CN109295462A - A kind of metal cleaning preparation method of efficient cleaner - Google Patents
A kind of metal cleaning preparation method of efficient cleaner Download PDFInfo
- Publication number
- CN109295462A CN109295462A CN201811044080.5A CN201811044080A CN109295462A CN 109295462 A CN109295462 A CN 109295462A CN 201811044080 A CN201811044080 A CN 201811044080A CN 109295462 A CN109295462 A CN 109295462A
- Authority
- CN
- China
- Prior art keywords
- parts
- cleaning
- stirring
- efficient cleaner
- metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/38—Polysiloxanes modified by chemical after-treatment
- C08G77/382—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon
- C08G77/388—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/38—Polysiloxanes modified by chemical after-treatment
- C08G77/382—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon
- C08G77/398—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon containing boron or metal atoms
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/40—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing molybdates, tungstates or vanadates
Abstract
The invention discloses a kind of preparation methods of metal cleaning efficient cleaner, the following steps are included: S1, by 2,3- epoxypropyltrimethylchloride chloride is mixed with allyl alcohol, stirring, containing hydrogen silicone oil, polymerization inhibitor, toluene and platinum catalyst, stirring, through being evaporated under reduced pressure is added after removing allyl alcohol, vacuum drying, obtains material A；S2, material A is mixed with deionized water, boric acid, lemon, stirs, obtains material B；S3, deionized water is mixed with molybdate, sodium citrate, is stirred, ethoxylated dodecyl alcohol, sodium metasilicate, hexamethylenetetramine, polyacrylic acid and solubilizer is then added, stirring adds material B, stirs, obtains metal cleaning efficient cleaner.A kind of metal cleaning proposed by the present invention preparation method of efficient cleaner, resulting product can rapidly, thoroughly remove the dirt and impurity of metal surface, while have many advantages, such as low bubble, easily rinsing.
Description
Technical field
The present invention relates to the preparation methods that cleaning agent technical field more particularly to a kind of cleaning of metal use efficient cleaner.
Background technique
With the fast development of China's industrial economy, intermetallic composite coating, food, doctor is gradually expanded in the field of industry cleaning link
The industrial circles such as treatment, weaving, automobile manufacture, ship, instrument and meter.Wherein, metal cleaning is raw to automobile metal parts machining
Produce it is most important, due to automobile metal components during transport, processing and manufacturing and maintenance etc. usually in metal surface
Various residues are left, therefore, automobile metal components have to be cleaned before carrying out next step use, and cleaning quality
Height directly affect automobile metal components and the service life using its automobile being assembled.Currently, China is cleaned
Agent cannot rapidly, thoroughly remove the dirt and impurity of metal surface when cleaning metal, while that there are foams when cleaning is more
And it is difficult to the problem of removing, these have all seriously affected the performance of metal product.
Summary of the invention
Technical problems based on background technology, the invention proposes a kind of preparations of metal cleaning efficient cleaner
Method, resulting product can rapidly, thoroughly remove the dirt and impurity of metal surface, while have many advantages, such as low bubble, easily rinsing.
A kind of metal cleaning proposed by the present invention preparation method of efficient cleaner, comprising the following steps:
S1,2,3- epoxypropyltrimethylchloride chloride is mixed with allyl alcohol, is stirred, Silicon Containing Hydrogen is added after removing allyl alcohol
Oil, polymerization inhibitor, toluene and platinum catalyst, stirring, are evaporated under reduced pressure, and are dried in vacuo, are obtained material A；
S2, material A is mixed with deionized water, boric acid, lemon, stirs, obtains material B；
S3, deionized water is mixed with molybdate, sodium citrate, is stirred, ethoxylated dodecyl alcohol, silicic acid is then added
Sodium, hexamethylenetetramine, polyacrylic acid and solubilizer, stirring, add material B, stir, obtain metal cleaning high-efficiency washing
Agent.
