CN109320896A - A kind of glass fiber reinforced ABS composite material and preparation method thereof - Google Patents
A kind of glass fiber reinforced ABS composite material and preparation method thereof Download PDFInfo
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- CN109320896A CN109320896A CN201810953527.4A CN201810953527A CN109320896A CN 109320896 A CN109320896 A CN 109320896A CN 201810953527 A CN201810953527 A CN 201810953527A CN 109320896 A CN109320896 A CN 109320896A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/06—Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials
- C08J5/08—Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials glass fibres
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2355/00—Characterised by the use of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08J2323/00 - C08J2353/00
- C08J2355/02—Acrylonitrile-Butadiene-Styrene [ABS] polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/004—Additives being defined by their length
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/14—Glass
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/02—Ingredients treated with inorganic substances
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
- C08K9/06—Ingredients treated with organic substances with silicon-containing compounds
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Abstract
The present invention relates to a kind of glass fiber reinforced ABS composite materials and preparation method thereof, belong to technical field of polymer materials, the glass fiber reinforced ABS composite material, including following component according to the weight ratio: ABS resin 60%~90%, modified glass-fiber 5%~35%, antistatic agent 3.0%~5.0%, antioxidant 0.1%~2.5%, lubricant 0.01%~1.0%.The invention also discloses the preparation methods of above-mentioned glass fiber reinforced ABS composite material.The present invention is compared with the glass fiber reinforced ABS composite material that general processing method obtains, the gradient-structure of organosilicone film layer is obviously improved the transmission effect of adhesion strength between fiber and matrix, stress and energy, to improve the mechanical property of composite material, such method makes the mechanical property of composite material can be improved one times or more；And hydroxyl dimethyl silicone polymer coupling agent Costco Wholesale is low, and economic benefit is more significant.
Description
Technical field
The invention belongs to technical field of polymer materials, it is related to a kind of glass fiber reinforced ABS composite material and its preparation
Method.
Background technique
Fiber-reinforced resin matrix compound material is that high-performance fiber is embedded in resin matrix, such as carbon fiber, glass fibers
Dimension, polyester fiber etc..Resin matrix can be divided into thermoplastic resin and two kinds of thermosetting resin, and common thermoplastic resin has
PE PP PVC ABS PS etc..ABS resin be acrylonitrile, three kinds of butadiene, styrene monomers are aggregated, be kneaded and manufactured one
Kind thermoplastics type's synthetic resin, has impact resistance, high rigidity, oil resistant, low temperature resistant, chemical resistance, mechanical strength and electrical resistance
Can be excellent, easy to process, processing dimension stability and lustrous surface are good, are easy to coating, coloring, can also carry out spraying gold
The secondary operation such as category, plating, welding, bonding, are the extremely extensive thermoplastic engineering plastics of purposes, are widely used in aviation boat
It, the industries such as automobile, building, electronic apparatus, packaging and textile industry.Although the purposes of ABS is extremely wide, its own one
A little deficiencies still limit the possibility, such as its intensity, hardness, dimensional stability and heat distortion temperature etc. of the application of its further expansion
Performance is not high, requires extremely harsh engineering mechanical components to some, ABS is then unable to satisfy.Glass fibre has density small, strong
The advantages that degree is high, thermoplasticity is good, resistant to chemical etching, excellent electrical property, good processing performance；With new material, the development of new technology,
People improved to composite material is made as using galss fiber reinforced resin the technology of resin matrix performance present it is dense
Interest, so high-performance glass fiber reinforced resin based composites become the research hotspot of material technology in recent years.
