CN109385022A - A kind of super film of lamination coating - Google Patents
A kind of super film of lamination coating Download PDFInfo
- Publication number
- CN109385022A CN109385022A CN201811018656.0A CN201811018656A CN109385022A CN 109385022 A CN109385022 A CN 109385022A CN 201811018656 A CN201811018656 A CN 201811018656A CN 109385022 A CN109385022 A CN 109385022A
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- Prior art keywords
- parts
- film
- super
- lamination coating
- powder
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2327/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2491/00—Characterised by the use of oils, fats or waxes; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2497/00—Characterised by the use of lignin-containing materials
- C08J2497/02—Lignocellulosic material, e.g. wood, straw or bagasse
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/04—Ingredients characterised by their shape and organic or inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0893—Zinc
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/387—Borates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
- C08K3/042—Graphene or derivatives, e.g. graphene oxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/22—Expanded, porous or hollow particles
- C08K7/24—Expanded, porous or hollow particles inorganic
- C08K7/26—Silicon- containing compounds
Abstract
The super film of a kind of lamination coating of the present invention, it film adhered is formed by multilayer is super, according to parts by weight, every layer of raw material composition are as follows: 100 parts of PVC sizing material, 5-10 parts of zinc powder, 5-10 parts of epoxidized soybean oil, 10-30 parts of plasticizer, 2~5 parts of Ge-Ba-Zn composite stabilizer, 20-50 parts of processing aid, it passes through the addition for matching raw material, obtain the super film of lamination coating, and zero shrinks, cut and using when be zero contraction.
Description
Technical field
The invention belongs to PVC technical fields, specifically, being related to a kind of super film of lamination coating.
Background technique
Polyvinyl chloride English abbreviation PVC, with less toxic, fire-retardant, cold-resistant, the environmentally friendly excellent performance of PVC film, increasingly
To vast purposes, it is widely used in the fields such as certificate, Bao Ce, packaging, luggage, clothes, footwear, automobile decoration, develops to
Visible PVC product everywhere in daily life field.By a little as it can be seen that the demand of PVC film is increasing.
PVC film main ingredient is polyvinyl chloride, separately has and other compositions are added to enhance its heat resistance, toughness, ductility
Deng.PVC film be liked deeply in the world today, a kind of rather popular and synthetic material for being also widely used.PVC film
Global usage amount be in second in various synthetic materials.In the material that can produce three-dimensional table facial mask, PVC film is most
Suitable material.
In order to meet the needs of people, the nature of original decorative material surface is generally substituted using PVC decorative Film at present
Lines generally fits together plural layers, and surface is decorative layer, but existing fitting low efficiency, and fitting effect is poor.
But PVC film, especially super film, it is easy to shrink in cutting and use, fold occurs, influences beauty,
And when cutting, due to shrinking, size is caused to shorten, and super film is not wear-resisting, is easy to tear.
Summary of the invention
The present invention overcomes the disadvantages of the prior art, provides a kind of super film of lamination coating, obtains lamination coating
Super film raw material and proportion, and zero shrink, cut and using when be zero contraction.
In order to solve the above-mentioned technical problem, the present invention is achieved by the following technical solutions:
A kind of super film of lamination coating, by multilayer it is super it is film adhered form, according to parts by weight, every layer of raw material composition
Are as follows: 100 parts of PVC sizing material, 5-10 parts of zinc powder, 5-10 parts of epoxidized soybean oil, 10-30 parts of plasticizer, Ge-Ba-Zn composite stabilizer 2~
5 parts, 20-50 parts of processing aid.
Further, the plasticizer includes 1-2 parts of graphene, 5-10 parts of zinc borate, 2-5 parts of waterglass, 3-7 parts of jet,
3-6 parts of phthalic anhydride.
Further, the processing aid includes: 2-4 parts of zinc stearate, 3-6 parts of diatomite, 4-8 parts of kaolin, fullerene
3-6 parts, 10-15 parts of aluminium oxide, 2-6 parts of glass powder, 4-8 parts of cocoanut fiber powder and 2-4 parts of montmorillonite powder.
Further, the plasticizer includes 1.5 parts of graphene, 8 parts of zinc borate, 4 parts of waterglass, 5 parts of jet, 5 parts of phthalic anhydride.
Further, the processing aid includes: 3 parts of zinc stearate, 4 parts of diatomite, 6 parts of kaolin, 4 parts of fullerene, oxygen
12 parts of aluminium of change, 5 parts of glass powder, 5.5 parts of cocoanut fiber powder and 3.5 parts of montmorillonite powder.
Compared with prior art, the beneficial effects of the present invention are:
The super film of a kind of lamination coating of the present invention, by multilayer it is super it is film adhered form, according to parts by weight, often
Layer raw material composition are as follows: 100 parts of PVC sizing material, 5-10 parts of zinc powder, 5-10 parts of epoxidized soybean oil, 10-30 parts of plasticizer, cadmium barium zinc are multiple
2~5 parts of stabilizer are closed, 20-50 parts of processing aid, by the addition of the proportion raw material, obtains the super film of lamination coating,
And zero shrink, cut and using when be zero contraction.
