CN109267340A - 一种抗静电整理剂及其制备方法 - Google Patents

一种抗静电整理剂及其制备方法 Download PDF

Info

Publication number
CN109267340A
CN109267340A CN201810871632.3A CN201810871632A CN109267340A CN 109267340 A CN109267340 A CN 109267340A CN 201810871632 A CN201810871632 A CN 201810871632A CN 109267340 A CN109267340 A CN 109267340A
Authority
CN
China
Prior art keywords
parts
antistatic
catalyst
agent
finishing agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810871632.3A
Other languages
English (en)
Inventor
茅瑞
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ningbo Axiang Fine Chemical Co Ltd
Original Assignee
Ningbo Axiang Fine Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ningbo Axiang Fine Chemical Co Ltd filed Critical Ningbo Axiang Fine Chemical Co Ltd
Priority to CN201810871632.3A priority Critical patent/CN109267340A/zh
Publication of CN109267340A publication Critical patent/CN109267340A/zh
Pending legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/48—Oxides or hydroxides of chromium, molybdenum or tungsten; Chromates; Dichromates; Molybdates; Tungstates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/58—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
    • D06M11/64—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides with nitrogen oxides; with oxyacids of nitrogen or their salts
    • D06M11/65—Salts of oxyacids of nitrogen
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
    • D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/144—Alcohols; Metal alcoholates
    • D06M13/148—Polyalcohols, e.g. glycerol or glucose
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/395—Isocyanates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • D06M15/05—Cellulose or derivatives thereof
    • D06M15/09—Cellulose ethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

本发明公开了一种抗静电整理剂，按重量份包括二甲基亚双羟乙基脲40‑45份、阳离子聚氨酯水乳液10‑15份、聚氧乙烯醚10‑15份、异氰酸酯2‑5份、壳聚糖20‑30份、催化剂2‑5份、抗静电剂5‑10份、水70‑80份，所述催化剂为Ti3Al1+xC2，其中x为0.1、0.15或0.2，所述抗静电剂按重量份包括二氧化硅40‑50份、氧化钼5‑10份、水杨酸甲酯5‑10份、甲基纤维素2‑5份、硝酸镱1‑2份、甘油50‑60份。本发明得到的一种抗静电整理剂，原料绿色无污染。采用本发明所述的织物抗静电整理剂整理织物，整理后的织物表面体积比电阻下降103‑104Ω·cm，且整理后面料的强力和延伸性无明显变化，基本保持了原有织物的风格和性能。

