CN109292991A - A kind of research method of difference floating bed filler purifying water effect - Google Patents

A kind of research method of difference floating bed filler purifying water effect Download PDF

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CN109292991A
CN109292991A CN201811295088.9A CN201811295088A CN109292991A CN 109292991 A CN109292991 A CN 109292991A CN 201811295088 A CN201811295088 A CN 201811295088A CN 109292991 A CN109292991 A CN 109292991A
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floating bed
water
water body
haydite
medical stone
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胡海波
王梅娟
范真
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Nanjing Forestry University
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/32Biological treatment of water, waste water, or sewage characterised by the animals or plants used, e.g. algae
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/0098Plants or trees
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/18Water
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    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/105Phosphorus compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/16Nitrogen compounds, e.g. ammonia
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/16Nitrogen compounds, e.g. ammonia
    • C02F2101/163Nitrates
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • C02F2101/38Organic compounds containing nitrogen

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Abstract

The invention discloses a kind of research method of different floating bed filler purifying water effects, this method has studied three kinds of different rich nutrition level water bodys: middle eutrophy, eutrophy, in weight eutrophy, floating bed filler: rice hull carbon, medical stone, haydite are to the clean-up effect of water quality.The result shows that rice hull carbon is to TN, NH in middle rich nutrition level water body4 +‑N、NO3 The removal effect of-N is better than medical stone and haydite;And to the removal effect of TP, haydite is substantially better than medical stone and rice hull carbon.From the point of view of the upgrowth situation of floating bed plant, in middle rich nutrition level and rich nutrition level water body, rice husk carbon filling material floating bed is substantially better than other two kinds of fillers.No matter purify water or plant growth should not use biological floating bed in weight eutrophic water body.Studying the different floating bed fillers effect that purifies water with to the shadow of plant growth can effectively instruct waste water control, and builds for wetlands ecosystems and provide scientific basis.

Description

A kind of research method of difference floating bed filler purifying water effect
Technical field
The invention belongs to floating bed studying technological domains, are related to a kind of research method of different floating bed filler purifying water effects, tool It says to body, is related to a kind of research method of different floating bed filler purifying water effects in different rich nutrition level water bodys.
Background technique
" China Environmental State Bulletin in 2015 " promulgated according to State Ministry of Environmental Protection: national surface water is generally slight dirty Dye, but water eutrophication outstanding problem.The state of the seven major basins such as the Changjiang river, the Yellow River, the Zhujiang River, Song Hua River, Huaihe River, Haihe River, the Liaohe River It controls in section, IV-V class and bad V class water quality section ratio reach 20.9% and 10.2%.In 60 lakes (reservoir) of monitoring In, eutrophic state accounts for 25.0%.It can be seen that the river of China, lake pollution constantly aggravate, eutrophication problem is outstanding It for protrusion, and is in continuous development trend.
The phenomenon that eutrophication is a kind of water body aging refers to that the enrichment in lake, reservoir and river water nitrogen and phosphorous nutrient is existing As.Its essence is the input and output due to nutriment are unbalance, the balance of water ecosystem broken, has destroyed its substance and follow Ring and energy flow cause the entire ecosystem gradually to move towards to wither away.Since the mankind's activities such as urbanization, industrialization aggravate, lake Eutrophication process can occur in recent years for pool (reservoir), not only bring about great losses to social economy, also can be to human body Health causes to seriously endanger, therefore extremely urgent to the improvement of eutrophic water body.Currently, the control and management of eutrophication water Measure mainly has physical method, chemical method and biological method.The above two cut both ways, not only at high cost, can also generate two Secondary pollution.Biological method mainly includes microorganism remediation, water plant is repaired and aquatic animal is repaired, wherein phytoremediation safety Property and stability are significantly larger than microorganism and animal reparation.
