CN109306587A - A kind of carbon fiber surface solvent cleaning removing means - Google Patents

A kind of carbon fiber surface solvent cleaning removing means Download PDF

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Publication number
CN109306587A
CN109306587A CN201811289386.7A CN201811289386A CN109306587A CN 109306587 A CN109306587 A CN 109306587A CN 201811289386 A CN201811289386 A CN 201811289386A CN 109306587 A CN109306587 A CN 109306587A
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CN
China
Prior art keywords
rinse bath
fiber
outlet pipe
removing means
carbon fiber
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Application number
CN201811289386.7A
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Chinese (zh)
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CN109306587B (en
Inventor
王永伟
曹伟伟
朱波
于宽
赵圣尧
高学平
张敏
乔琨
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Shandong University
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Shandong University
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Publication of CN109306587A publication Critical patent/CN109306587A/en
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B13/00Treatment of textile materials with liquids, gases or vapours with aid of vibration
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B23/00Component parts, details, or accessories of apparatus or machines, specially adapted for the treating of textile materials, not restricted to a particular kind of apparatus, provided for in groups D06B1/00 - D06B21/00
    • D06B23/02Rollers
    • D06B23/023Guiding rollers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B23/00Component parts, details, or accessories of apparatus or machines, specially adapted for the treating of textile materials, not restricted to a particular kind of apparatus, provided for in groups D06B1/00 - D06B21/00
    • D06B23/04Carriers or supports for textile materials to be treated
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B23/00Component parts, details, or accessories of apparatus or machines, specially adapted for the treating of textile materials, not restricted to a particular kind of apparatus, provided for in groups D06B1/00 - D06B21/00
    • D06B23/14Containers, e.g. vats
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B23/00Component parts, details, or accessories of apparatus or machines, specially adapted for the treating of textile materials, not restricted to a particular kind of apparatus, provided for in groups D06B1/00 - D06B21/00
    • D06B23/20Arrangements of apparatus for treating processing-liquids, -gases or -vapours, e.g. purification, filtration or distillation
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B23/00Component parts, details, or accessories of apparatus or machines, specially adapted for the treating of textile materials, not restricted to a particular kind of apparatus, provided for in groups D06B1/00 - D06B21/00
    • D06B23/20Arrangements of apparatus for treating processing-liquids, -gases or -vapours, e.g. purification, filtration or distillation
    • D06B23/22Arrangements of apparatus for treating processing-liquids, -gases or -vapours, e.g. purification, filtration or distillation for heating

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Treatment Of Fiber Materials (AREA)
  • Cleaning By Liquid Or Steam (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

The present invention relates to a kind of carbon fiber surface solvents to clean removing means, belongs to PAN fiber process units technical field.The cleaning removing means includes water tank, rinse bath, circulator, supersonic generator, ultrasonic probe, fiber godet, water inlet pipe and outlet pipe;The water tank is connected to rinse bath, and after the water tank, driving device, water inlet pipe, rinse bath and outlet pipe are sequentially communicated, outlet pipe is connected to water storage tank again;The supersonic generator is connect with the ultrasonic probe being arranged in rinse bath, and the fiber godet is arranged in rinse bath, and the fiber godet is made of main shaft roll body and fiber guide axis, and multiple fiber guide axis are around setting in principal axis roller body surface face.Fiber storage dimension of the present invention is parallel by multiple ultrasonic probes in transmission process, realizes the multiple ultrasonication to the PAN fiber of continuous operation;And whole device of the invention carries out in full-closed environment, ensure that cleaning effect and cleaning ambient.

