CN109294397A - A kind of preparation method of rapid curing peel type anticorona varinish - Google Patents
A kind of preparation method of rapid curing peel type anticorona varinish Download PDFInfo
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- CN109294397A CN109294397A CN201811135044.XA CN201811135044A CN109294397A CN 109294397 A CN109294397 A CN 109294397A CN 201811135044 A CN201811135044 A CN 201811135044A CN 109294397 A CN109294397 A CN 109294397A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
Abstract
The invention discloses a kind of preparation methods of rapid curing peel type anticorona varinish, belong to technical field of coatings.Bamboo fibre is made by raw material of thin bamboo strips used for weaving first in the present invention, to the micro- corruption of bamboo fibre, obtain porous bamboo fibre, porous bamboo fibre is subjected to hydro-thermal charing again, obtain stephanoporate bamboo charcoal fiber, the filter residue containing lignin is made by raw material of wheat straw again, aldol reaction occurs for the hydroxyl of carbonyl and stephanoporate bamboo charcoal fiber in lignin, generate ehter bond, ehter bond has polarity, and epoxy resin also has polarity, according to polarity compatible principle, modified porous bamboo charcoal fiber with identical polar is even closer in conjunction with epoxy resin, and the adhesive force of epoxy resin is good, leakage resistance is high, it is attached to anticorona varinish obtained firmly in substrate, it is not easily to fall off, organic carboxyl acid is chemically reacted with epoxy resin, improve the crosslinking rate of mixture, the curing time of anticorona varinish can be shortened, it has broad application prospects.
Description
Technical field
The invention discloses a kind of preparation methods of rapid curing peel type anticorona varinish, belong to technical field of coatings.
Background technique
Corona discharge is that field strength is prominent to be located (such as electrode is sharply located) local space air ionization and produce in severe non-uniform electric field
A kind of electric discharge phenomena of raw blue halation.
Anticorona varinish is generally mixed, is mainly used for by insulating varnish and non-metal conductor (carbon black, graphite etc.) powder
High-tension coil makees anticorona varinish, as the higher end turn of voltage in large high-voltage motor.Industrially require anticorona varinish
Surface resistivity is stable, adhesive force is strong, wearability is good, rate of drying is fast, shelf-stable, anticorona varinish can individually be coated in coil table
Face can also be coated in asbestos yarn, on glass tape, in wrapping in coil outer layer, or be coated on glass cloth and major insulation one-pass molding.
One trend of generator development is that voltage class is higher and higher, and capacity is increasing, especially large-scale air cooling machine
Group, this puts forward new requirements stator winding anticorona material, and not only single stator bar discharge inception voltage requires higher, and
Stator winding cannot in the process of running due to corona act on and end scaling loss.Meet this requirement a kind of method be exactly
One layer of high resistance anticorona varinish of bar end surface brushing after molding, and one layer of high resistance is sprayed on stator winding end surface
Anticorona varinish.
Current high resistance anticorona varinish that is domestic and using is the dry high resistant anticorona varinish of one-component gas, and paint base is epoxy-ester
Or polyesters gas dried lacquer, they seal container and condition of storage requirement is high, and storage life is short.Simultaneously as be gas dried lacquer,
If overweight coating, or be sprayed on the surface of adsorptivity, then the extremely difficult solidification of bottom anticorona varnish, required curing time is long,
To extreme influence bar or the adhesion and anti-corona performance on winding surface.
Therefore, inventing a kind of fast and not easily to fall off anticorona varinish of speed has positive effect to technical field of coatings.
Summary of the invention
Present invention mainly solves the technical issues of, for easy in external carbon black, graphite composite powder in current anticorona varinish
It falls off, influences its anticorona performance, while its required curing time is long, influences the defect of its adhesive force, provides one kind
The preparation method of rapid curing peel type anticorona varinish.
