CN109309149A - A kind of production method of inverted structure chip - Google Patents

A kind of production method of inverted structure chip Download PDF

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Publication number
CN109309149A
CN109309149A CN201811145973.9A CN201811145973A CN109309149A CN 109309149 A CN109309149 A CN 109309149A CN 201811145973 A CN201811145973 A CN 201811145973A CN 109309149 A CN109309149 A CN 109309149A
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layer
ohmic contact
algan
layers
gan
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张文杰
谢亮
金湘亮
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Jiangsu Core Z-Tek Electronic Science And Technology Co Ltd
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Jiangsu Core Z-Tek Electronic Science And Technology Co Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/005Processes
    • H01L33/0062Processes for devices with an active region comprising only III-V compounds
    • H01L33/0066Processes for devices with an active region comprising only III-V compounds with a substrate not being a III-V compound
    • H01L33/007Processes for devices with an active region comprising only III-V compounds with a substrate not being a III-V compound comprising nitride compounds
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/36Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the electrodes
    • H01L33/40Materials therefor

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Led Devices (AREA)
  • Electrodes Of Semiconductors (AREA)

Abstract

The invention discloses a kind of production methods of inverted structure chip, using tungsten copper alloy (WMoCu) as successively epitaxial growth u-GaN layers of substrate, n-AlGaN layers, multiple quantum well layer and p-GaN layer or p-AlGaN layers;Remove the p-GaN layer or p-AlGaN layers and multiple quantum well layer and part n-AlGaN layers of partial region;N-shaped metal ohmic contact is made on n-AlGaN layer;Remove the N-shaped metal ohmic contact on n-AlGaN layer;P-type ohmic contact layer is made in p-GaN layer or p-AlGaN layer;Metal barrier is made on p-type ohmic contact layer;Make ohmic contact point, growing n-type ohmic contact layer by lithography on n-AlGaN layers;It is made by following process.The present invention replaces traditional Sapphire Substrate tungsten copper alloy, not only reduces production cost and simplifies processing technology;It is obviously improved p-type Ohmic contact and N-shaped ohmic contact characteristic, improves the face p metal ohmic contact adhesiveness, reduces chip voltage, improves chip stability, improves productivity.

