is indeformable, and the floor film has preferable wearability, long service life.
Description
Technical field
The invention belongs to PVC technical fields, specifically, being related to a kind of zero shrinkage floor film.
Background technique
Polyvinyl chloride English abbreviation PVC, with less toxic, fire-retardant, cold-resistant, the environmentally friendly excellent performance of PVC film, increasingly
To vast purposes, it is widely used in the fields such as certificate, Bao Ce, packaging, luggage, clothes, footwear, automobile decoration, develops to
Visible PVC product everywhere in daily life field.By a little as it can be seen that the demand of PVC film is increasing.
PVC film main ingredient is polyvinyl chloride, separately has and other compositions are added to enhance its heat resistance, toughness, ductility
Deng.PVC film be liked deeply in the world today, a kind of rather popular and synthetic material for being also widely used.PVC film
Global usage amount be in second in various synthetic materials.In the material that can produce three-dimensional table facial mask, PVC film is most
Suitable material.
Floor film is covered in PVC floor surface, plays role in decoration, the wearability for needing to have certain, and is cutting
Be easy to shrink when using, when fold occurs, influences beauty, and cutting, due to shrinking, size is caused to shorten, and
Super film is not wear-resisting, is easy to tear.
Summary of the invention
The present invention overcomes the disadvantages of the prior art, provides a kind of zero shrinkage floor film, not only has preferably resistance to
Mill property, and floor film zero is shunk, and cuts and long-time use is indeformable.
In order to solve the above-mentioned technical problem, the present invention is achieved by the following technical solutions:
A kind of zero shrinkage floor film, according to weight ratio, raw material composition are as follows: 100 parts of PVC sizing material, 6-12 parts of zinc powder, epoxy
2-3 parts of soybean oil, 40-60 parts of plasticizer, 4-8 parts of polytetrafluoroethylene (PTFE), 2~4 parts of stabilizer, 20-40 parts of processing aid.
Further, the plasticizer is polyethylene glycol 20-25 parts, 10-15 parts of dipentaerythritol, 1-2 parts of graphene, metatitanic acid
2-3 parts and stearic acid 1-3 parts of ester.
Further, the stabilizer is 10-15 parts of alkyl acid esters, 8-16 parts of zeolite, 0.5-2 parts of titanium dioxide, stearic acid
2-5 parts and dibutyl tin dilaurate 10-20 parts of calcium.
Further, the processing aid be metallic antimony 2-4 parts, 1-2 parts of nanometer titanium dioxide antimony, 2-5 parts of tartaric acid, glacial acetic acid 3-
6 parts, 15-25 parts of rare earth oxide, 2-4 parts of graphene oxide, 5-10 parts of cocoanut fiber powder.
Further, the plasticizer is 22 parts of polyethylene glycol, 13 parts of dipentaerythritol, 1.5 parts of graphene, titanate esters 2.4
Part and 2 parts of stearic acid.
Further, the stabilizer is 12 parts of alkyl acid esters, 12 parts of zeolite, 1 part of titanium dioxide, 3 parts of calcium stearate and two
13 parts of dibutyl tin laurate.
Further, the processing aid is 3 parts of metallic antimony, 1.5 parts of nanometer titanium dioxide antimony, 3 parts of tartaric acid, 4 parts of glacial acetic acid, dilute
21 parts of native oxide, 3 parts of graphene oxide, 7 parts of cocoanut fiber powder.
Compared with prior art, the beneficial effects of the present invention are:
A kind of zero shrinkage floor film of the present invention, according to weight ratio, raw material composition are as follows: 100 parts of PVC sizing material, zinc powder
6-12 parts, 2-3 parts of epoxidized soybean oil, 40-60 parts of plasticizer, 4-8 parts of polytetrafluoroethylene (PTFE), 2~4 parts of stabilizer, processing aid 20-
40 parts, floor film zero is shunk, and cuts and long-time use is indeformable, and the floor film has preferable wearability, use
Service life is long.
Specific embodiment
Hereinafter, preferred embodiments of the present invention will be described, it should be understood that preferred embodiment described herein is only used
In the description and interpretation present invention, it is not intended to limit the present invention.
A kind of zero shrinkage floor film, according to weight ratio, raw material composition are as follows: 100 parts of PVC sizing material, 6-12 parts of zinc powder, epoxy
2-3 parts of soybean oil, 40-60 parts of plasticizer, 4-8 parts of polytetrafluoroethylene (PTFE), 2~4 parts of stabilizer, 20-40 parts of processing aid, polytetrafluoro
Ethylene effectively improves the wearability of floor film.
Wherein, plasticizer is 22 parts of polyethylene glycol, 13 parts of dipentaerythritol, 1.5 parts of graphene, 2.4 parts of titanate esters and hard
2 parts of resin acid.Stabilizer is 12 parts of alkyl acid esters, 12 parts of zeolite, 1 part of titanium dioxide, 3 parts of calcium stearate and di lauric dibutyl
13 parts of tin, enhance the addition of the stability of floor film, especially zeolite, enhances the inertia of floor film.Processing aid is metallic antimony 3
Part, 1.5 parts of nanometer titanium dioxide antimony, 3 parts of tartaric acid, 4 parts of glacial acetic acid, 21 parts of rare earth oxide, 3 parts of graphene oxide, cocoanut fiber
7 parts of powder, graphene oxide and cocoanut fiber powder make its zero contraction, nanometer two while the wearability for effectively improving floor film
Antimony oxide improves the ageing-resistant performance of final floor film product.
