CN109291563B - Antibacterial health-care ultraviolet-proof environment-friendly composite fabric and preparation method thereof - Google Patents

Antibacterial health-care ultraviolet-proof environment-friendly composite fabric and preparation method thereof Download PDF

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Publication number
CN109291563B
CN109291563B CN201811045089.8A CN201811045089A CN109291563B CN 109291563 B CN109291563 B CN 109291563B CN 201811045089 A CN201811045089 A CN 201811045089A CN 109291563 B CN109291563 B CN 109291563B
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fabric
yarns
polylactic acid
cotton
parts
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CN109291563A (en
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傅佳佳
叶远丽
陈太球
王炳来
巫瑛
蒋春燕
李飞
王鸿博
李楠楠
李嘉
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Jiangnan University
Swoto Protection and Technology Co Ltd
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Jiangnan University
Swoto Protection and Technology Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/12Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B9/047Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material made of fibres or filaments
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00Layers arrangement
    • B32B2250/033 layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00Layers arrangement
    • B32B2250/20All layers being fibrous or filamentary
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02Synthetic macromolecular fibres
    • B32B2262/0276Polyester fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/06Vegetal fibres
    • B32B2262/062Cellulose fibres, e.g. cotton
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/554Wear resistance
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/71Resistive to light or to UV
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/714Inert, i.e. inert to chemical degradation, corrosion
    • B32B2307/7145Rot proof, resistant to bacteria, mildew, mould, fungi
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/716Degradable
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/724Permeability to gases, adsorption
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2437/00Clothing

Abstract

The invention discloses an antibacterial, health-care and anti-ultraviolet environment-friendly composite fabric which is composed of a three-layer structure of an outer-layer fabric, an interlayer fabric and an inner-layer fabric, wherein the outer-layer fabric is a satin weave made of cotton/polylactic acid fiber blended yarns A and polyester yarns; the interlayer fabric is a through hole tissue made of soybean protein fiber yarns; the lining fabric is a plain weave made of cotton/polylactic acid fiber blended yarns B; the three layers of fabrics are bonded by reactive glue. The invention also discloses a preparation method of the fabric. The composite fabric is formed by compounding three layers of different yarns and fabrics with different tissue structures, the three layers of fabrics are compounded by the reactive glue, and the respective advantages can be effectively combined and mutually promoted, so that the composite fabric is light, thin, wear-resistant, even and smooth in fabric surface, soft and skin-friendly, and has the functions of ultraviolet resistance, antibiosis and health care.

Description

Antibacterial health-care ultraviolet-proof environment-friendly composite fabric and preparation method thereof
Technical Field
The invention belongs to the technical field of textile fabrics, and particularly relates to an antibacterial health-care ultraviolet-proof environment-friendly composite fabric and a preparation method thereof.
Background
With the improvement of living standard of substances, the requirements of people on textiles are not limited to the original basic characteristics of shielding, cold avoidance, comfort and the like, but are favored by textiles with functionality, such as antibiosis, anion, ultraviolet resistance and the like. With the health emphasis of people, the market increasingly demands textiles with special functions of antibiosis, health care and the like. Modern clothing is required to have fashionable and attractive social attributes, ultraviolet properties are ubiquitous, moderate ultraviolet radiation is beneficial to body health, clothing is generally light and thin in summer weather, skin is easy to be damaged by ultraviolet rays, the ultraviolet rays are the first natural enemies of people who love beauty and pursue health preservation, and once the ultraviolet rays are too strong, the clothing can cause harm to body health, skin cancer is caused, and even sick health is damaged. Therefore, whether the clothes have the antibacterial, health-care and ultraviolet-resistant performances is important except that basic requirements of skin-friendly comfort, air exhaust, moisture permeability, light weight, elegance and the like are met.
In addition, nowadays, people enter a fast fashion life rhythm, the use of clothes of young fashion ladies generally does not exceed 2 years, and old clothes without reuse value can be thoroughly discarded due to aesthetic fatigue or a fresh style which is introduced into the market, so that great waste is caused, and the energy conservation and environmental protection are not facilitated.