In order to build preferably landscape effect, planting type of the plant in water body is mostly artificial floating bed.Artificial floating bed Be people is planted in large-scale hygrophyte on floating bed carrier using cultivation technique without soil, bubble through the water column on, pass through plant root Absorption and sorption effect, cut down eutrophic water body in nitrogen, phosphorus and organic substance, rebuild in finite region and restore Ecology System, and water body is moved away from by harvesting plant, to reach purifying water effect, while building superaqual landscape.Research both at home and abroad Prove, it is biological floating bed have it is pollution-free, make full use of water surface space, effect stability, material source is wide, the advantages that being easily assembled to. However, the deeply popularization with application, some defects of floating bed with floating bed technical research are also more and more obvious, plant growth mistake It is withered and rotten to occur because of pest and disease damage or Catastrophe climate blade in journey, if mustn't go to timely cleaning, will generate secondary Pollution.The study found that hand-stuff is applied to biological floating bed, it is a kind of universal, feasible and practical technical measures, has good Good purifying water effect.But biological floating bed applicable situation, using effect are indefinite, cause huge waste in production practice, It is necessary to understand fully its research method.
Summary of the invention
It is an object of the present invention to propose a kind of research method of different floating bed filler purifying water effects, three kinds are had studied In different rich nutrition level water bodys (middle eutrophy, eutrophy, weight eutrophy), floating bed filler (rice hull carbon, medical stone, haydite) is right The clean-up effect of water quality.The result shows that (1), in terms of purifying water effect, in middle rich nutrition level water body, rice hull carbon is to TN, NH4 +- N、NO3 -The removal effect of-N is better than medical stone and haydite;And to the removal effect of TP, haydite is substantially better than medical stone and rice husk Charcoal.In rich nutrition level and weight rich nutrition level water body, the purifying water effect of filler floating bed does not have clear superiority.(2) in plant Growth aspect, in middle rich nutrition level and rich nutrition level water body, the upgrowth situation of floating bed plant, rice husk carbon filling material floating bed is obvious Better than other two kinds of fillers;And in weight rich nutrition level water body, the vegetation growth state of non-filling floating bed is best.(3) from net From the point of view of changing water quality and plant growth, in weight eutrophic water body, should not it use biological floating bed.
Its technical solution is as follows:
A kind of research method of difference floating bed filler purifying water effect, comprising the following steps:
Step 1, the selection for trying water body
Water body uses manual simulation's waste water.NH is added in tap water4CL、KNO3、KH2PO4, the pollution of nitrogen, phosphorus in water is simulated, Allot the eutrophic water of 3 kinds of middle eutrophy, eutrophy, weight eutrophy etc. different pollution levels.The ecology that different substrates are arranged is floating Bed, respectively rice hull carbon, medical stone and haydite, floating bed size are 1m*1m, and every kind of processing has 3 repetitions.Every 15 days, acquisition Water sample and plant sample measure TN, TP, NH in water4 +-N、NO3 -- N concentration, and measure the growth indexes of hygrophyte.
The selection of step 2, test plant and filler
Select yellow flag and Siberian iris for floating bed plant, the purchase of both plants is from before flowers market, experiment by root Soil is cleaned, and domestication adaptation two weeks is tested again in clear water;
The floating bed filler selected is rice hull carbon, medical stone and haydite, is compareed as packless blank test;
The foundation of step 3, floating bed system
What the present invention was built biological floating bed is made of kickboard, plantation basket, connection buckle.
Step 4, data statistics
It is for statistical analysis using SPSS19.0 software and Excel.
Further, in step 3, the kickboard is made of high-density polyethylene material, there is 9 plantations in one square metre Hole.
Further, in middle eutrophy and eutrophic water body, rice husk carbon filling material floating bed is obviously excellent to the clean-up effect of water quality In other fillers;And in weight rich nutrition level water body, the purifying water effect of non-filling floating bed is better than having the floating bed filled out.
Further, in middle eutrophy and rich nutrition level water body, upgrowth situation of the floating bed plant in rice husk carbon filling material Better than other fillers;In weight rich nutrition level water body, upgrowth situation of the floating bed plant in non-filling is better than having the floating of filler Bed.
