CN109252406A - A kind of energy conservation and environmental protection textile product dyeing aftertreatment technology - Google Patents

A kind of energy conservation and environmental protection textile product dyeing aftertreatment technology Download PDF

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Publication number
CN109252406A
CN109252406A CN201810901530.1A CN201810901530A CN109252406A CN 109252406 A CN109252406 A CN 109252406A CN 201810901530 A CN201810901530 A CN 201810901530A CN 109252406 A CN109252406 A CN 109252406A
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CN
China
Prior art keywords
textile product
minutes
environmental protection
aftertreatment technology
energy conservation
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Pending
Application number
CN201810901530.1A
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Chinese (zh)
Inventor
孙植和
彭铁平
罗刚
王勇
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Foshan Precision Textile Co Ltd
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Foshan Precision Textile Co Ltd
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Priority to CN201810901530.1A priority Critical patent/CN109252406A/en
Publication of CN109252406A publication Critical patent/CN109252406A/en
Pending legal-status Critical Current

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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/02After-treatment
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/02After-treatment
    • D06P5/04After-treatment with organic compounds
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/02After-treatment
    • D06P5/04After-treatment with organic compounds
    • D06P5/08After-treatment with organic compounds macromolecular
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/38General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Coloring (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention discloses a kind of energy conservation and environmental protection textile products to dye aftertreatment technology, comprising the following steps: step 1: by being washed 20-30 minutes in 55-65 DEG C of hot water using the textile product after reactive dyeing;Step 2: the glacial acetic acid that 1g/L is added is in textile product under acid condition, pH 4-4.5;20 minutes are kept the temperature at 50-60 DEG C after liquid step 3: addition Nanosurface activity is soaped, completes aftertreatment technology.Using the present invention, the number and dosage of washing can be reduced, and avoids the high demand that high temperature is soaped to thermal energy, is really achieved low emission, low pollution, high benefit, energy conservation and environmental protection clean manufacturing.

Description

A kind of energy conservation and environmental protection textile product dyeing aftertreatment technology
Technical field
The present invention relates to field of textiles more particularly to a kind of energy conservation and environmental protection textile product to dye aftertreatment technology.
Background technique
The dyeing of textile industry generates a large amount of sewage, the especially section of soaping of dyeing post-processing, in order to spin The dyeing residue for knitting product is rinsed well, and traditional process requirement is repeatedly washed, and high temperature is soaped, time consumption and energy consumption, and water consumption is big. One of routine tradition technical solution of soaping is as follows: 10-15 minute → acid neutralization 10-15 minutes → bis- is once washed after dyeing Secondary 95 DEG C of hot water of 10-15 minutes → high temperature of washing soap 10-20 minutes twice → 80 the cold water of DEG C hot water wash 10-15 minutes → again wash 10-15 minutes → acid neutralizes 10-15 minutes, and surveying PH5-7 → post-processing terminates.
In order to solve the technical problem of the technique, Chinese patent 105155246A discloses a kind of natural fiber cotton fabric It soaps technique, is drained after 1. dyeing;2. being drained after 60 DEG C of washing 5-10min;3. 40 DEG C of acid neutralize, pH value 6-7;4. being warming up to 60 DEG C add soap cerebroysin, drain after the 90-98 DEG C of 15-20min that soaps;5. cold water drains after washing 5-10min;6. cold water washes 5-10min After drain;The soap cerebroysin is by the nonionic surfactant of 33wt%, the anionic surfactant of 42wt% and 25wt% Enzyme preparation composition.From the point of view of technical solution disclosed above, it is desired nonetheless to which multiple washing and high temperature is soaped, although reducing washing Time and high temperature are soaped number, but still can not solve highly energy-consuming, highly water intensive technical problem.
Summary of the invention
Technical problem to be solved by the present invention lies in provide a kind of energy conservation and environmental protection textile product dyeing aftertreatment technology. The number and dosage of washing can be reduced, and avoids the high demand that high temperature is soaped to thermal energy, is really achieved low emission, low pollution, height Benefit, energy conservation and environmental protection clean manufacturing.
In order to solve the above-mentioned technical problems, the present invention provides a kind of energy conservation and environmental protection textile products to dye aftertreatment technology, The following steps are included:
Step 1: by being washed 20-30 minutes in 55-65 DEG C of hot water using the textile product after reactive dyeing;
Step 2: the glacial acetic acid that 1g/L is added is in textile product under acid condition, pH 4-4.5;
20 minutes are kept the temperature at 50-60 DEG C after liquid step 3: addition Nanosurface activity is soaped, completes aftertreatment technology.