Preferably, in S1,2,3- epoxypropyltrimethylchloride chloride is mixed with allyl alcohol, sodium hydrate aqueous solution is added
Regulation system pH value is 8.5-10, in 65-70 DEG C of stirring 1-2h, remove addition containing hydrogen silicone oil after allyl alcohol, polymerization inhibitor, toluene and
Platinum catalyst is evaporated under reduced pressure in 74-78 DEG C of stirring 2.5-3h, and vacuum drying obtains material A.
Preferably, in S1,2,3- epoxypropyltrimethylchloride chlorides, allyl alcohol, the weight ratio between containing hydrogen silicone oil are 1-
2:1-2:1.5-3。
Preferably, in S1, the molal weight of containing hydrogen silicone oil is 5500-6500g/mol, reactive hydrogen mass fraction is 0.18-
0.2%.
Preferably, in S1, vacuum drying temperature is 52-58 DEG C.
Preferably, in S2, material A and deionized water, boric acid, the weight ratio between lemon are 10-15:40-50:2-
4:1-2。
Preferably, in S2, whipping temp is 74-78 DEG C, mixing time 1-1.5h.
Preferably, in S3, by weight by 80-100 parts of deionized waters and 0.6-0.8 parts of molybdates, 0.8-1.2 portions of lemons
The mixing of sour sodium, in 52-58 DEG C of stirring to being completely dissolved, be then added 12-18 parts of ethoxylated dodecyl alcohols, 2-6 parts of sodium metasilicate,
4-8 parts of hexamethylenetetramines, 2-4 parts of polyacrylic acid and 4-6 parts of solubilizer are cooled to room temperature in 62-65 DEG C of stirring 18-25min
15-20 parts of material B are added, 15-20min is stirred, obtains metal cleaning efficient cleaner.
Preferably, in S3, the raw material of solubilizer includes: 5-10 parts of polyethylene glycol, sodium xylene sulfonate 4-8 by weight
Part, 2-4 parts of urea.
By optimization preparation process in the present invention, technological parameter is rationally set, first by 2,3- epoxypropyl trimethylammonium chloride
Ammonium and allyl alcohol stir, and it is anti-that open loop occurs for the hydroxyl in epoxy group and allyl alcohol in 2,3- epoxypropyltrimethylchloride chlorides
Should be to which allyl alcohol be grafted on 2,3- epoxypropyltrimethylchloride chloride, and then end alkenyl is introduced, then be with containing hydrogen silicone oil
Hydrosilylation occurs for the double bond of modifying agent, Si-H base and end alkenyl, and chain length increases, and increased activity is also effectively improved
The defect of the poorly water-soluble of containing hydrogen silicone oil, obtained material A is as cationic surfactant, and activity is high, degreasing result
Obviously, while defoaming, compatibility and amphipathic property are good, can effectively improve inventive article stability, and enhance this
The cleaning performance of invention product, while can effectively prevent causes inventive article clear because of the addition of ethoxylated dodecyl alcohol
Foam excessive defect when washing；Material A is mixed with boric acid, lemon again, whipping temp and time are rationally set, is occurred
Partial esterification reaction obtains material B and is added in system of the present invention, can effectively improve the biocompatibility and antirust of inventive article
Clean effect, while also there is certain bactericidal effect and fresh air effect；Again by by deionized water, molybdate, lemon
Sour sodium, ethoxylated dodecyl alcohol, sodium metasilicate, hexamethylenetetramine, polyacrylic acid, solubilizer are mixed, and each component is compatible
Property and good dispersion, and each component cooperate its have synergistic effect, make inventive article have it is good wetting, infiltration, cream
Change, dispersion, solubilising and low bubble performance, can rapidly, thoroughly remove the dirt and impurity of metal surface, have extensively to a variety of dirts
General adaptability, and be easy to rinse, and the protecting film of dense uniform, antirust, inhibition can be formed in metal surface after cleaning
Effect is obvious, effectively extends metal product service life.A kind of metal cleaning proposed by the present invention preparation of efficient cleaner
Method, resulting product can rapidly, thoroughly remove the dirt and impurity of metal surface, while have many advantages, such as low bubble, easily rinsing.