Description

A kind of carbon fiber surface solvent cleaning removing means
Technical field
The invention belongs to PAN fiber process units technical field more particularly to a kind of cleaning PAN carbon fiber surface solvents Device.
Background technique
Polyacrylonitrile (PAN) carbon fiber has a series of excellent characteristics such as high specific strength and specific modulus, is widely used in navigating In empty space flight and civilian industry.Preparation for high-performance carbon fibre, it is desirable that using the precursor of high quality.Carbon fiber is as strategy Product is always paid attention to by countries in the world, and each state is all in the research and development for being dedicated to PAN precursor, but domestic Industry of Carbon Fiber The developed countries such as Japan far are lagged behind, greatly develop that carbon fiber is extremely urgent, the key for producing carbon fiber is strand quality.? In the preparation process of PAN precursor, the factor for influencing precursor product quality is more, wherein the PAN fiber after preliminary draft is also A certain amount of residual DMSO solvent, they have plastication to PAN fiber, fibre single thread can be made to melt in process And.The presence of residual solvent can also make the fiber in later period preoxidation process form certain fault of construction, seriously reduce carbon fiber The intensity of dimension removes solvent generally using the method for washing, washes work therefore, it is necessary to which the solvent of residual in the fibre is removed Water used in sequence must be deionized water, just can guarantee do not introduce other impurities in fiber after washing in this way.
The factor of influence water washing effect is in addition to washing temperature, water consumption and other than the residence time, deionization in water-washing process Water is also most important to the effect degree and effect on PAN fiber surface, traditional static immersing method or recirculated water impact spray Leaching method is undesirable to the removing effect of PAN fiber residual solvent, it is therefore desirable to which a kind of physical mode of action effectively goes to reach Except the purpose of fiber surface solvent.207091708 U of patent CN discloses a kind of PAN base carbon fibre ultrasonic water cleaning device, Include ultrasonic transducer, gas gathering mask, frequency-adjustable ultrasonic rinsing bowl, spray rinsing system, filter screen;Frequency-adjustable ultrasonic water Heating device is installed in washing trough, connect control temperature with heating device by power supply;It washes trench bottom and welds three groups of ultrasonic waves Energy device, the electric energy that power supply is provided are changed into ultra sonic machinery vibration, generate high-frequency vibration and are cleaned;Filter screen is mounted on water Washing trough front and rear, spray rinsing device are welded on the cabinet of rear portion by square steel, are conveyed by pump.But this ultrasound The problems such as wave water washing device is undesirable there are the removing effect of residual solvent, therefore, it is necessary to study new cleaning PAN carbon fibers The device of surface solvent, to solve the above problems.
Summary of the invention
For above-mentioned problems of the prior art, the present invention is intended to provide a kind of cleaning removing of carbon fiber surface solvent Device.Water storage tank of the present invention is connect by two groups of disengaging water routes with external water tank, external water tank in water storage tank go from Sub- water is circulated under the action of driving water pump.It is parallel by multiple ultrasonic probes during fiber transmission, it realizes Multiple ultrasonication to the PAN fiber of continuous operation;And whole device of the invention carries out in full-closed environment, protects Demonstrate,prove cleaning effect and cleaning ambient.
An object of the present invention is to provide a kind of carbon fiber surface solvent cleaning removing means.
The second object of the present invention is to provide the application of above-mentioned carbon fiber surface solvent cleaning removing means.
For achieving the above object, specifically, the invention discloses following technical proposals:
Firstly, the invention discloses a kind of carbon fiber surface solvents to clean removing means, including water tank, rinse bath, follow Loop device, supersonic generator, fiber godet, ultrasonic probe, water inlet pipe and outlet pipe.
