CN109285941B - Induction type superconducting edge detector and preparation method thereof - Google Patents

Induction type superconducting edge detector and preparation method thereof Download PDF

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CN109285941B
CN109285941B CN201710602494.4A CN201710602494A CN109285941B CN 109285941 B CN109285941 B CN 109285941B CN 201710602494 A CN201710602494 A CN 201710602494A CN 109285941 B CN109285941 B CN 109285941B
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superconducting
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CN109285941A (en
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钟青
王雪深
李劲劲
曹文会
钟源
王兰若
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National Institute of Metrology
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Abstract

The invention relates to an induction type superconducting edge detector and a manufacturing method thereof, wherein the induction type superconducting edge detector comprises: the method comprises the following steps: the device comprises a substrate, an absorption layer, a dielectric layer, an insulating layer, a superconducting thin film layer and a Josephson bridge junction; the absorption layer is arranged on one surface of the substrate; the dielectric layer is arranged on the surface of the absorption layer far away from the substrate and has permeability; the insulating layer covers the absorption layer and the dielectric layer; the superconducting thin film layer is arranged on the surface, far away from the substrate, of the insulating layer and is arranged around the absorption layer and the dielectric layer in a continuous closed structure; the Josephson bridge junction is disposed on the superconducting thin film layer. The induction type superconducting edge detector comprises a dielectric layer with an anti-reflection effect on photons, and the absorption efficiency of the induction type superconducting edge detector on the single photons is improved.

Description

感应式超导边缘探测器及其制备方法Inductive superconducting edge detector and preparation method thereof

技术领域technical field

本发明属于超导电子信息技术领域,特别是涉及一种感应式超导边缘探测器及其制备方法。The invention belongs to the technical field of superconducting electronic information, in particular to an inductive superconducting edge detector and a preparation method thereof.

背景技术Background technique

单个粒子的基本物理量测量需要极度灵敏的探测器。超导转变边缘探测器(Superconducting transition edge sensors简称TES)就是一种这样的探测器,它是由超导薄膜构成,工作温度在其超导态与正常态很窄的范围之间,也就是超导电阻在零和正常值之间。The measurement of fundamental physical quantities of individual particles requires extremely sensitive detectors. Superconducting transition edge sensors (TES for short) is one such detector, which is composed of superconducting thin films and operates at a very narrow range between its superconducting state and its normal state, that is, superconducting Conductivity is between zero and normal.

自从Andrews在1949年提出超导转变边缘探测器后,超导转变边缘探测器有了巨大的进展。与常温的半导体单光子探测器,如雪崩二极管、或者光电倍增管相比,超导转变边缘探测器具有响应速度快,低探测能量的优点。Since Andrews proposed superconducting transition edge detectors in 1949, superconducting transition edge detectors have come a long way. Compared with normal temperature semiconductor single-photon detectors, such as avalanche diodes or photomultiplier tubes, superconducting transition edge detectors have the advantages of fast response speed and low detection energy.

超导转变边缘探测器为非常灵敏的检测仪器,传统的超导转变边缘探测器对光子吸收较弱,加上观测环境的影响,使得超导转变边缘探测器使用效果差,探测不够准确。The superconducting transition edge detector is a very sensitive detection instrument. The traditional superconducting transition edge detector has weak absorption of photons, and the influence of the observation environment makes the superconducting transition edge detector ineffective and inaccurate.

发明内容SUMMARY OF THE INVENTION

基于此,有必要针对上述问题,提供一种能够增强光子吸收的感应式超导边缘探测器及其制备方法。Based on this, it is necessary to provide an inductive superconducting edge detector capable of enhancing photon absorption and a preparation method thereof for the above problems.

一种感应式超导边缘探测器包括:An inductive superconducting edge detector includes:

衬底;substrate;

吸收层,设置在所述衬底的一个表面;an absorption layer, disposed on one surface of the substrate;

介质层,设置在所述吸收层远离与所述衬底的表面,所述介质层具有增透性;a dielectric layer, disposed on the surface of the absorption layer away from the substrate, and the dielectric layer has anti-reflection properties;

绝缘层,覆盖所述吸收层和介质层设置;an insulating layer, arranged to cover the absorption layer and the dielectric layer;

超导薄膜层,设置在所述绝缘层远离所述衬底的表面,并以连续闭合结构绕所述吸收层和介质层设置;a superconducting thin film layer, arranged on the surface of the insulating layer away from the substrate, and arranged around the absorption layer and the dielectric layer in a continuous closed structure;

约瑟夫森桥结,设置在所述超导薄膜层上。A Josephson bridge junction is arranged on the superconducting thin film layer.

在其中一个实施例中,所述吸收层为铌硅薄膜或纯铌薄膜,所述超导薄膜层为纯铌薄膜。In one embodiment, the absorption layer is a niobium silicon thin film or a pure niobium thin film, and the superconducting thin film layer is a pure niobium thin film.

在其中一个实施例中,所述铌硅薄膜中,所述铌在所述铌硅薄膜中所占比例大于等于81.5%且小于等于97.1%,所述铌硅薄膜的超导转变温度处在3.85K到7.1K之间。In one embodiment, in the niobium-silicon film, the proportion of the niobium in the niobium-silicon film is greater than or equal to 81.5% and less than or equal to 97.1%, and the superconducting transition temperature of the niobium-silicon film is 3.85 Between K and 7.1K.

在其中一个实施例中,所述吸收层和所述超导薄膜层的超导转变温度不同。In one of the embodiments, the superconducting transition temperatures of the absorber layer and the superconducting thin film layer are different.