Further, in middle eutrophy and rich nutrition level water body, most suitable floating bed filler is rice hull carbon;And in the rich battalion of weight It supports in water body, non-filling floating bed is best.
The invention has the benefit that
The present invention studies influence of the different floating bed fillers to the clean-up effect and plant growth of water quality and is of great significance, and can be wet Ground ecosystem construction and environmental protection provide scientific basis, avoid repeating to study the huge waste with production practices.It grinds herein Study carefully in three kinds of different rich nutrition level water bodys (middle eutrophy, eutrophy, weight eutrophy), floating bed filler (rice hull carbon, wheat meal Stone, haydite) to the clean-up effect of water quality.The result shows that rice hull carbon is to TN, NH in middle rich nutrition level water body4 +-N、NO3 -- The removal effect of N is better than medical stone and haydite;And to the removal effect of TP, haydite is substantially better than medical stone and rice hull carbon.In richness In nutritional profile and weight rich nutrition level water body, the purifying water effect of filler floating bed does not have clear superiority.Meanwhile in middle eutrophy journey In degree and rich nutrition level water body, the upgrowth situation of floating bed plant, rice husk carbon filling material floating bed is substantially better than other two kinds of fillers;And In weight rich nutrition level water body, filler floating bed plant upgrowth situation does not have a clear superiority.Therefore, in Heavyeutrophication water body In, no matter from purify water or plant growth from the point of view of, should not use biological floating bed.
Detailed description of the invention
Fig. 1 is the research method flow chart that purifies water, wherein " biological floating bed not have clear superiority " refers to using biological floating bed This method, in terms of purifying water, improving environment and promote plant growth, without clear superiority, it should use its other party Method, to avoid wasting, ensuring wetland ecoengineering construction quality.
Fig. 2 is construction plants landscape research method flow chart, clear in middle eutrophy and eutrophic water body, can use rice husk Carbon filling material floating bed promotes plant growth, and should not use biological floating bed construction plants landscape in weight eutrophic water body.
Fig. 3 difference filler floating bed is to different pollution level water body TN, NH4 +-N、NO3 -The removal effect of-N.Wherein, Fig. 3 (a) removal rate rice hull carbon (55.4%) > haydite (46.4%) > medical stone of 3 kinds of fillers to TN in middle eutrophic water body is indicated (43.6%) > blank (38.3%);Fig. 3 (b) indicates that three kinds of filler floating beds are to TN in water body when eutrophic extent is presented in water body Removal rate blank (69.9%) > haydite (69.8%) > rice hull carbon (64.2%) > medical stone (62.6%);Fig. 3 (c) is indicated in weight In eutrophic water body, the final removal rate blank (73.3%) of TN > rice hull carbon (71.2%) > medical stone (71.1%) > haydite (68.6%). Fig. 3 (d) indicates the NO in middle eutrophication water3 -The final removal rate of-N, rice hull carbon (68.3%) > blank (67.7%) > wheat meal Stone (66.6%) > haydite (65.4%);Fig. 3 (e) indicates the NO in rich nutrition level water body3 -The final removal rate medical stone of-N (80.3%) > rice hull carbon (79.4%) > haydite (79%) > blank (78.3%);Fig. 3 (f) is indicated in weight rich nutrition level water body, right NO3 -The final removal rate of-N is blank (83.6%) > rice hull carbon (82.9%) > haydite (82.3%) > medical stone (82.1%).Fig. 3 (g) It indicates for NH4 +The removal of-N, in middle rich nutrition level water body, final removal rate rice hull carbon (91.6%) > haydite (83.3%) > Medical stone (75%) > blank (41.7%);Fig. 3 (h) indicates the NH in the water body of rich nutrition level+-N 4Final removal rate: pottery Grain (78.6%) > rice hull carbon (75%) > medical stone (67.9%) > blank (64.2%);Fig. 3 (i) indicate weight rich nutrition level in, NH4 +The final removal rate of-N: rice hull carbon (84.8%) > haydite ≈ medical stone ≈ blank.