Specific embodiment
In the following, technical solution of the present invention is described in detail by specific embodiment.
Embodiment 1
A kind of metal cleaning proposed by the present invention preparation method of efficient cleaner, comprising the following steps:
S1,2,3- epoxypropyltrimethylchloride chloride is mixed with allyl alcohol, is stirred, Silicon Containing Hydrogen is added after removing allyl alcohol
Oil, polymerization inhibitor, toluene and platinum catalyst, stirring, are evaporated under reduced pressure, and are dried in vacuo, are obtained material A；
S2, material A is mixed with deionized water, boric acid, lemon, stirs, obtains material B；
S3, deionized water is mixed with molybdate, sodium citrate, is stirred, ethoxylated dodecyl alcohol, silicic acid is then added
Sodium, hexamethylenetetramine, polyacrylic acid and solubilizer, stirring, add material B, stir, obtain metal cleaning high-efficiency washing
Agent.
Embodiment 2
A kind of metal cleaning proposed by the present invention preparation method of efficient cleaner, comprising the following steps:
S1,2,3- epoxypropyltrimethylchloride chloride is mixed with allyl alcohol, sodium hydrate aqueous solution regulation system is added
PH value is 8.5, in 65 DEG C of stirring 2h, containing hydrogen silicone oil, polymerization inhibitor, toluene and platinum catalyst is added after removing allyl alcohol, at 74 DEG C
3h is stirred, through being evaporated under reduced pressure, is dried in vacuo at 52 DEG C, obtains material A；Wherein, 2,3- epoxypropyltrimethylchloride chloride, allyl
Weight ratio between alcohol, containing hydrogen silicone oil is 1:1:1.5；
S2, material A is mixed with deionized water, boric acid, lemon, in 74 DEG C of stirring 1.5h, obtains material B；Wherein,
Material A and deionized water, boric acid, the weight ratio between lemon are 10:40:2:1；The molal weight of containing hydrogen silicone oil is
5500g/mol, reactive hydrogen mass fraction are 0.2%；
S3,80 parts of deionized waters are mixed with 0.6 part of molybdate, 0.8 part of sodium citrate by weight, 52 DEG C of stirrings extremely
Be completely dissolved, then be added 12 parts of ethoxylated dodecyl alcohols, 2 parts of sodium metasilicate, 4 parts of hexamethylenetetramines, 2 parts of polyacrylic acid and
4 parts of solubilizer are cooled to room temperature in 62 DEG C of stirring 25min and add 15 parts of material B, stir 15min, obtain metal cleaning and use
Efficient cleaner；Wherein, the raw material of solubilizer includes: 5 parts of polyethylene glycol, 8 parts of sodium xylene sulfonate, 2 parts of urea by weight.