The water tank is connected to rinse bath, and the water tank, driving device, water inlet pipe, rinse bath and outlet pipe are successively After connection, outlet pipe is connected to water storage tank again, and the water inlet pipe includes the first water inlet pipe and the second water inlet pipe, first water inlet The side wall upper part of rinse bath is arranged in pipe, and the lower sidewall of rinse bath is arranged in second water inlet pipe, correspondingly, the side wall The top of opposite side is provided with the first outlet pipe, the second outlet pipe, and first outlet pipe, the second outlet pipe connect with water tank Logical, to realize circulating for cleaning solution, cleaning solution passes through the first water inlet pipe, the second water inlet pipe under the action of driving device Into in rinse bath, then returns in water tank and be recycled by the first outlet pipe, the second outlet pipe again.
Further, the driving device is water circulating pump;Preferably, the water tank and the first outlet pipe, second go out Flow velocity detection device is provided between water pipe, for the cleaning solution circulation rate real time monitoring to whole system.
The supersonic generator is connect with the ultrasonic probe being arranged in rinse bath, and the fiber godet is arranged clear In washing trough, and the fiber godet is made of main shaft roll body and fiber guide axis, and multiple fiber guide axis are around setting in master Beaming roller body surface face;Fiber godet i.e. of the invention is cage structure, and fiber can in this way passed on the surface of multiple guide axis It leads, realizes the abundant ultrasonic cleaning processing effect of the fascicular texture of PAN fiber.
The fiber godet is two groups, and every group is made of two fiber godets, and every group of godet passes through central principal axis It is fixed in rinse bath, the ultrasonic probe is arranged between two groups of fiber godets using multiple arranged in parallel modes;In this way It can be regulated and controled by power regulation and supersonic frequency, realize the multiple ultrasonication to the PAN fiber of continuous operation, guarantee residual The cleaning effect of solvent.
The wall of the rinse bath uses sandwich design, and the interlayer is embedded with multiple groups heating device, meanwhile, it is cleaning It is respectively provided with temperature measuring equipment in the interlayer of slot and in the cleaning solution of rinse bath, to monitor entire rinse bath and wherein cleaning solution in real time Temperature, to guarantee cleaning effect because cleaning temperature has important influence to cleaning effect,
The ultrasonic frequency that the ultrasonic probe issues is optional in 16.5-40KHz range.
The ultrasonic power of the ultrasonic probe is optional within the scope of 1000-4000W;The voltage of the ultrasonic generator is 220V。
Secondly, the invention discloses above-mentioned carbon fiber surface solvents to clean removing means answering in fiber preparation field With.
Compared with prior art, the beneficial effect that the present invention obtains is:
(1) fiber godet of the invention designs for cage structure, can make fiber on the surface of multiple guide axis in this way The abundant ultrasonic cleaning processing effect of the fascicular texture of PAN fiber is realized in conduction.
(2) rinse bath of the invention ensure that entire cleaning process by cooperating with temperature control system, water circulation system The stable circulation and temperature of middle cleaning solution are stablized, and ensure that entire cleaning effect and environmental stability.
(3) present invention is used parallel by multiple groups ultrasonic probe, is regulated and controled by power regulation and supersonic frequency, is realized pair The multiple ultrasonication of the PAN fiber of continuous operation, guarantees the cleaning effect of residual solvent
Detailed description of the invention
The accompanying drawings constituting a part of this application is used to provide further understanding of the present application, and the application's shows Meaning property embodiment and its explanation are not constituted an undue limitation on the present application for explaining the application.
Fig. 1 is the structural schematic diagram that carbon fiber surface solvent of the present invention cleans removing means.
Fig. 2 is the structural schematic diagram of fiber godet of the present invention.
Attached drawing acceptance of the bid note respectively represents: 1- water tank, 2- rinse bath, 3- circulator, 4- supersonic generator, 5- fiber Godet, 6- ultrasonic probe, the first water inlet pipe of 7-, the second water inlet pipe of 8-, the first outlet pipe of 9-, the second outlet pipe of 10-, 11- add Thermal, 12- temperature measuring equipment, 13- flow velocity detection device, 14- main shaft roll body, 15- fiber guide axis, 16- central principal axis, 17- carbon fiber.
Specific embodiment
It is noted that following detailed description is all illustrative, it is intended to provide further instruction to the application.Unless another It indicates, all technical and scientific terms used herein has usual with the application person of an ordinary skill in the technical field The identical meanings of understanding.
