CN109321072A - A kind of aqueous liquid two-component granite and marble paint of baked wheaten cake face type - Google Patents
A kind of aqueous liquid two-component granite and marble paint of baked wheaten cake face type Download PDFInfo
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- CN109321072A CN109321072A CN201811216027.9A CN201811216027A CN109321072A CN 109321072 A CN109321072 A CN 109321072A CN 201811216027 A CN201811216027 A CN 201811216027A CN 109321072 A CN109321072 A CN 109321072A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/10—Homopolymers or copolymers of methacrylic acid esters
- C09D133/12—Homopolymers or copolymers of methyl methacrylate
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of aqueous liquid two-component granite and marble paints of baked wheaten cake face type.It is made of A paint and B paint;A paint includes: water, the dispersing agent of hydrophobic ammonium salt, organosilicon mineral oil antifoam agent, titanium dioxide, glass pick pearl, white carbon black, blanc fixe, hydrophobic hydroxyethyl cellulose, propylene glycol, AMP-95, coalescing agent, modified silicone acrylic emulsion, magnesium silicate potassium, anticorrosion and bactericidal agent, modified Portland;B paint includes: modified Portland, organosilicon mineral oil antifoam agent, propylene glycol, AMP-95, pure-acrylic emulsion, coalescing agent, interleaving agent, anti-settling agent, anticorrosion and bactericidal agent, modified hydroxyl dispersion.Marble lacquer product of the invention is stablized, and function admirable is low in cost, stable storing, anti-floating color strength, and anti-layering is excellent, and construction is simple, water resistance is good, and weatherability is excellent, facilitates the raising of the total quality market of building coating, suits large area to popularize.
Description
Technical field
The invention belongs to technical field of chemical paint, and in particular to a kind of type aqueous liquid two-component granite in baked wheaten cake face is big
Marble paint.
Background technique
Currently, state guarantee environment puts more effort, traditional imitation stone lacquer, lacquer are since the limitation for adopting sand and country are to big
The rectification of gas pollution is fewer and fewer, and aqueous marble lacquer is since it is with anti-stone effect true to nature, excellent environmental-protecting performance,
The use scope in China expands year by year.But since technology is limited, the spread in performance of product is uneven, traditional aqueous liquid Dali
Mineral varnish is since development cost is excessively high and the design scheme of each technician is different and cost control requires that market is caused to compare
It is chaotic.Although existing market market are fine, the opposite difficulty of its application and development mode, the building in the baked wheaten cake face of traditional sense
The common 3 part liquid marble lacquers of coating and market, which burn face and are badly in need of innovation, regenerates.
Summary of the invention
To solve the above-mentioned problems, the invention proposes a kind of aqueous liquid two-component granite and marbles of baked wheaten cake face type
Paint.
A kind of type aqueous liquid two-component granite and marble paint in baked wheaten cake face is made of A paint and B paint;A is painted by following weight
The group of number is grouped as: 10-20 parts of water, 0.3-0.5 parts of the dispersing agent of hydrophobic ammonium salt, organosilicon mineral oil antifoam agent 0.1-0.3
Part, 0-1.5 parts of titanium dioxide, 5-6 parts of glass pick pearl, 0.5-1 parts of white carbon black, 2-3 parts of blanc fixe, hydrophobic ethoxy pricker dimension element
0.7-1 parts, 0.4-0.7 parts of propylene glycol, 0.15-0.25 parts of multifunctional assistant AMP-95,0.3-0.7 parts of coalescing agent, modified silicon
30-40 parts of acrylic emulsion, 0.5-1 parts of magnesium silicate potassium, 0.4-0.5 parts of anticorrosion and bactericidal agent, 0.3-1 parts of modified Portland;B paint by
The group of following parts by weight is grouped as: 10-30 parts of modified Portland, 0.1-0.3 parts of organosilicon mineral oil antifoam agent, propylene glycol
1.5-2.0 parts, 0.2-0.4 parts of multifunctional assistant AMP-95,60-80 parts of pure-acrylic emulsion, 1.5-2.2 parts of coalescing agent, interleaving agent
0.5-1 parts, 0.3-0.7 parts of anti-settling agent, 0.1-0.4 parts of anticorrosion and bactericidal agent, 0.3-0.7 parts of modified hydroxyl dispersion.
The dispersing agent of the hydrophobic ammonium salt is ammonium polyacrylate dipersant.
The coalescing agent is one or both of propandiol butyl ether or propylene glycol methyl ether acetate.
The anticorrosion and bactericidal agent is parachlorophenol, in 2- methylol ethyl alcohol, 2- methyl -2- methylol propyl alcohol
It is one or two kinds of.
