CN108250909A - A kind of cable - Google Patents

A kind of cable Download PDF

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Publication number
CN108250909A
CN108250909A CN201810128577.9A CN201810128577A CN108250909A CN 108250909 A CN108250909 A CN 108250909A CN 201810128577 A CN201810128577 A CN 201810128577A CN 108250909 A CN108250909 A CN 108250909A
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Prior art keywords
parts
seed meal
camellia seed
anticorona
stirred
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CN201810128577.9A
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Chinese (zh)
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不公告发明人
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Huian County Xin Xin Mstar Technology Ltd
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Huian County Xin Xin Mstar Technology Ltd
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Priority to CN201810128577.9A priority Critical patent/CN108250909A/en
Publication of CN108250909A publication Critical patent/CN108250909A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07HSUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
    • C07H1/00Processes for the preparation of sugar derivatives
    • C07H1/06Separation; Purification
    • C07H1/08Separation; Purification from natural products
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07HSUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
    • C07H15/00Compounds containing hydrocarbon or substituted hydrocarbon radicals directly attached to hetero atoms of saccharide radicals
    • C07H15/20Carbocyclic rings
    • C07H15/24Condensed ring systems having three or more rings
    • C07H15/256Polyterpene radicals
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07JSTEROIDS
    • C07J63/00Steroids in which the cyclopenta(a)hydrophenanthrene skeleton has been modified by expansion of only one ring by one or two atoms
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • C09D7/62Additives non-macromolecular inorganic modified by treatment with other compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/202Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure

Abstract

The present invention relates to a kind of cable, the cable surface is coated with anticorona high resistant coating, and the paint thickness is 0.19~0.28mm.Discharge rate can be reduced by 80~90% by anticorona high resistant coating, make cable floor sheet resistance disclosed in this invention up to 1011~1013 Ω, effective to reduce the death rate generated by high-tension cable electric shock;And the defects of line short caused by high-tension cable works under sleet situation and loose contact can be reduced, there is preferable stability.

