CN109293338A - A kind of negative ion antibiotic ceramic tile and its production technology - Google Patents
A kind of negative ion antibiotic ceramic tile and its production technology Download PDFInfo
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- CN109293338A CN109293338A CN201811066115.5A CN201811066115A CN109293338A CN 109293338 A CN109293338 A CN 109293338A CN 201811066115 A CN201811066115 A CN 201811066115A CN 109293338 A CN109293338 A CN 109293338A
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- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
- C04B33/1324—Recycled material, e.g. tile dust, stone waste, spent refractory material
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- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
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- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/628—Coating the powders or the macroscopic reinforcing agents
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- C04B35/628—Coating the powders or the macroscopic reinforcing agents
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- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
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- C03C2204/00—Glasses, glazes or enamels with special properties
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- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
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- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
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Abstract
The invention discloses a kind of negative ion antibiotic ceramic tiles, have used broken clay powder, diatom ooze and functional fibre cloth, can excite anion, kill bacterium, adjust temperature and humidity, also disclose its production method.The negative ion antibiotic ceramic tile, including idiosome, ground coat enamel and overglaze；The idiosome includes the component of following weight ratio: clay 18-23: sand 20-25: ceramic tile waste material 8-12: broken clay powder 0.2-0.5: diatomite 0.5-1: functional fibre cloth 2-3；The ground coat enamel includes the component of following weight ratio: clay 12-18: feldspar 15-20: quartzy 15-22: whiting 5-6: magnesium carbonate 5-6: nano silver 2-3: nano-titanium dioxide 2-3；The overglaze includes the component of following weight ratio: clay 10-12: feldspar 10-12: talcum 8-9: quartzy 3-4: nano silver 1-2: nano-titanium dioxide 1-2.
Description
Technical field
The present invention relates to ceramic tile field more particularly to a kind of negative ion antibiotic ceramic tile and its production technologies.
Background technique
Ceramic tile is with a long history, is metal oxide and half-metal oxide using fire resisting, by grinding, mixing, compacting,
The means such as glazing, sintering are prepared.
The quality of ceramic tile it is thick it is hard, wearability is high, but it is difficult to add other function substance, though be added to as
Itself structure is difficult to play a role.
How the novel ceramic tile for having different operational characteristiies is researched and developed on the basis of existing ceramic tile, be those skilled in the art
Member is badly in need of one of the direction of research and development.
Summary of the invention
The invention discloses a kind of negative ion antibiotic ceramic tiles, have used broken clay powder, diatom ooze and functional fibre cloth, can be with
Anion is excited, bacterium is killed, adjusts temperature and humidity, also discloses its production method.
A kind of negative ion antibiotic ceramic tile provided by the invention, including idiosome, ground coat enamel and overglaze；
The idiosome includes the component of following weight ratio:
Clay 18-23: sand 20-25: ceramic tile waste material 8-12: broken clay powder 0.2-0.5: diatomite 0.5-1: functional fibre cloth
2-3；
The ground coat enamel includes the component of following weight ratio:
Clay 12-18: feldspar 15-20: quartzy 15-22: whiting 5-6: magnesium carbonate 5-6: nano silver 0.05-0.1: nanometer
Titanium dioxide 0.05-0.15；
The overglaze includes the component of following weight ratio:
Clay 10-12: feldspar 10-12: talcum 8-9: quartzy 3-4: nano silver 0.05-0.1: nano-titanium dioxide 0.05-
0.15。
Preferably, the functional fibre cloth is nano silver fibre cloth and/or nanometer titanium dioxide fiber cloth.