Disclosure of Invention
The invention aims to provide a novel environment-friendly composite fabric with antibacterial, health-care and ultraviolet-proof functions.
In the present invention, "wt%" represents a mass percentage; in the blending ratio of each yarn in the present invention, the component ratios in each raw material are by weight unless otherwise specified.
The invention relates to an antibacterial, health-care and anti-ultraviolet environment-friendly composite fabric which is composed of an outer layer fabric, an interlayer fabric and an inner layer fabric, and is characterized in that,
the outer fabric is a satin weave made of cotton/polylactic acid fiber blended yarns A and polyester yarns, wherein the blending ratio of cotton to polylactic acid fiber of the cotton/polylactic acid fiber blended yarns is 25-35 wt% to 75-65 wt%;
the interlayer fabric is a through hole tissue made of soybean protein fiber yarns;
the inner layer fabric is a plain weave made of cotton/polylactic acid fiber blended yarns B, wherein the blending ratio of cotton to polylactic acid fiber of the cotton/polylactic acid fiber blended yarns is 18-22 wt% to 78-82 wt%;
the three layers of fabrics are bonded by reactive glue, and the reactive glue comprises the following components: 55-65 wt% of ethyl acrylate/acrylic ester copolymer emulsion, 17-22 wt% of chitin and 17-23 wt% of polylactic acid (polylactide).
The antibacterial health-care and anti-ultraviolet environment-friendly composite fabric is formed by compounding three layers of fabrics with different tissue structures, and has the advantages of antibacterial health care, ultraviolet resistance, environment friendliness and the like. The outer layer fabric is used as the outermost layer, and the composite fabric is endowed with excellent ultraviolet resistance and antibacterial performance. Firstly, the outer layer fabric is made according to a satin weave structure, so that the uvioresistant performance of the fabric can be effectively improved. The weave structure is different, the interweaving rule of the yarns is different, and the size of gaps among the yarns is different. At the same yarn density, the number of plain weaves is the largest, and many gaps are generated between yarns. The twill and the satin are different, particularly, the satin weave is long in floating, the interweaving times among yarns are small, the yarns are easy to be close to each other under the condition of the same density, gaps are small, the thread jumper on the satin is long, an included angle is small, the gloss is strong, the satin is smooth and attractive, and the ultraviolet resistance is good. And secondly, the warp and weft yarns of the outer layer fabric are polylactic acid yarns and polyester yarns, which have good ultraviolet resistance, and especially, the polyester has strong absorptivity for ultraviolet rays with the wavelength less than 300nm due to benzene rings in the molecular structure of the polyester, so that the ultraviolet resistance can be further improved. In addition, the polyester fiber has good strength and low price, and the polylactic acid yarn has better antibacterial performance.
The interlayer fabric is used as the middle layer, and has great influence on the light weight, the air exhaust, the moisture permeability and other properties of the composite fabric. The warp and weft yarns in the sandwich fabric are all soybean protein fiber yarns, have a through hole tissue structure, and have the advantages of light weight, air exhaust and moisture permeability. The soybean protein fiber yarn has good affinity with human skin, contains various amino acids necessary for human body, and has good antibacterial and health promoting effects. In addition, the soybean protein fiber has good solubility, can be selectively dissolved by biological enzyme (protease) in the later period, and the fabric of the outer layer and the inner layer is not influenced, so that the weight reduction treatment can be carried out on the fabric, the fabric style is lighter and more elegant, and the purposes of reducing weight and renewing use are achieved.
The inner layer fabric is the most close-fitting layer, the invention is made of polylactic acid fiber and cotton fiber blended yarn in a plain weave, and has the following advantages that the plain weave is lighter and thinner, more wear-resistant and more uniform in cloth cover than the fabric with the same specification. And secondly, the raw material adopts polylactic acid fiber and cotton fiber blended yarn, wherein the cotton fiber is soft and skin-friendly and is the most widely used natural fiber, and the polylactic acid fiber not only has excellent antibacterial performance, but also is skin-friendly, beauty and health-care and degradable. The blending ratio of the cotton and the polylactic acid fiber is limited to 20:80, so that the mechanical property of the lining fabric can be effectively improved. With the increase of the proportion of the polylactic acid fiber in the blended yarn, the breaking elongation of the cotton/polylactic acid fiber blended yarn is increased and then decreased, and when the proportion of the polylactic acid fiber in the cotton/polylactic acid fiber blended yarn is 80%, the breaking elongation of the cotton/polylactic acid fiber blended yarn is higher.