Description

A kind of production method of inverted structure chip
Technical field
The invention belongs to chip manufacturing technical fields, and in particular to a kind of production method of inverted structure chip.
Background technique
Traditional positive assembling structure LED (light emitting diode) chip, p-type GaN doping difficulty cause hole low It down and is not easy long thick and electric current is caused to be not easy to spread, currently generally use and prepare super thin metal film or ITO on the surface p-type GaN The method of film obtains electric current uniformly to spread.But metal film electrode layer will absorb part light and reduce light extraction efficiency, if will Its thickness is thinned in turn again limitation current-diffusion layer and realizes uniform reliable current spread on p-type GaN layer surface.ITO is saturating Although light rate up to 90%, for conductivity not as good as metal, the diffusion effect of electric current is also limited.And the electrode of this structure and Lead accomplishes light-emitting surface, and when work can block some light.Therefore, this p-type contact structures constrain the work electricity of LED chip Flow size.On the other hand, the PN junction heat of this structure is exported by Sapphire Substrate, very in view of sapphire thermal coefficient Low, thermally conductive pathways are longer for large-sized power cake core, and the thermal resistance of this LED chip is larger, operating current also by Limitation.
Although ultraviolet market is expected, ultraviolet LED especially wavelength is very high less than the ultraviolet LED technical threshold of 365nm. There is absorption in light of the GaN material for wavelength less than 365nm, so being less than the ultraviolet LED of 365nm, N-shaped for wavelength Semiconductor cannot be GaN material, generally use AlGaN material.It is (general that the Ohmic contact of n-AlGaN needs high temperature that could be formed Annealing temperature is greater than equal to 550 DEG C).For vertical structure/inverted structure chip, the Ohmic contact in the face p generallys use Ag Base, Al base reflective ohmic contact layer, it is more difficult formation and it is unstable.The process meeting of n-AlGaN high annealing formation Ohmic contact The Ohmic contact in the face p is destroyed, is used in usual technique and first makes N-shaped ohmic contact layer, then make p-type ohmic contact layer to avoid The problem of face p Ohmic contact is destroyed.But using first production N-shaped ohmic contact layer, then makes p-type ohmic contact layer and also can Bring new problem: such as p-type Ohmic contact annealing process destroys N-shaped Ohmic contact, and makes p-type Europe using stripping means Nurse contact layer (first makes N-shaped Ohmic contact and makes p-type Ohmic contact again, p-type ohmic contact layer can only use stripping technology system Make) adhesion issues etc. that introduce.
Summary of the invention
The present invention provides a kind of production methods of inverted structure purple chip, solve the above problem, provide a kind of lining Bottom is that tungsten copper alloy reduces cost and is obviously improved p-type Ohmic contact and N-shaped ohmic contact characteristic, improves the face p Ohmic contact Metallic adhesion reduces chip voltage, improves chip stability, the production method for mentioning large-duty inverted structure chip.
In order to solve the above-mentioned technical problem, the technical scheme adopted by the invention is that: a kind of production of inverted structure chip Method, comprising the following steps:
S1, using tungsten copper alloy (WmoCu) as substrate layer, the epitaxial growth AlN buffer layer on tungsten brass bottom, then according to U-GaN layers of secondary growth, n-AlGaN layers, multiple quantum well layer and p-GaN layer or p- AlGaN layer;
S2, the p-GaN layer that partial region is removed by photoetching and dry etching or p-AlGaN layers and multiple quantum well layer and portion Divide n-AlGaN layers, exposes n-AlGaN layer surface;
S3, N-shaped metal ohmic contact, and high annealing are made in n-AlGaN layer surface by the method for removing;
N-shaped metal ohmic contact on S4, erosion removal n-AlGaN layer;
S5, one layer of p-type ohmic contact layer is made in p-GaN layer or p-AlGaN layers of surface, and move back at 400 DEG C~550 DEG C Fiery 80s~220s, which is also mirror layer;
S6, one layer of metal barrier that can coat the p-type ohmic contact layer is made on the surface of p-type ohmic contact layer;
S7, a layer insulating is grown on metal barrier and n-AlGaN layer surface, makes n-AlGaN layers by lithography on the insulating layer Ohmic contact part, and by the insulating layer on the erosion removal Ohmic contact part after, then on the Ohmic contact part Growing n-type ohmic contact layer, and anneal;
S8, p-type electrode zone, and the insulating layer in the erosion removal region are first made by lithography, then thicken and p-electrode and n-electrode is made, Redeposited one layer of insulation material layer, and second electrode distribution is done, growth substrates and u-GaN layers are finally removed, and be roughened n-AlGaN Inverted structure LED chip is made in layer.
Preferably, in the step S3, N-shaped metal ohmic contact is one or more of titanium, aluminium, nickel, gold, alum, zirconium Combination or their alloy.
Preferably, in the step S3, the temperature of high annealing is 550 DEG C~1000 DEG C, and annealing time is 20S~60S, Annealing atmosphere is nitrogen.
Preferably, in the step S4, corrode the solution used as hydrochloric acid, nitric acid, sulfuric acid, hydrofluoric acid, phosphoric acid, ice vinegar The mixed liquor of one or more of acid, chloroazotic acid composition.