Description

一种抗静电整理剂及其制备方法
技术领域
本发明涉及一种纺织助剂，特别是一种抗静电整理剂及其制备方法。
背景技术
随着生活水平的提高，人们越来越重视生活的质量，希望能获得有舒适感的衣着以及卫生健康的居住环境，所以人们对于各种各样的纺织品要求越来越高，特别是安全、安心、舒适、健康、卫生、清洁等绿色观念的形成，使纺织品的抗静电、防臭后整理加工更加受到人们的重视。因此有必要研究一种更加有效的抗静电整理剂。
发明内容
本发明的目的是为了解决上述现有技术的不足而提供一种高效安全的抗静电整理剂及其制备方法。
为了实现上述目的，本发明所设计的一种抗静电整理剂，按重量份包括二甲基亚双羟乙基脲40-45份、阳离子聚氨酯水乳液10-15份、聚氧乙烯醚10-15份、异氰酸酯2-5份、壳聚糖20-30份、催化剂2-5份、抗静电剂5-10份、水70-80份，所述催化剂为Ti3Al1+xC2，其中x为0.1、0.15或 0.2，所述抗静电剂按重量份包括二氧化硅40-50份、氧化钼5-10份、水杨酸甲酯5-10份、甲基纤维素2-5份、硝酸镱1-2份、甘油50-60份。
一种抗静电整理剂的制备方法，包括以下步骤：
A、制备催化剂，取粉末TiO2与活性炭粉末混合均匀后，置于微波炉中，加热至1500℃，保持3~8 min，待冷却后稍加研磨得到TiC，然后按照Ti:Al:TiC=1:(1+x):2的比例将Ti、Al和TiC研磨混合后转移到不锈钢球磨罐中，罐中注入约2/3的聚乙二醇，球磨一段时间后，烘干后即得到催化剂；
B、制备抗静电剂，将二氧化硅40-50份、氧化钼5-10份、水杨酸甲酯5-10份、甲基纤维素2-5份、硝酸镱1-2份溶于甘油50-60份中，经搅拌均匀即得抗静电剂；
C、制备抗静电整理剂，将二甲基亚双羟乙基脲40-45份、阳离子聚氨酯水乳液10-15份、聚氧乙烯醚10-15份、异氰酸酯2-5份、壳聚糖20-30份、催化剂2-5份、抗静电剂5-10份、水70-80份加入到反应器中，用搅拌机低速搅拌4-6分钟，转速为100-150转/分钟，然后改为高速搅拌23-26分钟，转速为1500-2000转/分钟，搅拌分散均匀后即得抗静电整理剂。
所述催化剂为Ti3Al1+xC2，其中x为0.1、0.15或 0.2，这种复合结构具有优良的电子转移能力，可以有效地吸附和活化反应物，从而实现催化过程。
所述抗静电剂中的二氧化硅和氧化钼融合到甘油中可以起到抗静电的作用，而水杨酸甲酯和甲基纤维素起到润滑消泡的作用，硝酸镱则对纺织面料进行除臭的作用。
本发明得到的一种抗静电整理剂，原料绿色无污染。采用本发明所述的织物抗静电整理剂整理织物，整理后的织物表面体积比电阻下降103-104Ω·cm，且整理后面料的强力和延伸性无明显变化，基本保持了原有织物的风格和性能。
具体实施方式
下面结合实施例对本发明进一步说明。
实施例1：
本实施例提供的一种抗静电整理剂，按重量份包括二甲基亚双羟乙基脲40份、阳离子聚氨酯水乳液10份、聚氧乙烯醚10份、异氰酸酯2份、壳聚糖20份、催化剂2份、抗静电剂5份、水70份，所述催化剂为Ti3Al1.2C2，所述抗静电剂按重量份包括二氧化硅40份、氧化钼5份、水杨酸甲酯5份、甲基纤维素2份、硝酸镱1份、甘油50份。
一种抗静电整理剂的制备方法，包括以下步骤：
A、制备催化剂，取粉末TiO2与活性炭粉末混合均匀后，置于微波炉中，加热至1500℃，保持3~8 min，待冷却后稍加研磨得到TiC，然后按照Ti:Al:TiC=1:1.2:2的比例将Ti、Al和TiC研磨混合后转移到不锈钢球磨罐中，罐中注入约2/3的聚乙二醇，球磨一段时间后，烘干后即得到催化剂；
B、制备抗静电剂，将二氧化硅40份、氧化钼5份、水杨酸甲酯5份、甲基纤维素2份、硝酸镱1份溶于甘油50份中，经搅拌均匀即得抗静电剂；
C、制备抗静电整理剂，将二甲基亚双羟乙基脲40份、阳离子聚氨酯水乳液10份、聚氧乙烯醚10份、异氰酸酯2份、壳聚糖20份、催化剂2份、抗静电剂5份、水70份加入到反应器中，用搅拌机低速搅拌4-6分钟，转速为100-150转/分钟，然后改为高速搅拌23-26分钟，转速为1500-2000转/分钟，搅拌分散均匀后即得抗静电整理剂。
经实验，采用本实施例制得的抗静电整理剂来整理织物，整理后的织物表面体积比电阻下降103-104Ω·cm。
实施例2：
本实施例提供的一种抗静电整理剂，其大体配比和实施例1相同，其主要区别在于所述抗静电整理剂按重量份包括二甲基亚双羟乙基脲45份、阳离子聚氨酯水乳液15份、聚氧乙烯醚15份、异氰酸酯5份、壳聚糖30份、催化剂5份、抗静电剂10份、水80份。
经实验，采用本实施例制得的抗静电整理剂来整理织物，整理后的织物表面体积比电阻下降103-104Ω·cm。
实施例3：
本实施例提供的一种抗静电整理剂，其大体配比和实施例1相同，其主要区别在于所述抗静电剂按重量份包括二氧化硅50份、氧化钼10份、水杨酸甲酯10份、甲基纤维素5份、硝酸镱2份、甘油60份。
经实验，采用本实施例制得的抗静电整理剂来整理织物，整理后的织物表面体积比电阻下降103-104Ω·cm。
以上详细描述了本发明的优选实施方式，但是，本发明并不限于上述实施方式中的具体细节，在本发明的技术构思范围内，可以对本发明的技术方案进行多种简单变型，这些简单变型均属于本发明的保护范围。
另外需要说明的是，在上述具体实施方式中所描述的各个具体技术特征，在不矛盾的情况下，可以通过任何合适的方式进行组合，为了避免不必要的重复，本发明对各种可能的组合方式不再另行说明。
此外，本发明的各种不同的实施方式之间也可以进行任意组合，只要其不违背本发明的思想，其同样应当视为本发明所公开的内容。

Claims (2)