Embodiment 3
A kind of metal cleaning proposed by the present invention preparation method of efficient cleaner, comprising the following steps:
S1,2,3- epoxypropyltrimethylchloride chloride is mixed with allyl alcohol, sodium hydrate aqueous solution regulation system is added
PH value is 9.5, in 68 DEG C of stirring 1.5h, containing hydrogen silicone oil, polymerization inhibitor, toluene and platinum catalyst is added after removing allyl alcohol, 76
DEG C stirring 2.8h, through being evaporated under reduced pressure, 55 DEG C be dried in vacuo, obtain material A；Wherein, 2,3- epoxypropyltrimethylchloride chloride,
Weight ratio between allyl alcohol, containing hydrogen silicone oil is 1.5:1.5:2.5；
S2, material A is mixed with deionized water, boric acid, lemon, in 76 DEG C of stirring 1.2h, obtains material B；Wherein,
Material A and deionized water, boric acid, the weight ratio between lemon are 12:45:3:1.5；The molal weight of containing hydrogen silicone oil is
6500g/mol, reactive hydrogen mass fraction are 0.18%；
S3,90 parts of deionized waters are mixed with 0.7 part of molybdate, 1 part of sodium citrate by weight, in 55 DEG C of stirrings to complete
Then 15 parts of ethoxylated dodecyl alcohols, 5 parts of sodium metasilicate, 6 parts of hexamethylenetetramines, 3 parts of polyacrylic acid and 5 are added in fully dissolved
Part solubilizer is cooled to room temperature in 64 DEG C of stirring 22min and adds 18 parts of material B, stirs 18min, obtains metal cleaning height
Imitate cleaning agent；Wherein, the raw material of solubilizer includes: 8 parts of polyethylene glycol, 6 parts of sodium xylene sulfonate, 3 parts of urea by weight.
Embodiment 4
A kind of metal cleaning proposed by the present invention preparation method of efficient cleaner, comprising the following steps:
S1,2,3- epoxypropyltrimethylchloride chloride is mixed with allyl alcohol, sodium hydrate aqueous solution regulation system is added
PH value is 10, in 70 DEG C of stirring 1h, containing hydrogen silicone oil, polymerization inhibitor, toluene and platinum catalyst is added after removing allyl alcohol, stirs at 78 DEG C
2.5h is mixed, through being evaporated under reduced pressure, is dried in vacuo at 58 DEG C, obtains material A；Wherein, 2,3- epoxypropyltrimethylchloride chloride, allyl
Weight ratio between alcohol, containing hydrogen silicone oil is 2:2:3；The molal weight of containing hydrogen silicone oil is 6000g/mol, reactive hydrogen mass fraction is
0.19%；
S2, material A is mixed with deionized water, boric acid, lemon, in 78 DEG C of stirring 1h, obtains material B；Wherein, object
Expect that A and deionized water, boric acid, the weight ratio between lemon are 15:50:4:2；
S3,100 parts of deionized waters are mixed by weight with 0.8 part of molybdate, 1.2 parts of sodium citrates, is stirred at 58 DEG C
To being completely dissolved, 18 parts of ethoxylated dodecyl alcohols, 6 parts of sodium metasilicate, 8 parts of hexamethylenetetramines, 4 parts of polyacrylic acid are then added
It is cooled to room temperature in 65 DEG C of stirring 18min with 6 parts of solubilizer and adds 20 parts of material B, stir 20min, obtain metal cleaning
Use efficient cleaner；Wherein, the raw material of solubilizer includes: 10 parts of polyethylene glycol, 4 parts of sodium xylene sulfonate, urea 4 by weight
Part.
Embodiment 5
A kind of metal cleaning proposed by the present invention preparation method of efficient cleaner, comprising the following steps:
S1,2,3- epoxypropyltrimethylchloride chloride is mixed with allyl alcohol, sodium hydrate aqueous solution regulation system is added
PH value is 9, in 66 DEG C of stirring 1.8h, containing hydrogen silicone oil, polymerization inhibitor, toluene and platinum catalyst is added after removing allyl alcohol, at 75 DEG C
2.8h is stirred, through being evaporated under reduced pressure, is dried in vacuo at 55 DEG C, obtains material A；Wherein, 2,3- epoxypropyltrimethylchloride chloride, alkene
Weight ratio between propyl alcohol, containing hydrogen silicone oil is 1.2:1.6:2.5；The molal weight of containing hydrogen silicone oil is 6200g/mol, reactive hydrogen matter
Measuring score is 0.19%；
S2, material A is mixed with deionized water, boric acid, lemon, in 76 DEG C of stirring 1.2h, obtains material B；Wherein,
Material A and deionized water, boric acid, the weight ratio between lemon are 12:48:2.5:1.8；
S3,95 parts of deionized waters are mixed by weight with 0.65 part of molybdate, 1.1 parts of sodium citrates, is stirred at 56 DEG C
To being completely dissolved, 15 parts of ethoxylated dodecyl alcohols, 4 parts of sodium metasilicate, 5 parts of hexamethylenetetramines, 3.5 parts of polypropylene are then added
Acid and 5.5 parts of solubilizer are cooled to room temperature in 64 DEG C of stirring 24min and add 18 parts of material B, stir 16min, obtain metal
Efficient cleaner is used in cleaning；Wherein, the raw material of solubilizer includes: 8 parts of polyethylene glycol, 5 parts of sodium xylene sulfonate, urine by weight
3 parts of element.