Description

A kind of cable
It application No. is the 201610636362.9, applying date is on 08 05th, 2016 that the application, which is, invention and created name is A kind of divisional application of the patent of " preparation method of anticorona high resistant coating ".
Technical field
The invention discloses a kind of preparation methods of anticorona high resistant coating, belong to technical field of coatings.
Background technology
The generation of corona is curvature half around non-uniform electric field because rough conductor generates non-uniform electric field The small electrode of diameter nearby when voltage is increased to certain value, since free of air will discharge, forms corona.Because in electricity Dizzy peripheral electric field is very weak, does not collide free, and corona periphery charged particle is substantially electron ion, these ions are just formed Corona discharge current.Briefly, the small conductor electrode of radius of curvature just produces corona to atmospherical discharges.High-voltage motor Stator winding ventilation notch and straight line go out at notch, winding overhang electric field concentrate, when local location field strength reaches certain numerical value When, partial ionization occurs for gas, occurs blue-fluorescence at ionization, this is corona phenomenon.Corona generate fuel factor and ozone, Nitrogen oxide increases local temperature in coil, adhesive is caused to go bad, be carbonized, strands insulation and mica bleach, and then make Strand is loose, short circuit, insulation ag(e)ing.Running ultra-high/extra-high voltage transmission line of electricity inevitably collides with scratch in the construction process Inherently there is prominent metal object in conducting wire or conducting wire, form localized corona point of discharge.
Generally ultra-high/extra-high voltage is reduced using the method for increasing diameter of wire, division number or raising shaft tower height at present to lead Line corona loss.Although these methods can achieve the effect that reduce corona loss, input amount itself is big, and to existing presence The transmission line of electricity of corona defect, large-scale restringing or increase shaft tower highly seem unrealistic, have in practical operation Certain limitation.High-voltage motor Analysis of End Electric Field is extremely concentrated, to improve electric field distribution, at present both at home and abroad generally using carbonization Silicon Anti-Corona Material.Certainly, high-voltage motor injures human contact inestimable, this just urgently produces high resistant coating, reduces every Year death rate caused by high-voltage motor.There are electric discharge phenomena are abnormal, placement is easy for a long time for traditional anticorona high resistant coating Occur cracking, peeling and come off and during use weather sleet influence lead to the short circuit of circuit and loose contact, barrier property The defects of poor.
Invention content
Present invention mainly solves the technical issues of:For traditional anticorona high resistant coating, there are electric discharge phenomena exception, resistances Separating performance is undesirable, easily by outside environmental elements jamming pattern it is unstable the defects of, provide a kind of anticorona high resistant coating Preparation method.For the present invention using camellia seed meal as raw material, the obtained camellia seed meal powder that pulverizes and sieves mixes progress ultrasound with extractant Dispersion, collection washed with absolute ethyl alcohol after filter cake and obtained degreasing camellia seed meal powder of milling, powder and ethanol solution into Filtrate rotary evaporation is collected in row water-bath, and gained crystallization and magnesium nitrate, aluminum nitrate mixing, which are added dropwise sodium hydroxide solution reaction and are made, to be changed Property Tea Saponin Intercalated, water-bath after finally being mixed with toluene, epoxy resin and propane type epoxy resin of di phenolic group are cold But afterwards a kind of anticorona high resistant coating.The present invention by intercalation mode by Surface Activity of Tea Saponin agent by being placed in magnalium neatly Shi Zhong, due to the grain size of nano-particle in magnalium hydrotalcite is small, in large specific surface area and superficial layer intercalation by cationic surface Activating agent causes its atom proportion larger, may be such that it is fully bonded with polymer, make between particle and basal body interface Adhesive strength is enhanced, and is conducive to stress transfer, thus can bear larger load, efficiently solves traditional anticorona high resistant Coating there are electric discharge phenomena are abnormal, barrier property is undesirable, easily by outside environmental elements jamming pattern it is unstable the problem of.
In order to solve the above-mentioned technical problem, the technical solution adopted in the present invention is:
(1) camellia seed meal is collected, crushed and crosses 70~80 mesh sieve, camellia seed meal powder is prepared into, is then put Dry 3~5h at 65~80 DEG C, then in mass ratio 1:5, will dry camellia seed meal powder mixed with petroleum ether and stirring and 10~15min of ultrasonic disperse under 200~300W is filtered and is collected filter cake, after washing 3~5 times with absolute ethyl alcohol, at 65~80 DEG C 6~8h of lower drying simultaneously mills, and is prepared into degreasing camellia seed meal powder;
(2) in mass ratio 1:10, degreasing camellia seed meal powder and 40% ethanol solution of mass concentration are stirred, 65 It at~80 DEG C after 45~50min of heating water bath, filters and collects filtrate, then the rotary evaporated to dryness at 75~80 DEG C, collect Drying crystalline;
