CN109336549A - Function honeycomb ceramic and its manufacturing method - Google Patents

Function honeycomb ceramic and its manufacturing method Download PDF

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Publication number
CN109336549A
CN109336549A CN201811037077.0A CN201811037077A CN109336549A CN 109336549 A CN109336549 A CN 109336549A CN 201811037077 A CN201811037077 A CN 201811037077A CN 109336549 A CN109336549 A CN 109336549A
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Prior art keywords
parts
component
honeycomb ceramic
porcelain
porcelain billet
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Pending
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CN201811037077.0A
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Inventor
钱桂芳
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HUNAN YINHE CERAMICS INDUSTRY Co Ltd
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HUNAN YINHE CERAMICS INDUSTRY Co Ltd
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Priority to CN201811037077.0A priority Critical patent/CN109336549A/en
Publication of CN109336549A publication Critical patent/CN109336549A/en
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    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/10Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of rare earths
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/39Photocatalytic properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/50Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/56Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional monoliths
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
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    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/16Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay
    • C04B35/18Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay rich in aluminium oxide
    • C04B35/195Alkaline earth aluminosilicates, e.g. cordierite or anorthite
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    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
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    • C04B38/00Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/0006Honeycomb structures
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    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
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    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
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    • C04B41/85Coating or impregnation with inorganic materials
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    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
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    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
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    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
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    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/656Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
    • C04B2235/6567Treatment time

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Structural Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Catalysts (AREA)

Abstract

The invention discloses a kind of function honeycomb ceramic and its manufacturing method, the porcelain billet surface of function honeycomb ceramic coats photocatalyst catalyst;Wherein, the component and each component mass parts that porcelain used in the porcelain billet contains are as follows: 30 parts~40 parts of kaolin;Al2O320 parts~30 parts of micro mist;30 parts~40 parts of cordierite;0.5 part -12 parts of rare earth powder;Water: 15 parts~28 parts.The present invention not only has the effect of releasing negative oxygen ion and photocatalyst catalysis, but also improves its specific surface area, increases the adhesion of catalyst.

Description

Function honeycomb ceramic and its manufacturing method
Technical field
The present invention relates to a kind of function honeycomb ceramic and its manufacturing methods.
Background technique
Currently, influence of the industrial pollution to environment also everyday aggravates since industrial development is everyday accelerated, need to take measures Industrial pollution is reduced, is bettered people's living environment.
Summary of the invention
The technical problem to be solved by the present invention is to overcome the deficiencies of existing technologies, a kind of function honeycomb ceramic is provided, it Not only have the effect of releasing negative oxygen ion and photocatalyst catalysis, but also improve its specific surface area, increases the attached of catalyst Property.
In order to solve the above technical problems, the technical scheme is that a kind of function honeycomb ceramic, its porcelain billet surface Coat photocatalyst catalyst;Wherein, the component and each component mass parts that porcelain used in the porcelain billet contains are as follows:
30 parts~40 parts of kaolin;
Al2O320 parts~30 parts of micro mist
30 parts~40 parts of cordierite
0.5 part -12 parts of rare earth powder;
Water: 15 parts~28 parts.
The present invention also provides a kind of manufacturing method of function honeycomb ceramic, the step of method in contain:
S1: it stocks up according to each component and each component mass parts;
S2: each component being mixed and is mediated, then extrusion molding;
S3: and then 8h-15h is fired under 1280 DEG C -1360 DEG C of temperature environment, form porcelain billet;
S4: and then photocatalyst catalyst is coated on porcelain billet surface;
S5: roasting 3h-8h under 500 DEG C -800 DEG C of temperature environment again, and natural cooling forms.
After above-mentioned technical proposal, there is rare earth negative oxygen ion powder in formula of the invention, can be synthetically produced Negative oxygen ion, while surface is also coated with photocatalyst catalyst, has the effect of photocatalyst catalysis, and pass through the groups such as cordierite Divide and honeycomb structure is made, improves its specific surface area, increase the adhesion of catalyst.
Specific embodiment
In order that the present invention can be more clearly and readily understood, below according to specific embodiment, to the present invention make into One step detailed description.
Embodiment one
A kind of function honeycomb ceramic, its porcelain billet surface coat photocatalyst catalyst;Wherein, porcelain used in the porcelain billet Expect that the component contained and each component mass parts are as follows:
30 parts of kaolin;
Al2O320 parts of micro mist;
30 parts of cordierite;
0.5 part of rare earth powder;
Water: 15 parts.
Contain in the step of manufacturing method of the function honeycomb ceramic, method:
S1: it stocks up according to each component and each component mass parts;
S2: each component being mixed and is mediated, then extrusion molding;
S3: and then 8h is fired under 1280 DEG C of temperature environment, form porcelain billet;
S4: and then photocatalyst catalyst is coated on porcelain billet surface;
S5: roasting 3h under 500 DEG C of temperature environment again, and natural cooling forms.
Embodiment two
A kind of function honeycomb ceramic, its porcelain billet surface coat photocatalyst catalyst;Wherein, porcelain used in the porcelain billet Expect that the component contained and each component mass parts are as follows:
40 parts of kaolin;
Al2O330 parts of micro mist;
40 parts of cordierite;
12 parts of rare earth powder;
Water: 28 parts.
Wherein, contain following components in cordierite: MgO, 13.7 parts;Al2O3, 34.9 parts;SiO2, 51.4 parts.
Contain in the step of manufacturing method of the function honeycomb ceramic, method:
S1: it stocks up according to each component and each component mass parts;
S2: each component being mixed and is mediated, then extrusion molding;
S3: and then 15h is fired under 1360 DEG C of temperature environment, form porcelain billet;
S4: and then photocatalyst catalyst is coated on porcelain billet surface;
S5: roasting 8h under 800 DEG C of temperature environment again, and natural cooling forms.
Embodiment three
A kind of function honeycomb ceramic, its porcelain billet surface coat photocatalyst catalyst;Wherein, porcelain used in the porcelain billet Expect that the component contained and each component mass parts are as follows:
35 parts of kaolin;
Al2O325 parts of micro mist;
35 parts of cordierite;
6 parts of rare earth powder;
Water: 22 parts.
Contain in the step of manufacturing method of the function honeycomb ceramic, method:
S1: it stocks up according to each component and each component mass parts;
S2: each component being mixed and is mediated, then extrusion molding;
S3: and then 12h is fired under 1320 DEG C of temperature environment, form porcelain billet;
S4: and then photocatalyst catalyst is coated on porcelain billet surface;
S5: roasting 6h under 700 DEG C of temperature environment again, and natural cooling forms.
Rare earth powder is all had in the formula of three above embodiment, can be synthetically produced negative oxygen ion, while surface is also Coated with photocatalyst catalyst, the effect of photocatalyst catalysis is all had, and honeycomb structure is made by components such as cordierites, Its specific surface area is improved, the adhesion of catalyst is increased.
Particular embodiments described above has carried out further in detail the purpose of the present invention, technical scheme and beneficial effects It describes in detail bright, it should be understood that the above is only a specific embodiment of the present invention, is not intended to restrict the invention, it is all Within the spirit and principles in the present invention, any modification, equivalent substitution, improvement and etc. done should be included in guarantor of the invention Within the scope of shield.