The present invention provides a kind of production technologies of negative ion antibiotic ceramic tile, prepare negative ion antibiotic porcelain described above
Brick, comprising the following steps:
A, it prepares functional fibre cloth: being mixed with by functional materials and fiber cloth；
B, idiosome component: clay, sand, ceramic tile waste material, broken clay powder and diatomite is taken, after crushing plus suitable quantity of water stirs, and one
While being added to mold is uniformly sprinkled into functional fibre cloth on one side, form, idiosome is made in sintering；
Wherein, the weight ratio of idiosome component are as follows: clay 18-23: sand 20-25: ceramic tile waste material 8-12: broken clay powder 0.2-
0.5: diatomite 0.5-1: functional fibre cloth 2-3；
C, ground coat enamel component: clay, feldspar, quartz, whiting, magnesium carbonate is taken, is crushed, is added suitable quantity of water to stir, stir on one side
Nano silver and nano-titanium dioxide are added on one side, obtains glaze, to idiosome glaze spraying, sintering, ground coat enamel preparation is completed；
Wherein, the weight ratio of ground coat enamel component are as follows: clay 12-18: feldspar 15-20: quartzy 15-22: whiting 5-6: carbonic acid
Magnesium 5-6: nano silver 0.05-0.1: nano-titanium dioxide 0.05-0.15；
D, overglaze component: clay, feldspar, talcum and quartz is taken, is crushed, is added suitable quantity of water to stir, be added while stirring
Nano silver and nano-titanium dioxide, obtain glaze, and to the idiosome glaze spraying Jing Guo step B, sintering, overglaze preparation is completed；
The weight ratio of overglaze component: clay 10-12: feldspar 10-12: talcum 8-9: quartzy 3-4: nano silver 0.05-0.1:
Nano-titanium dioxide 0.05-0.15.
Preferably, described in step A prepares functional fibre cloth are as follows: prepares nano silver fibre cloth and/or preparation nanometer two
Titanium dioxide fiber cloth.
Preferably, the functional fibre cloth includes the nano silver fibre cloth and the nanometer titanium dioxide fiber cloth, institute
The weight ratio for stating nano silver fibre cloth and the nanometer titanium dioxide fiber cloth is 1:3.
Preferably, the functional fibre cloth is nano silver fibre cloth, and the nano silver fibre cloth for preparing of the step A specifically walks
Suddenly are as follows:
A101: taking neopelex, polyoxyethylene sorbitan monooleate, sodium metasilicate and partial size is 20-
The nano silver of 100nm mixes, and is placed in pure water ultrasonic high-speed stirred dispersion 1-3h, puts into high temperature glue, mixing is mixed
Material；
A102: debris cloth is added to the mixed material, the size of the debris cloth is 1*5mm~1*8mm；
A103: filtering takes debris cloth to dry, spare；
Wherein, neopelex, polyoxyethylene sorbitan monooleate, sodium metasilicate, pure water and nanometer
The weight ratio of silver are as follows: 0.2-0.8:1.5-3:0.3-0.6:100:6.
Preferably, the functional fibre cloth is nanometer titanium dioxide fiber cloth, and the step A's prepares nano-titanium dioxide
Fiber cloth specific steps are as follows:
A201, it takes partial size to be placed in weakly alkaline pure water for the nano-titanium dioxide of 10-60nm, stirs 15 minutes, surpass
Sound pitch speed is dispersed with stirring 1-2h, and neopelex, ultrasonic 30-60min is added；
A202, high temperature glue is added, mixing obtains mixed material；
A203, debris cloth is added to the mixed material, the size of the debris cloth is 1*5mm~1*8mm；
A204, filtering take debris cloth to dry, spare；
Wherein, the weight ratio of nano-titanium dioxide, neopelex and pure water is 20-35:1.5:100.
Preferably, the high temperature glue is inorganic high-temp glue.
Preferably, the partial size of the nano silver is 20-100nm, and the partial size of the nano-titanium dioxide is 20-80nm.
Preferably, the pH value of the weakly alkaline pure water is 7.8-8.5.
Negative ion antibiotic ceramic tile of the invention and its production technology, idiosome have used broken clay powder, diatom ooze and function fine
Wei Bu.Broken clay powder will form hole, when ceramic tile and air contact, hole can save the water in air after high temperature firing
Point；Peculiar smell can be absorbed in diatomite, and porous quality can also absorb moisture, adjusts humidity.Nano silver is added in ground coat enamel and overglaze
And nano-titanium dioxide, by moisture and air that the hole of idiosome provides, excitation generates antibacterial functions and excitation air is formed
Anion.
Further, functional fibre cloth is nano silver fibre cloth and/or nanometer titanium dioxide fiber cloth, nano silver fibre cloth
When being added to idiosome with nanometer titanium dioxide fiber cloth, the unique toughness having can be used as the toughness of glutinous agent enhancing ceramic tile,
Moisture and air, excitation fiber cloth can also be provided by the hole that broken clay powder is formed and the porous quality that diatomite is formed
On nano silver and nano-titanium dioxide have an effect, then be dissipated into air by the gap on ceramic tile periphery.