本发明还提供一种感应式超导边缘探测器制作方法,所述制作方法包括:The present invention also provides a method for manufacturing an inductive superconducting edge detector, the manufacturing method comprising:

提供一衬底,在所述衬底上生长吸收层,所述吸收层为铌硅薄膜或纯铌薄膜;A substrate is provided, and an absorption layer is grown on the substrate, and the absorption layer is a niobium-silicon film or a pure niobium film;

在所述吸收层表面沉积介质层,所述介质层对入射的单光子具有增透作用;A dielectric layer is deposited on the surface of the absorption layer, and the dielectric layer has an antireflection effect on incident single photons;

在所述介质层表面形成图案化的第一光刻胶层,覆盖第一预设区域的吸收层;A patterned first photoresist layer is formed on the surface of the dielectric layer to cover the absorption layer in the first preset area;

进行第一次刻蚀,刻蚀掉所述第一预设区域外的吸收层和介质层,暴露出所述衬底;performing a first etching, etching off the absorption layer and the dielectric layer outside the first preset area, and exposing the substrate;

去除光刻胶,沉积形成绝缘层,覆盖所述衬底及所述吸收层和介质层的外表面;removing the photoresist, depositing to form an insulating layer, covering the substrate and the outer surfaces of the absorption layer and the dielectric layer;

在所述绝缘层表面生长超导薄膜层,所述超导薄膜层为纯铌薄膜;A superconducting thin film layer is grown on the surface of the insulating layer, and the superconducting thin film layer is a pure niobium thin film;

在所述超导薄膜层上,形成图案化的第二光刻胶层,覆盖所述第二预设区域,所述第二预设区域为所述吸收层和介质层外围的环形连续区域;On the superconducting thin film layer, a patterned second photoresist layer is formed to cover the second preset area, and the second preset area is an annular continuous area around the absorption layer and the dielectric layer;

进行第二次刻蚀,刻蚀掉所述第二预设区域外的超导薄膜层,获得闭合环状超导结构为所述衬底表面上连续环绕在所述吸收层、介质层和部分绝缘层的外围;Perform a second etching, etch away the superconducting thin film layer outside the second preset area, and obtain a closed-loop superconducting structure that continuously surrounds the absorption layer, the dielectric layer and the part on the surface of the substrate the periphery of the insulating layer;

在所述闭合环状超导结构上,曝光制作出约瑟夫森桥结。On the closed loop superconducting structure, exposure produces a Josephson bridge junction.

在其中一个实施例中,所述进行第一次刻蚀,刻蚀掉所述第一预设区域外的吸收层和介质层,暴露出所述衬底的步骤包括:In one embodiment, the performing the first etching to remove the absorber layer and the dielectric layer outside the first preset area, and exposing the substrate includes:

采用氟基的等离子体进行第一次刻蚀,刻蚀掉所述第一预设区域外的吸收层,暴露出所述衬底。A fluorine-based plasma is used to perform the first etching, and the absorption layer outside the first preset area is etched away to expose the substrate.

在其中一个实施例中,所述去除光刻胶,沉积形成绝缘层,覆盖所述衬底及所述吸收层和介质层的外表面的步骤包括:In one embodiment, the steps of removing the photoresist, depositing to form an insulating layer, and covering the substrate and the outer surfaces of the absorption layer and the dielectric layer include:

将所述第一次刻蚀后的结构采用清洗剂进行去胶处理;The structure after the first etching is subjected to a degumming treatment with a cleaning agent;

在所述去胶后的结构表面,采用原子层沉积(ALD)技术沉积一5-10nm厚的绝缘层。On the surface of the structure after degumming, an insulating layer with a thickness of 5-10 nm is deposited by atomic layer deposition (ALD).

在其中一个实施例中,在所述进行第二次刻蚀,刻蚀掉所述第二预设区域外的超导薄膜层,获得所述闭合环状超导结构所述衬底表面上连续环绕在所述吸收层、介质层和部分绝缘层的外围的步骤中,所述进行第二次刻蚀的时间大于预定刻蚀纯铌薄膜所需时间。In one embodiment, during the second etching, the superconducting thin film layer outside the second preset area is etched away, so as to obtain the closed loop superconducting structure that is continuous on the surface of the substrate In the step of surrounding the periphery of the absorption layer, the dielectric layer and part of the insulating layer, the time for the second etching is longer than the predetermined time required for etching the pure niobium thin film.

在其中一个实施例中,所述在所述闭合环状超导结构上,曝光制作出约瑟夫森桥结的步骤包括:In one embodiment, the step of exposing and fabricating a Josephson bridge junction on the closed-loop superconducting structure includes:

在所述环状超导结构上,采用聚焦离子束(FIB)直接制作出约瑟夫森桥结或者采用电子束曝光(EBL)制作图形然后采用干法刻蚀制作出约瑟夫森桥结。On the ring-shaped superconducting structure, a Josephson bridge junction is directly fabricated by a focused ion beam (FIB) or a pattern is fabricated by an electron beam exposure (EBL) and then a Josephson bridge junction is fabricated by dry etching.

在其中一个实施例中,所述铌硅薄膜的制备方法包括:In one embodiment, the preparation method of the niobium silicon thin film includes:

提供磁控共溅射室以及设置在所述磁控共溅射室内的铌靶和硅靶;providing a magnetron co-sputtering chamber and a niobium target and a silicon target disposed in the magnetron co-sputtering chamber;

控制所述磁控溅射室的真空度及所述铌靶和所述硅靶以预定溅射气压、预定溅射功率进行磁控溅射预定溅射时间,在所述衬底表面沉积成形为所述吸收层或所述超导薄膜层,Control the vacuum degree of the magnetron sputtering chamber and the niobium target and the silicon target to perform magnetron sputtering with a predetermined sputtering gas pressure and a predetermined sputtering power for a predetermined sputtering time, and depositing a shape on the surface of the substrate as follows the absorption layer or the superconducting thin film layer,

其中,铌在所述吸收层中所占比例大于等于81.5%且小于等于97.1%,所述吸收层的超导转变温度在3.85K到7.1K之间。Wherein, the proportion of niobium in the absorption layer is greater than or equal to 81.5% and less than or equal to 97.1%, and the superconducting transition temperature of the absorption layer is between 3.85K and 7.1K.