(3) it counts in parts by weight, weighs 10~15 parts of magnesium nitrates, 10~15 parts of aluminum nitrates, 5~10 parts of above-mentioned preparations respectively Drying crystalline and 45~50 parts of deionized waters be placed in conical flask, be stirred and to three-necked flask be added dropwise 1mol/L hydrogen-oxygens Change sodium solution, wait be added dropwise to pH for 10.0~11.0 when stop be added dropwise and stand 10~12h, then filter and collect filter cake, Dry 20 at 65~70 DEG C~for 24 hours, it is prepared into modified Tea Saponin Intercalated;
(4) count in parts by weight, weigh respectively 45~50 parts of toluene, 10~15 parts of above-mentioned preparations modification Tea Saponin intercalation Magnalium hydrotalcite, 15~20 parts of epoxy resin and 45~50 parts of absolute ethyl alcohols are placed in beaker, after being stirred 10~15min, To addition in beaker and epoxy resin propane type epoxy resin of di phenolic group identical in quality, after the completion of to be added, it is stirred simultaneously 25~30min of heating water bath at 45~50 DEG C is placed in, then stands and is cooled to room temperature, you can is prepared into a kind of anticorona high resistant and applies Material.
The present invention application process be:Anticorona high resistant coating produced by the present invention is coated on high-tension cable layer surface, Paint thickness is 0.19~0.28mm, and 5~8min postcoolings are toasted at a temperature of 60~80 DEG C to room temperature, discharge rate reduces by 80~ 90%, cable floor sheet resistance extends 6~8 years up to 1011~1013 Ω, cable service life.
The beneficial effects of the invention are as follows:
(1) anticorona high resistant coating discharge rate, which is made, in the present invention reduces by 80~90%, cable floor sheet resistance up to 1011~ 1013 Ω, it is effective to reduce the death rate generated by high-tension cable electric shock;
(2) present invention makees additive using camellia seed meal as raw material with epoxy resin, there is excellent adhesiveness, reduces high pressure The defects of line short caused by cable works under sleet situation and loose contact, there is preferable stability.
Specific embodiment
Camellia seed meal is collected first, crushed and crosses 70~80 mesh sieve, is prepared into camellia seed meal powder, is then put Dry 3~5h at 65~80 DEG C, then in mass ratio 1:5, will dry camellia seed meal powder mixed with petroleum ether and stirring and 10~15min of ultrasonic disperse under 200~300W is filtered and is collected filter cake, after washing 3~5 times with absolute ethyl alcohol, at 65~80 DEG C 6~8h of lower drying simultaneously mills, and is prepared into degreasing camellia seed meal powder;In mass ratio 1:10, by degreasing camellia seed meal powder and matter Amount 40% ethanol solution of concentration is stirred, and at 65~80 DEG C after 45~50min of heating water bath, is filtered and is collected filtrate, with The rotary evaporated to dryness at 75~80 DEG C afterwards collects drying crystalline;Count in parts by weight, respectively weigh 10~15 parts of magnesium nitrates, 10~15 parts of aluminum nitrates, the drying crystalline of 5~10 parts of above-mentioned preparations and 45~50 parts of deionized waters are placed in conical flask, are stirred Mix simultaneously to three-necked flask be added dropwise 1mol/L sodium hydroxide solutions, wait be added dropwise to pH for 10.0~11.0 when stop be added dropwise and stand 10~12h is then filtered and is collected filter cake, dry 20 at 65~70 DEG C~for 24 hours, and it is prepared into modified Tea Saponin intercalation magnalium water Talcum;Count in parts by weight, weigh respectively 45~50 parts of toluene, 10~15 parts of above-mentioned preparations modification Tea Saponin intercalation magnalium water Talcum, 15~20 parts of epoxy resin and 45~50 parts of absolute ethyl alcohols are placed in beaker, after being stirred 10~15min, to beaker Middle addition and epoxy resin propane type epoxy resin of di phenolic group identical in quality, after the completion of to be added, be stirred and be placed in 45 25~30min of heating water bath at~50 DEG C then stands and is cooled to room temperature, you can is prepared into a kind of anticorona high resistant coating.
Example 1
Camellia seed meal is collected first, crushed and crosses 70 mesh sieve, is prepared into camellia seed meal powder, is subsequently placed at 65 Dry 3h at DEG C, then in mass ratio 1:5, dry camellia seed meal powder with petroleum ether and stirring is mixed and ultrasound is divided under 200W 10min is dissipated, filters and collects filter cake, after washing 3 times with absolute ethyl alcohol, 6h is dried at 65 DEG C and is milled, is prepared into degreasing oil Leached tea oil slag powder;In mass ratio 1:10, degreasing camellia seed meal powder and 40% ethanol solution of mass concentration are stirred, 65 It at DEG C after heating water bath 45min, filters and collects filtrate, then the rotary evaporated to dryness at 75 DEG C, collect drying crystalline;By weight Number meter is measured, 10 parts of magnesium nitrates, 10 parts of aluminum nitrates, the drying crystalline of 5 parts of above-mentioned preparations and 45 parts of deionized waters is weighed respectively and puts In conical flask, be stirred and to three-necked flask be added dropwise 1mol/L sodium hydroxide solutions, wait be added dropwise to pH for 10.0 when stop It is only added dropwise and stands 10h, then filter and collect filter cake, dry 20h, is prepared into modified Tea Saponin intercalation magnalium water at 65 DEG C Talcum;It counts in parts by weight, weighs 45 parts of toluene, the modification Tea Saponin Intercalated of 10 parts of above-mentioned preparations, 15 respectively Part epoxy resin and 45 parts of absolute ethyl alcohols are placed in beaker, after being stirred 10min, to addition in beaker and epoxy resin quality Identical propane type epoxy resin of di phenolic group after the completion of to be added, be stirred and be placed in heating water bath 25min at 45 DEG C, with It stands and is cooled to room temperature afterwards, you can be prepared into a kind of anticorona high resistant coating.