The pure-acrylic emulsion is the cream made of acrylic ester copolymer by acrylic acid, methacrylic acid, methyl methacrylate
Liquid.
The interleaving agent be polyoxyethylene sorbitan monooleate, aqueous polyamide wax, calcium stearate mixture.
The anti-settling agent is modified hydrogenated castor oil.
The utility model has the advantages that type aqueous liquid two-component granite and marble paint product in baked wheaten cake face provided by the invention is stablized, property
Can be excellent, low in cost, it is at high cost fundamentally to solve coating technology on the market, the disadvantages such as control of product quality difficulty, aqueous solution
State two-component granite and marble paint not only stable storing, anti-floating color strength, anti-layering is excellent, and construction is simple, water resistance is good, weather-proof
Property is excellent, and preceding low in cost, facilitates the raising of the total quality market of building coating, suits large area to popularize.
Specific embodiment
Following pure-acrylic emulsions are the cream made of acrylic ester copolymer by acrylic acid, methacrylic acid, methyl methacrylate
Liquid;Following interleaving agents be polyoxyethylene sorbitan monooleate, aqueous polyamide wax, calcium stearate according to 1:1:1 ratio
The mixture that example mixes.
Embodiment 1
A kind of type aqueous liquid two-component granite and marble paint in baked wheaten cake face is made of A paint and B paint;A is painted by following weight
The group of number is grouped as: 15 parts of water, 0.4 part of ammonium polyacrylate dipersant, 0.2 part of organosilicon mineral oil antifoam agent, titanium dioxide
0.7 part, 5.6 parts of glass pick pearl, 0.8 part of white carbon black, 2.5 parts of blanc fixe, hydrophobic ethoxy pricker dimension plain 0.8 part, propylene glycol
0.5 part, it is AMP-950.2 parts of multifunctional assistant, 0.5 part of propandiol butyl ether, modified 35 parts of silicone acrylic emulsion, 0.8 part of magnesium silicate potassium, right
0.45 part of chlorophenol, 0.7 part of modified Portland;The B paint is composed of the following parts by weight: 20 parts of modified Portland,
0.2 part of organosilicon mineral oil antifoam agent, 1.8 parts of propylene glycol, 0.3 part of multifunctional assistant AMP-95,70 parts of pure-acrylic emulsion, the third two
1.8 parts of alcohol butyl ether, 0.8 part of interleaving agent, 0.5 part of modified hydrogenated castor oil, 0.3 part of 2- methylol ethyl alcohol, modified hydroxyl point
0.5 part of granular media.
Embodiment 2
A kind of type aqueous liquid two-component granite and marble paint in baked wheaten cake face is made of A paint and B paint;A is painted by following weight
The group of number is grouped as: 10 parts of water, 0.3 part of ammonium polyacrylate dipersant, 0.1 part of organosilicon mineral oil antifoam agent, titanium dioxide
0.1 part, 5 parts of glass pick pearl, 0.5 part of white carbon black, 2 parts of blanc fixe, hydrophobic ethoxy pricker dimension plain 0.7 part, propylene glycol 0.4
Part, 0.3 part of propandiol butyl ether, is modified 30 parts of silicone acrylic emulsion, 0.5 part of magnesium silicate potassium, to chlorine at multifunctional assistant AMP-95 0.15
0.4 part of phenol, 0.3 part of modified Portland;B paint is composed of the following parts by weight: 10 parts of modified Portland, organic
0.1 part of silicon mineral oil defoaming agent, 1.5 parts of propylene glycol, 0.2 part of multifunctional assistant AMP-95,60 parts of pure-acrylic emulsion, propylene glycol fourth
1.5 parts of ether, 0.5 part of interleaving agent, 0.3 part of modified hydrogenated castor oil, 0.1 part of 2- methylol ethyl alcohol, modified hydroxyl dispersion
0.3 part.
Embodiment 3
A kind of type aqueous liquid two-component granite and marble paint in baked wheaten cake face is made of A paint and B paint;A is painted by following weight
The group of number is grouped as: 20 parts of water, 0.5 part of ammonium polyacrylate dipersant, 0.3 part of organosilicon mineral oil antifoam agent, titanium dioxide
1.5 parts, it is 6 parts of glass pick pearl, 1 part of white carbon black, 3 parts of blanc fixe, 1 part of hydrophobic ethoxy pricker dimension element, 0.7 part of propylene glycol, more
0.25 part of function additive AMP-95,0.7 part of propandiol butyl ether, modified 40 parts of silicone acrylic emulsion, 1 part of magnesium silicate potassium, parachlorophenol
0.5 part, 1 part of modified Portland;The B paint is composed of the following parts by weight: 30 parts of modified Portland, organic silicon mineral
0.3 part of oily defoaming agent, 2.0 parts of propylene glycol, 0.4 part of multifunctional assistant AMP-95,80 parts of pure-acrylic emulsion, propandiol butyl ether 2.2
Part, 1 part of interleaving agent, 0.7 part of modified hydrogenated castor oil, 0.4 part of 2- methylol ethyl alcohol, 0.7 part of modified hydroxyl dispersion.