The cleaning force of metal cleaning efficient cleaner obtained in 3-5 of the embodiment of the present invention is tested for the property, is walked
It is rapid as follows:
A, by No. 45 steel test piece polishing cleanings, test piece 1 is obtained, the quality of record test piece 1 is m0；
B, the immersion of test piece 1 is pre-heated to 10min in 80 DEG C of artificial greasy dirt, it is identical as artificial greasy dirt temperature to test piece 1
After propose test piece, be hung on 20min on test piece frame, scrape off the oil droplet of test piece congregate, make the greasy dirt dip-coating amount 110 in test piece
~120mg, obtains test piece 2, and the quality of record test piece 2 is m1；
C, test piece 2 is placed in cleaning agent of the present invention, first stands 2.5min, then pendulum washes 2.5min, then is washed with clear water pendulum
45s takes out test piece and is placed in 60 DEG C of drying boxes dry 50min, is cooled to room temperature after taking-up, obtains test piece 3, record test piece 3
Quality is m2.
The cleaning force of detergent solution is calculated as follows:
Wherein, the raw material of artificial greasy dirt includes following components by mass fraction: petroleum sodium sulfonate 25%, industrial albolene
25%, N32HL hydraulic oil 50%；Pendulum wash during, pendulum wash frequency (30 ± 1) it is secondary/min；In step c, stands and pendulum is washed and exists
It is carried out under the conditions of 40 DEG C of temperature.
The cleaning force of metal obtained cleaning efficient cleaner is as shown in the table in embodiment 3-5:
| Embodiment | Embodiment 3 | Embodiment 4 | Embodiment 5 |
| Cleaning force/% | 98.95 | 99.05 | 98.68 |
As upper table data Binding experiment step it is found that using a kind of metal cleaning high-efficiency washing made from the method for the present invention
Its degreasing of agent is high-efficient, and degreasing result is significant, while being easy to rinse, and is suitable for production application.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (9)
1. a kind of metal cleaning efficient cleaner, which is characterized in that its raw material includes: by weight
S1,2,3- epoxypropyltrimethylchloride chloride is mixed with allyl alcohol, stir, remove allyl alcohol after be added containing hydrogen silicone oil,
Polymerization inhibitor, toluene and platinum catalyst, stirring, are evaporated under reduced pressure, and are dried in vacuo, are obtained material A；
S2, material A is mixed with deionized water, boric acid, lemon, stirs, obtains material B；
S3, deionized water is mixed with molybdate, sodium citrate, stir, then be added ethoxylated dodecyl alcohol, sodium metasilicate,
Hexamethylenetetramine, polyacrylic acid and solubilizer, stirring, add material B, stir, obtain metal cleaning efficient cleaner.
2. metal cleaning efficient cleaner according to claim 1, which is characterized in that in S1, by 2,3- glycidyl three
Ammonio methacrylate is mixed with allyl alcohol, and addition sodium hydrate aqueous solution regulation system pH value is 8.5-10, in 65-70 DEG C of stirring 1-
Containing hydrogen silicone oil, polymerization inhibitor, toluene and platinum catalyst is added after removing allyl alcohol, in 74-78 DEG C of stirring 2.5-3h, through depressurizing in 2h
Distillation, vacuum drying, obtains material A.