The three layers of fabrics are bonded through the reactive glue, the components of the reactive glue comprise ethyl acrylate/acrylate copolymer emulsion, chitin and polylactic acid (polylactide), the reactive glue can react with the fabrics for crosslinking, the fabrics are bonded effectively, and the reactive glue has the advantages of environmental protection, no peculiar smell, no formaldehyde, lasting glue points and the like, and is very in line with the design concept of novel green and environment-friendly fabrics. The fabric bonded by the reactive glue can be dry-cleaned, has less glue amount and soft hand feeling, and is more comfortable and skin-friendly. And the added polylactic acid component is favorable for ultraviolet resistance, antibiosis and health care performance, and the chitin has very good antibiosis performance.
The raw materials of polylactic acid fiber, soybean protein fiber, cotton fiber and anti-reaction glue used by the fabric belong to green environment-friendly materials, and the production and processing of the fabric are beneficial to the safety and health of the ecological environment and accord with the concepts of green economy and sustainable development.
Preferably, in the outer-layer fabric, the cotton/polylactic acid fiber blended yarn A is used as weft yarn, and the linear density is 15-20, preferably 18 tex; the polyester yarns are used as warp yarns, and the linear density is 15-20, preferably 18 tex; the outer layer fabric had a thickness of 0.1 to 0.15mm and a warp and weft density of 133X 73 (the numerical values indicate the number of warp yarns and weft yarns arranged per square inch, the same applies hereinafter).
Preferably, in the sandwich fabric, warp yarns and weft yarns are all soybean protein fiber yarns, and the linear density is 15-20, preferably 18 tex; the thickness of the interlayer fabric is 0.05-0.1mm, and the warp and weft density is 65 multiplied by 78.
Preferably, in the lining fabric, warp yarns and weft yarns are cotton/polylactic acid fiber blended yarns B, and the linear density is 15-20, preferably 18 tex; the thickness of the lining is 0.05-0.1mm, and the warp and weft density is 128 multiplied by 68.
Preferably, the color of the outer layer fabric is designed to be orange, and generally, the darker the color, the better the ultraviolet resistance. The black and blue-hidden ultraviolet-proof performance is relatively good, and the dark fabric absorbs heat most at that time. Meanwhile, in consideration of the fashionable and attractive appearance of the fabric, in the common colors such as blue, white, yellow, red and orange in summer, the orange color has the best ultraviolet resistance and is very striking, so that the fabric is suitable for outdoor sportsmen to wear and use, and in case of threat, the striking color is convenient for rescue. And when can protect outdoor exercises, reduce by pedestrian, the danger of vehicle collision. Under the premise of the same other conditions, the ultraviolet resistance of the satin weave structure fabric is superior to that of plain weave and twill weave.
Preferably, the traditional Chinese medicine is subjected to soaking and finishing by using an aqueous solution of natural Chinese herbal medicines, wherein the natural Chinese herbal medicines comprise honeysuckle, coptis chinensis, dandelion, asarum and folium artemisiae argyi. The antibacterial, insect-proof and mildew-proof performances of the fabric can be further improved by adopting the water solution dipping and finishing of natural Chinese herbal medicines. The natural Chinese herbal medicines are low in price, but excellent in performance: the honeysuckle, the coptis chinensis and the dandelion have antibacterial performance, and the asarum and the folium artemisiae argyi have good insect-proof and mildew-proof performance.
Preferably, the natural Chinese herbal medicines comprise the following components in parts by weight: 10 parts of honeysuckle, 5-15 parts of coptis chinensis, 30-50 parts of dandelion, 5-15 parts of asarum and 25-35 parts of folium artemisiae argyi.