Claims (2)

1. a kind of function honeycomb ceramic, which is characterized in that its porcelain billet surface coats photocatalyst catalyst;Wherein, the porcelain billet The component and each component mass parts that used porcelain contains are as follows:
30 parts~40 parts of kaolin;
Al2O320 parts~30 parts of micro mist;
30 parts~40 parts of cordierite;
0.5 part -12 parts of rare earth powder;
Water: 15 parts~28 parts.
2. a kind of manufacturing method of function honeycomb ceramic as described in claim 1, it is characterised in that contain in the step of method:
S1: it stocks up according to each component and each component mass parts;
S2: each component being mixed and is mediated, then extrusion molding;
S3: and then 8h-15h is fired under 1280 DEG C -1360 DEG C of temperature environment, form porcelain billet;
S4: and then photocatalyst catalyst is coated on porcelain billet surface;
S5: roasting 3h-8h under 500 DEG C -800 DEG C of temperature environment again, and natural cooling forms.
CN201811037077.0A 2018-09-06 2018-09-06 Function honeycomb ceramic and its manufacturing method Pending CN109336549A (en)

Priority Applications (1)

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CN201811037077.0A CN109336549A (en) 2018-09-06 2018-09-06 Function honeycomb ceramic and its manufacturing method

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Application Number Priority Date Filing Date Title
CN201811037077.0A CN109336549A (en) 2018-09-06 2018-09-06 Function honeycomb ceramic and its manufacturing method

Publications (1)

Publication Number Publication Date
CN109336549A true CN109336549A (en) 2019-02-15

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CN201811037077.0A Pending CN109336549A (en) 2018-09-06 2018-09-06 Function honeycomb ceramic and its manufacturing method

Country Status (1)

Country Link
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112125645A (en) * 2020-09-16 2020-12-25 萍乡市恒升特种材料有限公司 Production process of photocatalyst ceramic honeycomb plate

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1657501A (en) * 2005-01-06 2005-08-24 北京交通大学 Micronporous ceramic plate and its preparation method
CN105272351A (en) * 2015-10-26 2016-01-27 青岛铸英特陶科技有限公司 Preparation method of rare earth ceramic foam filter
CN205216421U (en) * 2015-11-12 2016-05-11 山东洁康环保科技有限公司 Filter equipment of healthy wind purifying box
CN108059480A (en) * 2017-12-22 2018-05-22 承德人和矿业有限责任公司 A kind of illite function haydite and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1657501A (en) * 2005-01-06 2005-08-24 北京交通大学 Micronporous ceramic plate and its preparation method
CN105272351A (en) * 2015-10-26 2016-01-27 青岛铸英特陶科技有限公司 Preparation method of rare earth ceramic foam filter
CN205216421U (en) * 2015-11-12 2016-05-11 山东洁康环保科技有限公司 Filter equipment of healthy wind purifying box
CN108059480A (en) * 2017-12-22 2018-05-22 承德人和矿业有限责任公司 A kind of illite function haydite and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112125645A (en) * 2020-09-16 2020-12-25 萍乡市恒升特种材料有限公司 Production process of photocatalyst ceramic honeycomb plate

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Application publication date: 20190215

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