Specific embodiment
The invention discloses a kind of negative ion antibiotic ceramic tiles, including idiosome, ground coat enamel and overglaze；
The idiosome includes the component of following weight ratio:
Clay 18-23: sand 20-25: ceramic tile waste material 8-12: broken clay powder 0.2-0.5: diatomite 0.5-1: functional fibre cloth
2-3；
The ground coat enamel includes the component of following weight ratio:
Clay 12-18: feldspar 15-20: quartzy 15-22: whiting 5-6: magnesium carbonate 5-6: nano silver 0.05-0.1: nanometer
Titanium dioxide 0.05-0.15；
The overglaze includes the component of following weight ratio:
Clay 10-12: feldspar 10-12: talcum 8-9: quartzy 3-4: nano silver 0.05-0.1: nano-titanium dioxide 0.05-
0.15。
The functional fibre cloth is nano silver fibre cloth and/or nanometer titanium dioxide fiber cloth.
It should be noted that clay, sand, ceramic tile waste material, feldspar, quartz, whiting, magnesium carbonate, cunning that the present invention uses
The substances such as stone, it is essentially identical with the material composition of the prior art, therefore not burdensome its structural constituent of explanation situations such as.Wherein, such as
Clay is included there are many component substances, it is also possible to comprising quartz, but not collided with the quartz of foregoing description, the corresponding weight of the two
It is not complementary subject to amount is described according to said components, illustrate hereby.
Broken clay powder, specifically, can form hole in combustion at broken shape structure after clay crushing, water can be absorbed
Point and gas, adjust indoor temperature and humidity.Its main component be hydromica, kaolinite, montmorillonite, quartz and feldspar, structure with
Ingredient needed for traditional ceramic tile is similar, therefore has used broken clay powder, can provide substance needed for ceramic tile, moreover it is possible to make the embryo of ceramic tile
Body forms a small amount of novel hole configurationss, neither influences the structure and hardness of ceramic tile in this way, can also absorb moisture.
Diatomite can also form porous quality, and pore structure is small, can also absorb moisture, while it can also eliminate peculiar smell, point
Solve harmful chemical substance.
The above-mentioned hole formed through broken clay powder and diatomite, gap, are all small or extremely small, and pass through base
After the mixing compacting of body raw material, broken clay powder and diatomite are evenly distributed, and the hole gap of formation is evenly distributed, such structure
The hardness of ceramic tile will not be impacted substantially, along with the structure of fiber cloth, effectively enhance the toughness of ceramic tile, it is empty to offset hole
Gap is possible to bring minor impact.
Fiber cloth, also known as carbon fiber sheet, have very high strength, light weight, and high temperature high voltage resistant adds functional materials
Functional fibre cloth can be used as binder/glutinous agent, enhance the toughness and cementability of ceramic tile idiosome.
Nano silver fibre cloth and/or nanometer titanium dioxide fiber cloth can be used in functional fibre cloth, preferably uses simultaneously
Nano silver fibre cloth and nanometer titanium dioxide fiber cloth, weight ratio 1:3.Nano silver fibre cloth and nanometer titanium dioxide fiber cloth
It can be prepared according to following processes.
Nano silver fibre cloth, since it adheres to nano silver, nano silver is to the number such as Escherichia coli, gonococcus, chlamydia trachomatis
Ten kinds of pathogenic microorganisms have strong inhibition and killing effect, and will not generate drug resistance, can effectively antibacterial degerming,
The following concrete technology of preparation method is visible.
Nano silver fibre cloth is stained with nano silver for fiber cloth, ceramic tile in air, with the substance (such as bacterium) in air
Be in contact or air in substance can also be fallen into the hole inside idiosome by gap, at this point, nano silver fibre is distributed with
The ceramic tile idiosome of cloth can then be reacted with large area and the substance in air, the structure of matter be destroyed, to kill the objects such as bacterium
Matter.Since nano silver of the invention is by processing, it is less likely to occur to reunite in water, therefore the quality of nano silver is not readily susceptible to
It influences, activity can be kept for a long time.
Nanometer titanium dioxide fiber cloth, since it adheres to nano-titanium dioxide, nano-titanium dioxide is a kind of antibacterial agent, also
Energy oxygenolysis harmful substance, and it is harmless to the human body.
Nanometer titanium dioxide fiber cloth is stained with nano-titanium dioxide for fiber cloth, ceramic tile in air, with the object in air
Matter (such as pollutant, bacterium, pernicious gas) be in contact or air in substance can also be fallen into inside idiosome by gap
In hole, at this point, the ceramic tile idiosome of nanometer titanium dioxide fiber cloth, which is distributed with, to react with the substance.