It should be noted that term used herein above is merely to describe specific embodiment, and be not intended to restricted root According to the illustrative embodiments of the application.As used herein, unless the context clearly indicates otherwise, otherwise singular Also it is intended to include plural form, additionally, it should be understood that, when in the present specification using term "comprising" and/or " packet Include " when, indicate existing characteristics, step, operation, device, component and/or their combination.
As background technique is introduced, the cleaning device of existing polyacrylonitrile carbon fiber surface solvent still has residual The problems such as staying the removing effect of solvent undesirable.Therefore, the invention proposes a kind of carbon fiber surface solvents to clean removing means, With reference to the accompanying drawing and specific embodiment the present invention is described further.
Embodiment 1
As shown in Figure 1, a kind of carbon fiber surface solvent cleans removing means, including water tank 1, rinse bath 2, circulator 3, supersonic generator 4, fiber godet 5, ultrasonic probe, 6 water inlet pipes and outlet pipe.
The water tank 1 is connected to rinse bath 2, the water tank 1, driving device 3, water inlet pipe, rinse bath 2 and outlet pipe After being sequentially communicated, outlet pipe is connected to water storage tank again, and the water inlet pipe includes the first water inlet pipe 7 and the second water inlet pipe 8, and described the The side wall upper part of rinse bath 2 is arranged in one water inlet pipe 7, and the lower sidewall of rinse bath 2 is arranged in second water inlet pipe 8, accordingly Ground, the top of the side wall opposite side are provided with the first outlet pipe 9, the second outlet pipe 10, and first outlet pipe 9, second is discharged Pipe 10 is connected to water tank 1, to realize circulating for cleaning solution, cleaning solution is under the action of driving device 3 by the One water inlet pipe, the second water inlet pipe enter in rinse bath 2, then return to water tank by the first outlet pipe 9, the second outlet pipe 10 again It is recycled in 1.
The supersonic generator 4 is connect with the ultrasonic probe 6 being arranged in rinse bath 2, and the fiber godet 5 is arranged In rinse bath 2, the fiber godet 5 is two groups, and every group is made of two fiber godets 5, during every group of godet passes through Heart main shaft 16 is fixed in rinse bath 2, and two groups of fiber godets are arranged in using multiple arranged in parallel modes in the ultrasonic probe 6 Between 5;It can be regulated and controled in this way by power regulation and supersonic frequency, realize and the multiple ultrasound of the PAN fiber of continuous operation is made With guaranteeing the cleaning effect of residual solvent.
The wall of the rinse bath 2 uses sandwich design, and the interlayer is embedded with multiple groups heating device 11, meanwhile, Be respectively provided with temperature measuring equipment 12 in the interlayer of rinse bath 2 and in the cleaning solution of rinse bath 2, with monitor in real time entire rinse bath and its The temperature of middle cleaning solution, to guarantee cleaning effect, because cleaning temperature has important influence to cleaning effect.
Embodiment 2
A kind of carbon fiber surface solvent cleans removing means, and with embodiment 1, difference is: the fiber godet 5 is by leading Beaming roller body 14 and fiber guide axis 15 are constituted, and multiple fiber guide axis 15 are around setting on 14 surface of main shaft roll body (such as Fig. 2 institute Show);I.e. fiber godet is cage structure, and fiber 17 can in this way conducted on the surface of multiple guide axis, realizes PAN fiber Fascicular texture abundant ultrasonic cleaning processing effect.
Embodiment 3
A kind of carbon fiber surface solvent cleaning removing means, with embodiment 1, the driving device 3 is water circulating pump;It is described It is provided with flow velocity detection device 13 between water tank 1 and the first outlet pipe 9, the second outlet pipe 10, for whole system Cleaning solution circulation rate real time monitoring, the ultrasonic frequency that the ultrasonic probe issues is between 16.5-40KHz.It is described super The ultrasonic power of sonic probe is between 1000-4000W;The voltage of the ultrasonic generator is 220V.
The foregoing is merely preferred embodiment of the present application, are not intended to limit this application, for those skilled in the art For member, various changes and changes are possible in this application.Within the spirit and principles of this application, it is made it is any modification, Equivalent replacement, improvement etc., should be included within the scope of protection of this application.