本发明提供了一种感应式超导边缘探测器及其制作方法,此感应式超导边缘探测器包含有一层具有对光子具有增透作用的介质层,提高了感应式超导边缘探测器对单光子的吸收效率。The invention provides an inductive superconducting edge detector and a manufacturing method thereof. The inductive superconducting edge detector includes a medium layer with anti-reflection effect on photons, which improves the accuracy of the inductive superconducting edge detector. Single photon absorption efficiency.

附图说明Description of drawings

图1为本发明一个实施例的感应式超导边缘探测器结构俯视图;1 is a top view of the structure of an inductive superconducting edge detector according to an embodiment of the present invention;

图2为图1中AB线位置的剖面;Fig. 2 is the section of the AB line position in Fig. 1;

图3为本发明一个实施例的感应式超导边缘探测器制作方法的工艺流程图。3 is a process flow diagram of a method for fabricating an inductive superconducting edge detector according to an embodiment of the present invention.

主要元件符号说明Description of main component symbols

感应式超导边缘探测器 10Inductive superconducting edge detectors 10

衬底 100Substrate 100

吸收层 200Absorbent layer 200

介质层 300Dielectric Layer 300

绝缘层 400Insulation layer 400

超导薄膜层 500Superconducting thin film layer 500

约瑟夫森桥结 600Josephson Bridge Junction 600

第一光刻胶层 110first photoresist layer 110

第二光刻胶层 120second photoresist layer 120

具体实施方式Detailed ways

为了使本发明的目的、技术方案及优点更加清楚明白,以下结合附图及实施例对本发明进行进一步详细说明。应当理解,此处所描述的具体实施例仅用以解释本发明,并不用于限定本发明。In order to make the objectives, technical solutions and advantages of the present invention clearer, the present invention will be further described in detail below with reference to the accompanying drawings and embodiments. It should be understood that the specific embodiments described herein are only used to explain the present invention, but not to limit the present invention.

请参见图1和图2,本发明提供一种感应式超导边缘探测器10,包括:衬底100、吸收层200、介质层300、绝缘层400、超导薄膜层500和约瑟夫森桥结600;所述吸收层200设置在所述衬底100的一个表面;所述介质层300设置在所述吸收层200远离与所述衬底100的表面,所述介质层300具有增透性;所述绝缘层400覆盖所述吸收层200和介质层300设置;所述超导薄膜层500设置在所述绝缘层400远离所述衬底的表面,并以连续闭合结构环绕所述吸收层200和介质层300设置;所述约瑟夫森桥结600设置在所述超导薄膜层500上。1 and 2, the present invention provides an inductive superconducting edge detector 10, including: a substrate 100, an absorption layer 200, a dielectric layer 300, an insulating layer 400, a superconducting thin film layer 500 and a Josephson bridge junction 600; the absorption layer 200 is disposed on one surface of the substrate 100; the dielectric layer 300 is disposed on the surface of the absorption layer 200 away from the substrate 100, and the dielectric layer 300 has anti-reflection properties; The insulating layer 400 is arranged to cover the absorption layer 200 and the dielectric layer 300; the superconducting thin film layer 500 is arranged on the surface of the insulating layer 400 away from the substrate, and surrounds the absorption layer 200 in a continuous closed structure and the dielectric layer 300 are arranged; the Josephson bridge junction 600 is arranged on the superconducting thin film layer 500 .

所述衬底100材料可以为硅、硅化镁、氧化镁等。所述吸收层200设置在所述介质层300和所述衬底100之间,优选地所述吸收层200和所述介质层300齐平。所述介质层300可以为二氧化硅、氮化硅、或者其具有特殊设计的结构等。所述衬底100为带有氧化层的衬底。所述吸收层200和所述超导薄膜层500为超导材料制成。已知的超导材料有铌、氮化铌、铌硅混合材料等。所述闭合结构可以为环状、闭合矩形等。并且所述闭合结构的超导薄膜层500还可以包括该超导薄膜层两端带有两个超导薄膜制成连线,用于通入偏置电流。若偏置电流为直流电流,所述约瑟夫森桥结600至少两个,通过所述超导薄膜层并联而为的双结超导环。若偏置电流为射频电流,所述约瑟夫森桥结600可以为一个。The material of the substrate 100 may be silicon, magnesium silicide, magnesium oxide, or the like. The absorption layer 200 is disposed between the dielectric layer 300 and the substrate 100 , preferably the absorption layer 200 and the dielectric layer 300 are flush. The dielectric layer 300 may be silicon dioxide, silicon nitride, or a specially designed structure thereof. The substrate 100 is a substrate with an oxide layer. The absorption layer 200 and the superconducting thin film layer 500 are made of superconducting material. Known superconducting materials include niobium, niobium nitride, and niobium-silicon mixed materials. The closed structure may be annular, closed rectangular, or the like. In addition, the superconducting thin film layer 500 of the closed structure may also include two superconducting thin films at both ends of the superconducting thin film layer to form a connection line for passing a bias current. If the bias current is a direct current, there are at least two Josephson bridge junctions 600 , a double-junction superconducting loop formed by connecting the superconducting thin film layers in parallel. If the bias current is a radio frequency current, the number of the Josephson bridge junction 600 may be one.

本实施例中所提供的感应式超导边缘探测器10包括有一层具有对光子具有增透作用的介质层300,提高了感应式超导边缘探测器10对单光子的吸收效率。The inductive superconducting edge detector 10 provided in this embodiment includes a dielectric layer 300 having an antireflection effect on photons, which improves the absorption efficiency of the inductive superconducting edge detector 10 for single photons.