3. metal cleaning efficient cleaner according to claim 1 or claim 2, which is characterized in that in S1,2,3- glycidyl three
Ammonio methacrylate, allyl alcohol, the weight ratio between containing hydrogen silicone oil are 1-2:1-2:1.5-3.
4. the cleaning of metal described in any one of -3 efficient cleaner according to claim 1, which is characterized in that in S1, Silicon Containing Hydrogen
The molal weight of oil is 5500-6500g/mol, reactive hydrogen mass fraction is 0.18-0.2%.
5. the cleaning of metal described in any one of -4 efficient cleaner according to claim 1, which is characterized in that in S1, vacuum is dry
Dry temperature is 52-58 DEG C.
6. according to claim 1 metal described in any one of -5 cleaning use efficient cleaner, which is characterized in that in S2, material A with
Deionized water, boric acid, the weight ratio between lemon are 10-15:40-50:2-4:1-2.
7. the cleaning of metal described in any one of -6 efficient cleaner according to claim 1, which is characterized in that in S2, stirring temperature
Degree is 74-78 DEG C, mixing time 1-1.5h.
8. the cleaning of metal described in any one of -7 efficient cleaner according to claim 1, which is characterized in that in S3, by weight
Part mixes 80-100 parts of deionized waters with 0.6-0.8 parts of molybdates, 0.8-1.2 parts of sodium citrates, stirs at 52-58 DEG C to complete
Fully dissolved, then be added 12-18 part ethoxylated dodecyl alcohols, 2-6 parts of sodium metasilicate, 4-8 parts of hexamethylenetetramines, 2-4 parts gather
Acrylic acid and 4-6 parts of solubilizer are cooled to room temperature in 62-65 DEG C of stirring 18-25min and add 15-20 parts of material B, stirring
15-20min obtains metal cleaning efficient cleaner.
9. the cleaning of metal described in any one of -8 efficient cleaner according to claim 1, which is characterized in that in S3, solubilizer
Raw material by weight include: 5-10 parts of polyethylene glycol, 4-8 parts of sodium xylene sulfonate, 2-4 parts of urea.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811044080.5A CN109295462A (en) | 2018-09-07 | 2018-09-07 | A kind of metal cleaning preparation method of efficient cleaner |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811044080.5A CN109295462A (en) | 2018-09-07 | 2018-09-07 | A kind of metal cleaning preparation method of efficient cleaner |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109295462A true CN109295462A (en) | 2019-02-01 |
Family
ID=65166350
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811044080.5A Withdrawn CN109295462A (en) | 2018-09-07 | 2018-09-07 | A kind of metal cleaning preparation method of efficient cleaner |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109295462A (en) |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008024878A (en) * | 2006-07-25 | 2008-02-07 | Tokiwa Chemical Industries Co Ltd | Liquid detergent composition for metal |
| CN103510100A (en) * | 2013-09-26 | 2014-01-15 | 杨桂望 | Metal cleaning agent |
| CN104031755A (en) * | 2014-06-12 | 2014-09-10 | 王希贵 | Oil stain cleaning agent and preparation method thereof |
| CN104480489A (en) * | 2015-01-04 | 2015-04-01 | 麻城市天安纳米化工材料有限公司 | Environment-friendly efficient train cleaning agent and preparation method thereof |
| CN106555197A (en) * | 2015-09-28 | 2017-04-05 | 比亚迪股份有限公司 | A kind of aqueous cleaning agent and its preparation method and application |
| CN106701358A (en) * | 2017-01-13 | 2017-05-24 | 永兴隆诚高新材料有限公司 | Heavy greasy dirt cleaning agent and preparation method thereof |
| CN107761123A (en) * | 2017-10-13 | 2018-03-06 | 广州迪奕科环保科技有限公司 | A kind of environmentally friendly oil pipeline cleaning agent |
