CN109251708B - Energy-saving and environment-friendly adhesive - Google Patents
Energy-saving and environment-friendly adhesive Download PDFInfo
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- CN109251708B CN109251708B CN201710577341.9A CN201710577341A CN109251708B CN 109251708 B CN109251708 B CN 109251708B CN 201710577341 A CN201710577341 A CN 201710577341A CN 109251708 B CN109251708 B CN 109251708B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J163/00—Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Carbon And Carbon Compounds (AREA)
Abstract
The invention discloses an energy-saving and environment-friendly adhesive for bonding ceramic products, belonging to the technical field of preparation of environment-friendly materials. The composition is prepared from the following components in parts by weight: 100-150 parts of epoxy resin, 30-50 parts of polyimide, 10-20 parts of bronze powder, 30-50 parts of ceramic powder, 30-50 parts of vegetable gum, 1-3 parts of 3-amino-3- (4-hydroxyphenyl) propionic acid and 1-3 parts of carbon nano tube. The energy-saving environment-friendly adhesive is specially used for bonding ceramics, the bonding time is short, the tensile strength after bonding is strong, and the bonding components contain ceramic powder, so that bonding is tighter, bonding traces are reduced, and the bonding time is shortened and the tensile strength after bonding is enhanced by using the combination of the bronze powder, the vegetable gum and the amino-3- (4-hydroxyphenyl) propionic acid.
Description
Technical Field
The invention belongs to the technical field of preparation of environment-friendly materials, and particularly relates to an energy-saving environment-friendly adhesive for bonding ceramic products.
Background
The ceramic product is more and more widely applied to the life of people, has the advantages of no toxicity, no formaldehyde residue, no color change, high hardness, acid and alkali resistance, high pressure and high temperature resistance and the like, is not only applied to the fields of water cups, marmite and the like in daily life, but also more and more widely applied to the fields of artworks and the like, and the artworks made of the ceramic have the advantages of beauty, fastness and the like.
Patent 201410305454.X discloses a special ceramic viscose agent, which consists of the following raw material components in parts by weight: 10-15 parts of potassium carbonate, 15-20 parts of sodium bicarbonate, 10-20 parts of paraffin, 15-30 parts of glyceride, 15-30 parts of silicone oil, 5-15 parts of nano magnesium oxide, 5-15 parts of nano calcium oxide, 5-15 parts of nano zinc oxide, 15-20 parts of boron nitride, 20-30 parts of sodium polyacrylate and 10-20 parts of hydroxyethyl cellulose. The above adhesive also has a problem that the adhesive takes a long time to adhere and has a weak tensile strength after adhesion.
Disclosure of Invention
The invention aims to provide an energy-saving and environment-friendly adhesive for bonding ceramic products.
An energy-saving and environment-friendly viscose is prepared from the following components in parts by weight: 100-150 parts of epoxy resin, 30-50 parts of polyimide, 10-20 parts of bronze powder, 30-50 parts of ceramic powder, 30-50 parts of vegetable gum, 1-3 parts of 3-amino-3- (4-hydroxyphenyl) propionic acid and 1-3 parts of carbon nano tube.
The vegetable gum is one or more of peach gum, rosin, sesbania gum, guar gum, flax gum and fenugreek gum.
The energy-saving environment-friendly viscose also comprises 3-8 parts of a Moss extract.
The Chaksia extract is prepared by the following method: sun drying Moss, grinding into powder, adding 5-10 times of 1% tartaric acid solution, steaming for 12-24 hr, cooling to room temperature, centrifuging at 500rpm for 5-10min at 300-.
The preparation method of the energy-saving environment-friendly viscose glue comprises the following steps:
(1) taking 30-50 parts of vegetable gum, heating to melt at 60-120 ℃, adding 150 parts of epoxy resin 100 and 30-50 parts of polyimide, and stirring for 3-5 minutes;
(2) cooling to 40-50 ℃, adding 10-20 parts of bronze powder and 30-50 parts of ceramic powder, and stirring for 5-10 minutes;
(3) cooling to room temperature, adding 1-3 parts of 3-amino-3- (4-hydroxyphenyl) propionic acid and 1-3 parts of carbon nano tube, and stirring for 10-30 minutes to prepare the nano-composite material.
The invention has the beneficial effects that: the energy-saving environment-friendly adhesive is specially used for bonding ceramics, the bonding time is short, the tensile strength after bonding is strong, and the bonding components contain ceramic powder, so that bonding is tighter, bonding traces are reduced, and the bonding time is shortened and the tensile strength after bonding is enhanced by using the combination of the bronze powder, the vegetable gum and the amino-3- (4-hydroxyphenyl) propionic acid.