As the improvement of energy conservation and environmental protection textile product dyeing aftertreatment technology, the specific steps packet of the first step It includes:
(1) it will be placed in container using the textile product after reactive dyeing, 55-65 DEG C of hot water be added, washes 10- Water after 15 minutes in venting container;
(2) it is added 55-65 DEG C of hot water into container again, the water after washing 10-15 minutes in venting container, then again 50-60 DEG C of hot water is added.
As the improvement of energy conservation and environmental protection textile product dyeing aftertreatment technology, ice is added in the second step under stiring Acetic acid, and 10-15 minutes are kept the temperature at a temperature of 50-60 DEG C.
As the improvement of energy conservation and environmental protection textile product dyeing aftertreatment technology, the Nanosurface activity is soaped liquid packet Following main component is included to be made:
As the improvement of energy conservation and environmental protection textile product dyeing aftertreatment technology, the polyetheramine is by polyethylene glycol in height Ammonification obtains under warm high pressure.
As the improvement of energy conservation and environmental protection textile product dyeing aftertreatment technology, Nanosurface activity liquid of soaping is logical It crosses for polyetheramine, horse propylene copolymer, deionized water and enzyme preparation to be stirred 15-30 minutes by outfit and be made.
As the improvement of energy conservation and environmental protection textile product dyeing aftertreatment technology, the Nanosurface activity is soaped liquid Mass percent concentration is 2-6%.
The invention has the following beneficial effects:
Energy conservation and environmental protection dyeing aftertreatment technology of the present invention uses the technique of hot water washing, then using Nanosurface activity It soaps liquid, can carry out 50-60 DEG C of low temperature soaping in acid condition, Nanosurface activity liquid of soaping has dyeing residual liquid Degradation capability.The present invention not only reduces washing times, also avoids the high demand that high temperature is soaped to thermal energy, reduces energy consumption, and Process is few, and time-consuming short, efficiency significantly improves.The product for meeting concerned countries standard can be produced using technique of the present invention, It is really achieved low emission, low pollution, high benefit, energy conservation and environmental protection clean manufacturing.
Detailed description of the invention
Fig. 1 is a kind of flow chart of energy conservation and environmental protection textile product dyeing aftertreatment technology of the present invention;
Fig. 2 is a kind of another flow chart of energy conservation and environmental protection textile product dyeing aftertreatment technology of the present invention.
Specific embodiment
To make the object, technical solutions and advantages of the present invention clearer, the present invention is made into one below in conjunction with attached drawing Step ground detailed description.
Energy conservation and environmental protection of the present invention dyeing aftertreatment technology be for using the textile product after reactive dyeing into Row a series of subsequent handlings such as washes, soaps to remove the residue on textile product.According to standard GB/T 18401-2010 " national general safety technical code for textile products ", on textile product content of formaldehyde, pH value, dyefastness grade, peculiar smell and Decomposable this 5 projects of carcinogenic aromatic amine dyestuff are tested.Energy conservation and environmental protection of the present invention dyeing aftertreatment technology be in order to The technique for reaching the A class textile product of above-mentioned national standard and designing.
As shown in Figure 1, the present invention provides a kind of energy conservation and environmental protection textile product dyeing aftertreatment technology, comprising the following steps:
S100 will be washed 20-30 minutes in 55-65 DEG C of hot water using the textile product after reactive dyeing.
For tradition soaps technology, the present invention does not use cold water to wash, the heat that the water of addition is 55-65 DEG C Water, the step for water temperature the reason of designing on the one hand be textile product after reactive dyeing in a upper process in 60 DEG C Environment in, 55-65 DEG C of hot water be added be able to maintain textile product and still remain under the temperature environment, the environment of higher temperatures has Conducive to molecular motion, to accelerate residue second cosmic velocity from textile product;On the other hand, the S101 step is needed 50 PH value debugging is carried out under the conditions of DEG C, and since the temperature that hot water is added is slightly higher than 50 DEG C, a small amount of cold water cooling need to only be added Or the of short duration i.e. reachable process conditions of heating, if washed using cold water, temperature to reach S101 step if want it is longer plus The hot time.