在一个实施例中,所述吸收层200为铌硅薄膜或纯铌薄膜,所述超导薄膜层500为纯铌薄膜。在一个实施例中,所述吸收层200和所述超导薄膜层500的超导转变温度具有不同的超导转变温度。In one embodiment, the absorption layer 200 is a niobium silicon thin film or a pure niobium thin film, and the superconducting thin film layer 500 is a pure niobium thin film. In one embodiment, the superconducting transition temperatures of the absorption layer 200 and the superconducting thin film layer 500 have different superconducting transition temperatures.

在一个实施例中,所述吸收层200为铌硅薄膜。所述铌硅薄膜中,所述铌在所述铌硅薄膜中所占比例大于等于81.5%且小于等于97.1%,导致所述铌硅薄膜的超导转变温度处在3.85K到7.1K之间。以往,通过调节纯铌薄膜的厚度也可以调节超导薄膜层的超导转变温度。事实上,纯铌薄膜的厚度1nm时,超导转变温度为0.4K。而纯铌超导薄膜的厚度为5nm时,超导转变温度为5.9K。因此纯铌超导薄膜厚度的轻微改变对超导转变温度影响巨大,如此薄的超导薄膜均匀性也很难保证。本实施例采用的铌硅薄膜包括铌和硅成分,通过调节铌在铌硅薄膜中所占的比例可以得到超导转变温度处在3.85K到7.1K之间的超导薄膜层。而所述铌硅薄膜的厚度可以为20nm至70nm,此厚度范围制备过程中均匀性容易保证。In one embodiment, the absorber layer 200 is a niobium silicon thin film. In the niobium-silicon film, the proportion of the niobium in the niobium-silicon film is greater than or equal to 81.5% and less than or equal to 97.1%, so that the superconducting transition temperature of the niobium-silicon film is between 3.85K and 7.1K . In the past, the superconducting transition temperature of the superconducting thin film layer can also be adjusted by adjusting the thickness of the pure niobium thin film. In fact, the superconducting transition temperature is 0.4K when the thickness of pure niobium film is 1nm. When the thickness of pure niobium superconducting thin film is 5nm, the superconducting transition temperature is 5.9K. Therefore, a slight change in the thickness of the pure niobium superconducting film has a great influence on the superconducting transition temperature, and it is difficult to guarantee the uniformity of such a thin superconducting film. The niobium-silicon film used in this embodiment includes niobium and silicon components. By adjusting the proportion of niobium in the niobium-silicon film, a superconducting film layer with a superconducting transition temperature between 3.85K and 7.1K can be obtained. The thickness of the niobium-silicon thin film can be 20 nm to 70 nm, and the uniformity can be easily guaranteed in the preparation process of this thickness range.

带有两个约瑟夫森桥结的直流感应式超导边缘探测器应用时,对所述闭合状的超导薄膜层500和所述两个约瑟夫森桥结形成的双结超导环通入直流偏置电流,当偏置电流大于所述双结超导环的最大临界电流时,对所述双结超导环两端产生电压,并且这个电压数值随着所述双结超导环所感应的磁通量呈现周期性的变化。因此所述吸收层200和介质层300吸收光子后使所述双结超导环内的磁通量发生变化,此变化可通过电压数值的周期性变化反应出来。When the DC inductive superconducting edge detector with two Josephson bridge junctions is applied, the closed superconducting thin film layer 500 and the double junction superconducting ring formed by the two Josephson bridge junctions are supplied with direct current Bias current, when the bias current is greater than the maximum critical current of the double junction superconducting loop, a voltage is generated across the double junction superconducting loop, and this voltage value is induced by the double junction superconducting loop The magnetic flux exhibits periodic changes. Therefore, after the absorption layer 200 and the dielectric layer 300 absorb photons, the magnetic flux in the double-junction superconducting ring changes, and the change can be reflected by the periodic change of the voltage value.

请参见图3,本发明还提供一种感应式超导边缘探测器10制作方法,包括:Referring to FIG. 3, the present invention also provides a method for manufacturing an inductive superconducting edge detector 10, including:

S100,提供一衬底100,在所述衬底100上生长吸收层200,所述吸收层200为铌硅薄膜或纯铌薄膜。S100, a substrate 100 is provided, and an absorber layer 200 is grown on the substrate 100, and the absorber layer 200 is a niobium silicon film or a pure niobium film.

所述衬底100采用的材料可以为硅、硅化镁、氧化镁等。在所述衬底100上生长吸收层200。所述磁控溅射方式可以为直流溅射、交流溅射、射频磁控溅射、反应溅射、离子束溅射等。所述吸收层也可以为其它超导材料,如纯铌、氮化铌等。优选地,所述吸收层200生长在所述衬底100的一个表面上,并且与该表面齐平。The material used for the substrate 100 may be silicon, magnesium silicide, magnesium oxide, or the like. An absorber layer 200 is grown on the substrate 100 . The magnetron sputtering method may be direct current sputtering, alternating current sputtering, radio frequency magnetron sputtering, reactive sputtering, ion beam sputtering and the like. The absorber layer can also be other superconducting materials, such as pure niobium, niobium nitride and the like. Preferably, the absorber layer 200 is grown on one surface of the substrate 100 and is flush with the surface.

S200,在所述吸收层200表面沉积介质层300,所述介质层300对入射的单光子具有增透作用。S200 , depositing a dielectric layer 300 on the surface of the absorption layer 200 , and the dielectric layer 300 has an antireflection effect on incident single photons.

