CN109262942B - High-toughness plastic ruler - Google Patents
High-toughness plastic ruler Download PDFInfo
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- CN109262942B CN109262942B CN201811049217.6A CN201811049217A CN109262942B CN 109262942 B CN109262942 B CN 109262942B CN 201811049217 A CN201811049217 A CN 201811049217A CN 109262942 B CN109262942 B CN 109262942B
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- bamboo
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- powder
- reaction kettle
- grinding
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- 239000004033 plastic Substances 0.000 title claims abstract description 43
- 229920003023 plastic Polymers 0.000 title claims abstract description 43
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims abstract description 97
- 235000017491 Bambusa tulda Nutrition 0.000 claims abstract description 97
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims abstract description 97
- 241001330002 Bambuseae Species 0.000 claims abstract description 85
- 239000011425 bamboo Substances 0.000 claims abstract description 85
- 239000000843 powder Substances 0.000 claims abstract description 40
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 24
- 238000000227 grinding Methods 0.000 claims abstract description 18
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000007788 liquid Substances 0.000 claims abstract description 13
- 238000001746 injection moulding Methods 0.000 claims abstract description 8
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 8
- 238000002360 preparation method Methods 0.000 claims abstract description 8
- 239000000243 solution Substances 0.000 claims abstract description 8
- 239000004575 stone Substances 0.000 claims abstract description 8
- 239000002002 slurry Substances 0.000 claims abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 27
- 238000006243 chemical reaction Methods 0.000 claims description 24
- 238000003756 stirring Methods 0.000 claims description 24
- 239000000463 material Substances 0.000 claims description 22
- 239000004793 Polystyrene Substances 0.000 claims description 20
- 229920002223 polystyrene Polymers 0.000 claims description 20
- 239000008367 deionised water Substances 0.000 claims description 18
- 229910021641 deionized water Inorganic materials 0.000 claims description 18
- 238000005406 washing Methods 0.000 claims description 18
- 238000002156 mixing Methods 0.000 claims description 14
- 241000209128 Bambusa Species 0.000 claims description 12
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 12
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 12
- 238000001816 cooling Methods 0.000 claims description 12
- 229910052802 copper Inorganic materials 0.000 claims description 12
- 239000010949 copper Substances 0.000 claims description 12
- 238000010438 heat treatment Methods 0.000 claims description 12
- 238000003892 spreading Methods 0.000 claims description 9
- 238000005259 measurement Methods 0.000 claims description 7
- 238000005498 polishing Methods 0.000 claims description 7
- 238000002791 soaking Methods 0.000 claims description 7
- 238000005520 cutting process Methods 0.000 claims description 6
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 6
- 239000000839 emulsion Substances 0.000 claims description 6
- 239000000706 filtrate Substances 0.000 claims description 6
- 238000001914 filtration Methods 0.000 claims description 6
- 239000004570 mortar (masonry) Substances 0.000 claims description 6
- 230000007935 neutral effect Effects 0.000 claims description 6
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims description 6
- 239000010453 quartz Substances 0.000 claims description 6
- 238000007650 screen-printing Methods 0.000 claims description 6
- 238000007493 shaping process Methods 0.000 claims description 6
- 238000007873 sieving Methods 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims description 6
- 238000005303 weighing Methods 0.000 claims description 6
- 238000007639 printing Methods 0.000 claims description 4
- 239000000835 fiber Substances 0.000 abstract description 15
- 230000002035 prolonged effect Effects 0.000 abstract description 7
- 239000013078 crystal Substances 0.000 abstract description 4
- 239000002121 nanofiber Substances 0.000 abstract description 3
- 102000004190 Enzymes Human genes 0.000 abstract description 2
- 108090000790 Enzymes Proteins 0.000 abstract description 2
- 229920001410 Microfiber Polymers 0.000 abstract description 2
- 239000004698 Polyethylene Substances 0.000 abstract description 2
- 230000032683 aging Effects 0.000 abstract description 2
- 210000004027 cell Anatomy 0.000 abstract description 2
- 210000002421 cell wall Anatomy 0.000 abstract description 2
- 230000005684 electric field Effects 0.000 abstract description 2
- 238000000034 method Methods 0.000 abstract description 2
- 244000005700 microbiome Species 0.000 abstract description 2
- 239000003658 microfiber Substances 0.000 abstract description 2
- -1 polyethylene Polymers 0.000 abstract description 2