In order to solve the above-mentioned technical problem, the technical scheme adopted by the invention is that:
A kind of preparation method of rapid curing peel type anticorona varinish, it is characterised in that specific preparation step are as follows:
(1) it takes thin bamboo strips used for weaving to be put into the steam-explosion jar of steam blasting device, and is passed through steam into steam-explosion jar, until pressure in steam-explosion jar
Up to 2.4~2.8MPa, after 40~50s of pressure maintaining, steam-explosion jar discharge valve is opened, material moment in steam-explosion jar is made to be injected into reception
In tank, material in receiving tank is collected, steam explosion bamboo fibre is obtained;
(2) above-mentioned steam explosion bamboo fibre is put into hair enzyme room, the micro- rotten processing of hair enzyme 3~4 days obtains micro- bean curd stick fiber, then will be micro-
Bean curd stick fiber is put into hydrothermal reaction kettle, and under conditions of 200~300 DEG C, hydro-thermal carbonizes 2~3h, obtains stephanoporate bamboo charcoal fiber,
It is spare;
(3) wheat straw is taken, 50~60min of crushing in pulverizer is put into, obtains crushed material, crushed material is mixed with sodium hydroxide solution
After be stirred to react 40~50min, obtain mixed liquor, then into mixed liquor hydrochloric acid is added until pH becomes 2~3, filtering removal filter
Liquid collects the filter residue containing lignin;
(4) spare stephanoporate bamboo charcoal fiber and the above-mentioned filter residue containing lignin are put into reaction kettle after mixing, 70
Under conditions of~80 DEG C, it is stirred to react 60~90min, obtains modified porous bamboo charcoal fiber;
(5) reaction kettle is put into after mixing above-mentioned modified porous bamboo charcoal fiber, propanepoxy resin, malic acid solution
In, under conditions of temperature is 50~60 DEG C, it is stirred to react 1~2h, is discharged up to rapid curing peel type anticorona varinish.
The temperature of steam described in step (1) is 200~250 DEG C.
Temperature in hair enzyme room described in step (2) is 25~35 DEG C, and relative air humidity is 80~85%.
The mass ratio of crushed material described in step (3) and sodium hydroxide solution is 1 ︰ 1, the mass fraction of sodium hydroxide solution
It is 10%, the mass fraction of the hydrochloric acid of addition is 5%.
The mass ratio of spare stephanoporate bamboo charcoal fiber and the above-mentioned filter residue containing lignin described in step (4) is 1 ︰ 1.
The quality of above-mentioned modified porous bamboo charcoal fiber, propanepoxy resin, malic acid solution described in step (5)
Than being 10% for the mass fraction of 3 ︰, 3 ︰ 1, malic acid solution.
The beneficial effects of the present invention are:
Bamboo fibre is made by raw material of thin bamboo strips used for weaving first in the present invention, carries out micro- rotten processing to bamboo fibre, obtains porous bamboo fibre, then will
Porous bamboo fibre carries out hydrothermal carbonization, obtains stephanoporate bamboo charcoal fiber, then the filter residue containing lignin is made by raw material of wheat straw, will
Stephanoporate bamboo charcoal fiber and the filter residue hybrid reaction containing lignin obtain modified porous bamboo charcoal fiber, finally by modified porous bamboo charcoal
Fiber, propanepoxy resin and organic carboxyl acid blending reaction obtain rapid curing peel type anticorona varinish, this hair
It is bright that bamboo fibre is made by raw material of thin bamboo strips used for weaving first, to the micro- corruption of bamboo fibre, porous bamboo fibre is obtained, then porous bamboo fibre is subjected to water
Heat charing, obtains stephanoporate bamboo charcoal fiber, so that stephanoporate bamboo charcoal fiber surface has great amount of hydroxy group, it can be with ring used in the present invention
The Hydrogenbond of oxygen resin improves suction-operated of the stephanoporate bamboo charcoal fiber to epoxy resin, improves stephanoporate bamboo charcoal fiber and ring
The compatibility of oxygen resin, and after epoxy resin is attached in the porous structure of bamboo charcoal fiber, it can be to epoxy resin generation
Anchorage effect is managed, the adhesion strength of anticorona varinish is improved, then using wheat straw as the obtained filter residue containing lignin of raw material, in lignin
Carbonyl and the hydroxyl of stephanoporate bamboo charcoal fiber aldol reaction occurs, generate ehter bond, ehter bond has polarity, and epoxy resin
With polarity, according to polarity compatible principle, the modified porous bamboo charcoal fiber with identical polar more steps up in conjunction with epoxy resin
It is close, and the adhesive force of epoxy resin is good, leakage resistance is high, is attached to anticorona varinish obtained firmly in substrate, is not easy
It falls off, in addition organic carboxyl acid can be chemically reacted with epoxy resin, improve the crosslinking rate of mixture, can be shortened anticorona
It the curing time of paint, has broad application prospects.