所述介质层300可以为二氧化硅、氮化硅、或者其具有特殊设计的结构等。所述表面沉积可以为物理气相沉积。优选地,所述介质层300沉积在所述吸收层200与所述衬底100接触面的对应表面上,并且与该对应表面齐平。The dielectric layer 300 may be silicon dioxide, silicon nitride, or a specially designed structure thereof. The surface deposition may be physical vapor deposition. Preferably, the dielectric layer 300 is deposited on the corresponding surface of the contact surface between the absorption layer 200 and the substrate 100 and is flush with the corresponding surface.

S300,在所述介质层300表面形成图案化的第一光刻胶层110,覆盖第一预设区域的吸收层200。S300 , a patterned first photoresist layer 110 is formed on the surface of the dielectric layer 300 to cover the absorption layer 200 in the first predetermined area.

光刻胶为对光敏感的有机化合物。曝光前对显影液不可溶,曝光后可溶,以此通过曝光将特定区域保护起来。优选地,所述第一光刻胶层110覆盖所述介质层300与所述吸收层200接触面的对应表面上,并且覆盖该对应表面上中央部分区域。Photoresists are organic compounds that are sensitive to light. It is insoluble to the developer before exposure and soluble after exposure, so that specific areas are protected by exposure. Preferably, the first photoresist layer 110 covers the corresponding surface of the contact surface between the dielectric layer 300 and the absorption layer 200, and covers a central part of the corresponding surface.

S400,进行第一次刻蚀,刻蚀掉所述第一预设区域外的吸收层200和介质层300,暴露出所述衬底100。S400 , performing a first etching, etching off the absorption layer 200 and the dielectric layer 300 outside the first preset area, and exposing the substrate 100 .

所述刻蚀可以为干法刻蚀也可以为湿法刻蚀。优选地所述刻蚀为干法刻蚀的等离子体刻蚀。The etching may be dry etching or wet etching. Preferably, the etching is plasma etching of dry etching.

在一个实施例中,采用氟基的等离子体进行第一次刻蚀,刻蚀掉所述第一预设区域外的吸收层200和介质层300,暴露出所述衬底100。In one embodiment, a fluorine-based plasma is used to perform the first etching, and the absorption layer 200 and the dielectric layer 300 outside the first predetermined region are etched away to expose the substrate 100 .

用于刻蚀的等离子体一般为气态。氟基的等离子体可为碳氟化合物等离子体。在刻蚀过程中,根据目的和作用不同还可以采用氧气等离子体、氮气等离子体等。优选地,最终刻蚀后的结构为所述衬底100表面中央被所述吸收层200、介质层300和所述第一光刻胶层110覆盖,并且所述衬底100表面中央被所述吸收层200、介质层300和所述第一光刻胶层110齐平。The plasma used for etching is generally gaseous. The fluorine-based plasma may be a fluorocarbon plasma. In the etching process, oxygen plasma, nitrogen plasma, etc. can also be used according to different purposes and functions. Preferably, the final etched structure is that the center of the surface of the substrate 100 is covered by the absorption layer 200 , the dielectric layer 300 and the first photoresist layer 110 , and the center of the surface of the substrate 100 is covered by the The absorption layer 200 , the dielectric layer 300 and the first photoresist layer 110 are flush.

S500,去除剩余的第一光刻胶层,沉积形成绝缘层400,覆盖所述吸收层200和介质层300。S500 , removing the remaining first photoresist layer, and depositing to form an insulating layer 400 covering the absorption layer 200 and the dielectric layer 300 .

在一个实施例中,将所述第一次刻蚀后的结构采用清洗剂进行去胶处理。In one embodiment, the structure after the first etching is subjected to a degumming treatment with a cleaning agent.

在一个实施例中,在所述去胶后的结构表面,采用原子层沉积(ALD)技术沉积一原子厚度的绝缘层。In one embodiment, an insulating layer with a thickness of one atom is deposited on the surface of the debonded structure by using an atomic layer deposition (ALD) technique.

原子层沉积是一种可以将物质以单原子膜的形式一层一层的镀在基底表面的方法。原子层沉积与普通的化学沉积有相似之处。但在原子层沉积过程中,新一层原子膜的化学反应是直接与之前一层相关联的,这种方式使每次反应只沉积一层原子。采用原子层沉积(ALD)技术沉积一绝缘层的厚度为5-10nm。优选地,所述绝缘层400覆盖所述衬底100与所述吸收层200接触的表面暴露区域并对所述吸收层200和所述介质层的表面全包覆。用原子层沉积(ALD)制作的绝缘层400,可以是氧化硅,也可以是氧化铪。绝缘层400保证了吸收层200与超导薄膜层500之间绝缘,如此可使所述吸收层200的表面积达到最大,即所述吸收层200的外径接近于所述超导薄膜层500内径,有助于提高了感应式超导边缘探测器的探测效率。Atomic layer deposition is a method in which substances can be deposited layer by layer on the surface of a substrate in the form of a single atomic film. Atomic layer deposition is similar to ordinary chemical deposition. But in atomic layer deposition, the chemical reaction of a new layer of atoms is directly linked to the previous layer, in such a way that only one layer of atoms is deposited at each reaction. Atomic layer deposition (ALD) technique is used to deposit an insulating layer with a thickness of 5-10 nm. Preferably, the insulating layer 400 covers the exposed surface area of the substrate 100 in contact with the absorption layer 200 and completely covers the surfaces of the absorption layer 200 and the dielectric layer. The insulating layer 400 made by atomic layer deposition (ALD) may be silicon oxide or hafnium oxide. The insulating layer 400 ensures insulation between the absorbing layer 200 and the superconducting thin film layer 500 , so that the surface area of the absorbing layer 200 can be maximized, that is, the outer diameter of the absorbing layer 200 is close to the inner diameter of the superconducting thin film layer 500 , which helps to improve the detection efficiency of the inductive superconducting edge detector.