It should be noted that equipment and process used in the S100 step is same as the prior art or similar, only It is water temperature difference and washing time difference when being added, details are not described herein again.
S101, the glacial acetic acid that 1g/L is added are in textile product under acid condition, pH 4-4.5.
Be added glacial acetic acid can in textile product residue alkaline matter occur neutralization reaction, and continue addition until PH is 4-4.5, provides an acidic environment for the Nanosurface activity liquid of soaping that S102 step is added.
It should be noted that the present invention no longer washes after adding glacial acetic acid, but next step is directly added and is soaped Liquid, it is different from the effect that existing pickling neutralizes.
Preferably, glacial acetic acid is added in S101 step under stiring, and keeps the temperature 10-15 minutes at a temperature of 50-60 DEG C.
S102, is added Nanosurface activity and soaps and keep the temperature 20 minutes at 50-60 DEG C after liquid, completes aftertreatment technology.
The soaping agent of traditional technology generally soaps twice to textile product at 85 DEG C -95 DEG C, and this high temperature is soaped Technique heats water to 85 DEG C -95 DEG C, and energy consumption is high, and time-consuming.And using Nanosurface activity of the invention soap liquid can be in 50- It is once soaped under conditions of 60 DEG C of relatively low temperature, it is possible to reduce energy consumption and water consumption.
Nanosurface activity of the invention soap liquid include following main component be made:
The Nanosurface activity soap liquid by by polyetheramine, horse propylene copolymer, deionized water and enzyme preparation by outfit It is stirred 15-30 minutes and is made.
Wherein, horse propylene copolymer is chelated dispersants, so that polyetheramine and enzyme preparation are dispersed in around textile product. And dyestuff remaining in the microstructure fiber of textile product is difficult to release, polyetheramine can will be residual in microstructure fiber The dyestuff deposited is removed from textile product by way of dissolving, extracting, and last enzyme preparation acts on the color development functional group of dyestuff, To make dyestuff that oxidative decomposition occur.Therefore, the Nanosurface activity soap liquid to dyeing residual liquid have degradation capability, Dyeing residual liquid is set to decolourize.
It is that 2-6% Nanosurface activity is soaped liquid that the present invention adds mass percent concentration under 50-60 DEG C of relatively low temperature It soaps primary, dyestuff remaining in textile product microstructure fiber can be degraded, reach 95 DEG C of high temperature soaps of traditional soaping agent It washes twice and the primary effect of 80 DEG C of hot water wash.Have the advantage that (1) reduces washing times using technique of the present invention, Water consumption is reduced, low emission;(2) low temperature soaping consumes energy low;(3) process is few, and time-consuming short, efficiency improves.
It should be noted that need to can just play the work of dispersion under acidic environment since horse propylene copolymer is acidic materials With, therefore washing step together cannot be added such as traditional handicraft in the S101 step and S101 step.
Wherein, by polyethylene glycol, ammonification obtains the polyetheramine at high temperature under high pressure.
As shown in Fig. 2, the present invention also provides a kind of energy conservation and environmental protection textile products to dye aftertreatment technology, including following step It is rapid:
S200 will be placed in container using the textile product after reactive dyeing, 55-65 DEG C of hot water, washing be added Water after 10-15 minutes in venting container;
S201 is added 55-65 DEG C of hot water, the water after washing 10-15 minutes in venting container into container again, then weighs The new hot water for being added 50-60 DEG C;
S202, the glacial acetic acid that 1g/L is added are in textile product under acid condition, pH 4-4.5;
S203, is added Nanosurface activity and soaps and keep the temperature 20 minutes at 50-60 DEG C after liquid, completes aftertreatment technology.
The present embodiment and previous embodiment the difference is that, the present embodiment will split into water twice the step of primary washing It washes, the time washed every time shortens half.Have the advantage that first wash highly concentrated using the method washed twice Dyeing residual liquid first removes, and the concentration that when second wash fills the water water washing dyeing raffinate again will reduce, and water washing effect is more preferably.
In addition to this, the conditions such as other steps, condition, equipment, liquid of soaping are all identical, this embodiment repeats no more, reference Previous embodiment.
It is further illustrated below by specific embodiment:
Take identical dyestuff and textile product by dyeing as sample, sample 1 is using traditional dyeing post-processing side The product of method;Sample 2-6 is the product using the dyeing post-processing approach of 1-5 of the embodiment of the present invention.
