CN109294033A - A kind of plastic-wood material - Google Patents

A kind of plastic-wood material Download PDF

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Publication number
CN109294033A
CN109294033A CN201811076653.2A CN201811076653A CN109294033A CN 109294033 A CN109294033 A CN 109294033A CN 201811076653 A CN201811076653 A CN 201811076653A CN 109294033 A CN109294033 A CN 109294033A
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CN
China
Prior art keywords
plastic
wood material
wood
weight percent
powder
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Pending
Application number
CN201811076653.2A
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Chinese (zh)
Inventor
严正
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JIANGXI XINSENDAI PLASTIC WOOD TECHNOLOGY Co Ltd
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JIANGXI XINSENDAI PLASTIC WOOD TECHNOLOGY Co Ltd
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Application filed by JIANGXI XINSENDAI PLASTIC WOOD TECHNOLOGY Co Ltd filed Critical JIANGXI XINSENDAI PLASTIC WOOD TECHNOLOGY Co Ltd
Priority to CN201811076653.2A priority Critical patent/CN109294033A/en
Publication of CN109294033A publication Critical patent/CN109294033A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/38Boron-containing compounds
    • C08K2003/387Borates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Dry Formation Of Fiberboard And The Like (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of plastic-wood material, the weight percent of each component are as follows: plastics 46.8~63.3%, wood powder 18.9~29.6%, sodium cellulose glycolate 5.4~9.7%, copper acetate 2.8~5.1%, Tea Saponin 1.6~1.9%, talcum powder 3.3~4.8%, toner 0.8~1.2%, lubricant 0.8~1.2%, compatilizer 1.5~2.2%, manganese compound 0.5~0.7%, borax 0.2~0.6% moulds the wooden reclaimed materials 0~12.5%, total weight percent 100%.The present invention is by the improvement on formula, to reach intensity, hardness and the wear-resisting property etc. of enhancing plastic-wood material.Plastic-wood material of the present invention has good impact strength, anti-pressure ability, ability of anti-deformation, wear-resisting property and low water absorption, and not easy to wear, fracture, warpage and deformation can be widely applied to various occasions.