S600,在所述绝缘层400表面生长一超导薄膜层500,所述超导薄膜层为铌薄膜。S600, growing a superconducting thin film layer 500 on the surface of the insulating layer 400, where the superconducting thin film layer is a niobium thin film.

所述磁控溅射方式可以为直流溅射、交流溅射、射频磁控溅射、反应溅射、离子束溅射等。所述超导薄膜层可以为其它超导材料,如纯铌、氮化铌等。优选地,所述超导薄膜层500生长在所述绝缘层400表面,并与所述绝缘层400表面的侧边齐平。The magnetron sputtering method may be direct current sputtering, alternating current sputtering, radio frequency magnetron sputtering, reactive sputtering, ion beam sputtering and the like. The superconducting thin film layer can be other superconducting materials, such as pure niobium, niobium nitride and the like. Preferably, the superconducting thin film layer 500 is grown on the surface of the insulating layer 400 and is flush with the sides of the surface of the insulating layer 400 .

S700,在所述超导薄膜层500上,形成图案化的第二光刻胶层120,覆盖所述第二预设区域,所述第二预设区域为设置在所述吸收层200和介质层300外围闭合状连续区域。S700, on the superconducting thin film layer 500, a patterned second photoresist layer 120 is formed to cover the second preset area, and the second preset area is disposed on the absorption layer 200 and the medium The layer 300 has a closed continuous area on the periphery.

S800,进行第二次刻蚀,刻蚀掉所述第二预设区域外的超导薄膜层500,获得闭合环状超导结构为所述衬底表面上连续环绕在所述吸收层、介质层和部分绝缘层的外围。S800 , perform a second etching, etch away the superconducting thin film layer 500 outside the second preset area, and obtain a closed-loop superconducting structure that continuously surrounds the absorption layer and the medium on the surface of the substrate layer and part of the periphery of the insulating layer.

在一个实施例中,在所述进行第二次刻蚀,刻蚀出所述第二预设结构的步骤中,所述进行第二次刻蚀的时间大于预定刻蚀铌薄膜所需时间。In one embodiment, in the step of performing the second etching to etch out the second preset structure, the time for performing the second etching is longer than the predetermined time required for etching the niobium thin film.

进行第二次刻蚀的时间实际应比预定刻蚀铌薄膜所需时间长出预定时间。铌薄膜的刻蚀速率大约是介质层300的刻蚀速率的10倍。若刻蚀时间超过预定刻蚀铌薄膜所需时间,先暴露出来的吸收层上的介质层就会被减薄,并且介质层的刻蚀深度不会影响到透光的性能,而其下面的吸收层不会被刻蚀。优选地,经过第二次刻蚀后形成具体结构为:所述吸收层200位于所述衬底100表面的中央,所述超导薄膜层500为闭合状,可以为环形也可以为矩形等闭合结构,环绕于所述吸收层200外围。并且在所述超导薄膜层500与所述衬底之间、所述超导薄膜层500与所述吸收层200和介质层300之间设有绝缘层400。The time for the second etching should actually be longer than the predetermined time required for etching the niobium thin film. The etching rate of the niobium thin film is about 10 times that of the dielectric layer 300 . If the etching time exceeds the predetermined time required to etch the niobium thin film, the dielectric layer on the first exposed absorber layer will be thinned, and the etching depth of the dielectric layer will not affect the light transmission performance, while the underlying dielectric layer will be thinned. The absorber layer will not be etched. Preferably, the specific structure formed after the second etching is as follows: the absorption layer 200 is located in the center of the surface of the substrate 100 , and the superconducting thin film layer 500 is closed, which may be annular or rectangular, etc. The structure surrounds the periphery of the absorption layer 200 . And an insulating layer 400 is provided between the superconducting thin film layer 500 and the substrate, and between the superconducting thin film layer 500 and the absorption layer 200 and the dielectric layer 300 .

由于所述吸收层200上需要增透膜,这些材料在刻蚀铌的工艺中刻蚀速率很低,在制作吸收层200后,再制作介质层300,最后再沉积超导薄膜层500,绝缘层400相当于在吸收层200与超导薄膜层500之间加了刻蚀阻挡层。在刻蚀预设结构结束后,不会对吸收层200继续刻蚀,保证了器件性能的稳定性和可重复性。绝缘层400是为了吸收层与超导薄膜层500不能形成超导连接。Since the absorption layer 200 needs an anti-reflection film, the etching rate of these materials is very low in the process of etching niobium. After the absorption layer 200 is fabricated, the dielectric layer 300 is fabricated, and finally the superconducting thin film layer 500 is deposited. The layer 400 is equivalent to adding an etch stop layer between the absorber layer 200 and the superconducting thin film layer 500 . After the etching of the preset structure is completed, the absorption layer 200 will not be further etched, which ensures the stability and repeatability of the device performance. The insulating layer 400 is for preventing the superconducting connection between the absorber layer and the superconducting thin film layer 500 .

S900,在所述闭合环状超导结构上,曝光制作出约瑟夫森桥结600。S900 , exposing the closed-loop superconducting structure to form a Josephson bridge junction 600 .

在其中一个实施例中,在所述环状超导结构上,采用聚焦离子束(FIB)直接制作出约瑟夫森桥结600;或者采用电子束曝光(EBL)制作图形,然后采用干法刻蚀制作出约瑟夫森桥结600。In one of the embodiments, on the annular superconducting structure, the Josephson bridge junction 600 is directly fabricated by using focused ion beam (FIB); or the pattern is fabricated by electron beam exposure (EBL), and then dry etching is used Make Josephson Bridge Knot 600.