Specific embodiment
It takes thin bamboo strips used for weaving to be put into the steam-explosion jar of steam blasting device, and is passed through into steam-explosion jar and is preheated to 200~250 DEG C of steaming
Vapour after 40~50s of pressure maintaining, is opened steam-explosion jar discharge valve, is made in steam-explosion jar until pressure is up to 2.4~2.8MPa in steam-explosion jar
Material moment is injected into receiving tank, collects material in receiving tank, obtains steam explosion bamboo fibre;Above-mentioned steam explosion bamboo fibre is put into
It sends out in enzyme room, is 25~35 DEG C in temperature, under conditions of relative air humidity is 80~85%, the micro- rotten processing of hair enzyme 3~4 days is obtained
It is put into hydrothermal reaction kettle to micro- bean curd stick fiber, then by micro- bean curd stick fiber, under conditions of 200~300 DEG C, hydro-thermal charing 2~
3h obtains stephanoporate bamboo charcoal fiber, spare;Wheat straw is taken, 50~60min of crushing in pulverizer is put into, crushed material is obtained, by mass ratio
For 1 ︰ 1 crushed material mixed with the sodium hydroxide solution that mass fraction is 10% after be stirred to react 40~50min, obtain mixed liquor,
The hydrochloric acid that mass fraction is 5% is added into mixed liquor again until pH becomes 2~3, filtering removal filtrate, collection contains lignin
Filter residue;It is in mass ratio that 1 ︰ 1 is put into after mixing by spare stephanoporate bamboo charcoal fiber and the above-mentioned filter residue containing lignin
In reaction kettle, under conditions of 70~80 DEG C, it is stirred to react 60~90min, obtains modified porous bamboo charcoal fiber;By above-mentioned modification
The malic acid solution that stephanoporate bamboo charcoal fiber, propanepoxy resin, mass fraction are 10% is 3 ︰, 3 ︰ 1 mixing in mass ratio
After be put into reaction kettle, under conditions of temperature is 50~60 DEG C, be stirred to react 1~2h, discharge up to rapid curing peel
Type anticorona varinish.
Example 1
It takes thin bamboo strips used for weaving to be put into the steam-explosion jar of steam blasting device, and is passed through into steam-explosion jar and is preheated to 200 DEG C of steam, until vapour
Pressure reaches 2.4MPa in quick-fried tank, after pressure maintaining 40s, opens steam-explosion jar discharge valve, is injected into material moment and connects
In closed cans, material in receiving tank is collected, steam explosion bamboo fibre is obtained;Above-mentioned steam explosion bamboo fibre is put into hair enzyme room, is in temperature
25 DEG C, under conditions of relative air humidity is 80%, the micro- rotten processing of hair enzyme 3 days obtains micro- bean curd stick fiber, then by micro- bean curd stick fiber
It is put into hydrothermal reaction kettle, under conditions of 200 DEG C, hydro-thermal carbonizes 2h, obtains stephanoporate bamboo charcoal fiber, spare;Wheat straw is taken, is put into
50min is crushed in pulverizer, obtains crushed material, and the sodium hydroxide for being 10% by crushed material and mass fraction that mass ratio is 1 ︰ 1 is molten
It is stirred to react 40min after liquid mixing, obtains mixed liquor, then the hydrochloric acid that addition mass fraction is 5% into mixed liquor is until pH becomes
2, filtering removal filtrate collects the filter residue containing lignin;By spare stephanoporate bamboo charcoal fiber and the above-mentioned filter containing lignin
Slag is that 1 ︰ 1 is put into reaction kettle after mixing in mass ratio, under conditions of 70 DEG C, is stirred to react 60min, and it is more to obtain modification
Hole bamboo charcoal fiber;Above-mentioned modified porous bamboo charcoal fiber, propanepoxy resin, mass fraction is molten for 10% malic acid
Liquid is to be put into reaction kettle after 3 ︰, 3 ︰ 1 is mixed in mass ratio, under conditions of temperature is 50 DEG C, is stirred to react 1h, discharges to obtain the final product
Rapid curing peel type anticorona varinish.
