CN109266412A - 环保型甲醇汽油复合添加剂 - Google Patents

环保型甲醇汽油复合添加剂 Download PDF

Info

Publication number
CN109266412A
CN109266412A CN201811408774.2A CN201811408774A CN109266412A CN 109266412 A CN109266412 A CN 109266412A CN 201811408774 A CN201811408774 A CN 201811408774A CN 109266412 A CN109266412 A CN 109266412A
Authority
CN
China
Prior art keywords
compound additive
parts
methanol gasoline
propylene glycol
environment
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201811408774.2A
Other languages
English (en)
Inventor
税正强
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Luzhou Hydrogen Power Energy Co Ltd High-Tech Branch
Original Assignee
Luzhou Hydrogen Power Energy Co Ltd High-Tech Branch
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Luzhou Hydrogen Power Energy Co Ltd High-Tech Branch filed Critical Luzhou Hydrogen Power Energy Co Ltd High-Tech Branch
Priority to CN201811408774.2A priority Critical patent/CN109266412A/zh
Publication of CN109266412A publication Critical patent/CN109266412A/zh
Withdrawn legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/16Hydrocarbons
    • C10L1/1616Hydrocarbons fractions, e.g. lubricants, solvents, naphta, bitumen, tars, terpentine
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/185Ethers; Acetals; Ketals; Aldehydes; Ketones
    • C10L1/1852Ethers; Acetals; Ketals; Orthoesters
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/19Esters ester radical containing compounds; ester ethers; carbonic acid esters
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/22Organic compounds containing nitrogen
    • C10L1/222Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/22Organic compounds containing nitrogen
    • C10L1/228Organic compounds containing nitrogen containing at least one carbon-to-nitrogen double bond, e.g. guanidines, hydrazones, semicarbazones, imines; containing at least one carbon-to-nitrogen triple bond, e.g. nitriles
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/30Organic compounds compounds not mentioned before (complexes)
    • C10L1/305Organic compounds compounds not mentioned before (complexes) organo-metallic compounds (containing a metal to carbon bond)
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2230/00Function and purpose of a components of a fuel or the composition as a whole
    • C10L2230/22Function and purpose of a components of a fuel or the composition as a whole for improving fuel economy or fuel efficiency

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

本发明公开了环保型甲醇汽油复合添加剂,按重量份配比计算,所述复合添加剂包括以下组分:N‑乙酰基‑2‑甲基‑1,3‑丙二胺,3~8份,丙二醇单甲醚乙酸酯,0.6~1.9份,碳酸二甲酯,0.2~1.4份,丙二醇单甲醚乙酸酯,1~4份,环戊二烯三羰基锰,0.1~0.9份,乙基叔丁基醚,0.3~1.6份,N,N’‑二亚水杨酸‑1,2‑丙二胺,2~5份,8‑羟基喹啉,0.1~0.7份,石脑油,0.05~0.3份。本发明提供了一种具有制备方法简单、环保效果好等优点的甲醇汽油复合添加剂,在保障甲醇汽油的燃烧效率、且利于增强动力的同时,大大增加了燃烧后一氧化碳的减排率以及烟尘的减排率。