Embodiment 4
A kind of type aqueous liquid two-component granite and marble paint in baked wheaten cake face is made of A paint and B paint;A is painted by following weight
The group of number is grouped as: 15 parts of water, 0.4 part of ammonium polyacrylate dipersant, 0.2 part of organosilicon mineral oil antifoam agent, titanium dioxide
0.7 part, 5.6 parts of glass pick pearl, 0.8 part of white carbon black, 2.5 parts of blanc fixe, hydrophobic ethoxy pricker dimension plain 0.8 part, propylene glycol
0.5 part, it is AMP-950.2 parts of multifunctional assistant, 0.5 part of propandiol butyl ether, modified 35 parts of silicone acrylic emulsion, 0.8 part of magnesium silicate potassium, right
0.45 part of chlorophenol, 0.7 part of modified Portland, 3 parts of stone of Pueraria lobota fluorine lithium;The B paint is composed of the following parts by weight: modified
20 parts of silicate, 0.2 part of organosilicon mineral oil antifoam agent, 1.8 parts of propylene glycol, 0.3 part of multifunctional assistant AMP-95, pure C cream
70 parts of liquid, 1.8 parts of propandiol butyl ether, 0.8 part of interleaving agent, 0.5 part of modified hydrogenated castor oil, 0.3 part of 2- methylol ethyl alcohol,
0.5 part of modified hydroxyl dispersion.
Embodiment 5
A kind of type aqueous liquid two-component granite and marble paint in baked wheaten cake face is made of A paint and B paint;A is painted by following weight
The group of number is grouped as: 15 parts of water, 0.4 part of ammonium polyacrylate dipersant, 0.2 part of organosilicon mineral oil antifoam agent, titanium dioxide
0.7 part, 5.6 parts of glass pick pearl, 0.8 part of white carbon black, 2.5 parts of blanc fixe, hydrophobic ethoxy pricker dimension plain 0.8 part, propylene glycol
0.5 part, it is AMP-950.2 parts of multifunctional assistant, 0.5 part of propandiol butyl ether, modified 35 parts of silicone acrylic emulsion, 0.8 part of magnesium silicate potassium, right
0.45 part of chlorophenol, 0.7 part of modified Portland, 3 parts of stone of chlorine fluorine calcium;The B paint is composed of the following parts by weight: modified
20 parts of silicate, 0.2 part of organosilicon mineral oil antifoam agent, 1.8 parts of propylene glycol, 0.3 part of multifunctional assistant AMP-95, pure C cream
70 parts of liquid, 1.8 parts of propandiol butyl ether, 0.8 part of interleaving agent, 0.5 part of modified hydrogenated castor oil, 0.3 part of 2- methylol ethyl alcohol,
0.5 part of modified hydroxyl dispersion.
Embodiment 6
A kind of type aqueous liquid two-component granite and marble paint in baked wheaten cake face is made of A paint and B paint;A is painted by following weight
The group of number is grouped as: 15 parts of water, 0.4 part of ammonium polyacrylate dipersant, 0.2 part of organosilicon mineral oil antifoam agent, titanium dioxide
0.7 part, 5.6 parts of glass pick pearl, 0.8 part of white carbon black, 2.5 parts of blanc fixe, hydrophobic ethoxy pricker dimension plain 0.8 part, propylene glycol
0.5 part, it is AMP-950.2 parts of multifunctional assistant, 0.5 part of propandiol butyl ether, modified 35 parts of silicone acrylic emulsion, 0.8 part of magnesium silicate potassium, right
0.45 part of chlorophenol, 0.7 part of modified Portland, 3 parts of Tourmaline stone;The B paint is composed of the following parts by weight: modified
20 parts of silicate, 0.2 part of organosilicon mineral oil antifoam agent, 1.8 parts of propylene glycol, 0.3 part of multifunctional assistant AMP-95, pure C cream
70 parts of liquid, 1.8 parts of propandiol butyl ether, 0.8 part of interleaving agent, 0.5 part of modified hydrogenated castor oil, 0.3 part of 2- methylol ethyl alcohol,
0.5 part of modified hydroxyl dispersion.