Example 2
It takes thin bamboo strips used for weaving to be put into the steam-explosion jar of steam blasting device, and is passed through into steam-explosion jar and is preheated to 225 DEG C of steam, until vapour
Pressure reaches 2.6MPa in quick-fried tank, after pressure maintaining 45s, opens steam-explosion jar discharge valve, is injected into material moment and connects
In closed cans, material in receiving tank is collected, steam explosion bamboo fibre is obtained;Above-mentioned steam explosion bamboo fibre is put into hair enzyme room, is in temperature
30 DEG C, under conditions of relative air humidity is 82%, the micro- rotten processing of hair enzyme 3 days obtains micro- bean curd stick fiber, then by micro- bean curd stick fiber
It is put into hydrothermal reaction kettle, under conditions of 250 DEG C, hydro-thermal carbonizes 2.5h, obtains stephanoporate bamboo charcoal fiber, spare;Wheat straw is taken, is put
Enter and crush 55min in pulverizer, obtain crushed material, by the crushed material that mass ratio is 1 ︰ 1 and the sodium hydroxide that mass fraction is 10%
It is stirred to react 45min after solution mixing, obtains mixed liquor, then the hydrochloric acid that addition mass fraction is 5% into mixed liquor is until pH becomes
It is 2, filtering removal filtrate collects the filter residue containing lignin;By spare stephanoporate bamboo charcoal fiber and above-mentioned containing lignin
Filter residue is that 1 ︰ 1 is put into reaction kettle after mixing in mass ratio, under conditions of 75 DEG C, is stirred to react 70min, is modified
Stephanoporate bamboo charcoal fiber;By above-mentioned modified porous bamboo charcoal fiber, propanepoxy resin, the malic acid that mass fraction is 10%
Solution is to be put into reaction kettle after 3 ︰, 3 ︰ 1 is mixed in mass ratio, under conditions of temperature is 55 DEG C, is stirred to react 1.5h, discharges
Up to rapid curing peel type anticorona varinish.
Example 3
It takes thin bamboo strips used for weaving to be put into the steam-explosion jar of steam blasting device, and is passed through into steam-explosion jar and is preheated to 250 DEG C of steam, until vapour
Pressure reaches 2.8MPa in quick-fried tank, after pressure maintaining 50s, opens steam-explosion jar discharge valve, is injected into material moment and connects
In closed cans, material in receiving tank is collected, steam explosion bamboo fibre is obtained;Above-mentioned steam explosion bamboo fibre is put into hair enzyme room, is in temperature
35 DEG C, under conditions of relative air humidity is 85%, the micro- rotten processing of hair enzyme 4 days obtains micro- bean curd stick fiber, then by micro- bean curd stick fiber
It is put into hydrothermal reaction kettle, under conditions of 300 DEG C, hydro-thermal carbonizes 3h, obtains stephanoporate bamboo charcoal fiber, spare;Wheat straw is taken, is put into
60min is crushed in pulverizer, obtains crushed material, and the sodium hydroxide for being 10% by crushed material and mass fraction that mass ratio is 1 ︰ 1 is molten
It is stirred to react 50min after liquid mixing, obtains mixed liquor, then the hydrochloric acid that addition mass fraction is 5% into mixed liquor is until pH becomes
3, filtering removal filtrate collects the filter residue containing lignin;By spare stephanoporate bamboo charcoal fiber and the above-mentioned filter containing lignin
Slag is that 1 ︰ 1 is put into reaction kettle after mixing in mass ratio, under conditions of 80 DEG C, is stirred to react 90min, and it is more to obtain modification
Hole bamboo charcoal fiber;Above-mentioned modified porous bamboo charcoal fiber, propanepoxy resin, mass fraction is molten for 10% malic acid
Liquid is to be put into reaction kettle after 3 ︰, 3 ︰ 1 is mixed in mass ratio, under conditions of temperature is 60 DEG C, is stirred to react 2h, discharges to obtain the final product
Rapid curing peel type anticorona varinish.
Comparative example
With the rapid curing peel type anticorona varinish of Shenzhen company production as a comparison case to produced by the present invention quickly solid
The rapid curing peel type anticorona varinish changed in peel type anticorona varinish and comparative example carries out performance detection, and testing result is such as
Shown in table 1:
Test method:
Curing rate test: the anticorona varinish in example 1~3 and comparative example is stirred into after ten minutes uniformly painting at room temperature
End turn or stator winding end are brushed, is brushed with a thickness of 0.1mmm, is solidified at room temperature, measure curing time.
Adhesive force test is detected by the standard of GB/T9286.
Corona loss power and discharge inception voltage test are detected by GB10003-88 standard.