Description

环保型甲醇汽油复合添加剂
技术领域
本发明涉及汽车燃油技术领域,具体涉及一种环保型甲醇汽油复合添加剂。
背景技术
甲醇是由煤、焦、天然气、轻油、重油等为原料合成生产的工业甲醇,甲醇的性质:工业甲醇有毒、易燃、易爆。在常温常压下,甲醇为无色、透明、易流动、易挥发的液体,具有与乙醇相似的气味。甲醇汽油在动力性能上是否可以替代汽、柴油。甲醇汽油需要由甲醇、汽油和核心添加剂配置而成,甲醇汽油技术已成熟。甲醇掺入量一般为5%~30%。以掺入15%者为最多,称M15甲醇汽油。抗爆性能好,研究法辛烷值(RON)随甲醇掺入量的增加而增高,马达法辛烷值(MON)则不受影响。燃烧排出物的毒性比普通含铅汽油小,排气中一氧化碳含量也较少。燃烧清洁性能良好。但一般的甲醇汽油对汽油发动机的腐蚀性和对橡胶材料的溶胀率都较大,且易于分层,低温运转性能和冷起动性能不及纯汽油,可用作车用汽油代用品。许多国家作了大量使用试验,有的也在产业化使用。
甲醇汽油由基础汽油、甲醇及添加剂组成。甲醇汽油的技术关键核心是添加剂的技术水平和质量控制。甲醇汽油添加剂的技术含量,是决定调配甲醇汽油品质优良的灵魂。甲醇汽油添加剂是一种新型环保燃料助剂产品,是在甲醇(符合GB338-2004优等品甲醇指标)中加入一种复合添加剂后对甲醇进行变性处理,再按照规定比例和普通汽油混合后作为车用燃料,使其改性,使其燃烧速度、气化热值、互溶性、爆发力加速性能、润滑性、抑制腐蚀性等方面接近传统汽油的甲醇燃料,低比例甲醇汽油M15-M30无须对发动机和装置进行改造,可直接使用。高比例甲醇汽油M85-M100则需要给车辆安装甲醇转换器进行改造。
但目前的燃料油在燃烧时,存在环保问题严重等问题,因此提供一款环保甲醇汽油复合添加剂具有重要意义。
发明内容
本发明所要解决的技术问题是:现有的甲醇汽油燃烧时存在较大的环保问题,本发明提供了解决上述问题的环保型甲醇汽油复合添加剂。
本发明通过下述技术方案实现:
环保型甲醇汽油复合添加剂,按重量份配比计算,所述复合添加剂包括以下组分:
N-乙酰基-2-甲基-1,3-丙二胺,3~8份,
丙二醇单甲醚乙酸酯,0.6~1.9份,
碳酸二甲酯,0.2~1.4份,
丙二醇单甲醚乙酸酯,1~4份,
环戊二烯三羰基锰,0.1~0.9份,
乙基叔丁基醚,0.3~1.6份,
N,N’-二亚水杨酸-1,2-丙二胺,2~5份,
8-羟基喹啉,0.1~0.7份,
石脑油,0.05~0.3份。
进一步地,按重量份配比计算,所述复合添加剂包括以下组分:
N-乙酰基-2-甲基-1,3-丙二胺,4份,
丙二醇单甲醚乙酸酯,1.6份,
碳酸二甲酯,0.9份,
丙二醇单甲醚乙酸酯,3份,
环戊二烯三羰基锰,0.3份,
乙基叔丁基醚,0.5份,
N,N’-二亚水杨酸-1,2-丙二胺,3份,
8-羟基喹啉,0.5份,
石脑油,0.18份。
进一步地,按重量份配比计算,所述复合添加剂包括以下组分:
N-乙酰基-2-甲基-1,3-丙二胺6份,
丙二醇单甲醚乙酸酯,0.9份,
碳酸二甲酯,0.7份,
丙二醇单甲醚乙酸酯,2份,
环戊二烯三羰基锰,0.8份,
乙基叔丁基醚,1.3份,
N,N’-二亚水杨酸-1,2-丙二胺,4份,
8-羟基喹啉,0.5份,
石脑油,0.07份。
进一步地,所述复合添加剂是通过将各组分按配比混合后,在40~45℃温度条件下进行搅拌混合均匀制得环保甲醇汽油复合添加剂。