Detailed Description
The present invention is further illustrated by the following specific examples.
Example 1
An energy-saving and environment-friendly viscose is prepared from the following components in parts by weight: 120 parts of epoxy resin, 40 parts of polyimide, 15 parts of bronze powder, 40 parts of ceramic powder, 40 parts of peach gum, 2 parts of 3-amino-3- (4-hydroxyphenyl) propionic acid and 2 parts of carbon nano tube.
The preparation method of the energy-saving environment-friendly viscose glue comprises the following steps:
(1) taking 40 parts of peach gum, heating to melt at 90 ℃, adding 120 parts of epoxy resin and 40 parts of polyimide, and stirring for 4 minutes;
(2) cooling to 45 ℃, adding 15 parts of bronze powder and 40 parts of ceramic powder, and stirring for 8 minutes;
(3) cooling to room temperature, adding 2 parts of 3-amino-3- (4-hydroxyphenyl) propionic acid and 2 parts of carbon nano tube, and stirring for 20 minutes to prepare the nano-composite material.
Example 2
An energy-saving and environment-friendly viscose is prepared from the following components in parts by weight: 100 parts of epoxy resin, 30 parts of polyimide, 10 parts of bronze powder, 30 parts of ceramic powder, 30 parts of rosin, 1 part of 3-amino-3- (4-hydroxyphenyl) propionic acid and 1 part of carbon nano tube.
The preparation method of the energy-saving environment-friendly viscose glue comprises the following steps:
(1) taking 30 parts of rosin, heating to the temperature of 120 ℃ until the rosin is molten, adding 100 parts of epoxy resin and 30 parts of polyimide, and stirring for 3 minutes;
(2) cooling to 40 ℃, adding 10 parts of bronze powder and 30 parts of ceramic powder, and stirring for 5 minutes;
(3) cooling to room temperature, adding 1 part of 3-amino-3- (4-hydroxyphenyl) propionic acid and 1 part of carbon nano tube, and stirring for 10-30 minutes to prepare the nano-composite material.
Example 3
An energy-saving and environment-friendly viscose is prepared from the following components in parts by weight: 150 parts of epoxy resin, 50 parts of polyimide, 20 parts of bronze powder, 50 parts of ceramic powder, 50 parts of sesbania gum, 3 parts of 3-amino-3- (4-hydroxyphenyl) propionic acid and 3 parts of carbon nano tube.
The preparation method of the energy-saving environment-friendly viscose glue comprises the following steps:
(1) taking 50 parts of sesbania gum, heating to melt at 60 ℃, adding 150 parts of epoxy resin and 50 parts of polyimide, and stirring for 5 minutes;
(2) cooling to 50 ℃, adding 20 parts of bronze powder and 50 parts of ceramic powder, and stirring for 10 minutes;
(3) cooling to room temperature, adding 3 parts of 3-amino-3- (4-hydroxyphenyl) propionic acid and 3 parts of carbon nano tube, and stirring for 30 minutes to prepare the nano-composite material.
Example 4
An energy-saving and environment-friendly viscose is prepared from the following components in parts by weight: 120 parts of epoxy resin, 40 parts of polyimide, 15 parts of rutile powder, 40 parts of ceramic powder, 40 parts of peach gum, 2 parts of 3-amino-3- (4-hydroxyphenyl) propionic acid, 2 parts of carbon nano tube and 6 parts of Moss extract.
The Chaksia extract is prepared by the following method: sun drying Moss, grinding into powder, adding 8 times of 1% tartaric acid solution, decocting for 18 hr, cooling to room temperature, centrifuging at 400rpm for 8min, and removing supernatant to obtain viscous semisolid Moss extract.
The preparation method of the energy-saving environment-friendly viscose glue comprises the following steps:
(1) taking 40 parts of peach gum, heating to melt at 90 ℃, adding 120 parts of epoxy resin and 40 parts of polyimide, and stirring for 4 minutes;
(2) cooling to 45 ℃, adding 15 parts of bronze powder and 40 parts of ceramic powder, and stirring for 8 minutes;
(3) cooling to room temperature, adding 2 parts of 3-amino-3- (4-hydroxyphenyl) propionic acid, 2 parts of carbon nano tube and 6 parts of Moss extract, and stirring for 20 minutes to obtain the final product.
Example 5
An energy-saving and environment-friendly viscose is prepared from the following components in parts by weight: 120 parts of epoxy resin, 40 parts of polyimide, 15 parts of bronze powder, 40 parts of ceramic powder, 40 parts of peach gum, 2 parts of 3-amino-3- (4-hydroxyphenyl) propionic acid, 2 parts of carbon nano tube and 6 parts of Sichuan jasmine extract.