具体地,在所述环状超导结构上,采用聚焦离子束(FIB)制作出两个约瑟夫森桥结600。聚焦离子束是一种精密的微加工手段,有非常高的加工精度,最细能加工出的几十纳米的线条。这主要是因为在固体材料中离子的能量转移效率远远高于电子。常用的电子束曝光抗蚀剂对离子的灵敏度要比对电子束高100倍以上。除了精度高之外,离子束曝光的另一优点是几乎没有邻近效应。由于离子本身的质量远大于电子,离子在抗蚀剂中的散射范围要远小于电子,并且几乎没有背散射效应。Specifically, on the annular superconducting structure, two Josephson bridge junctions 600 are fabricated by using a focused ion beam (FIB). Focused ion beam is a precise micro-machining method, with very high machining accuracy, the thinnest line that can be processed is tens of nanometers. This is mainly because the energy transfer efficiency of ions in solid materials is much higher than that of electrons. Commonly used electron beam exposure resists are more than 100 times more sensitive to ions than to electron beams. In addition to the high precision, another advantage of ion beam exposure is that there are virtually no proximity effects. Since the mass of the ion itself is much greater than that of the electron, the scattering range of the ion in the resist is much smaller than that of the electron, and there is almost no backscattering effect.

在一个实施例中,完成步骤S700后步骤S800之前对第二刻录胶进行清洗,以使制作过程中FIB离子束直接轰击样品表面不需要的部分时不带光刻胶,直接形成预设的结构。减少光刻胶的污染,提高制备质量。In one embodiment, after the step S700 is completed, the second recording resin is cleaned before the step S800, so that the FIB ion beam directly bombards the unneeded part of the sample surface without the photoresist during the production process, and the preset structure is directly formed . Reduce photoresist contamination and improve preparation quality.

在其中一个实施例中,所述铌硅薄膜的制备方法包括:In one embodiment, the preparation method of the niobium silicon thin film includes:

提供磁控共溅射室以及设置在所述磁控共溅射室内的铌靶和硅靶;providing a magnetron co-sputtering chamber and a niobium target and a silicon target disposed in the magnetron co-sputtering chamber;

控制所述磁控溅射室的真空度及所述铌靶和所述硅靶以预定溅射气压、预定溅射功率进行磁控溅射预定溅射时间,在所述衬底表面沉积成形为所述吸收层或所述超导薄膜层,Control the vacuum degree of the magnetron sputtering chamber and the niobium target and the silicon target to perform magnetron sputtering with a predetermined sputtering gas pressure and a predetermined sputtering power for a predetermined sputtering time, and depositing a shape on the surface of the substrate as follows the absorption layer or the superconducting thin film layer,

其中,铌在所述吸收层中所占比例大于等于81.5%且小于等于97.1%,导致所述吸收层的超导转变温度在3.85K到7.1K之间。Wherein, the proportion of niobium in the absorber layer is greater than or equal to 81.5% and less than or equal to 97.1%, resulting in a superconducting transition temperature of the absorber layer between 3.85K and 7.1K.

目前感应式超导边缘探测器内包含两种超导转变温度不同的铌膜或者铌硅膜。一种应用于超导薄膜层,通常其超导转变温度(Tc)大约是9K。另一种应用于吸收层的吸收薄膜由更薄的铌膜或者铌硅膜构成。这两种薄膜分别沉积、刻蚀或者剥离形成结构。超导薄膜层采用纯铌薄膜而吸收层采用铌硅薄膜便于形成吸收层和超导薄膜层转变温度不同的感应式超导边缘探测器。At present, the inductive superconducting edge detector contains two kinds of niobium films or niobium-silicon films with different superconducting transition temperatures. One is applied to superconducting thin film layers, which typically have a superconducting transition temperature (T c ) of about 9K. Another absorber film applied to the absorber layer consists of a thinner niobium film or a niobium silicon film. The two films are deposited, etched or lifted off to form the structures, respectively. The superconducting thin film layer adopts pure niobium thin film and the absorption layer adopts niobium silicon thin film, which is convenient to form an inductive superconducting edge detector with different transition temperatures of the absorption layer and the superconducting thin film layer.

传统上,制作感应式超导边缘探测器可行的方法是先采用沉积、刻蚀的方法形成的超导薄膜层的结构,然后采用剥离的方法,形成吸收层。剥离的方法需要先用光刻胶形成图形,然后放入溅射腔室中,沉积超导薄膜层,然后剥离形成吸收结构。剥离的方法虽然可行,但是通常沉积超导薄膜层的溅射设备都需要极高的真空度,带光刻胶进入设备,会影响沉积薄膜的质量。Traditionally, a feasible method for making an inductive superconducting edge detector is to first use a structure of a superconducting thin film layer formed by deposition and etching, and then use a stripping method to form an absorption layer. The lift-off method requires first patterning with photoresist, then placing it in a sputtering chamber, depositing a superconducting thin film layer, and then lift-off to form an absorbing structure. Although the peeling method is feasible, the sputtering equipment for depositing the superconducting thin film layer usually requires a very high degree of vacuum, and entering the equipment with photoresist will affect the quality of the deposited film.

本发明此制作方法设计合理,在制作过程中进行了去胶处理,使得做磁控溅射时不再掺杂光刻胶,提升了超导薄膜层的沉积质量。The manufacturing method of the present invention has a reasonable design, and a degumming treatment is performed during the manufacturing process, so that the photoresist is no longer doped during magnetron sputtering, and the deposition quality of the superconducting thin film layer is improved.

以上所述实施例的各技术特征可以进行任意的组合,为使描述简洁,未对上述实施例中的各个技术特征所有可能的组合都进行描述,然而,只要这些技术特征的组合不存在矛盾,都应当认为是本说明书记载的范围。The technical features of the above-described embodiments can be combined arbitrarily. For the sake of brevity, all possible combinations of the technical features in the above-described embodiments are not described. However, as long as there is no contradiction between the combinations of these technical features, All should be regarded as the scope described in this specification.