- 229920000573 polyethylene Polymers 0.000 abstract description 2
- 238000006116 polymerization reaction Methods 0.000 abstract description 2
- 230000036561 sun exposure Effects 0.000 abstract 1
- 239000000203 mixture Substances 0.000 description 9
- 238000005452 bending Methods 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 241001391944 Commicarpus scandens Species 0.000 description 3
- 230000035882 stress Effects 0.000 description 2
- 208000013201 Stress fracture Diseases 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/0001—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor characterised by the choice of material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B13/00—Conditioning or physical treatment of the material to be shaped
- B29B13/10—Conditioning or physical treatment of the material to be shaped by grinding, e.g. by triturating; by sieving; by filtering
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/0053—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor combined with a final operation, e.g. shaping
- B29C2045/0077—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor combined with a final operation, e.g. shaping removing burrs or flashes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2025/00—Use of polymers of vinyl-aromatic compounds or derivatives thereof as moulding material
- B29K2025/04—Polymers of styrene
- B29K2025/06—PS, i.e. polystyrene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2511/00—Use of natural products or their composites, not provided for in groups B29K2401/00 - B29K2509/00, as filler
- B29K2511/14—Wood, e.g. woodboard or fibreboard
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/752—Measuring equipment
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Woven Fabrics (AREA)
- Dry Formation Of Fiberboard And The Like (AREA)
- Reinforced Plastic Materials (AREA)
Abstract
The invention discloses a high-toughness plastic ruler, and belongs to the field of preparation of school supplies. The invention firstly makes bamboo splints into bamboo splits, then soaks the bamboo splits with biogas slurry, uses enzyme generated by microorganism in the biogas slurry to activate bamboo fibers, then carries out sun exposure and aging to further reduce the bonding force between the fibers, then uses NaOH solution to mix with the bamboo splits at high temperature to promote the microfiber silk layer to slide and swell, then uses liquid nitrogen to process to form ice crystals in fiber cells, then carries out stone grinding to break the ice crystals in cell walls under the action of pressure to separate the fibers into micro-nano fiber whiskers, mixes the micro-nano fiber whiskers with special-shaped polyethylene powder obtained by polymerization under the condition of an electric field according to a proportion, carries out injection molding, and prints scales after grinding to obtain the high-toughness plastic ruler. The ruler disclosed by the invention has the advantages of high toughness of bamboo fibers, high impact strength, difficulty in breaking, greatly prolonged service life compared with the traditional plastic ruler, and capability of being popularized and used on a large scale.
Description
Technical Field
The invention discloses a high-toughness plastic ruler, and belongs to the field of preparation of school supplies.
Background
The ruler is used for measuring length and is widely applied to mathematics, measurement, engineering and other subjects. The ruler is a ruler-shaped gauge with accurate straight edges, is also called a space ruler and is a very common length measuring instrument, and the stationery is common. At present, use more ruler and divide according to the material and mainly have: 1. the alloy ruler is long in service life, but is difficult to recover after being bent and deformed, and the production cost is relatively high compared with other materials, the accuracy is reduced after abrasion, and the ruler cannot be repaired; 2. the wooden ruler is light in weight, convenient to carry, limited in service life, easy to crack after meeting water, poor in flexibility and easy to break; 3. the plastic ruler has the advantages that the elastic modulus of plastic is between that of rubber and that of fiber, the plastic ruler can deform to a certain degree under stress, the common plastic ruler is composed of hard plastic and soft plastic, the elastic modulus of the soft plastic is close to that of the rubber, the hard plastic is close to that of the fiber, the hardness of the soft plastic is low, the plastic ruler is easy to deform under stress, the application range is limited, the hard plastic has certain hardness, the preparation process is simple, the materials are cheap and easy to obtain, the plasticity is strong, the plastic ruler is widely used as the ruler material in study articles at present, but the plastic is easy to age and yellow, if the use frequency is too high, the scales and the like of the plastic ruler are easy to wear, the toughness is poor, the plastic ruler is easy to break, corners are easy.