Description

A kind of plastic-wood material
Technical field
The present invention relates to technical field of composite materials, in particular to a kind of plastic-wood material and preparation method thereof.
Background technique
Plastic-wood material is also Wood-plastic material, mainly with plastics such as polypropylene (PP), polyethylene (PE), polyvinyl chloride (PVC) The waste plastic of equal recycling is raw material, is process by plant fibers such as addition wood powders.Since modeling wood has both the water-fast of plastics Two kinds of characteristics of anti-corrosion and the texture of timber, so that it becomes a kind of function admirable and very durable outdoor building materials;Plastic-wood material With waterproof, moisture-proof, high-environmental, timber use can be largely substituted, is a kind of low-carbon of great development prospect, green, is recycled Regenerated ecomaterial, but since plastic-wood material is often easy to be worn in actual use, be broken, deform, so as to cause The service performance of the product as made from the plastic-wood material substantially reduces, and service life is shorter.
Summary of the invention
The purpose of the present invention is overcome the deficiencies of the prior art and provide a kind of plastic-wood material wear-resisting, with long service life.
The invention adopts the following technical scheme: a kind of plastic-wood material, the weight percent of each component are as follows: plastics 46.8~ 63.3%, wood powder 18.9~29.6%, sodium cellulose glycolate 5.4~9.7%, copper acetate 2.8~5.1%, Tea Saponin 1.6~ 1.9%, talcum powder 3.3~4.8%, toner 0.8~1.2%, lubricant 0.8~1.2%, compatilizer 1.5~2.2%, manganese Object 0.5~0.7% is closed, borax 0.2~0.6% moulds the wooden reclaimed materials 0~12.5%, total weight percent 100%.
Preferably, the weight percent of each component of the plastic-wood material are as follows: plastics 51.4%, wood powder 21.2%, hydroxyl first Base sodium cellulosate 6.3%, copper acetate 3.6%, Tea Saponin 1.8%, talcum powder 3.7%, toner 0.95%, lubricant 1.05%, Compatilizer 1.9%, manganese compound 0.6%, borax 0.4% mould the wooden reclaimed materials 7.1%.
Preferably, the lubricant is stearate.
Preferably, the compatilizer is isocyanates.
Preferably, the manganese compound is manganese chloride or manganese carbonate.
Preferably, the plastics are polyethylene particle or/and PP GRANULES.
The beneficial effects of the present invention are: the present invention is by the improvement on formula, to reach enhancing plastic-wood material Intensity, hardness and wear-resisting property etc..Plastic-wood material of the present invention have good impact strength, anti-pressure ability, ability of anti-deformation, Wear-resisting property and low water absorption, not easy to wear, fracture, warpage and deformation, can be widely applied to various occasions.
Specific embodiment
A kind of plastic-wood material of the present invention is described in further detail combined with specific embodiments below.
Embodiment 1
A kind of plastic-wood material, the weight percent of each component are as follows: polyethylene particle 51.4%, wood powder 21.2%, methylol Sodium cellulosate 6.3%, copper acetate 3.6%, Tea Saponin 1.8%, talcum powder 3.7%, toner 0.95%, zinc stearate 1.05%, Methyl diphenylene diisocyanate 1.9%, manganese chloride 0.6%, borax 0.4% mould the wooden reclaimed materials 7.1%.
The plastic-wood material is prepared via a method which:
(1) prepared by premix: wood powder is added in high mixer, with high-speed stirred 5 minutes of 1500~2500 revs/min, Wood powder humid control is 0.5% hereinafter, other each components are then respectively adding, by above-mentioned mixing by the hot mixing system discharging of batch mixer To cold mixing system, 40 DEG C are cooled to, premix is obtained;
(2) semi-finished product are granulated pellet preparation: by premix through parallel double-screw extruder extruding pelletization, technological temperature setting At 180~200 DEG C, it is to be used that pellet etc. is granulated as semi-finished product;
(3) prepared by extrusion molding: the particle after extruding pelletization is added to extrusion molding in conical double-screw, technological temperature 160~180 DEG C are set in, is squeezed out by mold to get finished product plastic-wood material is arrived.
Embodiment 2
A kind of plastic-wood material, the weight percent of each component are as follows: PP GRANULES 54.5%, wood powder 24.1%, methylol Sodium cellulosate 7.1%, copper acetate 3.9%, Tea Saponin 1.7%, talcum powder 3.9%, toner 0.95%, calcium stearate 1.05%, Toluene di-isocyanate(TDI) 1.8%, manganese carbonate 0.6%, borax 0.4%.
The plastic-wood material is prepared via a method which:
(1) prepared by premix: wood powder is added in high mixer, with high-speed stirred 5 minutes of 1500~2500 revs/min, Wood powder humid control is 0.5% hereinafter, other each components are then respectively adding, by above-mentioned mixing by the hot mixing system discharging of batch mixer To cold mixing system, 40 DEG C are cooled to, premix is obtained;
(2) semi-finished product are granulated pellet preparation: by premix through parallel double-screw extruder extruding pelletization, technological temperature setting At 180~200 DEG C, it is to be used that pellet etc. is granulated as semi-finished product;
(3) prepared by extrusion molding: the particle after extruding pelletization is added to extrusion molding in conical double-screw, technological temperature 160~180 DEG C are set in, is squeezed out by mold to get finished product plastic-wood material is arrived.
Embodiment 3
A kind of plastic-wood material, the weight percent of each component are as follows: polyethylene particle 46.8%, wood powder 29.6%, methylol Sodium cellulosate 9.7%, copper acetate 2.8%, Tea Saponin 1.9%, talcum powder 3.3%, toner 1.2%, zinc stearate 1.2%, first Phenylene diisocyanate 2.2%, manganese carbonate 0.7%, borax 0.6%.
The plastic-wood material is prepared via a method which:
(1) prepared by premix: wood powder is added in high mixer, with high-speed stirred 5 minutes of 1500~2500 revs/min, Wood powder humid control is 0.5% hereinafter, other each components are then respectively adding, by above-mentioned mixing by the hot mixing system discharging of batch mixer To cold mixing system, 40 DEG C are cooled to, premix is obtained;
(2) semi-finished product are granulated pellet preparation: by premix through parallel double-screw extruder extruding pelletization, technological temperature setting At 180~200 DEG C, it is to be used that pellet etc. is granulated as semi-finished product;
(3) prepared by extrusion molding: the particle after extruding pelletization is added to extrusion molding in conical double-screw, technological temperature 160~180 DEG C are set in, is squeezed out by mold to get finished product plastic-wood material is arrived.
Embodiment 4
A kind of plastic-wood material, the weight percent of each component are as follows: PP GRANULES 47.9%, wood powder 18.9%, methylol Sodium cellulosate 5.4%, copper acetate 5.1%, Tea Saponin 1.6%, talcum powder 4.8%, toner 0.8%, calcium stearate 0.8%, two Methylenebis phenyl isocyanate 1.5%, manganese chloride 0.5%, borax 0.2% mould the wooden reclaimed materials 12.5%.
The plastic-wood material is prepared via a method which:
(1) prepared by premix: wood powder is added in high mixer, with high-speed stirred 5 minutes of 1500~2500 revs/min, Wood powder humid control is 0.5% hereinafter, other each components are then respectively adding, by above-mentioned mixing by the hot mixing system discharging of batch mixer To cold mixing system, 40 DEG C are cooled to, premix is obtained;
(2) semi-finished product are granulated pellet preparation: by premix through parallel double-screw extruder extruding pelletization, technological temperature setting At 180~200 DEG C, it is to be used that pellet etc. is granulated as semi-finished product;
(3) prepared by extrusion molding: the particle after extruding pelletization is added to extrusion molding in conical double-screw, technological temperature 160~180 DEG C are set in, is squeezed out by mold to get finished product plastic-wood material is arrived.
Embodiment 5
A kind of plastic-wood material, the weight percent of each component are as follows: polyethylene particle 63.3%, wood powder 18.9%, methylol Sodium cellulosate 5.5%, copper acetate 2.9%, Tea Saponin 1.7%, talcum powder 3.4%, toner 0.9%, zinc stearate 0.9%, first Phenylene diisocyanate 1.6%, manganese carbonate 0.6%, borax 0.3%.
The plastic-wood material is prepared via a method which:
(1) prepared by premix: wood powder is added in high mixer, with high-speed stirred 5 minutes of 1500~2500 revs/min, Wood powder humid control is 0.5% hereinafter, other each components are then respectively adding, by above-mentioned mixing by the hot mixing system discharging of batch mixer To cold mixing system, 40 DEG C are cooled to, premix is obtained;
(2) semi-finished product are granulated pellet preparation: by premix through parallel double-screw extruder extruding pelletization, technological temperature setting At 180~200 DEG C, it is to be used that pellet etc. is granulated as semi-finished product;
(3) prepared by extrusion molding: the particle after extruding pelletization is added to extrusion molding in conical double-screw, technological temperature 160~180 DEG C are set in, is squeezed out by mold to get finished product plastic-wood material is arrived.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention Made any modifications, equivalent replacements, and improvements etc., should all be included in the protection scope of the present invention within mind and principle.
Beneficial effects of the present invention are further illustrated below by experimental data, and modeling wood is impregnated in water, after 72 hours Its weight is weighed again, measures its 72 hours water absorption rates;Using universal testing machine, the bending of hardness-testing device difference test product The mechanical property parameters such as performance, wear-resisting property;Comparative example is using plastic-wood material common in the market, the weight percent of component Are as follows: polyethylene particle 60%, wood powder 30%, talcum powder 4%, toner 12%, lubricant 2%, compatilizer 2%.
Test result is as shown in table 1 below:
Every test performance correlation data of 1 plastic-wood material of table
As it can be seen from table 1 plastic-wood material performance of the invention is substantially better than common plastic-wood material in the market.