The present invention application process be:Anticorona high resistant coating produced by the present invention is coated on high-tension cable layer surface, Paint thickness is 0.19mm, and 5min postcoolings are toasted at a temperature of 60 DEG C to room temperature, and discharge rate reduces by 80%, cable layer surface electricity Resistance extends 6 years up to 1011 Ω, cable service life.
Example 2
Camellia seed meal is collected first, crushed and crosses 75 mesh sieve, is prepared into camellia seed meal powder, is subsequently placed at 70 Dry 4h at DEG C, then in mass ratio 1:5, dry camellia seed meal powder with petroleum ether and stirring is mixed and ultrasound is divided under 250W 13min is dissipated, filters and collects filter cake, after washing 4 times with absolute ethyl alcohol, 7h is dried at 70 DEG C and is milled, is prepared into degreasing oil Leached tea oil slag powder;In mass ratio 1:10, degreasing camellia seed meal powder and 40% ethanol solution of mass concentration are stirred, 70 It at DEG C after heating water bath 47min, filters and collects filtrate, then the rotary evaporated to dryness at 77 DEG C, collect drying crystalline;By weight Number meter is measured, 13 parts of magnesium nitrates, 13 parts of aluminum nitrates, the drying crystalline of 7 parts of above-mentioned preparations and 47 parts of deionized waters is weighed respectively and puts In conical flask, be stirred and to three-necked flask be added dropwise 1mol/L sodium hydroxide solutions, wait be added dropwise to pH for 10.5 when stop It is only added dropwise and stands 11h, then filter and collect filter cake, dry 22h, is prepared into modified Tea Saponin intercalation magnalium water at 67 DEG C Talcum;It counts in parts by weight, weighs 47 parts of toluene, the modification Tea Saponin Intercalated of 13 parts of above-mentioned preparations, 17 respectively Part epoxy resin and 47 parts of absolute ethyl alcohols are placed in beaker, after being stirred 13min, to addition in beaker and epoxy resin quality Identical propane type epoxy resin of di phenolic group after the completion of to be added, be stirred and be placed in heating water bath 27min at 47 DEG C, with It stands and is cooled to room temperature afterwards, you can be prepared into a kind of anticorona high resistant coating.
The present invention application process be:Anticorona high resistant coating produced by the present invention is coated on high-tension cable layer surface, Paint thickness is 0.23mm, and 7min postcoolings are toasted at a temperature of 70 DEG C to room temperature, and discharge rate reduces by 85%, cable layer surface electricity Resistance extends 7 years up to 1012 Ω, cable service life.
Example 3
Camellia seed meal is collected first, crushed and crosses 80 mesh sieve, is prepared into camellia seed meal powder, is subsequently placed at 80 Dry 5h at DEG C, then in mass ratio 1:5, dry camellia seed meal powder with petroleum ether and stirring is mixed and ultrasound is divided under 300W 15min is dissipated, filters and collects filter cake, after washing 5 times with absolute ethyl alcohol, 8h is dried at 80 DEG C and is milled, is prepared into degreasing oil Leached tea oil slag powder;In mass ratio 1:10, degreasing camellia seed meal powder and 40% ethanol solution of mass concentration are stirred, 80 It at DEG C after heating water bath 50min, filters and collects filtrate, then the rotary evaporated to dryness at 80 DEG C, collect drying crystalline;By weight Number meter is measured, 15 parts of magnesium nitrates, 15 parts of aluminum nitrates, the drying crystalline of 10 parts of above-mentioned preparations and 50 parts of deionized waters is weighed respectively and puts In conical flask, be stirred and to three-necked flask be added dropwise 1mol/L sodium hydroxide solutions, wait be added dropwise to pH for 11.0 when stop It is only added dropwise and stands 12h, then filter and collect filter cake, dried for 24 hours at 70 DEG C, be prepared into modified Tea Saponin intercalation magnalium water Talcum;It counts in parts by weight, weighs 50 parts of toluene, the modification Tea Saponin Intercalated of 15 parts of above-mentioned preparations, 20 respectively Part epoxy resin and 50 parts of absolute ethyl alcohols are placed in beaker, after being stirred 15min, to addition in beaker and epoxy resin quality Identical propane type epoxy resin of di phenolic group after the completion of to be added, be stirred and be placed in heating water bath 30min at 50 DEG C, with It stands and is cooled to room temperature afterwards, you can be prepared into a kind of anticorona high resistant coating.
The present invention application process be:Anticorona high resistant coating produced by the present invention is coated on high-tension cable layer surface, Paint thickness is 0.28mm, and 8min postcoolings are toasted at a temperature of 80 DEG C to room temperature, and discharge rate reduces by 90%, cable layer surface electricity Resistance extends 8 years up to 1013 Ω, cable service life.