| CN108486587A (en) * | 2018-05-18 | 2018-09-04 | 华南师范大学 | A kind of environmentally-friendly water-based metal cleaner and preparation method thereof |
-
2018
- 2018-09-07 CN CN201811044080.5A patent/CN109295462A/en not_active Withdrawn
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008024878A (en) * | 2006-07-25 | 2008-02-07 | Tokiwa Chemical Industries Co Ltd | Liquid detergent composition for metal |
| CN103510100A (en) * | 2013-09-26 | 2014-01-15 | 杨桂望 | Metal cleaning agent |
| CN104031755A (en) * | 2014-06-12 | 2014-09-10 | 王希贵 | Oil stain cleaning agent and preparation method thereof |
| CN104480489A (en) * | 2015-01-04 | 2015-04-01 | 麻城市天安纳米化工材料有限公司 | Environment-friendly efficient train cleaning agent and preparation method thereof |
| CN106555197A (en) * | 2015-09-28 | 2017-04-05 | 比亚迪股份有限公司 | A kind of aqueous cleaning agent and its preparation method and application |
| CN106701358A (en) * | 2017-01-13 | 2017-05-24 | 永兴隆诚高新材料有限公司 | Heavy greasy dirt cleaning agent and preparation method thereof |
| CN107761123A (en) * | 2017-10-13 | 2018-03-06 | 广州迪奕科环保科技有限公司 | A kind of environmentally friendly oil pipeline cleaning agent |
| CN108486587A (en) * | 2018-05-18 | 2018-09-04 | 华南师范大学 | A kind of environmentally-friendly water-based metal cleaner and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR20030088125A (en) | Low foaming/defoaming compositions containing alkoxylated quaternary ammonium compounds | |
| CN105297047B (en) | A kind of stainless steel cleaner | |
| CN103834481A (en) | Compound medical equipment multi-enzyme cleaning agent | |
| US6146427A (en) | Method for cleaning hydrocarbon-containing greases and oils from fabric in laundry washing applications | |
| CN109055960A (en) | A kind of low bubble cleaning agent of metal cleaning | |
| CN102230183A (en) | Cleaning and antirust agent for secondary processing of casting parts and preparation method thereof | |
| CN110158107A (en) | A kind of Wax removal water and its preparation process for medal polish part | |
| CN110227978A (en) | A kind of galvanized steel sheet surface treatment process | |
| CN109338384A (en) | A kind of water base metal cleaning agent and preparation method thereof | |
| CN104818156B (en) | A kind of tableware immersion compound powder improving low temperature greasy dirt cleaning effect | |
| JP3610434B2 (en) | Nonionic surfactant | |
| JPS58149372A (en) | Foam washing method | |
| CN109295462A (en) | A kind of metal cleaning preparation method of efficient cleaner | |
| CN114164054A (en) | Cleaning composition for removing protein stains | |
| JP7214869B2 (en) | Acid cleaning composition for enhanced stain removal | |
| CN108754507A (en) | A kind of ultrasonic cleaning agent and preparation method and application method | |
| JP4627438B2 (en) | Soaping method for reactive dyes | |
| JP4447370B2 (en) | Cleaning composition for CIP | |
| CN113150887B (en) | Neutral cleaning agent for water-in-oil cosmetics and preparation method thereof | |
| CN107447527A (en) | A kind of scouring agent for wollen fabrics | |
| CN107164103A (en) | A kind of high-performance scale removal detergent with sterilizing, its preparation method and its application method | |
| CN107760450A (en) | A kind of neutral dirty cleaning agent of weight | |
| CN110982639A (en) | Water-based cleaning agent for industrial oil stains and preparation method thereof | |
| CN108950573B (en) | A kind of process of surface treatment of valve | |
| JP4578853B2 (en) | Cleaning composition for CIP |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20190201 |