Preferably, in the step S5, p-type ohmic contact layer the preparation method comprises the following steps: first mixed using ethyl alcohol, hydrochloric acid, nitric acid It closes liquid to handle p-GaN layer or p-AlGaN layers of surface, then using electron beam evaporation method in p-GaN layer or p- The surface of AlGaN layer deposits one layer of p-type metal ohmic contact, and photoetching corrosion goes out p-type ohmic contact layer, and at 350 DEG C~550 DEG C Lower annealing 60s~300s.
Preferably, in the step S6, metal barrier using one or more of nickel, gold, titanium, platinum, palladium, tungsten or it Alloy be made.
Preferably, in the step S7, N-shaped ohm connect layer using one or more of nickel, gold, titanium, platinum, palladium, tungsten or Their alloy is made.
Preferably, in the step S7, the temperature of the annealing is 25 DEG C~300 DEG C, and annealing time is 20S~180S.
Advantageous effects of the invention: the present invention replaces traditional Sapphire Substrate tungsten copper alloy, not only It reduces production cost and simplifies processing technology;It is obviously improved p-type Ohmic contact and N-shaped ohmic contact characteristic, improves the face p ohm Metallic adhesion is contacted, chip voltage is reduced, improves chip stability, improves productivity.
Specific embodiment
The invention will be further described below.Following embodiment is only used for clearly illustrating technical side of the invention Case, and not intended to limit the protection scope of the present invention.
Embodiment one:
S1, using tungsten copper alloy (WmoCu) as substrate layer, the epitaxial growth AlN buffer layer on tungsten brass bottom, then according to U-GaN layers of secondary growth, n-AlGaN layers, multiple quantum well layer and p- AlGaN layer;
S2, the p- AlGaN layer that partial region is removed by photoetching and dry etching and multiple quantum well layer and part n-AlGaN Layer exposes n-AlGaN layer surface;
S3, N-shaped metal ohmic contact is made in n-AlGaN layer surface by the method for removing, N-shaped metal ohmic contact is titanium Aluminium alloy, and high annealing, the temperature of high annealing are 700 DEG C, annealing time 50S, and annealing atmosphere is nitrogen;
S4, using etchant solution hydrochloric acid, nitric acid mixed liquor removal n-AlGaN layer on N-shaped metal ohmic contact;
S5, the surface of p-GaN layer is handled using ethyl alcohol, hydrochloric acid, nitric acid mixed liquor, then is existed using electron beam evaporation method One layer of p-type ohmic contact layer is made on the surface of p-GaN layer, and the 200s that anneals at 350 DEG C, the p-type ohmic contact layer are also Mirror layer;
S6, one layer of metal barrier that can coat the p-type ohmic contact layer, metal are made on the surface of p-type ohmic contact layer Barrier layer is made of Nitinol;
S7, a layer insulating is grown on metal barrier and n-AlGaN layer surface, makes n-AlGaN layers by lithography on the insulating layer Ohmic contact part, and by the insulating layer on the erosion removal Ohmic contact part after, then on the Ohmic contact part Growing n-type ohmic contact layer, and annealing, N-shaped ohm connect layer using one or more of nickel, gold, titanium, platinum, palladium, tungsten or they Alloy be made, the temperature of annealing is 300 DEG C, annealing time 160s;
S8, p-type electrode zone, and the insulating layer in the erosion removal region are first made by lithography, then thicken and p-electrode and n-electrode is made, Redeposited one layer of insulation material layer, and second electrode distribution is done, growth substrates and u-GaN layers are finally removed, and be roughened n-AlGaN Inverted structure chip is made in layer.
Embodiment two:
S1, using tungsten copper alloy as substrate layer, epitaxial growth AlN buffer layer, then successively grows on tungsten brass bottom U-GaN layers, n-AlGaN layers, multiple quantum well layer and p-GaN layer;
S2, the p-GaN layer that partial region is removed by photoetching and dry etching and multiple quantum well layer and part n-AlGaN layers, Expose n-AlGaN layer surface;
S3, N-shaped metal ohmic contact is made in n-AlGaN layer surface by the method for removing, N-shaped metal ohmic contact is titanium Aluminium alloy, and high annealing, the temperature of high annealing are 650 DEG C, annealing time 45S, and annealing atmosphere is nitrogen;
S4, the N-shaped metal ohmic contact on n-AlGaN layer is removed using etchant solution sulfuric acid;
S5, the surface of p-GaN layer is handled using ethyl alcohol, hydrochloric acid, nitric acid mixed liquor, then is existed using electron beam evaporation method One layer of p-type ohmic contact layer is made on the surface of p-GaN layer, and the 100s that anneals at 500 DEG C, the p-type ohmic contact layer are also Mirror layer;
S6, one layer of metal barrier that can coat the p-type ohmic contact layer, metal are made on the surface of p-type ohmic contact layer Barrier layer is made of tungsten;
S7, a layer insulating is grown on metal barrier and n-AlGaN layer surface, makes n-AlGaN layers by lithography on the insulating layer Ohmic contact part, and by the insulating layer on the erosion removal Ohmic contact part after, then on the Ohmic contact part Growing n-type ohmic contact layer, and annealing, N-shaped ohm connect layer using one or more of nickel, gold, titanium, platinum, palladium, tungsten or they Alloy be made, the temperature of annealing is 260 DEG C, annealing time 120S;
S8, p-type electrode zone, and the insulating layer in the erosion removal region are first made by lithography, then thicken and p-electrode and n-electrode is made, Redeposited one layer of insulation material layer, and second electrode distribution is done, growth substrates and u-GaN layers are finally removed, and be roughened n-AlGaN Inverted structure chip is made in layer.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art For member, without departing from the technical principles of the invention, several improvement and deformations can also be made, these improvement and deformations Also it should be regarded as protection scope of the present invention.