After absorbing luminous energy due to nano-titanium dioxide, particle surface electronics is activated, and positively charged structure is generated, with aqueous vapor
Contact can generate active oxygen and hydroxyl free radical, and therefore, what nanometer titanium dioxide carbon cloth and above-mentioned substance occurred react can be with
Pollutant, bacterium, oxidation operation are resolved into harmless carbon dioxide and water.
In the present invention, the aqueous vapor of hole storage provides aqueous vapor power for nano-titanium dioxide, is transmitted by ceramic tile gap
Luminous energy provide luminous energy power for nano-titanium dioxide so that nano-titanium dioxide reacts with harmful substance, generate
Innocuous substance；Meanwhile hydroxyl free radical is contacted with air, takes away the positive electron of oxygen, formed negative aeroion (i.e. negative oxygen from
Son).Anion has calmness, analgesia, antibechic, antipruritic, diuresis, increases the benefits of appetite, blood pressure lowering, is easy to make us feeling happy.
What the effect of nano silver and nano-titanium dioxide as can be seen from the above description, ground coat enamel of the invention and overglaze used receives
Meter Yin and nano-titanium dioxide are the structures due to ground coat enamel and overglaze and thick not as good as idiosome, both is easy and ceramic tile table
The air and substance in face react, and glaze be not be fully sealed/it is closed, slight void can be passed to air and
Small substance, while overglaze tells on, ground coat enamel can also tell on.
Further, ground coat enamel is connect with idiosome, and the hole hole of idiosome can be the nano-titanium dioxide of ground coat enamel and receive
The harmful substance that rice silver provides power and need to handle effectively improves purification degerming speed.
The present invention also provides a kind of production technologies of negative ion antibiotic ceramic tile, prepare negative ion antibiotic porcelain described above
Brick, comprising the following steps:
A, it prepares functional fibre cloth: being mixed with by functional materials and fiber cloth；
B, idiosome component: clay, sand, ceramic tile waste material, broken clay powder and diatomite is taken, after crushing plus suitable quantity of water stirs, and one
While being added to mold is uniformly sprinkled into functional fibre cloth on one side, form, idiosome is made in sintering；
Wherein, the weight ratio of idiosome component are as follows: clay 18-23: sand 20-25: ceramic tile waste material 8-12: broken clay powder 0.2-
0.5: diatomite 0.5-1: functional fibre cloth 2-3；
C, ground coat enamel component: clay, feldspar, quartz, whiting, magnesium carbonate is taken, is crushed, is added suitable quantity of water to stir, stir on one side
Nano silver and nano-titanium dioxide are added on one side, obtains glaze, to idiosome glaze spraying, sintering, ground coat enamel preparation is completed；
Wherein, the weight ratio of ground coat enamel component are as follows: clay 12-18: feldspar 15-20: quartzy 15-22: whiting 5-6: carbonic acid
Magnesium 5-6: nano silver 0.05-0.1: nano-titanium dioxide 0.05-0.15；
D, overglaze component: clay, feldspar, talcum and quartz is taken, is crushed, is added suitable quantity of water to stir, be added while stirring
Nano silver and nano-titanium dioxide, obtain glaze, and to the idiosome glaze spraying Jing Guo step B, sintering, overglaze preparation is completed；
The weight ratio of overglaze component: clay 10-12: feldspar 10-12: talcum 8-9: quartzy 3-4: nano silver 0.05-0.1:
Nano-titanium dioxide 0.05-0.15.
Above-mentioned formed suitable quantity of water, can deploy according to prior art purpose and be set, those skilled in the art are equal
It is known, not burdensome explanation herein.
Preferably, described in step A prepares functional fibre cloth are as follows: prepares nano silver fibre cloth and/or preparation nanometer two
Titanium dioxide fiber cloth.
Preferably, the functional fibre cloth includes the nano silver fibre cloth and the nanometer titanium dioxide fiber cloth, institute
The weight ratio for stating nano silver fibre cloth and the nanometer titanium dioxide fiber cloth is 1:3.
The structure of fiber cloth can increase viscosity for green body, can substitute a small amount of clay in certain degree, moreover it is possible to increase for idiosome
Toughness.