Disclosure of Invention
Aiming at the problems of poor toughness, brittleness, low impact strength, easy occurrence of stress fracture and short service life of the traditional plastic ruler in the preparation and use processes, the invention provides a preparation method of a high-toughness plastic ruler, which comprises the steps of firstly forming bamboo splits from bamboo chips, then soaking the bamboo splits with methane liquid, activating bamboo fibers by using enzyme generated by microorganisms in the methane liquid, then exposing and aging by sunlight to further reduce the bonding force among the fibers, then mixing the bamboo splits with NaOH solution at high temperature to promote the sliding and swelling of a microfiber fiber layer, then treating with liquid nitrogen to form ice crystals in fiber cells, and finally grinding by a stone mill to crack the ice crystals in cell walls under the action of pressure to separate the fibers into micro-nano fiber whiskers, and mixing the special-shaped polyethylene powder obtained by polymerization under the condition of an electric field in proportion, performing injection molding, polishing, and then printing scales to obtain the high-toughness plastic ruler. The ruler disclosed by the invention has the advantages of high toughness of bamboo fibers, high impact strength, difficulty in breaking, greatly prolonged service life compared with the traditional plastic ruler, and capability of being popularized and used on a large scale.
In order to solve the technical problems, the technical scheme adopted by the invention is as follows:
(1) taking 4-6 bamboos with the diameter of 3-5 cm and the length of 1.2-1.5 m, manually slicing the bamboos into thin bamboo strips, collecting the thin bamboo strips, soaking the thin bamboo strips in biogas slurry for 24-36 h, taking out the thin bamboo strips, washing the thin bamboo strips for 3-5 times by using deionized water, uniformly spreading the thin bamboo strips under the sunlight, and exposing the thin bamboo strips for 7-10 days;
(2) after the insolation is finished, cutting the bamboo skin into 3-5 cm short bamboo skin by a chopper, pouring the short bamboo skin into a beaker filled with 1-2L of 6-8% sodium hydroxide solution, then turning the beaker into a digital display speed measurement constant temperature magnetic stirrer, stirring and reacting for 30-45 min at a constant temperature under the conditions that the temperature is 160-180 ℃ and the rotating speed is 600-800 r/min, filtering, removing filtrate, and washing filter residues with deionized water until the washing water is neutral;
(3) cooling the obtained filter residue by using liquid nitrogen for 40-60 s, then quickly paving the filter residue on the surface of a millstone of a stone mill, grinding for 10-15 min, and sieving by using a sieve of 400-600 meshes after grinding to obtain micro-nano bamboo powder for later use;
(4) adding 4-6 g of sodium dodecyl benzene sulfonate into a quartz reaction kettle containing 300-400 mL of deionized water, starting a reaction kettle stirrer, stirring and mixing at the rotating speed of 300-500 r/min for 10-20 min, starting a reaction kettle heater, heating to 70-80 ℃, inserting a copper electrode into emulsion of the reaction kettle, communicating the copper electrode with a pressure resistance tester, setting the direct-current voltage to be 220-380V, sequentially adding 0.4-0.6 g of potassium persulfate and 80-100 mL of styrene under the constant-temperature constant-voltage stirring state, reacting for 4-6 h, transferring the obtained material into an oven, drying for 6-8 h at the temperature of 80-90 ℃, and grinding into powder by using a mortar to obtain special-shaped polystyrene powder;
(5) weighing 35-40 parts by weight of the micro-nano bamboo powder for standby in the step (3) and 60-80 parts by weight of the obtained special-shaped polystyrene powder in sequence, adding the obtained special-shaped polystyrene powder into a mixer, stirring and mixing the obtained special-shaped polystyrene powder for 30-45 min at the rotating speed of 600-800 r/min, adding the obtained mixed material into a screw injection molding machine, heating to melt the mixed material, injecting the melted material into a cavity of a ruler mold through a screw, shaping and cooling, manually polishing to remove burrs, and then printing scales on a polished ruler blank through a screen printing to obtain the high-toughness plastic ruler.
Physical properties of the present invention: the density of the high-toughness plastic ruler is 1.05-1.08 g/cm3, the tensile strength is 49.6-50.6 MPa, the bending strength is 96.2-97.6 MPa, the elongation at break is 1.6-2.0%, the Vicat softening point is 230-240 DEG F, and the service life of the ruler can be prolonged by 12-24 months compared with that of a traditional plastic ruler.
The invention has the beneficial effects that:
(1) the high-toughness plastic ruler disclosed by the invention is high in toughness, not easy to break, and greatly prolonged in service life compared with the traditional plastic ruler, and the problem of white pollution to the environment after being discarded can be reduced;
(2) the modified bamboo fiber is adopted as the toughening fiber, the raw materials are cheap and easy to obtain, the plasticity is strong, the preparation process is simple, and the obtained plastic ruler can be widely used as a school supply.