进一步地,所述复合添加剂在甲醇汽油中添加量为汽油总质量的0.3~0.6%。
本发明具有如下的优点和有益效果:
本发明提供了一种具有制备方法简单、环保效果好等优点的甲醇汽油复合添加剂,在保障甲醇汽油的燃烧效率、且利于增强动力的同时,大大增加了燃烧后一氧化碳的减排率以及烟尘的减排率。
具体实施方式
为使本发明的目的、技术方案和优点更加清楚明白,下面结合实施例,对本发明作进一步的详细说明,本发明的示意性实施方式及其说明仅用于解释本发明,并不作为对本发明的限定。
实施例1
本实施例提供了一种环保型甲醇汽油复合添加剂,按重量份配比计算,所述复合添加剂包括以下组分:
N-乙酰基-2-甲基-1,3-丙二胺,3份,
丙二醇单甲醚乙酸酯,1.9份,
碳酸二甲酯,1.4份,
丙二醇单甲醚乙酸酯,4份,
环戊二烯三羰基锰,0.1份,
乙基叔丁基醚,0.3份,
N,N’-二亚水杨酸-1,2-丙二胺,5份,
8-羟基喹啉,0.1份,
石脑油,0.05份。
所述复合添加剂是通过将各组分按配比混合后,在40℃温度条件下进行搅拌混合均匀制得环保甲醇汽油复合添加剂。制备获得的复合添加剂在甲醇汽油中添加量为汽油总质量的0.3%。
实施例2
本实施例提供了一种环保型甲醇汽油复合添加剂,按重量份配比计算,所述复合添加剂包括以下组分:
N-乙酰基-2-甲基-1,3-丙二胺,8份,
丙二醇单甲醚乙酸酯,0.6份,
碳酸二甲酯,0.2份,
丙二醇单甲醚乙酸酯,1份,
环戊二烯三羰基锰,0.9份,
乙基叔丁基醚,1.6份,
N,N’-二亚水杨酸-1,2-丙二胺,2份,
8-羟基喹啉,0.7份,
石脑油,0.3份。
所述复合添加剂是通过将各组分按配比混合后,在45℃温度条件下进行搅拌混合均匀制得环保甲醇汽油复合添加剂。制备获得的复合添加剂在甲醇汽油中添加量为汽油总质量的0.6%。
实施例3
本实施例提供了一种环保型甲醇汽油复合添加剂,按重量份配比计算,所述复合添加剂包括以下组分:
N-乙酰基-2-甲基-1,3-丙二胺,4份,
丙二醇单甲醚乙酸酯,1.6份,
碳酸二甲酯,0.9份,
丙二醇单甲醚乙酸酯,3份,
环戊二烯三羰基锰,0.3份,
乙基叔丁基醚,0.5份,
N,N’-二亚水杨酸-1,2-丙二胺,3份,
8-羟基喹啉,0.5份,
石脑油,0.18份。
所述复合添加剂是通过将各组分按配比混合后,在42℃温度条件下进行搅拌混合均匀制得环保甲醇汽油复合添加剂。制备获得的复合添加剂在甲醇汽油中添加量为汽油总质量的0.4%。
实施例4
本实施例提供了一种环保型甲醇汽油复合添加剂,按重量份配比计算,所述复合添加剂包括以下组分:
N-乙酰基-2-甲基-1,3-丙二胺6份,
丙二醇单甲醚乙酸酯,0.9份,
碳酸二甲酯,0.7份,
丙二醇单甲醚乙酸酯,2份,
环戊二烯三羰基锰,0.8份,
乙基叔丁基醚,1.3份,
N,N’-二亚水杨酸-1,2-丙二胺,4份,
8-羟基喹啉,0.5份,
石脑油,0.07份。
所述复合添加剂是通过将各组分按配比混合后,在42℃温度条件下进行搅拌混合均匀制得环保甲醇汽油复合添加剂。制备获得的复合添加剂在甲醇汽油中添加量为汽油总质量的0.4%。
以上所述的具体实施方式,对本发明的目的、技术方案和有益效果进行了进一步详细说明,所应理解的是,以上所述仅为本发明的具体实施方式而已,并不用于限定本发明的保护范围,凡在本发明的精神和原则之内,所做的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。