Indices are as follows:
Finally, it should be noted that these are only the preferred embodiment of the present invention, it is not intended to restrict the invention, although
Referring to embodiment, invention is explained in detail, for those skilled in the art, still can be to aforementioned
Technical solution documented by each embodiment is modified or equivalent replacement of some of the technical features, but it is all
Within the spirit and principles in the present invention, any modification, equivalent replacement, improvement and so on should be included in protection of the invention
Within the scope of.
Claims (7)
1. a kind of zero shrinkage floor film, which is characterized in that according to weight ratio, raw material composition are as follows: 100 parts of PVC sizing material, zinc powder 6-
12 parts, 2-3 parts of epoxidized soybean oil, 40-60 parts of plasticizer, 4-8 parts of polytetrafluoroethylene (PTFE), 2~4 parts of stabilizer, processing aid 20-40
Part.
2. a kind of zero shrinkage floor film according to claim 1, which is characterized in that the plasticizer is polyethylene glycol 20-25
Part, 10-15 parts of dipentaerythritol, 1-2 parts of graphene, 2-3 parts of titanate esters and 1-3 parts of stearic acid.
3. a kind of zero shrinkage floor film according to claim 2, which is characterized in that the stabilizer is alkyl acid esters 10-15
Part, 8-16 parts of zeolite, 0.5-2 parts of titanium dioxide, 2-5 parts of calcium stearate and 10-20 parts of dibutyl tin dilaurate.
4. according to zero shrinkage floor film of one kind described in claim 3, which is characterized in that the processing aid is metallic antimony 2-4 parts, is received
1-2 parts of antimony trichloride of rice, 2-5 parts of tartaric acid, 3-6 parts of glacial acetic acid, 15-25 parts of rare earth oxide, 2-4 parts of graphene oxide, coconut
5-10 parts of fiber powder.
5. a kind of zero shrinkage floor film according to claim 4, which is characterized in that the plasticizer be 22 parts of polyethylene glycol,
13 parts of dipentaerythritol, 1.5 parts of graphene, 2.4 parts of titanate esters and 2 parts of stearic acid.
6. a kind of zero shrinkage floor film according to claim 5, which is characterized in that the stabilizer be 12 parts of alkyl acid esters,
12 parts of zeolite, 1 part of titanium dioxide, 3 parts of calcium stearate and 13 parts of dibutyl tin dilaurate.
7. according to zero shrinkage floor film of one kind described in claim 6, which is characterized in that the processing aid is 3 parts of metallic antimony, nanometer
1.5 parts of antimony trichloride, 3 parts of tartaric acid, 4 parts of glacial acetic acid, 21 parts of rare earth oxide, 3 parts of graphene oxide, 7 parts of cocoanut fiber powder.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811018747.4A CN109337233A (en) | 2018-09-03 | 2018-09-03 | A kind of zero shrinkage floor film |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811018747.4A CN109337233A (en) | 2018-09-03 | 2018-09-03 | A kind of zero shrinkage floor film |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109337233A true CN109337233A (en) | 2019-02-15 |
Family
ID=65297117
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811018747.4A Withdrawn CN109337233A (en) | 2018-09-03 | 2018-09-03 | A kind of zero shrinkage floor film |
Country Status (1)
| Country | Link |
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| CN (1) | CN109337233A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110283402A (en) * | 2019-05-29 | 2019-09-27 | 安徽同心林塑胶科技有限公司 | PVC floor graphene-based additive and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103044804A (en) * | 2012-12-11 | 2013-04-17 | 浙江博泰塑胶有限公司 | Flame-retardant transparent floor film and production technology thereof |
| CN107474429A (en) * | 2017-08-15 | 2017-12-15 | 安徽嘉阳新材料科技有限公司 | A kind of wear-resistant flame-retardant floorboard film and preparation method thereof |
| CN107698890A (en) * | 2017-10-18 | 2018-02-16 | 安徽嘉阳新材料科技有限公司 | A kind of processing technology of floor film |
-
2018
- 2018-09-03 CN CN201811018747.4A patent/CN109337233A/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103044804A (en) * | 2012-12-11 | 2013-04-17 | 浙江博泰塑胶有限公司 | Flame-retardant transparent floor film and production technology thereof |
| CN107474429A (en) * | 2017-08-15 | 2017-12-15 | 安徽嘉阳新材料科技有限公司 | A kind of wear-resistant flame-retardant floorboard film and preparation method thereof |
| CN107698890A (en) * | 2017-10-18 | 2018-02-16 | 安徽嘉阳新材料科技有限公司 | A kind of processing technology of floor film |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110283402A (en) * | 2019-05-29 | 2019-09-27 | 安徽同心林塑胶科技有限公司 | PVC floor graphene-based additive and preparation method thereof |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20190215 |