Detailed Description
Taking 4-6 bamboos with the diameter of 3-5 cm and the length of 1.2-1.5 m, manually slicing the bamboos into thin bamboo strips, collecting the thin bamboo strips, soaking the thin bamboo strips in biogas slurry for 24-36 h, taking out the thin bamboo strips, washing the thin bamboo strips for 3-5 times by using deionized water, uniformly spreading the thin bamboo strips under the sunlight, and exposing the thin bamboo strips for 7-10 days; after the insolation is finished, cutting the bamboo skin into 3-5 cm short bamboo skin by a chopper, pouring the short bamboo skin into a beaker filled with 1-2L of 6-8% sodium hydroxide solution, then turning the beaker into a digital display speed measurement constant temperature magnetic stirrer, stirring and reacting for 30-45 min at a constant temperature under the conditions that the temperature is 160-180 ℃ and the rotating speed is 600-800 r/min, filtering, removing filtrate, and washing filter residues with deionized water until the washing water is neutral; cooling the obtained filter residue by using liquid nitrogen for 40-60 s, then quickly paving the filter residue on the surface of a millstone of a stone mill, grinding for 10-15 min, and sieving by using a sieve of 400-600 meshes after grinding to obtain micro-nano bamboo powder for later use; adding 4-6 g of sodium dodecyl benzene sulfonate into a quartz reaction kettle containing 300-400 mL of deionized water, starting a reaction kettle stirrer, stirring and mixing at the rotating speed of 300-500 r/min for 10-20 min, starting a reaction kettle heater, heating to 70-80 ℃, inserting a copper electrode into emulsion of the reaction kettle, communicating the copper electrode with a pressure resistance tester, setting the direct-current voltage to be 220-380V, sequentially adding 0.4-0.6 g of potassium persulfate and 80-100 mL of styrene under the constant-temperature constant-voltage stirring state, reacting for 4-6 h, transferring the obtained material into an oven, drying for 6-8 h at the temperature of 80-90 ℃, and grinding into powder by using a mortar to obtain special-shaped polystyrene powder; weighing 35-40 parts of standby micro-nano bamboo powder and 60-80 parts of the obtained special-shaped polystyrene powder in sequence by weight, adding the obtained special-shaped polystyrene powder into a mixer, stirring and mixing the obtained mixture for 30-45 min at the rotating speed of 600-800 r/min, adding the obtained mixture into a screw injection molding machine, heating to melt the mixture, injecting the melted material into a cavity of a ruler mold through a screw, shaping and cooling, manually polishing to remove burrs, and then printing scales on a polished ruler blank through a screen printing manner to obtain the high-toughness plastic ruler.
Example 1
Taking 4 bamboos with the diameter of 3cm and the length of 1.2m, manually slicing the bamboos into bamboo splits, collecting the bamboo splits, soaking the bamboo splits in biogas liquid for 24 hours, taking out the bamboo splits, washing the bamboo splits with deionized water for 3 times, and then uniformly spreading the bamboo splits in the sun and exposing the bamboo splits to the sun for 7 days; after the insolation is finished, cutting the bamboo skin into 3cm short bamboo skin by a chopper, pouring the short bamboo skin into a beaker filled with 1L of sodium hydroxide solution with the mass concentration of 6%, then turning the beaker into a digital display speed measurement constant temperature magnetic stirrer, stirring and reacting for 30min at the constant temperature of 160 ℃ and the rotating speed of 600r/min, filtering, removing filtrate, and washing filter residue with deionized water until washing water is neutral; cooling the obtained filter residue with liquid nitrogen for 40s, rapidly spreading on the surface of a millstone of a stone mill, grinding for 10min, and sieving with a 400-mesh sieve to obtain micro-nano bamboo powder for later use; adding 4g of sodium dodecyl benzene sulfonate into a quartz reaction kettle containing 300mL of deionized water, starting a reaction kettle stirrer, stirring and mixing at the rotating speed of 300r/min for 10min, starting a reaction kettle heater, heating to 70 ℃, then inserting a copper electrode into emulsion of the reaction kettle, communicating the copper electrode with a pressure resistance tester, setting the direct-current voltage to be 220V, sequentially adding 0.4g of potassium persulfate and 80mL of styrene under the constant-temperature constant-voltage stirring state, reacting for 4h, transferring the obtained material into an oven, drying for 6h under the condition of 80 ℃, and grinding into powder by using a mortar to obtain special-shaped polystyrene powder; weighing 35 parts of standby micro-nano bamboo powder and 60 parts of the obtained special-shaped polystyrene powder in sequence according to parts by weight, adding the obtained special-shaped polystyrene powder into a mixer, stirring and mixing the obtained mixture for 30min at a rotating speed of 600r/min, adding the obtained mixture into a screw injection molding machine, heating to melt the mixture, injecting the melted material into a ruler mold cavity through a screw, carrying out shaping and cooling, manually polishing to remove burrs, and then carrying out silk-screen printing on a polished ruler blank to obtain the high-toughness plastic ruler.