It is well known that glass fibre belongs to inorganic matter, be difficult to resin matrix it is compatible, so using glass fibre
The critical process for increasing the composite material of resin matrix is to be surface-treated to glass fibre using suitable technique, to increase
The compatibility of glass and resin matrix.There are many method, including coupling agent surface treatment, coupling agent are same for fiberglass surfacing processing
Other auxiliary agent collaboration surface treatments, fiberglass surfacing grafting processing, plasma surface treatment etc., glass surface coupling processing
It is to study more technology at present.At present both at home and abroad various graft modification purposes common coupling agents have phenyl triethoxysilane,
Three tert-butyl peroxide silane of vinyl, butadienyl triethoxysilane etc., there is certain graft modification to glass fibre
Effect, wherein the physical property of the short glass fiber reinforced ABS of phenyl triethoxysilane graft modification also can be by the performance of ABS resin
Promotion is close to or up to one times, but above-mentioned coupling agent Costco Wholesale is high, while also variant in reinforcing effect, to composite material
Best condition has not yet been reached in performance boost.
Summary of the invention
Hydroxyl dimethyl silicone polymer coupling agent graft modification glass fibre is used the purpose of the present invention is to provide a kind of
Reinforced ABS composite material and preparation method.
In order to achieve the above object, the technical scheme is that
A kind of glass fiber reinforced ABS composite material, including following component according to the weight ratio: ABS resin 60%~
90%, modified glass-fiber 5%~35%, antistatic agent 3.0%~5.0%, antioxidant 0.1%~2.5%, lubricant
0.01%~1.0%.
Further, the modified glass-fiber is handled through perhydroxyl radical dimethyl silicone polymer coupling agent graft modification
Glass fibre.
Further, the antistatic agent is alkyl phosphate diethanolamine salt.
Further, the antioxidant is tetrapentaerythritol acid esters.
Further, the lubricant is polyethylene wax.
A kind of preparation method of above-mentioned glass fiber reinforced ABS composite material, includes the following steps:
A, glass fibre graft modification handle: first by glass fibre in 480~500 DEG C of high temperature calcination 15min, remove
Fiberglass surfacing size is removed, then glass fibre infiltration is sufficiently stirred 10 in the hydrochloric acid solution of mass concentration 30~40%
Minute, allow solution can sufficiently sized glass fibres surface, remove the impurity and metal oxide of fiberglass surfacing, make glass fibers
Dimension table face is pure and forms even grade hole on surface, then glass fibre is placed in pure water and is sufficiently stirred after clear Xian 70
It is 30 minutes dry in DEG C baking oven；Then, the acidification dehydrated alcohol of configuration quality concentration 5%, by mass fraction 60:5:20:15's
Glass fibre, hydroxyl dimethyl silicone polymer, distilled water, acidification dehydrated alcohol are configured to lotion by ratio, in 80 DEG C of temperature
Under be sufficiently stirred 1 hour, reaction product filters with ethyl alcohol, washing, obtains the poly- diformazan of hydroxyl after dry under conditions of 105 DEG C
(chemical structural formula is [R (CH to radical siloxane3)2SiOH] n) it is grafted the modified glass-fiber of processing；
B, modified glass-fiber obtained in ABS resin and above-mentioned steps a composite molding: is separately added into exhaust
Two charging hoppers of twin-screw extrusion mechanism, by feeding spiro rod by resin, grafting treated glass fibre and auxiliary agent together
It is sent into barrel, the weight proportion of each component: ABS resin 60%~90%, modified glass-fiber 5%~35%, antistatic agent
3.0%~5.0%, antioxidant 0.1%~2.5%, lubricant 0.01%~1.0%；Since glass is through the poly- diformazan of perhydroxyl radical
The processing of radical siloxane silane coupling agent, glass surface have a large amount of and equally distributed low pole R group, make itself and ABS resin
Compatibility be greatly improved, under the mechanical agitation power of twin-screw, glass fibre and resin mixing are equal in barrel
It is even, the volatile materials in mixing is removed by extruder exhaust section, through die extrusion material strip after further plasticating, then through cold
But, dry, it then can be cut into pellet.
Further, the glass fibre in the step a is alkali-free short glass fiber, 10~15um of fibre diameter, fibre length 1
~5mm.