Reference example
Textile product after reactive dyeing is once washed 15 minutes, is emptied;
It is added in glacial acetic acid and 15 minutes;
Add water, carries out secondary washing 15 minutes;
95 DEG C of hot water of high temperature soap 20 minutes twice;
80 DEG C hot water wash 15 minutes;
Cold water is washed 15 minutes again;
Be added glacial acetic acid in and 15 minutes, test pH value be 6;
Post-processing terminates, and obtains sample 1.
Embodiment 1
It will be washed 30 minutes in 55 DEG C of hot water using the textile product after reactive dyeing;It is added under stiring The glacial acetic acid of 1g/L, pH 4-4.5, and keep the temperature 10-15 minutes at 50 °C;It is 5% that mass percent concentration, which is added, Nanosurface activity soaps and keeps the temperature 20 minutes at 50 DEG C after liquid, completes aftertreatment technology, obtains sample 2.
The Nanosurface activity soap liquid include following main component be made:
The Nanosurface activity soap liquid by by polyetheramine, horse propylene copolymer, deionized water and enzyme preparation by outfit It is stirred 30 minutes and is made.
Embodiment 2
It will be placed in container using the textile product after reactive dyeing, 58 DEG C of hot water be added, after washing 15 minutes Water in venting container;65 DEG C of hot water is added into container again, washes the water in venting container after ten minutes, then adds again Enter 55 DEG C of hot water;The glacial acetic acid of 1g/L, pH 4-4.5 are added under stiring, and keeps the temperature 10 minutes at a temperature of 55 DEG C;Add Entering mass percent concentration is that 3% Nanosurface activity soaps and keeps the temperature 20 minutes at 55 DEG C after liquid, completes aftertreatment technology, obtains Sample 3.
Nanosurface activity soap liquid include following main component be made:
The Nanosurface activity soap liquid by by polyetheramine, horse propylene copolymer, deionized water and enzyme preparation by outfit It is stirred 20 minutes and is made.
Embodiment 3
It will be washed 20 minutes in 65 DEG C of hot water using the textile product after reactive dyeing;It is added under stiring The glacial acetic acid of 1g/L, pH 4-4.5, and 12 minutes are kept the temperature at a temperature of 52 DEG C;It is 2% nanometer that mass percent concentration, which is added, Surface-active soaps and keeps the temperature 20 minutes at 60 DEG C after liquid, completes aftertreatment technology, obtains sample 4.
Nanosurface activity soap liquid include following main component be made:
The Nanosurface activity soap liquid by by polyetheramine, horse propylene copolymer, deionized water and enzyme preparation by outfit It is stirred 25 minutes and is made.
Embodiment 4
It will be washed 25 minutes in 62 DEG C of hot water using the textile product after reactive dyeing;It is added under stiring The glacial acetic acid of 1g/L, pH 4-4.5, and 12 minutes are kept the temperature at a temperature of 53 DEG C;It is 4% nanometer that mass percent concentration, which is added, Surface-active soaps and keeps the temperature 20 minutes at 53 DEG C after liquid, completes aftertreatment technology, obtains sample 5.
Nanosurface activity soap liquid include following main component be made:
The Nanosurface activity soap liquid by by polyetheramine, horse propylene copolymer, deionized water and enzyme preparation by outfit It is stirred 30 minutes and is made.
Embodiment 5
It will be placed in container using the textile product after reactive dyeing, 62 DEG C of hot water be added, washing is after ten minutes Water in venting container;60 DEG C of hot water is added into container again, washes the water in venting container after ten minutes, then adds again Enter 55 DEG C of hot water;The glacial acetic acid of 1g/L, pH 4-4.5 are added under stiring, and keeps the temperature 15 minutes at 50 °C;Add Entering mass percent concentration is that 4% Nanosurface activity soaps and keeps the temperature 20 minutes at 50 DEG C after liquid, completes aftertreatment technology, obtains Sample 6.
Nanosurface activity soap liquid include following main component be made:
The Nanosurface activity soap liquid by by polyetheramine, horse propylene copolymer, deionized water and enzyme preparation by outfit It is stirred 30 minutes and is made.
By the test method of standard GB/T 18401-2010 " national general safety technical code for textile products " to sample 1-6 is detected, and test result is as follows:
From sample 1-6 as it can be seen that can all textile product be made to reach A using traditional handicraft and dyeing aftertreatment technology of the invention Class standard.But using embodiment 1-5 relative to traditional handicraft, one ton of cloth of every production at least saves water 20-25 tons.Saving vapour 0.7-1 tons (saturated vapor), 40-75 kilowatts of using electricity wisely.