1 anticorona varinish performance measurement result of table
Test item | Example 1 | Example 2 | Example 3 | Comparative example |
Curing time (h) | 19 | 18 | 18 | 45 |
Adhesive force (grade) | 0 | 0 | 0 | 3 |
Corona loss power (W/m) | 20.9 | 20.7 | 20.5 | 25.6 |
Discharge inception voltage increases (kV) | 27 | 27 | 28 | 15 |
According to above-mentioned detection data, rapid curing peel type anticorona varinish curing time of the invention is short, and room temperature only needs
18h can be fully cured, and adhesive force is good, and not easily to fall off in external carbon black, graphite composite powder, corona loss power is low, bloom electricity
Pressure can increase 28kV, and anticorona performance is good, has broad application prospects.
Claims (6)
1. a kind of preparation method of rapid curing peel type anticorona varinish, it is characterised in that specific preparation step are as follows:
(1) it takes thin bamboo strips used for weaving to be put into the steam-explosion jar of steam blasting device, and is passed through steam into steam-explosion jar, until pressure in steam-explosion jar
Up to 2.4~2.8MPa, after 40~50s of pressure maintaining, steam-explosion jar discharge valve is opened, material moment in steam-explosion jar is made to be injected into reception
In tank, material in receiving tank is collected, steam explosion bamboo fibre is obtained;
(2) above-mentioned steam explosion bamboo fibre is put into hair enzyme room, the micro- rotten processing of hair enzyme 3~4 days obtains micro- bean curd stick fiber, then will be micro-
Bean curd stick fiber is put into hydrothermal reaction kettle, and under conditions of 200~300 DEG C, hydro-thermal carbonizes 2~3h, obtains stephanoporate bamboo charcoal fiber,
It is spare;
(3) wheat straw is taken, 50~60min of crushing in pulverizer is put into, obtains crushed material, crushed material is mixed with sodium hydroxide solution
After be stirred to react 40~50min, obtain mixed liquor, then into mixed liquor hydrochloric acid is added until pH becomes 2~3, filtering removal filter
Liquid collects the filter residue containing lignin;
(4) spare stephanoporate bamboo charcoal fiber and the above-mentioned filter residue containing lignin are put into reaction kettle after mixing, 70
Under conditions of~80 DEG C, it is stirred to react 60~90min, obtains modified porous bamboo charcoal fiber;
(5) reaction kettle is put into after mixing above-mentioned modified porous bamboo charcoal fiber, propanepoxy resin, malic acid solution
In, under conditions of temperature is 50~60 DEG C, it is stirred to react 1~2h, is discharged up to rapid curing peel type anticorona varinish.
2. a kind of preparation method of rapid curing peel type anticorona varinish according to claim 1, it is characterised in that: step
Suddenly the temperature of steam described in (1) is 200~250 DEG C.
3. a kind of preparation method of rapid curing peel type anticorona varinish according to claim 1, it is characterised in that: step
Suddenly the temperature in hair enzyme room described in (2) is 25~35 DEG C, and relative air humidity is 80~85%.
4. a kind of preparation method of rapid curing peel type anticorona varinish according to claim 1, it is characterised in that: step
Suddenly the mass ratio of crushed material and sodium hydroxide solution described in (3) is 1 ︰ 1, and the mass fraction of sodium hydroxide solution is 10%, is added
Hydrochloric acid mass fraction be 5%.
5. a kind of preparation method of rapid curing peel type anticorona varinish according to claim 1, it is characterised in that: step
Suddenly the mass ratio of stephanoporate bamboo charcoal fiber spare described in (4) and the above-mentioned filter residue containing lignin is 1 ︰ 1.
6. a kind of preparation method of rapid curing peel type anticorona varinish according to claim 1, it is characterised in that: step
Suddenly above-mentioned modified porous bamboo charcoal fiber, propanepoxy resin described in (5), malic acid solution mass ratio be 3 ︰, 3 ︰ 1,
The mass fraction of malic acid solution is 10%.
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CN111516073A (en) * | 2020-05-09 | 2020-08-11 | 浙江省林业科学研究院 | Preparation method of bamboo fiber molding composite material |
CN114989696A (en) * | 2022-05-31 | 2022-09-02 | 福建泉州旺拉利建材有限公司 | Mortar surface viscosity enhancing interface agent and use method thereof |
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CN114989696A (en) * | 2022-05-31 | 2022-09-02 | 福建泉州旺拉利建材有限公司 | Mortar surface viscosity enhancing interface agent and use method thereof |
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Application publication date: 20190201 |