Further, benzene radicals, ring can be used in the R group of hydroxyl dimethyl silicone polymer coupling agent in the step a
Any one in oxygen groups, amine groups three.
Further, in the step b bringing-up section temperature of vented twin-screw extruder be followed successively by 180 DEG C, 230 DEG C,
240 DEG C, 230 DEG C of head temperature, 220 DEG C of die temperature, screw speed 350r/min.
Compared to the prior art, the beneficial effects of the present invention are:
The present invention is using ABS as resin matrix, using hydroxyl dimethyl silicone polymer as coupling agent, to the short glass fibers of alkali-free
Dimension table face carries out graft modification, and the glass fibre and ABS resin and other chemical assistants after graft modification are squeezed through melt blending
Fiberglass reinforced type composite material is prepared out；Good compatibility is obtained between modified glass and ABS resin matrix, greatly
The interface binding power between glass fibre phase and ABS resin phase is improved, reduces the separation of resin phase with fiber phase, makes fiber
Mutually high-strength mechanical property is effectively married again in composite material, to improve the mechanical property of composite material, tensile strength, bending are strong
Degree is respectively increased 117%, 122%, while the heat resistance of composite material, water imbibition and dimensional stability have obtained good change
Kind, the raising of the strength of materials can allow product to keep the raw material usage for reducing 15%-20% in the case that intensity is constant, simultaneously
Hydroxyl dimethyl silicone polymer coupling agent Costco Wholesale is low, then because glass and grafting processing material cost, process costs compared with
It is low, bring cost savings are reduced in conjunction with material utilization amount, it is contemplated that 10% or more economic effect can be created for the manufacture of ABS components
Benefit；The present invention is compared with the glass fiber reinforced ABS composite material that general processing method obtains, the gradient knot of organosilicone film layer
Structure is obviously improved the transmission effect of adhesion strength between fiber and matrix, stress and energy, to improve composite wood
The mechanical property of material, such method make the mechanical property of composite material can be improved one times or more.
Detailed description of the invention
The following describes the present invention in detail with reference to the accompanying drawings and specific embodiments:
Fig. 1 is the process flow diagram that the present invention prepares glass fiber reinforced ABS composite material.
Specific embodiment
The embodiment of the present invention is given below, the present invention is specifically described by embodiment.It is necessary to it is pointed out here that
, embodiment is that should not be understood as limitation of the scope of the invention, the technology in the field to further instruction of the present invention
Personnel can make some adjustment to the contents of the present invention.
It is understood that the general formula of the chemical structure of silane coupling agent can surface are as follows: RnSiX(4-n), wherein R be can be with resin base
Body generates the organic group of different degrees of affinity or chemical reaction.The present invention uses hydroxyl dimethyl silicone polymer ([R (CH3)
2SiOH] it n) is used as coupling agent, graft modification is carried out to fiberglass surfacing.
In addition, glass fibre can be divided into roving glass fiber, fixed length glass and continuous glass-fiber from length classification, continuous glass-fiber state at present
Interior most widely used, roving glass fiber rose at home in recent years, and yield gradually rises, and fixed length glass is usually the modified factory of foreign capitals and the country
Some Enterprises are with that is, short glass fiber signified on ordinary meaning, the present invention use short glass fiber, 10~15um of fibre diameter, fiber
1~5mm of length；Glass fibre is generally alkali-free glass fiber, alkali-free glass fiber physical property and the following Tables 1 and 2 of Exemplary chemical ingredient
It is shown:
1 alkali-free glass fiber physical property of table
| Tensile strength Mpa | Elasticity modulus Mpa | Elongation % | Relative density |
| 3400 | 71 | 3.35 | 2.52 |
2 alkali-free glass fiber chemical component of table
| Chemical component | SiO2 | Al2O3 | B2O3 | MgO | CaO | Na2O |
| Alkali-free glass fiber | 52.4% | 14.4% | 10.6% | 4.6% | 17.2% | 0.8% |
The main component of alkali-free glass fiber is SiO2, and fiber surface, which absorbs water, produces hydroxyl, and hydroxyl reacts i.e. with the coupling agent
The silane group of chemical bonds can be formed on glass surface, the R group on coupling agent is directed to ABS resin, can be phenyl ring base
Group, epoxy group, any one in amine groups three.Its reaction equation is as follows:
By above-mentioned chemical reaction, coupling agent molecule chain is grafted to glass surface, covers fiberglass surfacing uniformly
One layer of organosilicone film, organosilicone film contain-Si-O- flexible chain, R group are connected in-Si-O- flexible chain the first line of a couplet, in R group
Containing hydroxy functional group, there is polarity, have by the gradient-structure of inorganic opposite organic phase gradually transition, to make glass fibre
Good compatibility is obtained with ABS matrix.