Preferably, the functional fibre cloth is nano silver fibre cloth, and the nano silver fibre cloth for preparing of the step A specifically walks
Suddenly are as follows:
A101: neopelex (SDBS), polyoxyethylene sorbitan monooleate (Tween 80), silicic acid are taken
Sodium (Na2SiO3·9H2O it) is mixed with partial size for the nano silver of 20-100nm, is placed in pure water ultrasonic high-speed stirred dispersion 1-
3h, puts into high temperature glue, and mixing obtains mixed material；
A102: debris cloth is added to the mixed material, the size of the debris cloth is 1*5mm~1*8mm；
A103: filtering takes debris cloth to dry, spare；
Wherein, neopelex, polyoxyethylene sorbitan monooleate, sodium metasilicate, pure water and nanometer
The weight ratio of silver are as follows: 0.2-0.8:1.5-3:0.3-0.6:100:6.
More a step is said: neopelex, sodium metasilicate, pure water, is received polyoxyethylene sorbitan monooleate
The weight ratio of meter Yin and high temperature glue are as follows: 0.2-0.8:1.5-3:0.3-0.6:100:6:5-10.
Preferably, the high temperature glue is inorganic high-temp glue.
Inorganic high-temp glue generally can achieve 500-1750 DEG C, mainly be made of inorganic nano material through polycondensation reaction, pH
Value is neutrality, can be used for the bonding of ceramics etc..
The so-called inorganic high-temp glue of the present invention can choose inorganic high-temp glue available on the market, as long as making nano silver viscous
It on debris cloth, realizes that it is sprinkled into the mold for preparing idiosome, therefore does not limit the manufacturer etc. of inorganic high-temp glue selection herein
Element.
Preferably, the functional fibre cloth is nanometer titanium dioxide fiber cloth, and the step A's prepares nano-titanium dioxide
Fiber cloth specific steps are as follows:
A201, it takes partial size to be placed in weakly alkaline pure water for the nano-titanium dioxide of 10-60nm, stirs 15 minutes, surpass
Sound pitch speed is dispersed with stirring 1-2h, and neopelex, ultrasonic 30-60min is added；
A202, high temperature glue is added, mixing obtains mixed material；
A203, debris cloth is added to the mixed material, the size of the debris cloth is 1*5mm~1*8mm；
A204, filtering take debris cloth to dry, spare；
Wherein, the weight ratio of nano-titanium dioxide, neopelex and pure water is 20-35:1.5:100.
Wherein, the weight ratio of nano-titanium dioxide, neopelex, pure water and high temperature glue is 20-35:
1.5:100:5-10.
Above-mentioned to prepare in nano silver fibre cloth and nanometer titanium dioxide fiber cloth, pure water can also select deionized water.
Debris cloth is preferably rectangular configuration, or close with rectangular configuration, and length and width are 1*5mm~1*8mm.
Preferably, the partial size of the nano silver is 20-100nm, and the partial size of the nano-titanium dioxide is 20-80nm.
Preferably, the pH value of the weakly alkaline pure water is 7.8-8.5.
As it can be seen that negative ion antibiotic ceramic tile of the invention and its production technology, idiosome has used broken clay powder, diatom ooze and function
It can fiber cloth.Broken clay powder will form hole, when ceramic tile and air contact, hole can be saved in air after high temperature firing
Moisture；Peculiar smell can be absorbed in diatomite, and porous quality can also absorb moisture, adjusts humidity.It is received in ground coat enamel and overglaze addition
Meter Yin and nano-titanium dioxide, by moisture and air that the hole of idiosome provides, excitation generates antibacterial functions and excitation air
Form anion.
Further, functional fibre cloth is nano silver fibre cloth and/or nanometer titanium dioxide fiber cloth, nano silver fibre cloth
When being added to idiosome with nanometer titanium dioxide fiber cloth, the unique toughness having can be used as the toughness of glutinous agent enhancing ceramic tile,
Moisture and air, excitation fiber cloth can also be provided by the hole that broken clay powder is formed and the porous quality that diatomite is formed
On nano silver and nano-titanium dioxide have an effect, then be dissipated into air by the gap on ceramic tile periphery.