Claims (6)

1. a kind of plastic-wood material, which is characterized in that the weight percent of each component are as follows: plastics 46.8~63.3%, wood powder 18.9 ~29.6%, sodium cellulose glycolate 5.4~9.7%, copper acetate 2.8~5.1%, Tea Saponin 1.6~1.9%, talcum powder 3.3 ~4.8%, toner 0.8~1.2%, lubricant 0.8~1.2%, compatilizer 1.5~2.2%, manganese compound 0.5~0.7%, Borax 0.2~0.6% moulds the wooden reclaimed materials 0~12.5%, total weight percent 100%.
2. plastic-wood material according to claim 1, which is characterized in that the weight percent of each component are as follows: plastics 51.4%, Wood powder 21.2%, sodium cellulose glycolate 6.3%, copper acetate 3.6%, Tea Saponin 1.8%, talcum powder 3.7%, toner 0.95%, lubricant 1.05%, compatilizer 1.9%, manganese compound 0.6%, borax 0.4%, the wooden reclaimed materials 7.1% of modeling.
3. plastic-wood material according to claim 1 or 2, which is characterized in that the lubricant is stearate.
4. plastic-wood material according to claim 1 or 2, which is characterized in that the compatilizer is isocyanates.
5. plastic-wood material according to claim 1 or 2, which is characterized in that the manganese compound is manganese chloride or manganese carbonate.
6. plastic-wood material according to claim 1 or 2, which is characterized in that the plastics are polyethylene particle or/and poly- third Alkene particle.
CN201811076653.2A 2018-09-14 2018-09-14 A kind of plastic-wood material Pending CN109294033A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811076653.2A CN109294033A (en) 2018-09-14 2018-09-14 A kind of plastic-wood material

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Application Number Priority Date Filing Date Title
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CN109294033A true CN109294033A (en) 2019-02-01

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110157205A (en) * 2019-04-18 2019-08-23 浙江长兴森大竹木制品有限公司 A kind of formula and production method based on resistance to deformation WPC composite material
CN111518408A (en) * 2020-05-30 2020-08-11 安徽春和明生环保新材料科技有限公司 Flame-retardant and weather-resistant reinforced resin-plastic-wood composite material
CN111534123A (en) * 2020-05-30 2020-08-14 安徽春和明生环保新材料科技有限公司 Preparation process for resin-plastic-wood composite material

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104804462A (en) * 2015-04-20 2015-07-29 青岛保利康新材料有限公司 Plastic wood material

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104804462A (en) * 2015-04-20 2015-07-29 青岛保利康新材料有限公司 Plastic wood material

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110157205A (en) * 2019-04-18 2019-08-23 浙江长兴森大竹木制品有限公司 A kind of formula and production method based on resistance to deformation WPC composite material
CN111518408A (en) * 2020-05-30 2020-08-11 安徽春和明生环保新材料科技有限公司 Flame-retardant and weather-resistant reinforced resin-plastic-wood composite material
CN111534123A (en) * 2020-05-30 2020-08-14 安徽春和明生环保新材料科技有限公司 Preparation process for resin-plastic-wood composite material

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Application publication date: 20190201

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