The invention also aims to provide a method for preparing the fabric, which comprises the following steps:
a) weaving the outer layer fabric, namely weaving satin weave by adopting the cotton/polylactic acid fiber blended yarn A and polyester yarn through a forward weaving method;
b) weaving the interlayer fabric, namely weaving the soybean protein fiber yarn into a through hole tissue by a forward-through method;
c) weaving the lining fabric, namely weaving the cotton/polylactic acid fiber blended yarn B into plain weave by a forward-through method;
d) and (3) bonding the three layers of fabrics, spraying the reactive glue to the surfaces of the three layers of fabrics by adopting a fine mist spraying method, compacting, cleaning redundant glue components after glue is compounded with the fabrics, and drying to obtain the compound fabrics.
In the step d, a fine mist spraying method is adopted, sprayed fine liquid drops can be better combined with the fabric, the fabric bonded by the process is smoother and softer, and raw materials are saved.
Preferably, the method further comprises a post-finishing step, the post-finishing step comprising the operations of: soaking the bonded composite fabric in an aqueous solution of natural Chinese herbal medicines at 70-80 ℃, preferably 75 ℃; the natural Chinese herbal medicines comprise honeysuckle, coptis, dandelion, asarum and folium artemisiae argyi. The dipping temperature can not be too high or too low, the polylactic acid is easy to decompose when too high, and too low is not beneficial to the combination and sterilization of the effective components in the medicinal materials and the fabric, so that the dipping temperature is preferably controlled to be about 75 ℃, the proper heating temperature is beneficial to the combination of the effective components in the medicinal materials and the fabric, the secondary sterilization effect can also be realized, and meanwhile, the polylactic acid can be prevented from being easy to decompose at high temperature.
Preferably, the natural Chinese herbal medicines comprise the following components in parts by weight: 10 parts of honeysuckle, 5-15 parts of coptis chinensis, 30-50 parts of dandelion, 5-15 parts of asarum and 25-35 parts of folium artemisiae argyi.
Further preferably, the natural Chinese herbal medicines comprise the following components in parts by weight: 10 parts of honeysuckle, 8-10 parts of coptis chinensis, 35-45 parts of dandelion, 8-10 parts of asarum and 28-32 parts of folium artemisiae argyi.
The invention has the beneficial effects that:
the antibacterial, health-care and ultraviolet-proof environment-friendly composite fabric is formed by compounding three layers of fabrics with different weave structures, wherein the outer layer fabric is made of cotton/polylactic acid blended yarns and polyester yarns in a satin weave structure, so that the novel composite fabric can be endowed with excellent ultraviolet resistance and antibacterial performance; the sandwich layer is made of warp and weft yarns which are soybean protein fiber yarns and have a through hole tissue structure, has the advantages of lightness and thinness, air exhaust, moisture permeability and beauty and health care, and can selectively degrade sandwich layer fabric after being used for a period of time to reduce weight of the fabric, so that the fabric is lighter, thinner and more elegant in style; the inner layer fabric is made of polylactic acid fiber and cotton fiber blended yarns in a plain weave structure, and is light, thin, wear-resistant, even in cloth cover, soft, skin-friendly and excellent in antibacterial performance. The three layers of fabrics are compounded through the reactive glue, and the respective advantages can be effectively combined and mutually promoted, so that the novel fabric not only has the advantages of softness, skin friendliness and wearing comfort, but also has the functions of ultraviolet resistance, antibiosis and health care. After the fabric is used for a period of time, the interlayer fabric can be selectively degraded, and the fabric is subjected to weight reduction treatment, so that the fabric is lighter, thinner and more elegant in style and can be reused.
Drawings
FIG. 1 is a drawing of an outer shell fabric of the present invention;
FIG. 2 is a weave diagram and a pattern layout of the outer fabric of the invention;
FIG. 3 is a drafting pattern of the sandwich fabric of the present invention;
FIG. 4 is a weave and a pattern of a sandwich fabric according to the present invention;
FIG. 5 is a drafting pattern of the inner layer fabric of the present invention;
FIG. 6 is a weave diagram and a grain layout of the lining fabric of the present invention.