Claims (1)

1. a kind of cable, which is characterized in that the cable layer surface is coated with anticorona high resistant coating, and the paint thickness is 0.19~0.28mm, the anticorona high resistant coating are prepared by following steps:
(1) camellia seed meal is collected, crushed and crosses 70~80 mesh sieve, camellia seed meal powder is prepared into, is subsequently placed at 65 Dry 3~5h at~80 DEG C, then in mass ratio 1:5, will dry camellia seed meal powder mixed with petroleum ether and stirring and 200~ 10~15min of ultrasonic disperse under 300W is filtered and is collected filter cake, after washing 3~5 times with absolute ethyl alcohol, is done at 65~80 DEG C Dry 6~8h simultaneously mills, and degreasing camellia seed meal powder is made;
(2) in mass ratio 1:10, degreasing camellia seed meal powder and 40% ethanol solution of mass concentration are stirred, 65~80 It at DEG C after 45~50min of heating water bath, filters and collects filtrate, then the rotary evaporated to dryness at 75~80 DEG C, collect drying Crystallization;
(3) count in parts by weight, weigh respectively 10~15 parts of magnesium nitrates, 10~15 parts of aluminum nitrates, 5~10 parts of above-mentioned preparations it is dry Constipation crystalline substance and 45~50 parts of deionized waters are placed in conical flask, are stirred and 1mol/L sodium hydroxides are added dropwise to three-necked flask Solution stops being added dropwise when being added dropwise to pH and be 10.0~11.0 and stands 10~12h, then filter and collect filter cake, 65~ Dry 20 at 70 DEG C~for 24 hours, modified Tea Saponin Intercalated is made;
(4) count in parts by weight, weigh respectively 45~50 parts of toluene, 10~15 parts of above-mentioned preparations modification Tea Saponin intercalation magnalium Hydrotalcite, 15~20 parts of epoxy resin and 45~50 parts of absolute ethyl alcohols are placed in beaker, after being stirred 10~15min, to burning Addition and epoxy resin propane type epoxy resin of di phenolic group identical in quality, after the completion of to be added, be stirred and be placed in cup 25~30min of heating water bath at 45~50 DEG C then stands and is cooled to room temperature, you can is prepared into a kind of anticorona high resistant coating.
CN201810128577.9A 2016-08-05 2016-08-05 A kind of cable Withdrawn CN108250909A (en)

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CN201810128577.9A CN108250909A (en) 2016-08-05 2016-08-05 A kind of cable
CN201610636362.9A CN106221500B (en) 2016-08-05 2016-08-05 A kind of preparation method of anticorona high resistant coating

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109294397A (en) * 2018-09-28 2019-02-01 胡果青 A kind of preparation method of rapid curing peel type anticorona varinish

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CN102260316A (en) * 2011-05-23 2011-11-30 井冈山茶油有限公司 Method for purifying tea saponin from oil tea seed cake pulp
CN103160183A (en) * 2013-04-03 2013-06-19 哈尔滨理工大学 Preparation method of nano anticorona varnish
CN103583538A (en) * 2013-10-14 2014-02-19 广东中迅农科股份有限公司 Flame-retardant-containing mancozeb wettable powder
CN104091641A (en) * 2014-08-01 2014-10-08 应夏英 Cable

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CN1330907A (en) * 2000-06-09 2002-01-16 普罗科德有限公司 Chair with synchronous swing seat and back
US8963344B2 (en) * 2009-12-07 2015-02-24 Sumitomo Bakelite Co., Ltd. Epoxy resin composition for semiconductor encapsulation, cured product thereof, and semiconductor device
CN104099591A (en) * 2014-06-19 2014-10-15 锐展(铜陵)科技有限公司 Light scent type surface treating agent for aluminum alloy
CN105175476B (en) * 2015-09-02 2016-12-28 施淑琴 A kind of method extracting tea saponin from cake of camellia oleifera seeds

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Publication number Priority date Publication date Assignee Title
CN102260316A (en) * 2011-05-23 2011-11-30 井冈山茶油有限公司 Method for purifying tea saponin from oil tea seed cake pulp
CN103160183A (en) * 2013-04-03 2013-06-19 哈尔滨理工大学 Preparation method of nano anticorona varnish
CN103583538A (en) * 2013-10-14 2014-02-19 广东中迅农科股份有限公司 Flame-retardant-containing mancozeb wettable powder
CN104091641A (en) * 2014-08-01 2014-10-08 应夏英 Cable

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109294397A (en) * 2018-09-28 2019-02-01 胡果青 A kind of preparation method of rapid curing peel type anticorona varinish

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CN106221500A (en) 2016-12-14

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