以上所述实施例仅表达了本发明的几种实施方式,其描述较为具体和详细,但并不能因此而理解为对发明专利范围的限制。应当指出的是,对于本领域的普通技术人员来说,在不脱离本发明构思的前提下,还可以做出若干变形和改进,这些都属于本发明的保护范围。因此,本发明专利的保护范围应以所附权利要求为准。The above-mentioned embodiments only represent several embodiments of the present invention, and the descriptions thereof are specific and detailed, but should not be construed as a limitation on the scope of the invention patent. It should be pointed out that for those of ordinary skill in the art, without departing from the concept of the present invention, several modifications and improvements can also be made, which all belong to the protection scope of the present invention. Therefore, the protection scope of the patent of the present invention should be subject to the appended claims.

Claims (10)

1. An inductive superconducting edge finder, comprising:
a substrate;
an absorption layer disposed on one surface of the substrate;
the dielectric layer is arranged on the surface, far away from the substrate, of the absorption layer and has permeability;
the insulating layer covers the substrate, the absorbing layer and the outer surface of the dielectric layer, the insulating layer is made of silicon oxide or hafnium oxide, and the thickness of the insulating layer is 5-10 nm;
the superconducting thin film layer is arranged on the surface, far away from the substrate, of the insulating layer and is arranged around the absorption layer and the dielectric layer in a continuous closed structure;
a Josephson bridge junction disposed on the superconducting thin film layer.
2. The inductive superconducting edge finder of claim 1,
the absorption layer is a niobium-silicon film or a pure niobium film, and the superconducting film layer is a pure niobium film.
3. An inductive superconducting edge detector according to claim 2, wherein the niobium in the niobium-silicon thin film accounts for more than or equal to 81.5% and less than or equal to 97.1%, and the superconducting transition temperature of the niobium-silicon thin film is between 3.85K and 7.1K.
4. An inductively superconducting edge finder according to claim 3, wherein the absorption layer and the superconducting thin film layer have different superconducting transition temperatures.
5. A method of fabricating an inductive superconducting edge probe, the method comprising:
providing a substrate, and growing an absorption layer on the substrate, wherein the absorption layer is a niobium-silicon film or a pure niobium film;
depositing a dielectric layer on the surface of the absorption layer, wherein the dielectric layer has an anti-reflection effect on incident single photons;
forming a patterned first photoresist layer on the surface of the dielectric layer, and covering the absorption layer of the first preset area;
etching the absorption layer and the dielectric layer outside the first preset area for the first time to expose the substrate;
removing the photoresist, depositing to form an insulating layer, covering the substrate, the absorbing layer and the outer surface of the dielectric layer, wherein the insulating layer is silicon dioxide or hafnium dioxide, and the thickness of the insulating layer is 5-10 nm;
growing a superconducting thin film layer on the surface of the insulating layer, wherein the superconducting thin film layer is a pure niobium thin film;
forming a patterned second photoresist layer on the superconducting thin film layer to cover a second preset area, wherein the second preset area is an annular continuous area at the periphery of the absorption layer and the dielectric layer;
performing second etching to etch the superconducting thin film layer outside the second preset region to obtain a closed annular superconducting structure, wherein the closed annular superconducting structure is formed by continuously surrounding the absorption layer, the dielectric layer and part of the insulating layer on the surface of the substrate;
and exposing the closed annular superconducting structure to manufacture a Josephson bridge junction.
6. The method for manufacturing an induction type superconducting edge detector according to claim 5, wherein the step of performing the first etching to etch away the absorption layer and the dielectric layer outside the first predetermined region and expose the substrate comprises:
and etching the absorption layer outside the first preset area by adopting fluorine-based plasma for the first time to expose the substrate.
7. The method of claim 5, wherein the steps of removing the photoresist, depositing an insulating layer, and covering the substrate and the outer surfaces of the absorber and dielectric layers comprise:
carrying out photoresist removing treatment on the structure after the first etching by adopting a cleaning agent;
and depositing an insulating layer with the thickness of 5-10nm on the surface of the structure after the photoresist is removed by adopting an Atomic Layer Deposition (ALD) technology.
8. The method for manufacturing an induction type superconducting edge detector according to claim 5, wherein in the step of performing the second etching to etch off the superconducting thin film layer outside the second preset region to obtain the closed annular superconducting structure, the substrate surface continuously surrounds the periphery of the absorption layer, the dielectric layer and the partial insulating layer, and the time for performing the second etching is longer than the time required for etching the pure niobium thin film.
9. An inductive superconducting edge detector fabrication method according to claim 5 wherein said step of exposing said closed loop superconducting structure to form a Josephson bridge junction comprises:
on the annular superconducting structure, a Josephson bridge junction is directly manufactured by adopting a Focused Ion Beam (FIB) or is manufactured by adopting an electron beam Exposure (EBL) to manufacture a pattern and then is manufactured by adopting dry etching.
10. The method for manufacturing an inductive superconducting edge probe according to claim 5, wherein the method for manufacturing the niobium-silicon thin film comprises the following steps:
providing a magnetron co-sputtering chamber and a niobium target and a silicon target which are arranged in the magnetron co-sputtering chamber;
controlling the vacuum degree of the magnetron sputtering chamber and carrying out magnetron sputtering on the niobium target and the silicon target for a preset sputtering time at a preset sputtering air pressure and a preset sputtering power, depositing and forming the absorption layer or the superconducting thin film layer on the surface of the substrate,
wherein, niobium accounts for more than or equal to 81.5% and less than or equal to 97.1% of the absorption layer, and the superconducting transition temperature of the absorption layer is between 3.85K and 7.1K.
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