Experimental example:
Type aqueous liquid two-component granite and marble paint in baked wheaten cake face prepared by embodiment 1-6 is coated on square brick surface,
Thickness 8mm, is dried, and is put into the sodium hydroxide solution of 2mol/L and is impregnated 48 hours and 96 hours, is observed surface corrosion and is fallen off
Situation, experimental result are shown in Table 1:
Table 1
The aqueous liquid two-component granite and marble paint of the present invention burns face: actual experiment data be storage 1 year or more no
Divide water, non-swelling, free from extraneous odour, viscosity stabilization.0 degree of low temperature without exception March to 50 degree of circulations of room temperature, and artificial ageing resistance reaches state
Family's standard, 1500 hours soaked not to fall off, no significant change, without obvious loss of gloss.Water-fast 96 hours alkali resistances without exception 48 hours
It is without exception.Stain resistance 2400 hours without exception.
Claims (7)
1. a kind of aqueous liquid two-component granite and marble paint of baked wheaten cake face type, which is characterized in that be made of A paint and B paint;It is described
A paint is composed of the following parts by weight: 0.3-0.5 parts of dispersing agent, the organosilicon mineral oil of 10-20 parts of water, hydrophobic ammonium salt
0.1-0.3 parts of defoaming agent, 5-6 parts of glass pick pearl, 0.5-1 parts of white carbon black, 2-3 parts of blanc fixe, is dredged 0-1.5 parts of titanium dioxide
0.7-1 parts of water hydroxyethyl cellulose, 0.4-0.7 parts of propylene glycol, 0.15-0.25 parts of multifunctional assistant AMP-95, coalescing agent
0.3-0.7 parts, modified silicone acrylic emulsion 30-40 parts, 0.5-1 parts of magnesium silicate potassium, 0.4-0.5 parts of anticorrosion and bactericidal agent, modified Portland
0.3-1 parts;The B paint is composed of the following parts by weight: 10-30 parts of modified Portland, organosilicon mineral oil antifoam agent
0.1-0.3 parts, 1.5-2.0 parts of propylene glycol, 0.2-0.4 parts of multifunctional assistant AMP-95,60-80 parts of pure-acrylic emulsion, coalescing agent
1.5-2.2 parts, 0.5-1 parts of interleaving agent, 0.3-0.7 parts of anti-settling agent, 0.1-0.4 parts of anticorrosion and bactericidal agent, modified hydroxyl dispersion
0.3-0.7 parts.
2. type aqueous liquid two-component granite and marble paint in a kind of baked wheaten cake face according to claim 1, which is characterized in that
The dispersing agent of the hydrophobic ammonium salt is ammonium polyacrylate dipersant.
3. type aqueous liquid two-component granite and marble paint in a kind of baked wheaten cake face according to claim 1, which is characterized in that
The coalescing agent is one or both of propandiol butyl ether or propylene glycol methyl ether acetate.
4. type aqueous liquid two-component granite and marble paint in a kind of baked wheaten cake face according to claim 1, which is characterized in that
The anticorrosion and bactericidal agent is one of parachlorophenol, 2- methylol ethyl alcohol, 2- methyl -2- methylol propyl alcohol or two
Kind.
5. type aqueous liquid two-component granite and marble paint in a kind of baked wheaten cake face according to claim 1, which is characterized in that
The pure-acrylic emulsion is the lotion made of acrylic ester copolymer by acrylic acid, methacrylic acid, methyl methacrylate.
6. type aqueous liquid two-component granite and marble paint in a kind of baked wheaten cake face according to claim 1, which is characterized in that
The interleaving agent be polyoxyethylene sorbitan monooleate, aqueous polyamide wax, calcium stearate mixture.
7. type aqueous liquid two-component granite and marble paint in a kind of baked wheaten cake face according to claim 1, which is characterized in that
The anti-settling agent is modified hydrogenated castor oil.
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CN201811216027.9A CN109321072A (en) | 2018-10-18 | 2018-10-18 | A kind of aqueous liquid two-component granite and marble paint of baked wheaten cake face type |
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Cited By (1)
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WO2023009418A1 (en) * | 2021-07-30 | 2023-02-02 | Swimc Llc | Concentrated surface treatment product and method of preparing, packaging and applying |
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CN107118645A (en) * | 2017-06-08 | 2017-09-01 | 广东东艺宝建材有限公司 | A kind of waterproof artificial granite speckle multicolor finish and preparation method thereof |
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