Claims (8)

1. a kind of production method of inverted structure chip, which comprises the following steps:
S1, using tungsten copper alloy as substrate layer, epitaxial growth AlN buffer layer, then successively grows on tungsten brass bottom U-GaN layers, n-AlGaN layers, multiple quantum well layer and p-GaN layer or p- AlGaN layer;
S2, the p-GaN layer that partial region is removed by photoetching and dry etching or p-AlGaN layers and multiple quantum well layer and portion Divide n-AlGaN layers, exposes n-AlGaN layer surface;
S3, N-shaped metal ohmic contact, and high annealing are made in n-AlGaN layer surface by the method for removing;
N-shaped metal ohmic contact on S4, erosion removal n-AlGaN layer;
S5, one layer of p-type ohmic contact layer is made in p-GaN layer or p-AlGaN layers of surface, and move back at 400 DEG C~550 DEG C Fiery 80s~220s, which is also mirror layer;
S6, one layer of metal barrier that can coat the p-type ohmic contact layer is made on the surface of p-type ohmic contact layer;
S7, a layer insulating is grown on metal barrier and n-AlGaN layer surface, makes n-AlGaN layers by lithography on the insulating layer Ohmic contact part, and by the insulating layer on the erosion removal Ohmic contact part after, then on the Ohmic contact part Growing n-type ohmic contact layer, and anneal;
S8, p-type electrode zone, and the insulating layer in the erosion removal region are first made by lithography, then thicken and p-electrode and n-electrode is made, Redeposited one layer of insulation material layer, and second electrode distribution is done, growth substrates and u-GaN layers are finally removed, and be roughened n-AlGaN Inverted structure UV LED chip is made in layer.
2. a kind of production method of inverted structure chip according to claim 1, which is characterized in that in the step S3, n Type metal ohmic contact is the combination of one or more of titanium, aluminium, nickel, gold, alum, zirconium or their alloy.
3. a kind of production method of inverted structure chip according to claim 1, which is characterized in that in the step S3, The temperature of high annealing is 550 DEG C~1000 DEG C, and annealing time is 20S~60S, and annealing atmosphere is nitrogen.
4. a kind of production method of inverted structure chip according to claim 1, which is characterized in that in the step S4, Corrode the solution used to mix for what one or more of hydrochloric acid, nitric acid, sulfuric acid, hydrofluoric acid, phosphoric acid, glacial acetic acid, chloroazotic acid formed Close liquid.
5. a kind of production method of inverted structure chip according to claim 1, which is characterized in that in the step S5, p Type ohmic contact layer the preparation method comprises the following steps: first using, ethyl alcohol, hydrochloric acid, nitric acid mixed liquor are to p-GaN layer or p-AlGaN layers of table Face is handled, and is then deposited one layer of p-type ohm in p-GaN layer or p-AlGaN layers of surface using electron beam evaporation method and is connect Metal is touched, photoetching corrosion goes out p-type ohmic contact layer, and the 60s~300s that anneals at 350 DEG C~550 DEG C.
6. a kind of production method of inverted structure chip according to claim 1, which is characterized in that in the step S6, Metal barrier is made of one or more of nickel, gold, titanium, platinum, palladium, tungsten or their alloy.
7. a kind of production method of inverted structure chip according to claim 1, which is characterized in that in the step S7, n Type ohm is connect layer and is made of one or more of nickel, gold, titanium, platinum, palladium, tungsten or their alloy.
8. a kind of production method of inverted structure chip according to claim 1, which is characterized in that in the step S7, The temperature of the annealing is 25 DEG C~300 DEG C, and annealing time is 20S~180S.
CN201811145973.9A 2018-09-29 2018-09-29 A kind of production method of inverted structure chip Pending CN109309149A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112071966A (en) * 2020-08-12 2020-12-11 深圳市光脉电子有限公司 Ultraviolet LED epitaxial structure, light source device and preparation method of ultraviolet LED epitaxial structure

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103441212A (en) * 2013-09-16 2013-12-11 江西量一光电科技有限公司 LED (Light Emitting Diode) chip manufacturing technology, LED chip structure and LED chip packaging structure
CN108011002A (en) * 2017-11-30 2018-05-08 广东省半导体产业技术研究院 A kind of UV LED chip production method

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103441212A (en) * 2013-09-16 2013-12-11 江西量一光电科技有限公司 LED (Light Emitting Diode) chip manufacturing technology, LED chip structure and LED chip packaging structure
CN108011002A (en) * 2017-11-30 2018-05-08 广东省半导体产业技术研究院 A kind of UV LED chip production method

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112071966A (en) * 2020-08-12 2020-12-11 深圳市光脉电子有限公司 Ultraviolet LED epitaxial structure, light source device and preparation method of ultraviolet LED epitaxial structure

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