A kind of glass fiber reinforced ABS composite material of the invention, including following component according to the weight ratio: ABS tree
Rouge 60%~90%, modified glass-fiber 5%~35%, antistatic agent 3.0%~5.0%, antioxidant 0.1%~2.5%,
Lubricant 0.01%~1.0%.Wherein, modified glass-fiber is through at perhydroxyl radical dimethyl silicone polymer coupling agent graft modification
The glass fibre of reason；Antistatic agent is alkyl phosphate diethanolamine salt；Antioxidant is tetrapentaerythritol acid esters；The lubrication
Agent is polyethylene wax.
As shown in Figure 1, it illustrates a kind of preparation method of above-mentioned glass fiber reinforced ABS composite material of the invention,
Include the following steps:
A, glass fibre graft modification handle: first by glass fibre in 480~500 DEG C of high temperature calcination 15min, remove
Fiberglass surfacing size is removed, then glass fibre infiltration is sufficiently stirred 10 in the hydrochloric acid solution of mass concentration 30~40%
Minute, allow solution can sufficiently sized glass fibres surface, remove the impurity and metal oxide of fiberglass surfacing, make glass fibers
Dimension table face is pure and forms even grade hole on surface, then glass fibre is placed in pure water and is sufficiently stirred after clear Xian 70
It is 30 minutes dry in DEG C baking oven；Then, the acidification dehydrated alcohol of configuration quality concentration 5%, by mass fraction 60:5:20:15's
Glass fibre, hydroxyl dimethyl silicone polymer, distilled water, acidification dehydrated alcohol are configured to lotion by ratio, in 80 DEG C of temperature
Under be sufficiently stirred 1 hour, reaction product filters with ethyl alcohol, washing, obtains the poly- diformazan of hydroxyl after dry under conditions of 105 DEG C
The modified glass of radical siloxane (chemical structural formula is [R (CH3) 2SiOH] n, and wherein R group uses benzene radicals) grafting processing
Fiber；By XRD analysis, glass grafting rate 0.36% thinks glass grafting rate with 0.3%~0.5% at present in industry
It (wt%) is optimum state.The promotion effect of composite property is analyzed in glass grafting, is carried out at coupling agent grafting
Reason and the composite materials property contrast test for not carrying out grafting processing, the results are shown in Table 3, as can be seen from the table, be added even
Joining agent has apparent effect to the promotion of mechanical property.