Removal effect of Fig. 4 difference filler floating bed to different pollution level water body TP.Wherein, Fig. 4 (a) is indicated in middle rich battalion It supports in water body, to the final removal rate of TP: haydite (83.3%) > medical stone (83.1%) > rice hull carbon (72.2%) > blank (72%); Fig. 4 (b) indicates the final removal rate of TP: haydite (89.3%) > medical stone (85.7%) > blank in the water body of rich nutrition level (85.2%) > rice hull carbon (83.2%);Fig. 4 (c) expression is in weight eutrophic water body, the final removal rate of TP: haydite (92.5%) > Medical stone (90%) > blank (89%) > rice hull carbon (42.5%).
Specific embodiment
Technical solution of the present invention is described in further detail with reference to the accompanying drawings and detailed description.
1 materials and methods
1.1 for trying water body
This test water body uses manual simulation's waste water.According to Shu Jinhua in " evaluation of Chinese Main Lakes eutrophic extent " In the evaluation criterion mentioned, NH is added in tap water4CL、KNO3、KH2PO4, the pollution of nitrogen, phosphorus in water is simulated, middle richness is allotted The eutrophic water of 3 kinds of nutrition, eutrophy, weight eutrophy etc. different pollution levels.The biological floating bed of different substrates is set, respectively Rice hull carbon, medical stone and haydite, floating bed size are 1m*1m, and every kind of processing has 3 repetitions.Every 15 days, water sample and plant are acquired Sample measures TN, TP, NH in water4 +-N、NO3 -- N concentration, and measure the growth indexes of hygrophyte.
1.2 test plant and filler
The yellow flag and Siberian iris that the present invention selects Yangtze River Delta common are floating bed plant, the purchase of both plants It buys and cleans root soil from before flowers market, experiment, domestication adaptation two weeks is tested again in clear water.
The floating bed filler selected is rice hull carbon, medical stone and haydite.Rice hull carbon main component is the rice husk of carbonization, is had close The feature that degree is big, specific gravity is small, absorption property is good;Medical stone is a kind of natural silicate mineral, has very strong suction-operated And exchange interaction;Haydite is the ceramic granule manually produced, has good permeability and water-retaining property.Control is sky with non-filling White test.
1.3 floating bed systems
What the present invention was built biological floating bed is made of kickboard, plantation basket, connection buckle.Wherein, kickboard is by high density polyethylene (HDPE) material Material is made, and has 9 implantation holes in a square meter.
1.4 data statistics
It is for statistical analysis using SPSS19.0 software and Excel.
2 interpretations of result
2.1 effects of purification quality
2.1.1 to TN, NH in water4 +-N、NO3 -The removal of-N
As shown in figure 3, three kinds of filler floating beds are roughly the same to the final removal effect of TN in middle eutrophication water, but Early period is tested, when second of sampling determination, the removal rate of rice hull carbon is significantly greater than haydite and medical stone.From figure 3, it can be seen that In middle rich nutrition level water body, removal rate rice hull carbon (55.4%) > haydite (46.4%) > medical stone of three kinds of fillers to TN (43.6%) > blank (38.3%);When eutrophic extent is presented in water body, removal rate of three kinds of filler floating beds to TN in water body Blank (69.9%) > haydite (69.8%) > rice hull carbon (64.2%) > medical stone (62.6%);It is final to remove in weight eutrophic water body Rate blank (73.3%) > rice hull carbon (71.2%) > medical stone (71.1%) > haydite (68.6%).
NO3 -The removal rate of-N and TN are different.In middle eutrophication water, NO3 -The final removal rate of-N, rice husk Charcoal (68.3%) > blank (67.7%) > medical stone (66.6%) > haydite (65.4%);In rich nutrition level water body, NO3 -- N is most Whole removal rate medical stone (80.3%) > rice hull carbon (79.4%) > haydite (79%) > blank (78.3%);In weight rich nutrition level water body In, to NO3 -The final removal rate of-N is blank (83.6%) > rice hull carbon (82.9%) > haydite (82.3%) > medical stone (82.1%).