The density of the high-toughness plastic ruler is 1.05g/cm3, the tensile strength is 49.6MPa, the bending strength is 96.2MPa, the elongation at break is 1.6%, the Vicat softening point is 230 DEG F, and the service life of the ruler is prolonged by 12 months compared with that of the traditional plastic ruler.
Example 2
Taking 5 bamboos with the diameter of 4cm and the length of 1.4m, manually slicing the bamboos into bamboo splits, collecting the bamboo splits, soaking the bamboo splits in biogas liquid for 30h, taking out the bamboo splits, washing the bamboo splits with deionized water for 4 times, and then uniformly spreading the bamboo splits in the sun and exposing the bamboo splits to the sun for 8 days; after the insolation is finished, cutting the bamboo skin into 4cm short bamboo skin by a guillotine, pouring the short bamboo skin into a beaker filled with 1.5L of 7% sodium hydroxide solution, then turning the beaker into a digital display speed measurement constant temperature magnetic stirrer, stirring and reacting for 38min at the constant temperature of 170 ℃ and the rotating speed of 700r/min, filtering, removing filtrate, and washing filter residue with deionized water until the washing water is neutral; cooling the obtained filter residue with liquid nitrogen for 50s, rapidly spreading on the surface of a millstone of a stone mill, grinding for 12min, and sieving with a 500-mesh sieve to obtain micro-nano bamboo powder for later use; adding 5g of sodium dodecyl benzene sulfonate into a quartz reaction kettle containing 350mL of deionized water, starting a reaction kettle stirrer, stirring and mixing at the rotating speed of 400r/min for 15min, starting a reaction kettle heater, heating to 75 ℃, then inserting a copper electrode into emulsion of the reaction kettle, communicating the copper electrode with a pressure resistance tester, setting the direct-current voltage to 300V, sequentially adding 0.5g of potassium persulfate and 90mL of styrene under the constant-temperature constant-voltage stirring state, reacting for 5h, transferring the obtained material into an oven, drying for 7h at the temperature of 85 ℃, and grinding into powder by using a mortar to obtain special-shaped polystyrene powder; weighing 38 parts of standby micro-nano bamboo powder and 70 parts of the obtained special-shaped polystyrene powder in sequence according to parts by weight, adding the obtained special-shaped polystyrene powder into a mixer, stirring and mixing the mixture for 40min at the rotating speed of 700r/min, adding the obtained mixture into a screw injection molding machine, heating to melt the mixture, injecting the melted material into a ruler mold cavity through a screw, carrying out shaping and cooling, manually polishing to remove burrs, and then carrying out silk-screen printing on the polished ruler blank to obtain the high-toughness plastic ruler.
The density of the high-toughness plastic ruler is 1.06g/cm3, the tensile strength is 50MPa, the bending strength is 97MPa, the elongation at break is 1.8%, the Vicat softening point is 235 DEG F, and the service life of the ruler can be prolonged by 18 months compared with that of the traditional plastic ruler.