Front and back material mechanical performance comparison (glass fiber content wt%:30%) is added in 3 coupling agent of table
| Test item | Not plus coupling agent | Coupling agent is added | Unit |
| Tensile strength | 105 | 124 | MPa |
| Bending strength | 140 | 175 | MPa |
| IZOD notch impact strength (1/8 30 DEG C) | 18 | 22 | J/M |
B, modified glass-fiber obtained in ABS resin and above-mentioned steps a composite molding: is separately added into exhaust
Two charging hoppers of twin-screw extrusion mechanism, by feeding spiro rod by resin, grafting treated glass fibre and auxiliary agent together
It is sent into barrel, the weight proportion of each component: ABS resin 60%~90%, modified glass-fiber 5%~35%, antistatic agent
3.0%~5.0%, antioxidant 0.1%~2.5%, lubricant 0.01%~1.0%；Wherein, vented twin-screw extruder
Bringing-up section temperature be followed successively by 180 DEG C, 230 DEG C, 240 DEG C, 230 DEG C of head temperature, 220 DEG C of die temperature, screw speed 350r/
min；Since glass is handled through perhydroxyl radical dimethyl silicone polymer silane coupling agent, glass surface has a large amount of and equally distributed
Low pole R group makes the compatibility of itself and ABS resin be greatly improved, under the mechanical agitation power of twin-screw, material
Glass fibre and resin are uniformly mixed in cylinder, are removed the volatile materials in mixing by extruder exhaust section, are further plasticated
By die extrusion material strip, then through cooling, drying, pellet then can be cut into.
The present invention compared with the glass fiber reinforced ABS composite material that general processing method obtains, organosilicone film layer
Gradient-structure is obviously improved the transmission effect of adhesion strength between fiber and matrix, stress and energy, to improve
The mechanical property of composite material, such method make the mechanical property of composite material can be improved one times or more, enhancing front and back ABS
The physical property table of comparisons is as follows:
The table 4ABS physical property table of comparisons (glass fiber content wt%:30%)
| ABS | Reinforced ABS | Unit | |
| Glass fiber content | 0 | 30 | % |
| Bending modulus | 2.7 | 11.3 | GPa |
| Bending strength | 79 | 175 | MPa |
| Tensile strength | 48 | 124 | MPa |
| Elongation at break | 20 | 2 | % |
| IZOD notch impact strength (1/8 30 DEG C) | 20 | 22 | J/M |
| Density | 1.05 | 1.28 | g/cm3 |
| Linear expansion coefficient | 76.8 | 21.7 | 10-6/K |
| Water absorption rate | 0.3 | 0.15 | % |
| Heat distortion temperature (unannealed) | 88 | 105 | ℃ |
| Rockwell hardness | 65 | 114 | M |
Claims (9)
1. a kind of glass fiber reinforced ABS composite material, which is characterized in that including following component according to the weight ratio: ABS tree
Rouge 60%~90%, modified glass-fiber 5%~35%, antistatic agent 3.0%~5.0%, antioxidant 0.1%~2.5%,
Lubricant 0.01%~1.0%.
2. glass fiber reinforced ABS composite material according to claim 1, which is characterized in that the modified glass-fiber
It is the glass fibre handled through perhydroxyl radical dimethyl silicone polymer coupling agent graft modification.
3. glass fiber reinforced ABS composite material according to claim 1, which is characterized in that the antistatic agent is alkane
Base phosphate diethanolamine salt.
4. glass fiber reinforced ABS composite material according to claim 1, which is characterized in that the antioxidant is four
Pentaerythrite acid esters.
5. glass fiber reinforced ABS composite material according to claim 1, which is characterized in that the lubricant is poly- second
Alkene wax.