Below bySpecific embodimentIt is described:
The production technology of negative ion antibiotic ceramic tile, comprising the following steps:
A, functional fibre cloth is prepared:
A1: nano silver fibre cloth is prepared:
A101, weight ratio is taken to be the polyethenoxy sorbitan list of the neopelex of 0.2-0.8,1.5-3
Oleate, the sodium metasilicate of 0.3-0.6 and 6 partial size be 20-100nm nano silver mix, be placed in weight ratio be 100 pure water
Middle ultrasound high-speed stirred disperses 1-3h, puts into the high temperature glue of 5-10, mixes, obtain mixed material；
A102, debris cloth is added to the mixed material, the size of the debris cloth is 1*5mm~1*8mm；
A103, filtering take debris cloth to dry, spare；
A2: nanometer titanium dioxide fiber cloth is prepared:
The nano-titanium dioxide that A201, the partial size for taking weight ratio to be 20-35 are 10-60nm is placed in weakly alkaline weight ratio
It in 100 pure water, stirs 15 minutes, ultrasonic high-speed stirred disperses 1-2h, and the dodecyl benzene sulfonic acid that weight ratio is 1.5 is added
Sodium, ultrasonic 30-60min；
A202, the high temperature glue that weight ratio is 5-10 is added, mixing obtains mixed material；
A203, debris cloth is added to the mixed material, the size of the debris cloth is 1*5mm~1*8mm；
A204, filtering take debris cloth to dry, spare.
B, take idiosome component, calculated with weight ratio: the clay of 18-23, the sand of 20-25,8-12 ceramic tile waste material, 0.2-
The diatomite of 0.5 broken clay powder and 0.5-1, after crushing plus suitable quantity of water stirs, and uniformlys while being added to mold and is sprinkled into weight
Amount is formed than the above-mentioned functional fibre cloth (ratio of nano silver fibre cloth and nanometer titanium dioxide fiber cloth is 1:3) for 2-3,
Idiosome is made in sintering；
C, take ground coat enamel component, calculated with weight ratio: the clay of 12-18, the feldspar of 15-20, the quartz of 15-22,5-6 it is white
The magnesium carbonate of chalk powder, 5-6, crush, add suitable quantity of water to stir, is added while stirring weight ratio be 0.05-0.1 nano silver with
Weight ratio is the nano-titanium dioxide of 0.05-0.15, obtains glaze, and to idiosome glaze spraying, sintering, ground coat enamel preparation is completed；
D, overglaze component is taken, is calculated with weight ratio: the clay of 10-12, the feldspar of 10-12, the talcum of 8-9 and the stone of 3-4
English crushes, suitable quantity of water is added to stir, and it is the nano silver of 0.05-0.1 and receiving for 0.05-0.15 that weight ratio is added while stirring
Rice titanium dioxide, obtains glaze, and to the idiosome glaze spraying Jing Guo step B, sintering, overglaze preparation is completed.
Negative ion antibiotic ceramic tile of the present invention is made as a result,.
It is described in detail below by specific embodiment:
Embodiment 1
The production technology of negative ion antibiotic ceramic tile, comprising the following steps:
A, functional fibre cloth is prepared:
A1: nano silver fibre cloth is prepared:
A101, the neopelex for taking 50g, the polyoxyethylene sorbitan monooleate of 200g, 50g silicon
The partial size of sour sodium and 600g are the nano silver of 30nm, and mixing is placed in 10KG pure water ultrasonic high-speed stirred dispersion 2h, investment
The high temperature glue of 800g, mixing, obtains mixed material；
A102, debris cloth is added to the mixed material, the size of debris cloth is 1*5mm~1*8mm；
A103, filtering take debris cloth to dry, spare；
A2: nanometer titanium dioxide fiber cloth is prepared:
A201, the nano-titanium dioxide for taking 2Kg partial size to be 30nm are placed in the 10Kg pure water that pH value is 8.0, stirring 10
Minute, ultrasonic high-speed stirred disperses 2h, and 150g neopelex, ultrasonic 60min is added；
A202, the high temperature glue that 800g is added, mixing, obtain mixed material；
A203, debris cloth is added to mixed material, the size of debris cloth is 1*5mm~1*8mm；
A204, filtering take debris cloth to dry, spare.
B, idiosome component, 20Kg clay, 20Kg sand, 10Kg ceramic tile waste material, the broken clay powder of 0.5Kg and 1Kg diatomite, powder are taken
After broken plus suitable quantity of water stirs, and uniformlys while being added to mold and is sprinkled into functional fibre cloth, according to said components (clay, sand, porcelain
Brick waste material, broken clay powder and diatomite): functional fibre cloth=20:1 ratio is launched, and is formed, and idiosome is made in sintering.