Finally, it should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention rather than protects to the present invention The limitation of range is protected, although the invention is described in detail with reference to the preferred embodiments, those skilled in the art should Understand, it can be with modification or equivalent replacement of the technical solution of the present invention are made, without departing from the essence of technical solution of the present invention And range.

Claims (7)

1. a kind of energy conservation and environmental protection textile product dyes aftertreatment technology, which comprises the following steps:
Step 1: by being washed 20-30 minutes in 55-65 DEG C of hot water using the textile product after reactive dyeing;
Step 2: the glacial acetic acid that 1g/L is added is in textile product under acid condition, pH 4-4.5;
20 minutes are kept the temperature at 50-60 DEG C after liquid step 3: addition Nanosurface activity is soaped, completes aftertreatment technology.
2. energy conservation and environmental protection textile product as described in claim 1 dyes aftertreatment technology, which is characterized in that the tool of the first step Body step includes:
(1) it will be placed in container using the textile product after reactive dyeing, 55-65 DEG C of hot water is added, washing 10-15 divides Water after clock in venting container;
(2) 55-65 DEG C of hot water, the water after washing 10-15 minutes in venting container is added into container again, then rejoins 50-60 DEG C of hot water.
3. energy conservation and environmental protection textile product as described in claim 1 dyes aftertreatment technology, which is characterized in that the second step is stirring Lower addition glacial acetic acid is mixed, and keeps the temperature 10-15 minutes at a temperature of 50-60 DEG C.
4. energy conservation and environmental protection textile product as described in claim 1 dyes aftertreatment technology, which is characterized in that the Nanosurface is living Property soap liquid include following main component be made:
5. energy conservation and environmental protection textile product as claimed in claim 4 dyes aftertreatment technology, which is characterized in that the polyetheramine is by gathering Ammonification obtains ethylene glycol at high temperature under high pressure.
6. energy conservation and environmental protection textile product as claimed in claim 4 dyes aftertreatment technology, which is characterized in that the Nanosurface is living Property soap liquid by by polyetheramine, horse propylene copolymer, deionized water and enzyme preparation by outfit be stirred 15-30 minutes be made.
7. energy conservation and environmental protection textile product as described in claim 1 dyes aftertreatment technology, which is characterized in that the Nanosurface is living Property soap liquid mass percent concentration be 2-6%.
CN201810901530.1A 2018-08-08 2018-08-08 A kind of energy conservation and environmental protection textile product dyeing aftertreatment technology Pending CN109252406A (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU1151625A1 (en) * 1983-01-06 1985-04-23 Литовский Научно-Исследовательский Институт Текстильной Промышленности Method of washing textile materials of polyurethane fibres and their blends with polyamide fibres after dyeing with acid dyes
CN102660404A (en) * 2012-05-04 2012-09-12 冠宏股份有限公司 Low-temperature soaping agent as well as preparation method and application thereof
CN103642606A (en) * 2013-11-30 2014-03-19 常熟市华宇针织印染有限公司 Preparation method of low-temperature soaping agent
CN104109587A (en) * 2014-07-03 2014-10-22 赵彰 Low temperature soaping enzyme and application of same in reactive dyeing and soaping process
CN105670833A (en) * 2016-02-26 2016-06-15 苏州三和开泰花线织造有限公司 Non-foaming low-temperature soaping agent for reactive dye and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU1151625A1 (en) * 1983-01-06 1985-04-23 Литовский Научно-Исследовательский Институт Текстильной Промышленности Method of washing textile materials of polyurethane fibres and their blends with polyamide fibres after dyeing with acid dyes
CN102660404A (en) * 2012-05-04 2012-09-12 冠宏股份有限公司 Low-temperature soaping agent as well as preparation method and application thereof
CN103642606A (en) * 2013-11-30 2014-03-19 常熟市华宇针织印染有限公司 Preparation method of low-temperature soaping agent
CN104109587A (en) * 2014-07-03 2014-10-22 赵彰 Low temperature soaping enzyme and application of same in reactive dyeing and soaping process
CN105670833A (en) * 2016-02-26 2016-06-15 苏州三和开泰花线织造有限公司 Non-foaming low-temperature soaping agent for reactive dye and preparation method thereof

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