Detailed Description
The invention is further illustrated by the following examples and figures. It should be understood that the following examples are illustrative only and are not intended to limit the scope of the present invention.
Example 1
An antibacterial, health-care and anti-ultraviolet environment-friendly composite fabric is composed of an outer-layer fabric, an interlayer fabric and an inner-layer fabric in a three-layer structure and is prepared through the following steps.
a) Weaving of the outer layer fabric:
adopting cotton/polylactic acid fiber blended yarn A and polyester yarn to weave satin texture by a forward weaving method; fig. 1 is its drafting pattern, and fig. 2 is its organization pattern and pattern layout (since the drafting is a forward drafting method, the organization pattern and pattern layout are the same, and the same is applied below).
Wherein the blending ratio of the cotton and the polylactic acid fiber of the cotton/polylactic acid fiber blended yarn A is 30 wt% to 70 wt%. Wherein, the cotton/polylactic acid fiber blended yarn is used as weft yarn, and the linear density is 18 tex; the terylene yarn is used as warp yarn, and the linear density is 18 tex; the thickness of the outer layer fabric is 0.1-0.15mm, a high-density weaving method is adopted, and the warp and weft density is 133 multiplied by 73. Preferably, the outer layer fabric is orange in color.
b) Weaving the interlayer fabric:
adopting soybean protein fiber yarn to weave through-hole tissue by a clockwise-through method; fig. 3 is an drafting diagram thereof, and fig. 4 is an organization diagram and a texture layout thereof. Wherein, the warp and the weft are both soybean protein fiber yarns, and the linear density is 18 tex; the thickness of the interlayer fabric is 0.05-0.1mm, and the warp and weft density is 65 multiplied by 78.
c) Weaving of the inner layer fabric:
the cotton/polylactic acid fiber blended yarn B is woven into plain weave by a forward-through method; fig. 5 is an drafting diagram thereof, and fig. 6 is an organization diagram and a texture layout thereof. Wherein the blending ratio of the cotton and the polylactic acid fiber of the cotton/polylactic acid fiber blended yarn is 20 wt% to 80 wt%. Wherein, the warp yarns and the weft yarns are cotton/polylactic acid fiber blended yarns, and the linear density is 18 tex; the thickness of the lining is 0.05-0.1mm, and the warp and weft density is 128 multiplied by 68.
d) Bonding of the three layers of fabrics:
spraying reactive glue on the surfaces of the three layers of fabrics by adopting a fine mist spraying method, compacting, cleaning redundant glue components after the glue is compounded with the fabrics, and drying to obtain the compound fabrics.
The formula of the reaction type glue comprises: 60 wt% of ethyl acrylate/acrylate copolymer emulsion, 20 wt% of chitin and 20 wt% of polylactic acid (polylactide).
e) And (3) after finishing:
soaking the bonded composite fabric in 75 ℃ aqueous solution of natural Chinese herbal medicines for 24 hours, taking out and drying in the air;
the preparation method of the aqueous solution of the natural Chinese herbal medicines comprises the following steps: putting honeysuckle (1kg), coptis (1kg), dandelion (4kg), asarum (1kg) and folium artemisiae argyi (3kg) into clear water (100kg), uniformly mixing, and carrying out water bath at the constant temperature of 75 ℃ for 24 hours.
The antibacterial, health-care and ultraviolet-proof environment-friendly composite fabric is formed by compounding three layers of fabrics with different weave structures, wherein the outer layer fabric is made of cotton/polylactic acid blended yarns and polyester yarns in a satin weave structure, so that the novel composite fabric can be endowed with excellent ultraviolet resistance and antibacterial performance; the sandwich layer is made of warp and weft yarns which are soybean protein fiber yarns and have a through hole tissue structure, has the advantages of lightness and thinness, air exhaust, moisture permeability and beauty and health care, and can selectively degrade sandwich layer fabric after being used for a period of time to reduce weight of the fabric, so that the fabric is lighter, thinner and more elegant in style; the inner layer fabric is made of polylactic acid fiber and cotton fiber blended yarns in a plain weave structure, and is light, thin, wear-resistant, even in cloth cover, soft, skin-friendly and excellent in antibacterial performance. The three layers of fabrics are compounded through the reactive glue, and the respective advantages can be effectively combined and mutually promoted, so that the novel fabric not only has the advantages of softness, skin friendliness and wearing comfort, but also has the functions of ultraviolet resistance, antibiosis and health care.