Claims (5)

1.环保型甲醇汽油复合添加剂,其特征在于,按重量份配比计算,所述复合添加剂包括以下组分:
N-乙酰基-2-甲基-1,3-丙二胺,3~8份,
丙二醇单甲醚乙酸酯,0.6~1.9份,
碳酸二甲酯,0.2~1.4份,
丙二醇单甲醚乙酸酯,1~4份,
环戊二烯三羰基锰,0.1~0.9份,
乙基叔丁基醚,0.3~1.6份,
N,N’-二亚水杨酸-1,2-丙二胺,2~5份,
8-羟基喹啉,0.1~0.7份,
石脑油,0.05~0.3份。
2.根据权利要求1所述的环保型甲醇汽油复合添加剂,其特征在于,按重量份配比计算,所述复合添加剂包括以下组分:
N-乙酰基-2-甲基-1,3-丙二胺,4份,
丙二醇单甲醚乙酸酯,1.6份,
碳酸二甲酯,0.9份,
丙二醇单甲醚乙酸酯,3份,
环戊二烯三羰基锰,0.3份,
乙基叔丁基醚,0.5份,
N,N’-二亚水杨酸-1,2-丙二胺,3份,
8-羟基喹啉,0.5份,
石脑油,0.18份。
3.根据权利要求1所述的环保型甲醇汽油复合添加剂,其特征在于,按重量份配比计算,所述复合添加剂包括以下组分:
N-乙酰基-2-甲基-1,3-丙二胺6份,
丙二醇单甲醚乙酸酯,0.9份,
碳酸二甲酯,0.7份,
丙二醇单甲醚乙酸酯,2份,
环戊二烯三羰基锰,0.8份,
乙基叔丁基醚,1.3份,
N,N’-二亚水杨酸-1,2-丙二胺,4份,
8-羟基喹啉,0.5份,
石脑油,0.07份。
4.根据权利要求1所述的环保型甲醇汽油复合添加剂,其特征在于,所述复合添加剂是通过将各组分按配比混合后,在40~45℃温度条件下进行搅拌混合均匀制得环保甲醇汽油复合添加剂。
5.根据权利要求1所述的环保型甲醇汽油复合添加剂,其特征在于,所述复合添加剂在甲醇汽油中添加量为汽油总质量的0.3~0.6%。
CN201811408774.2A 2018-11-23 2018-11-23 环保型甲醇汽油复合添加剂 Withdrawn CN109266412A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811408774.2A CN109266412A (zh) 2018-11-23 2018-11-23 环保型甲醇汽油复合添加剂

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811408774.2A CN109266412A (zh) 2018-11-23 2018-11-23 环保型甲醇汽油复合添加剂

Publications (1)

Publication Number Publication Date
CN109266412A true CN109266412A (zh) 2019-01-25

Family

ID=65190102

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201811408774.2A Withdrawn CN109266412A (zh) 2018-11-23 2018-11-23 环保型甲醇汽油复合添加剂

Country Status (1)

Country Link
CN (1) CN109266412A (zh)

Similar Documents

Publication Publication Date Title
FI74726B (fi) Foergasarbraensle.
AU2011269623B2 (en) Clear, high efficient and environmentally friendly gasoline product
Arya et al. A review on the effect of engine performance and emission characteristics of CI Engine using Diesel-Biodiesel-Additives fuel blend
CN109207214A (zh) 一种环保型的汽油添加剂及其制备方法
Gopinath et al. Experimental investigation on the effect of adding di methyl carbonate to gasoline in a SI engine performance
CN103254949A (zh) 一种高效汽油辛烷值促进剂
CN103122263B (zh) 一种燃料添加剂及应用其的低碳清洁燃料
CN102634385B (zh) 甲醇汽油
CN110846091B (zh) 草酸酯类新型含氧燃油或燃油添加剂及其应用
CN105670717B (zh) 一种甲醇汽油添加剂
CN101386797B (zh) 环保型车用轻烃燃料
CN107629824A (zh) 一种无铅车用合成燃料
CN109161412A (zh) 一种车用环保醇基燃料
CN109266412A (zh) 环保型甲醇汽油复合添加剂
CN115287106A (zh) 一种用于压燃发动机的汽油类燃料
CN102127471A (zh) 醚基燃料
WO2011085665A1 (zh) 醚基燃料
CN111171883A (zh) 一种戊酸酯类柴油混合燃料
CN111944567A (zh) 一种高热值环保燃烧油
CN109837112A (zh) 一种醇基车用燃料
CN109266411A (zh) 改进甲醇汽油稳定剂
AU2020102695A4 (en) Alcohol/ether fuel for diesel vehicles
CN109705932A (zh) 一种环保节能增标剂
CN114276843B (zh) 一种m85甲醇汽油组成物及其制备方法
CN108034461A (zh) 醇类燃油添加剂及其制备方法

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WW01 Invention patent application withdrawn after publication

Application publication date: 20190125

WW01 Invention patent application withdrawn after publication