For NH4 +The removal of-N, in middle rich nutrition level water body, final removal rate rice hull carbon (91.6%) > haydite (83.3%) > medical stone (75%) > blank (41.7%);In the water body of rich nutrition level, NH4Final removal rate: haydite (78.6%) > rice hull carbon (75%) > medical stone (67.9%) > blank (64.2%);In weight rich nutrition level, NH4 +- N's finally goes Except rate: rice hull carbon (84.8%) > haydite ≈ medical stone ≈ blank.
In different degrees of eutrophic water body, the denitrification of different fillers is not also identical, possible mechanism are as follows: this examination The rice husk carbon for testing use, rich in nutrient needed for rice-straw fibre and plant growth, in the water body of middle eutrophic extent In, the denitrification effect of rice hull carbon is substantially better than medical stone and haydite, illustrates that rice hull carbon had both promoted plant in middle eutrophic water body Object growth, but because itself good absorption property generates good effect to purification of water quality;In rich nutrition level and the rich battalion of weight It supports in degree water body, N nutrition contained by water body itself is enough even much larger than amount needed for plant growth, therefore rice hull carbon is made For filler, surface forms the microbial population for being suitble to it to decompose, and rice hull carbon is adsorbed the microorganism decomposition on its surface, into water body Part N, P element are discharged, in addition nitration reaction makes N element be eventually converted into N2;In weight eutrophic water body, N contained by water body, Content needed for P element content is much higher than plant normal growth, therefore floating bed filler is net with water quality to plant growth instead Inhibition and coercion are played in change.It can be seen that floating bed filler is not suitable in Heavyeutrophication water body.
Removal to TP in water
As shown in figure 4, different floating bed fillers are also different to the removal rate of TP in water in different degrees of eutrophic water body.? In middle eutrophic water body, to the final removal rate of TP: haydite (83.3%) > medical stone (83.1%) > rice hull carbon (72.2%) > blank (72%);In the water body of rich nutrition level, haydite (89.3%) > medical stone (85.7%) > blank (85.2%) > rice hull carbon (83.2%);In weight eutrophic water body, haydite (92.5%) > medical stone (90%) > blank (89%) > rice hull carbon (42.5%).
If floating bed plant root system is grown in water, root system absorbs the nutrient (P, N) in water body first, but floating After filler is added in bed, filler is directly contacted with root system, therefore the nutrient in root system preferential absorption filler.It is selected in the present invention When with filler, the content of nutrient: haydite<medical stone<rice hull carbon, thus in water P absorption, haydite floating bed>medical stone is floating Bed > rice hull carbon floating bed.
2.2 vegetation growth state
During research, yellow flag and Siberian iris growing state are all very good, survival rate 100%.
In middle eutrophic water body, yellow flag height increament: rice hull carbon (15cm) > medical stone (13cm) > haydite (10cm) > Blank (8cm);Siberian iris height increament: rice hull carbon (12cm) > medical stone (11cm) > haydite (10cm) > blank (6cm).In eutrophic water body, yellow flag height increament: rice hull carbon (23cm) > medical stone (21cm) > haydite (20cm) > blank (16cm);Siberian iris height increament: rice hull carbon (15cm) > medical stone (12cm) > haydite (10cm) > blank (8cm).? In weight eutrophic water body, yellow flag height increament: blank (21cm) > haydite (18cm) > medical stone (16cm) > rice hull carbon (12cm);Siberian iris height increament: blank (17cm) > haydite (14cm) > medical stone (10cm) > rice hull carbon (8cm).