The fabric manufactured in the embodiment 1 of the invention is subjected to antibacterial, ultraviolet-resistant and wear-resistant performance tests.
1. And (3) testing antibacterial performance:
according to the evaluation of the antibacterial performance of the textile of the national standard GB/T20944.1-2007
The first agar plate diffusion method is adopted, and the test strains are staphylococcus aureus and escherichia coli. Table 1 shows the criteria for the evaluation of the antibacterial effect.
TABLE 1 evaluation of antibacterial Effect
Figure GDA0002265978490000071
The fabric of the invention is subjected to qualitative antibacterial performance test, and the test result shows that: the width of the bacteriostatic zone is 0-1mm, and no bacteria are propagated below the sample. Therefore, the antibacterial effect was evaluated as being good.
2. Ultraviolet resistance test
According to the evaluation of the ultraviolet resistance of the textile of national standard GB/T18830-2009
The evaluation method comprises the following steps: standard specification when the UV protection factor UPF>40, and a long-wave ultraviolet transmittance T (UVA)AV<At 5%, it can be called "UV-protection product".
Tests show that the UPF of the fabric is more than 50, T (UVA)AV3 percent, excellent ultraviolet resistance and accordance with the standard.
3. Abrasion resistance test
According to the determination of the wear resistance of the national standard GB/T21196 Martindale fabric
Determination of mass loss: under a certain load, the sample in the clamp moves in a curved plane along a track to rub with the abrasive, and the wear resistance is determined according to the mass difference between the sample before and after rubbing at a specific rubbing frequency.
The test shows that the test result of the fabric is shown in table 2 after 1000 times of rubbing, the mass loss is very small, the mass loss percentage is less than 1%, and the fabric has very good wear resistance.
Table 2 abrasion resistance test results of the inventive fabrics
Mass before friction Mass before friction Wear resistance
100g 99.12g Is excellent in
In addition, the clothes made of the fabric can selectively degrade the interlayer fabric after being used for a period of time, and the fabric is subjected to weight reduction treatment, so that the fabric is lighter, thinner and more elegant in style and can be reused. Nowadays, people enter a fast fashion life rhythm, the clothes of young fashion ladies can not be used for more than 2 years, and the old clothes without reuse value can be completely discarded due to aesthetic fatigue or the fact that a fresh style is introduced into the market. However, if the clothes made of the novel fabric of the invention are used, when a consumer uses the clothes for a period of time and does not want to wear the clothes and discard the clothes, some bio-enzyme detergent can be bought in the market, and the soybean protein fiber is processed, so that the clothes become a light and thin sun-proof clothes which can be used for outdoor sports or on-duty and off-duty roads, can protect ultraviolet rays, can be recycled and is very economical. For consumers who like outdoor sports, the fabric before losing weight is thicker and heavier, and is suitable for wearing in spring and autumn, and if the consumers wear for a period of time and want to discard, the fabric can also lose weight and be used for wearing in summer. The interlayer fabric is independently designed, and the biological enzyme only dissolves the soybean protein fiber, so the plate type cannot be changed.
While the preferred embodiments of the present invention have been illustrated and described, it will be understood by those skilled in the art that various changes in form and details may be made therein without departing from the spirit and scope of the invention as defined by the appended claims.