6. a kind of preparation method of above-mentioned glass fiber reinforced ABS composite material, which comprises the steps of:
A, glass fibre graft modification handle: first by glass fibre in 480~500 DEG C of high temperature calcination 15min, remove glass
Glass fiber surface size, then glass fibre infiltration is sufficiently stirred 10 points in the hydrochloric acid solution of mass concentration 30~40%
Clock, allow solution can sufficiently sized glass fibres surface, remove the impurity and metal oxide of fiberglass surfacing, make glass fibre
Surface is pure and forms even grade hole on surface, then glass fibre is placed in pure water clear Xian is sufficiently stirred after at 70 DEG C
It is 30 minutes dry in baking oven；Then, the acidification dehydrated alcohol of configuration quality concentration 5%, by the ratio of mass fraction 60:5:20:15
Example by glass fibre, hydroxyl dimethyl silicone polymer, distilled water, acidification dehydrated alcohol be configured to lotion, 80 DEG C at a temperature of
It is sufficiently stirred 1 hour, reaction product is filtered with ethyl alcohol, washed, and obtains hydroxyl poly dimethyl after dry under conditions of 105 DEG C
(chemical structural formula is [R (CH to siloxanes3)2SiOH] n) it is grafted the modified glass-fiber of processing；
B, modified glass-fiber obtained in ABS resin and above-mentioned steps a composite molding: is separately added into the double spiral shells of exhaust
Resin, grafting treated glass fibre and auxiliary agent are sent by two charging hoppers of bar extrusion mechanism together by feeding spiro rod
In barrel, the weight proportion of each component: ABS resin 60%~90%, modified glass-fiber 5%~35%, antistatic agent 3.0%
~5.0%, antioxidant 0.1%~2.5%, lubricant 0.01%~1.0%；Since glass is through perhydroxyl radical polydimethylsiloxanes
The processing of alkane silane coupling agent, glass surface have a large amount of and equally distributed low pole R group, keep it compatible with ABS resin
Property be greatly improved, glass fibre and resin are uniformly mixed under the mechanical agitation power of twin-screw, in barrel, are passed through
Extruder exhaust section removes the volatile materials in mixing, through die extrusion material strip after further plasticating, then through cooling, drying,
Then pellet can be cut into.
7. the preparation method of glass fiber reinforced ABS composite material according to claim 6, which is characterized in that the step
Glass fibre in rapid a is alkali-free short glass fiber, 10~15um of fibre diameter, 1~5mm of fibre length.
8. the preparation method of glass fiber reinforced ABS composite material according to claim 7, which is characterized in that the step
Benzene radicals, epoxy group can be used, in amine groups three in the R group of hydroxyl dimethyl silicone polymer coupling agent in rapid a
Any one.
9. the preparation method of glass fiber reinforced ABS composite material according to claim 6, which is characterized in that the step
The bringing-up section temperature of vented twin-screw extruder is followed successively by 180 DEG C, 230 DEG C, 240 DEG C, 230 DEG C of head temperature, mouth mold in rapid b
220 DEG C of temperature, screw speed 350r/min.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113308328A (en) * | 2021-01-19 | 2021-08-27 | 北京工商大学 | Method for reducing alcohol content and removing turbidity of white spirit |
| CN114133693A (en) * | 2021-11-17 | 2022-03-04 | 重庆会通科技有限公司 | Antistatic imitation cloth-grain three-dimensional texture material for household appliances and preparation method thereof |
| CN116535701A (en) * | 2023-07-03 | 2023-08-04 | 广东永鑫华新型材料有限公司 | Preparation method of glass fiber reinforced ABS composite material |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105219013A (en) * | 2015-11-18 | 2016-01-06 | 上海瀚氏模具成型有限公司 | Damage resistant ABS plastic and preparation method thereof |
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2018
- 2018-08-21 CN CN201810953527.4A patent/CN109320896A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105219013A (en) * | 2015-11-18 | 2016-01-06 | 上海瀚氏模具成型有限公司 | Damage resistant ABS plastic and preparation method thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113308328A (en) * | 2021-01-19 | 2021-08-27 | 北京工商大学 | Method for reducing alcohol content and removing turbidity of white spirit |
| CN113308328B (en) * | 2021-01-19 | 2022-03-04 | 北京工商大学 | Method for reducing alcohol content and removing turbidity of white spirit |
| CN114133693A (en) * | 2021-11-17 | 2022-03-04 | 重庆会通科技有限公司 | Antistatic imitation cloth-grain three-dimensional texture material for household appliances and preparation method thereof |
| CN116535701A (en) * | 2023-07-03 | 2023-08-04 | 广东永鑫华新型材料有限公司 | Preparation method of glass fiber reinforced ABS composite material |
| CN116535701B (en) * | 2023-07-03 | 2023-09-15 | 广东永鑫华新型材料有限公司 | Preparation method of glass fiber reinforced ABS composite material |
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