1.一种抗静电整理剂，其特征在于，按重量份包括二甲基亚双羟乙基脲40-45份、阳离子聚氨酯水乳液10-15份、聚氧乙烯醚10-15份、异氰酸酯2-5份、壳聚糖20-30份、催化剂2-5份、抗静电剂5-10份、水70-80份，所述催化剂为Ti3Al1+xC2，其中x为0.1、0.15或 0.2，所述抗静电剂按重量份包括二氧化硅40-50份、氧化钼5-10份、水杨酸甲酯5-10份、甲基纤维素2-5份、硝酸镱1-2份、甘油50-60份。
2.一种如权利要求1所述的抗静电整理剂的制备方法，其特征在于，包括以下步骤：
A、制备催化剂，取粉末TiO2与活性炭粉末混合均匀后，置于微波炉中，加热至1500℃，保持3~8 min，待冷却后稍加研磨得到TiC，然后按照Ti:Al:TiC=1:(1+x):2的比例将Ti、Al和TiC研磨混合后转移到不锈钢球磨罐中，罐中注入约2/3的聚乙二醇，球磨一段时间后，烘干后即得到催化剂；
B、制备抗静电剂，将二氧化硅40-50份、氧化钼5-10份、水杨酸甲酯5-10份、甲基纤维素2-5份、硝酸镱1-2份溶于甘油50-60份中，经搅拌均匀即得抗静电剂；
C、制备抗静电整理剂，将二甲基亚双羟乙基脲40-45份、阳离子聚氨酯水乳液10-15份、聚氧乙烯醚10-15份、异氰酸酯2-5份、壳聚糖20-30份、催化剂2-5份、抗静电剂5-10份、水70-80份加入到反应器中，用搅拌机低速搅拌4-6分钟，转速为100-150转/分钟，然后改为高速搅拌23-26分钟，转速为1500-2000转/分钟，搅拌分散均匀后即得抗静电整理剂。
CN201810871632.3A 2018-08-02 2018-08-02 一种抗静电整理剂及其制备方法 Pending CN109267340A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810871632.3A CN109267340A (zh) 2018-08-02 2018-08-02 一种抗静电整理剂及其制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810871632.3A CN109267340A (zh) 2018-08-02 2018-08-02 一种抗静电整理剂及其制备方法

Publications (1)

Publication Number Publication Date
CN109267340A true CN109267340A (zh) 2019-01-25

Family

ID=65153048

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810871632.3A Pending CN109267340A (zh) 2018-08-02 2018-08-02 一种抗静电整理剂及其制备方法

Country Status (1)

Country Link
CN (1) CN109267340A (zh)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112981647A (zh) * 2021-02-07 2021-06-18 康宝莱(宁波)织造有限公司 一种野生柞蚕丝拉毛纱及其制备方法

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112981647A (zh) * 2021-02-07 2021-06-18 康宝莱(宁波)织造有限公司 一种野生柞蚕丝拉毛纱及其制备方法

Similar Documents

Publication Publication Date Title
KR101451320B1 (ko) 기능성 원사의 제조방법
CN101671952B (zh) 负离子整理液及其制备方法和负离子功能性无缝内衣
CN109267340A (zh) 一种抗静电整理剂及其制备方法
CN101638846A (zh) 抑菌抗静电多功能无纺布
CN105220481B (zh) 一种婴儿服装专用的抗静电面料
CN106351014A (zh) 红豆绒远红外发热保暖功能面料
CN1923294A (zh) 抗菌、除臭、净化空气的组合物、其制备方法及应用
CN107287899A (zh) 棉织物的抗菌整理方法
CN102733177B (zh) 一种隔热涂层织物
CN105175591A (zh) 有机蒙脱土改性聚乙烯醇缩甲醛海绵的制备方法
CN107142529A (zh) 一种羽毛球加工用羽毛洗毛工艺
CN108060493A (zh) 抗辐射靠垫及其制备方法
CN106319672B (zh) 一种光催化纤维及其制备方法
CN1451811A (zh) 纳米银系抗菌织物的制备工艺及应用
CN109208332A (zh) 一种抗菌整理剂及其制备方法
CN108823964A (zh) 一种氧化锌-银复合抗菌棉织物的制备方法
CN105821665A (zh) 一种多功能es纤维纺丝油剂
CN108018617A (zh) 一种吸湿抗静电涤纶的制备方法
CN107080699A (zh) 一种改性凹凸棒土高舒适性剃须膏及其制备方法
CN106869988A (zh) 一种防止煤炭自燃用阻化剂的制备方法
CN103103744A (zh) 一种保暖织物整理剂及其制备方法
CN103182088B (zh) Plga修饰磁性纳米簇及其制备方法和应用
CN108609857A (zh) 一种采用催化裂化废催化剂制备微晶玻璃的方法
CN109016717A (zh) 大衣面料的生产工艺
CN106377131A (zh) 一种具备除螨功能的高分子健康枕及其制备方法

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20190125

WD01 Invention patent application deemed withdrawn after publication