Example 3
Taking 6 bamboos with the diameter of 5cm and the length of 1.5m, manually slicing the bamboos into bamboo splits, collecting the bamboo splits, soaking the bamboo splits in biogas liquid for 36h, taking out the bamboo splits, washing the bamboo splits with deionized water for 5 times, and then uniformly spreading the bamboo splits in the sun and exposing the bamboo splits to the sun for 10 days; after the insolation is finished, cutting the bamboo skin into 5cm short bamboo skin by a chopper, pouring the short bamboo skin into a beaker filled with 2L of sodium hydroxide solution with the mass concentration of 8%, then turning the beaker into a digital display speed measurement constant temperature magnetic stirrer, stirring and reacting for 45min at the constant temperature of 180 ℃ and the rotating speed of 800r/min, filtering, removing filtrate, and washing filter residue with deionized water until washing water is neutral; cooling the obtained filter residue with liquid nitrogen for 60s, rapidly spreading on the surface of a millstone of a stone mill, grinding for 15min, and sieving with a 600-mesh sieve to obtain micro-nano bamboo powder for later use; adding 6g of sodium dodecyl benzene sulfonate into a quartz reaction kettle containing 400mL of deionized water, starting a reaction kettle stirrer, stirring and mixing at the rotating speed of 500r/min for 20min, starting a reaction kettle heater, heating to 80 ℃, then inserting a copper electrode into emulsion of the reaction kettle, communicating the copper electrode with a pressure resistance tester, setting the direct-current voltage to 380V, sequentially adding 0.6g of potassium persulfate and 100mL of styrene under the constant-temperature constant-voltage stirring state, reacting for 6h, transferring the obtained material into an oven, drying for 8h at the temperature of 90 ℃, and grinding into powder by using a mortar to obtain special-shaped polystyrene powder; weighing 40 parts of standby micro-nano bamboo powder and 80 parts of the obtained special-shaped polystyrene powder in sequence according to parts by weight, adding the obtained special-shaped polystyrene powder into a mixer, stirring and mixing for 45min at the rotating speed of 800r/min, adding the obtained mixed material into a screw injection molding machine, heating to melt the mixed material, injecting the melted material into a ruler mold cavity through a screw, carrying out shaping and cooling, manually polishing to remove burrs, and then carrying out silk-screen printing on the polished ruler blank to obtain the high-toughness plastic ruler.
The density of the high-toughness plastic ruler is 1.08g/cm3, the tensile strength is 50.6MPa, the bending strength is 97.6MPa, the elongation at break is 2.0%, the Vicat softening point is 240 DEG F, and the service life of the ruler is prolonged by 24 months compared with that of the traditional plastic ruler.
Claims (1)
1. The high-toughness plastic ruler is characterized by being prepared by the following preparation method, and the preparation method comprises the following specific steps:
(1) taking 4-6 bamboos with the diameter of 3-5 cm and the length of 1.2-1.5 m, manually slicing the bamboos into thin bamboo strips, collecting the thin bamboo strips, soaking the thin bamboo strips in biogas slurry for 24-36 h, taking out the thin bamboo strips, washing the thin bamboo strips for 3-5 times by using deionized water, uniformly spreading the thin bamboo strips under the sunlight, and exposing the thin bamboo strips for 7-10 days;
(2) after the insolation is finished, cutting the bamboo skin into 3-5 cm short bamboo skin by a chopper, pouring the short bamboo skin into a beaker filled with 1-2L of 6-8% sodium hydroxide solution, then turning the beaker into a digital display speed measurement constant temperature magnetic stirrer, stirring and reacting for 30-45 min at a constant temperature under the conditions that the temperature is 160-180 ℃ and the rotating speed is 600-800 r/min, filtering, removing filtrate, and washing filter residues with deionized water until the washing water is neutral;
(3) cooling the obtained filter residue by using liquid nitrogen for 40-60 s, then quickly paving the filter residue on the surface of a millstone of a stone mill, grinding for 10-15 min, and sieving by using a sieve of 400-600 meshes after grinding to obtain micro-nano bamboo powder for later use;
(4) adding 4-6 g of sodium dodecyl benzene sulfonate into a quartz reaction kettle containing 300-400 mL of deionized water, starting a reaction kettle stirrer, stirring and mixing at the rotating speed of 300-500 r/min for 10-20 min, starting a reaction kettle heater, heating to 70-80 ℃, inserting a copper electrode into emulsion of the reaction kettle, communicating the copper electrode with a pressure resistance tester, setting the direct-current voltage to be 220-380V, sequentially adding 0.4-0.6 g of potassium persulfate and 80-100 mL of styrene under the constant-temperature constant-voltage stirring state, reacting for 4-6 h, transferring the obtained material into an oven, drying for 6-8 h at the temperature of 80-90 ℃, and grinding into powder by using a mortar to obtain special-shaped polystyrene powder;
(5) weighing 35-40 parts by weight of the micro-nano bamboo powder for standby in the step (3) and 60-80 parts by weight of the obtained special-shaped polystyrene powder in sequence, adding the obtained special-shaped polystyrene powder into a mixer, stirring and mixing the obtained special-shaped polystyrene powder for 30-45 min at the rotating speed of 600-800 r/min, adding the obtained mixed material into a screw injection molding machine, heating to melt the mixed material, injecting the melted material into a cavity of a ruler mold through a screw, shaping and cooling, manually polishing to remove burrs, and then printing scales on a polished ruler blank through a screen printing to obtain the high-toughness plastic ruler.