In middle eutrophic water body and eutrophic water body, there is the floating bed plant upgrowth situation of filler to be substantially better than packless Floating bed is conducive to strengthen and plant this is because floating bed filler is conducive to plant growth in middle eutrophy and rich nutrition level water body Object root activity and growth rate;And inhibiting effect is played in weight rich nutrition level water body.Therefore, in weight eutrophic water body In, the plant growth amount of non-filling floating bed is better than the floating bed plant for having filler.
3 conclusions and discussion
(1) in terms of purifying water effect, in middle rich nutrition level water body, rice hull carbon is to TN, NH4 +-N、NO3 -The removal effect of-N is excellent In medical stone and haydite;And to the removal effect of TP, haydite is substantially better than medical stone and rice hull carbon.And in rich nutrition level and again In rich nutrition level water body, the purifying water effect of filler floating bed does not have clear superiority, but for TP, the water purification effect of haydite floating bed Fruit is better than medical stone and rice hull carbon floating bed.
(2) in terms of plant growth, in middle rich nutrition level and rich nutrition level water body, the upgrowth situation of floating bed plant, Rice husk carbon filling material floating bed is substantially better than other two kinds of fillers;And in weight rich nutrition level water body, the plant of non-filling floating bed is raw Long situation is best.
(3) it from purifying water with from the point of view of plant growth, in weight eutrophic water body, should not use biological floating bed.
The foregoing is only a preferred embodiment of the present invention, the scope of protection of the present invention is not limited to this, it is any ripe Know those skilled in the art within the technical scope of the present disclosure, the letter for the technical solution that can be become apparent to Altered or equivalence replacement are fallen within the protection scope of the present invention.

Claims (2)

1. a kind of research method of difference floating bed filler purifying water effect, which comprises the following steps:
Step 1, the selection for trying water body
Water body uses manual simulation's waste water;NH is added in tap water4CL、KNO3、KH2PO4, the pollution of nitrogen, phosphorus in water is simulated, is matched The eutrophic water of the different pollution levels of middle eutrophy, eutrophy, 3 kinds of weight eutrophy out;The biological floating bed of different substrates is set, point Not Wei rice hull carbon, medical stone and haydite, floating bed size is 1m*1m, and every kind of processing has 3 repetitions;Every 15 days, acquire water sample and Plant sample measures TN, TP, NH in water4 +-N、NO3 -- N concentration, and measure hygrophyte growth indexes;
The selection of step 2, test plant and filler
It selects yellow flag and Siberian iris for floating bed plant, cleans root soil before experiment, tame and adapt in clear water Two weeks is tested again;
The floating bed filler selected is rice hull carbon, medical stone and haydite, is compareed using non-filling as blank test;
The foundation of step 3, floating bed system
That builds biological floating bed is made of kickboard, plantation basket, connection buckle;
Step 4, data statistics
It is for statistical analysis using SPSS19.0 software and Excel.
2. the research method of difference floating bed filler purifying water effect according to claim 1, which is characterized in that in step 3, institute It states kickboard to be made of high-density polyethylene material, there is 9 implantation holes in one square metre.
CN201811295088.9A 2018-11-01 2018-11-01 A kind of research method of difference floating bed filler purifying water effect Pending CN109292991A (en)

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CN104817228A (en) * 2015-04-15 2015-08-05 北京林业大学 Solar power nitrogen and phosphorus removal biological box array used for in-situ purification for eutrophic slow flow water body
CN104876335A (en) * 2015-06-01 2015-09-02 北京建筑大学 Two-phase bioretention pond with synchronous phosphorous and nitrogen removal function and construction method thereof
CN205076890U (en) * 2015-09-26 2016-03-09 浙江省环境保护科学设计研究院 Ecological bed that floats of integration
CN206940551U (en) * 2017-07-13 2018-01-30 南京八本堂环保科技有限公司 Tank type solar energy chinampa and ecological water body repair system

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19512907C1 (en) * 1995-04-06 1996-06-27 Ivan Prof Dr Ing Sekoulov Purificn. of water, e.g. from sewers
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Application publication date: 20190201