Wherein, the ratio of nano silver fibre cloth and nanometer titanium dioxide fiber cloth is 1:3.
C, ground coat enamel component is taken,
18Kg clay, 15Kg feldspar, 20Kg quartz, 5Kg whiting, 5Kg magnesium carbonate crush, suitable quantity of water are added to stir, on one side
0.1Kg nano silver and 0.15Kg nano-titanium dioxide is added in stirring on one side, obtains glaze, to idiosome glaze spraying, sintering, ground coat enamel preparation
It completes；
D, overglaze component is taken, 10Kg clay, 12Kg feldspar, 8Kg talcum and 3Kg quartz crush, suitable quantity of water are added to stir, and one
It is 0.1Kg nano silver and 0.15Kg nano-titanium dioxide that weight ratio, which is added, in side stirring on one side, obtains glaze, to by step B
Idiosome glaze spraying, sintering, overglaze preparation are completed.
Negative ion antibiotic ceramic tile of the present invention is made as a result,.
The present embodiment 1 is that the ingredient and dosage based on " specific embodiment " are tested, if any clerical mistake then with specific implementation
Subject to example.
Embodiment 2
The present embodiment 2 is substantially the same manner as Example 1, unlike:
B, the broken clay powder of 18Kg clay, 0.2Kg and 0.5Kg diatomite, according to said components (clay, sand, ceramic tile waste material,
Broken clay powder and diatomite): functional fibre cloth=16:1 ratio is launched, and is formed, and idiosome is made in sintering.
Embodiment 3
The present embodiment 3 is substantially the same manner as Example 1, unlike
B, the broken clay powder of 18Kg clay, 0.2Kg and 0.5Kg diatomite, according to said components (clay, sand, ceramic tile waste material,
Broken clay powder and diatomite): functional fibre cloth=30:1 ratio is launched, and is formed, and idiosome is made in sintering.
From embodiment 1-3 as it can be seen that using embodiment 1 as basic embodiment, embodiment 2 reduces the weight of clay, increases
The ratio of functional fibre cloth, embodiment 3 reduce the weight of clay, reduce the ratio of functional fibre cloth, by embodiment 1-3
Obtained ceramic tile is compared:
1, judge by impact strength the toughness of ceramic tile: the toughness of embodiment 2 is most strong, and embodiment 1 is taken second place, embodiment
3 toughness is minimum；
2, using Bactericidal test, the ceramic tile of embodiment 1-3 is cut into fritter, chooses the identical ceramic tile of weight, every reality
Apply example choose 2, be respectively put into 6 simultaneously culture inhibition zone in, observe antibacterial situation, static 10 days, embodiment 1 and implementation
The antibacterial situation of example 2 is essentially optimal, and sterilization purification ability is strong.
As it can be seen that the ceramic tile prepared through the invention, can enhance toughness, antibacterial sterilizing and the purification air of ceramic tile.
Above-mentioned technical solution in the embodiment of the present invention carries out clear and detailed description, it is clear that described implementation
Example is only a part of the embodiments of the present invention, rather than whole embodiments.Based on the embodiments of the present invention, this field is common
Technical staff's all other embodiment obtained without making creative work belongs to the model that the present invention protects
It encloses.
Claims (10)
1. a kind of negative ion antibiotic ceramic tile, which is characterized in that including idiosome, ground coat enamel and overglaze；
The idiosome includes the component of following weight ratio:
Clay 18-23: sand 20-25: ceramic tile waste material 8-12: broken clay powder 0.2-0.5: diatomite 0.5-1: functional fibre cloth 2-3；
The ground coat enamel includes the component of following weight ratio:
Clay 12-18: feldspar 15-20: quartzy 15-22: whiting 5-6: magnesium carbonate 5-6: nano silver 0.05-0.1: nano-silica
Change titanium 0.05-0.15；
The overglaze includes the component of following weight ratio:
Clay 10-12: feldspar 10-12: talcum 8-9: quartzy 3-4: nano silver 0.05-0.1: nano-titanium dioxide 0.05-0.15.
2. negative ion antibiotic ceramic tile according to claim 1, which is characterized in that the functional fibre cloth is nano silver fibre
Cloth and/or nanometer titanium dioxide fiber cloth.