Claims (10)

1. An antibacterial, health-care and anti-ultraviolet environment-friendly composite fabric, which is composed of three-layer structures of an outer-layer fabric, an interlayer fabric and an inner-layer fabric,
the outer fabric is a satin weave made of cotton/polylactic acid fiber blended yarns A and polyester yarns, wherein the blending ratio of cotton to polylactic acid fiber of the cotton/polylactic acid fiber blended yarns is 25-35 wt% to 75-65 wt%;
the interlayer fabric is a through hole tissue made of soybean protein fiber yarns;
the inner layer fabric is a plain weave made of cotton/polylactic acid fiber blended yarns B, wherein the blending ratio of cotton to polylactic acid fiber of the cotton/polylactic acid fiber blended yarns is 18-22 wt% to 78-82 wt%;
the three layers of fabrics are bonded by reactive glue, and the reactive glue comprises the following components: 55-65 wt% of ethyl acrylate/acrylic ester copolymer emulsion, 17-22 wt% of chitin and 17-23 wt% of polylactic acid (polylactide).
2. The antibacterial, health-care and anti-ultraviolet environment-friendly composite fabric as claimed in claim 1, wherein in the outer fabric, cotton/polylactic acid fiber blended yarns A are used as weft yarns, and the linear density is 15-20 tex; the polyester yarns are used as warp yarns, and the linear density is 15-20 tex; the thickness of the outer layer fabric is 0.1-0.15mm, and the warp and weft density is 133 multiplied by 73.
3. The antibacterial, health-care and anti-ultraviolet environment-friendly composite fabric as claimed in claim 1, wherein in the interlayer fabric, warp yarns and weft yarns are both soybean protein fiber yarns, and the linear density is 15-20 tex; the thickness of the interlayer fabric is 0.05-0.1mm, and the warp and weft density is 65 multiplied by 78.
4. The antibacterial, health-care and ultraviolet-proof environment-friendly composite fabric as claimed in claim 1, wherein in the inner fabric, warp yarns and weft yarns are cotton/polylactic acid fiber blended yarns B, and the linear density is 15-20 tex; the thickness of the lining is 0.05-0.1mm, and the warp and weft density is 128 multiplied by 68.
5. The antibacterial, health-care and ultraviolet-proof environment-friendly composite fabric as claimed in claim 1, wherein the outer layer fabric is orange in color.
6. The antibacterial, health-care and anti-ultraviolet environment-friendly composite fabric as claimed in claim 1, which is subjected to dipping and finishing by aqueous solution of natural Chinese herbal medicines, wherein the natural Chinese herbal medicines comprise honeysuckle, coptis chinensis, dandelion, asarum and folium artemisiae argyi.
7. The antibacterial, health-care and anti-ultraviolet environment-friendly composite fabric as claimed in claim 6, wherein the natural Chinese herbal medicines are in the following weight ratio: 10 parts of honeysuckle, 5-15 parts of coptis chinensis, 30-50 parts of dandelion, 5-15 parts of asarum and 25-35 parts of folium artemisiae argyi.
8. A method for preparing the fabric of any one of claims 1 to 5, comprising the steps of:
a) weaving the outer layer fabric, namely weaving satin weave by adopting the cotton/polylactic acid fiber blended yarn A and polyester yarn through a forward weaving method;
b) weaving the interlayer fabric, namely weaving the soybean protein fiber yarn into a through hole tissue by a forward-through method;
c) weaving the lining fabric, namely weaving the cotton/polylactic acid fiber blended yarn B into plain weave by a forward-through method;
d) and (3) bonding the three layers of fabrics, spraying the reactive glue to the surfaces of the three layers of fabrics by adopting a fine mist spraying method, compacting, cleaning redundant glue components after glue is compounded with the fabrics, and drying to obtain the compound fabrics.
9. The method of claim 8, further comprising a post-finishing step, the post-finishing step comprising the operations of: soaking the bonded composite fabric in a 70-80 ℃ aqueous solution of natural Chinese herbal medicines; the natural Chinese herbal medicines comprise honeysuckle, coptis, dandelion, asarum and folium artemisiae argyi.
10. The method of claim 9, wherein the natural Chinese herbal medicines are prepared from the following raw materials in parts by weight: 10 parts of honeysuckle, 5-15 parts of coptis chinensis, 30-50 parts of dandelion, 5-15 parts of asarum and 25-35 parts of folium artemisiae argyi.
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