Claims (10)

1. a kind of carbon fiber surface solvent cleans removing means, it is characterised in that: including water tank, rinse bath, circulator, surpass Sonic generator, ultrasonic probe, fiber godet, water inlet pipe and outlet pipe;
The water tank is connected to rinse bath, and the water tank, driving device, water inlet pipe, rinse bath and outlet pipe are sequentially communicated Afterwards, outlet pipe is connected to water storage tank again;
The supersonic generator is connect with the ultrasonic probe being arranged in rinse bath, and the fiber godet is arranged in rinse bath In, and the fiber godet is made of main shaft roll body and fiber guide axis, multiple fiber guide axis are around setting in principal axis roller Body surface face.
2. carbon fiber surface solvent as described in claim 1 cleans removing means, it is characterised in that: the water inlet pipe includes the The side wall upper part of rinse bath, the second water inlet pipe setting is arranged in one water inlet pipe and the second water inlet pipe, first water inlet pipe In the lower sidewall of rinse bath, correspondingly, the top of the side wall opposite side is provided with the first outlet pipe, the second outlet pipe, described First outlet pipe, the second outlet pipe are connected to water tank.
3. carbon fiber surface solvent as described in claim 1 cleans removing means, it is characterised in that: the fiber godet is Two groups, every group is made of two fiber godets, and every group of godet is fixed in rinse bath by central principal axis.
4. carbon fiber surface solvent as claimed in claim 3 cleans removing means, it is characterised in that: the ultrasonic probe uses Multiple arranged in parallel modes are arranged between two groups of fiber godets.
5. carbon fiber surface solvent as described in claim 1 cleans removing means, it is characterised in that: the wall of the rinse bath Using sandwich design, the interlayer is embedded with multiple groups heating device.
6. carbon fiber surface solvent as described in claim 1 cleans removing means, it is characterised in that: the interlayer of the rinse bath Temperature measuring equipment is respectively provided in interior and rinse bath cleaning solution.
7. carbon fiber surface solvent as claimed in any one of claims 1 to 6 cleans removing means, it is characterised in that: the ultrasound The ultrasonic frequency issued pop one's head between 16.5-40KHz.
8. carbon fiber surface solvent as claimed in any one of claims 1 to 6 cleans removing means, it is characterised in that: the ultrasound The ultrasonic power of probe is between 1000-4000W.
9. carbon fiber surface solvent as claimed in any one of claims 1 to 6 cleans removing means, it is characterised in that: the water storage Flow velocity detection device is provided between tank and the first outlet pipe, the second outlet pipe;Preferably, the driving device is circulation Water pump.
10. if the described in any item carbon fiber surface solvent cleaning removing means of claim 1-9 are in fiber preparation field Using.
CN201811289386.7A 2018-10-31 2018-10-31 Carbon fiber surface solvent washs desorption device Active CN109306587B (en)

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CN201811289386.7A CN109306587B (en) 2018-10-31 2018-10-31 Carbon fiber surface solvent washs desorption device

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Application Number Priority Date Filing Date Title
CN201811289386.7A CN109306587B (en) 2018-10-31 2018-10-31 Carbon fiber surface solvent washs desorption device

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CN109306587A true CN109306587A (en) 2019-02-05
CN109306587B CN109306587B (en) 2024-01-12

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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06173155A (en) * 1992-09-14 1994-06-21 Nippon Steel Corp Method for washing carbon yarn and device therefor
CN2649617Y (en) * 2003-11-08 2004-10-20 江阴市科达机械电子有限公司 Double-side supersonic wave device
CN2785728Y (en) * 2005-04-21 2006-06-07 山东大学 Ultrasonic cleaning machine
CN105040130A (en) * 2015-09-11 2015-11-11 西安康本材料有限公司 Polyacrylonitrile-based carbon fiber protofilament multilayer washing apparatus
CN205295562U (en) * 2015-12-24 2016-06-08 中国石油天然气股份有限公司 Carbon fiber precursor washing device
CN106319689A (en) * 2016-10-26 2017-01-11 张家港市港鹰实业有限公司 Carbon fiber precursor washing device and washing method
CN207091708U (en) * 2017-08-03 2018-03-13 浙江精功碳纤维有限公司 A kind of PAN base carbon fibres ultrasonic wave water washing device
CN209144439U (en) * 2018-10-31 2019-07-23 山东大学 A kind of carbon fiber surface solvent cleaning removing means

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06173155A (en) * 1992-09-14 1994-06-21 Nippon Steel Corp Method for washing carbon yarn and device therefor
CN2649617Y (en) * 2003-11-08 2004-10-20 江阴市科达机械电子有限公司 Double-side supersonic wave device
CN2785728Y (en) * 2005-04-21 2006-06-07 山东大学 Ultrasonic cleaning machine
CN105040130A (en) * 2015-09-11 2015-11-11 西安康本材料有限公司 Polyacrylonitrile-based carbon fiber protofilament multilayer washing apparatus
CN205295562U (en) * 2015-12-24 2016-06-08 中国石油天然气股份有限公司 Carbon fiber precursor washing device
CN106319689A (en) * 2016-10-26 2017-01-11 张家港市港鹰实业有限公司 Carbon fiber precursor washing device and washing method
CN207091708U (en) * 2017-08-03 2018-03-13 浙江精功碳纤维有限公司 A kind of PAN base carbon fibres ultrasonic wave water washing device
CN209144439U (en) * 2018-10-31 2019-07-23 山东大学 A kind of carbon fiber surface solvent cleaning removing means

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