3. a kind of production technology of negative ion antibiotic ceramic tile, which is characterized in that it is anti-to prepare anion of any of claims 1 or 2
Bacterium ceramic tile, comprising the following steps:
A, it prepares functional fibre cloth: being mixed with by functional materials and fiber cloth；
B, idiosome component: clay, sand, ceramic tile waste material, broken clay powder and diatomite is taken, after crushing plus suitable quantity of water stirs, and adds on one side
It adds to mold and is uniformly sprinkled into functional fibre cloth on one side, form, idiosome is made in sintering；
Wherein, the weight ratio of idiosome component are as follows: clay 18-23: sand 20-25: ceramic tile waste material 8-12: broken clay powder 0.2-0.5: silicon
Diatomaceous earth 0.5-1: functional fibre cloth 2-3；
C, take ground coat enamel component: clay, feldspar, quartz, whiting, magnesium carbonate, crush, suitable quantity of water is added to stir. while stirring
Nano silver and nano-titanium dioxide is added, obtains glaze, to idiosome glaze spraying, sintering, ground coat enamel preparation is completed；
Wherein, the weight ratio of ground coat enamel component are as follows: clay 12-18: feldspar 15-20: quartzy 15-22: whiting 5-6: magnesium carbonate 5-
6: nano silver 0.05-0.1: nano-titanium dioxide 0.05-0.15；
D, overglaze component: clay, feldspar, talcum and quartz is taken, is crushed, is added suitable quantity of water to stir, nanometer is added while stirring
Silver and nano-titanium dioxide, obtain glaze, and to the idiosome glaze spraying Jing Guo step B, sintering, overglaze preparation is completed；
The weight ratio of overglaze component: clay 10-12: feldspar 10-12: talcum 8-9: quartzy 3-4: nano silver 0.05-0.1: nanometer
Titanium dioxide 0.05-0.15.
4. the production technology of negative ion antibiotic ceramic tile according to claim 3, which is characterized in that the system in step A
Standby functional fibre cloth are as follows: prepare nano silver fibre cloth and/or prepare nanometer titanium dioxide fiber cloth.
5. the production technology of negative ion antibiotic ceramic tile according to claim 4, which is characterized in that the functional fibre cloth bag
Include the nano silver fibre cloth and the nanometer titanium dioxide fiber cloth, the nano silver fibre cloth and the nano-titanium dioxide
The weight ratio of fiber cloth is 1:3.
6. the production technology of negative ion antibiotic ceramic tile according to claim 4, which is characterized in that the functional fibre cloth is
Nano silver fibre cloth, the step A's prepares nano silver fibre cloth specific steps are as follows:
A101: taking neopelex, polyoxyethylene sorbitan monooleate, sodium metasilicate and partial size is 20-100nm
Nano silver mixing, be placed in pure water ultrasonic high-speed stirred dispersion 1-3h, put into high temperature glue, mixing obtains mixed material；
A102: debris cloth is added to the mixed material, the size of the debris cloth is 1*5mm~1*8mm；
A103: filtering takes debris cloth to dry, spare；
Wherein, neopelex, polyoxyethylene sorbitan monooleate, sodium metasilicate, pure water and nano silver
Weight ratio are as follows: 0.2-0.8:1.5-3:0.3-0.6:100:6.
7. the production technology of negative ion antibiotic ceramic tile according to claim 4, which is characterized in that the functional fibre cloth is
Nanometer titanium dioxide fiber cloth, the step A's prepares nanometer titanium dioxide fiber cloth specific steps are as follows:
A201, it takes partial size to be placed in weakly alkaline pure water for the nano-titanium dioxide of 10-60nm, stirs 15 minutes, ultrasound is high
Speed is dispersed with stirring 1-2h, and neopelex, ultrasonic 30-60min is added；
A202, high temperature glue is added, mixing obtains mixed material；
A203, debris cloth is added to the mixed material, the size of the debris cloth is 1*5mm~1*8mm；
A204, filtering take debris cloth to dry, spare；
Wherein, the weight ratio of nano-titanium dioxide, neopelex and pure water is 20-35:1.5:100.
8. according to right want 6 or 7 described in negative ion antibiotic ceramic tile production technology, which is characterized in that the high temperature glue is
Inorganic high-temp glue.
9. the production technology of the negative ion antibiotic ceramic tile according to any one of claim 3-7, which is characterized in that described
The partial size of nano silver is 20-100nm, and the partial size of the nano-titanium dioxide is 20-80nm.
10. the production technology of negative ion antibiotic ceramic tile according to claim 7, which is characterized in that described weakly alkaline pure
The pH value of water purification is 7.8-8.5.
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