Specific embodiment
Hereinafter, preferred embodiments of the present invention will be described, it should be understood that preferred embodiment described herein is only used
In the description and interpretation present invention, it is not intended to limit the present invention.
A kind of super film of lamination coating, by multilayer it is super it is film adhered form, according to parts by weight, every layer of raw material composition
Are as follows: 100 parts of PVC sizing material, 8 parts of zinc powder, 7 parts of epoxidized soybean oil, 23.5 parts of plasticizer, 4 parts of Ge-Ba-Zn composite stabilizer, processing helps
43 parts of agent.
Plasticizer includes 1.5 parts of graphene, 8 parts of zinc borate, 4 parts of waterglass, 5 parts of jet, 5 parts of phthalic anhydride, phthalic anhydride and graphite
The addition of alkene keeps its ductility more preferable, and zinc borate, waterglass and jet keep its temperature flowing more preferable.
Processing aid includes: 3 parts of zinc stearate, 4 parts of diatomite, 6 parts of kaolin, 4 parts of fullerene, 12 parts of aluminium oxide, glass
5 parts of glass powder, 5.5 parts of cocoanut fiber powder and 3.5 parts of montmorillonite powder, fullerene and cocoanut fiber powder increase the tough of the super film of PVC
Property, diatomite, kaolin and montmorillonite powder are unlikely to deform it, are not easy to shrink.
It is formulated and proportion, realizes the fitting of the super film of multilayer.
Indices are as follows:
Finally, it should be noted that these are only the preferred embodiment of the present invention, it is not intended to restrict the invention, although
Referring to embodiment, invention is explained in detail, for those skilled in the art, still can be to aforementioned
Technical solution documented by each embodiment is modified or equivalent replacement of some of the technical features, but it is all
Within the spirit and principles in the present invention, any modification, equivalent replacement, improvement and so on should be included in protection of the invention
Within the scope of.
Claims (5)
1. a kind of super film of lamination coating, which is characterized in that by multilayer it is super it is film adhered form, according to parts by weight, often
Layer raw material composition are as follows: 100 parts of PVC sizing material, 5-10 parts of zinc powder, 5-10 parts of epoxidized soybean oil, 10-30 parts of plasticizer, cadmium barium zinc are multiple
Close 2~5 parts of stabilizer, 20-50 parts of processing aid.
2. the super film of a kind of lamination coating according to claim 1, which is characterized in that the plasticizer includes graphene 1-
2 parts, 5-10 parts of zinc borate, 2-5 parts of waterglass, 3-7 parts of jet, 3-6 parts of phthalic anhydride.
3. the super film of a kind of lamination coating according to claim 2, which is characterized in that the processing aid includes: tristearin
Sour zinc 2-4 parts, 3-6 parts of diatomite, 4-8 parts of kaolin, 3-6 parts of fullerene, 10-15 parts of aluminium oxide, 2-6 parts of glass powder, coconut
4-8 parts and montmorillonite powder 2-4 parts of fiber powder.
4. the super film of a kind of lamination coating according to claim 3, which is characterized in that the plasticizer includes graphene
1.5 parts, 8 parts of zinc borate, 4 parts of waterglass, 5 parts of jet, 5 parts of phthalic anhydride.
5. the super film of a kind of lamination coating according to claim 4, which is characterized in that the processing aid includes: tristearin
3 parts of sour zinc, 4 parts of diatomite, 6 parts of kaolin, 4 parts of fullerene, 12 parts of aluminium oxide, 5 parts of glass powder, 5.5 parts of cocoanut fiber powder and
3.5 parts of montmorillonite powder.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811018656.0A CN109385022A (en) | 2018-09-03 | 2018-09-03 | A kind of super film of lamination coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811018656.0A CN109385022A (en) | 2018-09-03 | 2018-09-03 | A kind of super film of lamination coating |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109385022A true CN109385022A (en) | 2019-02-26 |
Family
ID=65417540
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811018656.0A Withdrawn CN109385022A (en) | 2018-09-03 | 2018-09-03 | A kind of super film of lamination coating |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109385022A (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102924844A (en) * | 2012-10-09 | 2013-02-13 | 李永平 | Ultra-permeable PVC (polyvinyl chloride) film and preparation method thereof |
-
2018
- 2018-09-03 CN CN201811018656.0A patent/CN109385022A/en not_active Withdrawn
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102924844A (en) * | 2012-10-09 | 2013-02-13 | 李永平 | Ultra-permeable PVC (polyvinyl chloride) film and preparation method thereof |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20190226 |
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| WW01 | Invention patent application withdrawn after publication |