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| CN201811049217.6A CN109262942B (en) | 2016-08-08 | 2016-08-08 | High-toughness plastic ruler |
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| CN201610646716.8A CN106273203B (en) | 2016-08-08 | 2016-08-08 | A kind of preparation method of high toughness plastic ruler |
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| CN201811049446.8A Active CN109262944B (en) | 2016-08-08 | 2016-08-08 | Preparation method of high-toughness plastic ruler |
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| CN201610646716.8A Expired - Fee Related CN106273203B (en) | 2016-08-08 | 2016-08-08 | A kind of preparation method of high toughness plastic ruler |
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| CN114276975B (en) * | 2021-03-30 | 2024-09-17 | 赣南师范大学 | Preparation method of hollow and multi-hollow hybrid cells |
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| CN101891913A (en) * | 2010-07-19 | 2010-11-24 | 浙江味老大工贸有限公司 | Method for preparing bamboo plastic chopping board |
| CN105367991A (en) * | 2015-11-04 | 2016-03-02 | 梅庆波 | Preparation method for bamboo charcoal particle-hollow microsphere-phenolic resin ternary composite plate |
| CN105585014A (en) * | 2014-10-23 | 2016-05-18 | 庄亚林 | A preparing method of active bamboo charcoal powder |
| CN106273203B (en) * | 2016-08-08 | 2018-11-02 | 泉州方寸新材料科技有限公司 | A kind of preparation method of high toughness plastic ruler |
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| CN101270219B (en) * | 2008-04-18 | 2010-11-03 | 浙江嘉民塑胶有限公司 | Rubber toughening phenolic resin injection molding material |
| CN101504109B (en) * | 2009-03-11 | 2012-05-16 | 杭州华海木业有限公司 | Bamboo plastic section bar and shaping method |
| EP2766156A4 (en) * | 2011-10-13 | 2015-11-11 | Univ Connecticut | Process for particleboard manufacture |
| CN104908129B (en) * | 2015-06-24 | 2016-07-06 | 湖北省轻工业科学研究设计院 | A kind of production method of artificial Scobis Diospyroris Ebeni |
| CN105385025A (en) * | 2015-10-28 | 2016-03-09 | 安徽宁国市伟诚纤维制品有限公司 | High-performance glass fiber composite baseball bat and manufacturing method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101891913A (en) * | 2010-07-19 | 2010-11-24 | 浙江味老大工贸有限公司 | Method for preparing bamboo plastic chopping board |
| CN105585014A (en) * | 2014-10-23 | 2016-05-18 | 庄亚林 | A preparing method of active bamboo charcoal powder |
| CN105367991A (en) * | 2015-11-04 | 2016-03-02 | 梅庆波 | Preparation method for bamboo charcoal particle-hollow microsphere-phenolic resin ternary composite plate |
| CN106273203B (en) * | 2016-08-08 | 2018-11-02 | 泉州方寸新材料科技有限公司 | A kind of preparation method of high toughness plastic ruler |
Also Published As
| Publication number | Publication date |
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| CN109262944A (en) | 2019-01-25 |
| CN109262944B (en) | 2020-12-25 |
| CN106273203B (en) | 2018-11-02 |
| CN109262943B (en) | 2020-10-27 |
| CN106273203A (en) | 2017-01-04 |
| CN109262942A (en) | 2019-01-25 |
| CN109262943A (en) | 2019-01-25 |
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Effective date of registration: 20200804 Address after: 301600 100 meters south of guzhuangzi village, Liangtou Town, Jinghai District, Tianjin Applicant after: Tianjin Hexing Stationery Co.,Ltd. Address before: 213000 New Dragon shopping mall, Longhu street, Xinbei District, Changzhou, Jiangsu, 6699 Applicant before: Wu Bin |
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