The jasminum chuanxiong extractive is prepared by the following method: drying leaves of the carnation in the sun, grinding into powder, adding 1% tartaric acid solution in 6 times of the weight portion, cooking for 15 hours, cooling to room temperature, centrifuging at 300rpm for 10min, and removing supernatant to obtain the viscous semisolid extract of the carnation.
The preparation method of the energy-saving environment-friendly viscose glue comprises the following steps:
(1) taking 40 parts of peach gum, heating to melt at 90 ℃, adding 120 parts of epoxy resin and 40 parts of polyimide, and stirring for 4 minutes;
(2) cooling to 45 ℃, adding 15 parts of bronze powder and 40 parts of ceramic powder, and stirring for 8 minutes;
(3) cooling to room temperature, adding 2 parts of 3-amino-3- (4-hydroxyphenyl) propionic acid, 2 parts of carbon nano tube and 6 parts of Sichuan jasmine extract, and stirring for 20 minutes to prepare the external traditional Chinese medicine.
Comparative example 1
An energy-saving and environment-friendly viscose is prepared from the following components in parts by weight: 120 parts of epoxy resin, 40 parts of polyimide, 40 parts of ceramic powder, 40 parts of peach gum, 2 parts of 3-amino-3- (4-hydroxyphenyl) propionic acid and 2 parts of carbon nano tube.
The preparation method of the energy-saving environment-friendly viscose glue comprises the following steps:
(1) taking 40 parts of peach gum, heating to melt at 90 ℃, adding 120 parts of epoxy resin and 40 parts of polyimide, and stirring for 4 minutes;
(2) cooling to 45 ℃, adding 40 parts of ceramic powder, and stirring for 8 minutes;
(3) cooling to room temperature, adding 2 parts of 3-amino-3- (4-hydroxyphenyl) propionic acid and 2 parts of carbon nano tube, and stirring for 20 minutes to prepare the nano-composite material.
Comparative example 2
An energy-saving and environment-friendly viscose is prepared from the following components in parts by weight: 120 parts of epoxy resin, 40 parts of polyimide, 15 parts of bronze powder, 40 parts of ceramic powder, 40 parts of peach gum and 2 parts of carbon nano tube.
The preparation method of the energy-saving environment-friendly viscose glue comprises the following steps:
(1) taking 40 parts of peach gum, heating to melt at 90 ℃, adding 120 parts of epoxy resin and 40 parts of polyimide, and stirring for 4 minutes;
(2) cooling to 45 ℃, adding 15 parts of bronze powder and 40 parts of ceramic powder, and stirring for 8 minutes;
(3) cooling to room temperature, adding 2 parts of carbon nano tube, and stirring for 20 minutes to prepare the carbon nano tube.
The method comprises the following steps of selecting ceramic tiles with uniform sizes, selecting the viscose glue of the examples 1-5 and the comparative examples 1-2, wherein the bonding area is 10 square centimeters, the bonding thickness is 0.5 millimeter, calculating the bonding time (taking the condition that the bonded tiles are not fallen off under the action of gravity as a standard) and the tensile resistance (counted by the force of mechanical pulling) after bonding for 10 hours, and obtaining the experimental results shown in the table 1:
TABLE 1
As can be seen from table 1, the bonding time of examples 4 and 5 is significantly lower than that of example 1, and compared with example 1, the other experimental conditions are the same, only the more moss extract is added in example 4, and the more jasminum alatum extract is added in example 5, which proves that the moss extract and the jasminum alatum extract have the efficacy of shortening the bonding time of the composition; the bonding time of the comparative example 1 is obviously longer than that of the example 1, compared with the example 1, other experimental conditions are the same, only the bronze powder is added into the comparative example 1, and the bronze powder is proved to have the effect of shortening the bonding time of the composition; the tensile resistance of comparative example 2 is significantly lower than that of example 1, and compared with example 1, the other experimental conditions are the same, only the comparative example 2 adds less 3-amino-3- (4-hydroxyphenyl) propionic acid, and the 3-amino-3- (4-hydroxyphenyl) propionic acid is proved to have the efficacy of enhancing the tensile resistance of the composition.
Claims (3)
1. The energy-saving and environment-friendly viscose glue is characterized by being prepared from the following components in parts by weight: 100-150 parts of epoxy resin, 30-50 parts of polyimide, 10-20 parts of bronze powder, 30-50 parts of ceramic powder, 30-50 parts of vegetable gum, 1-3 parts of 3-amino-3- (4-hydroxyphenyl) propionic acid and 1-3 parts of carbon nano tube.
2. The energy-saving and environment-friendly viscose glue according to claim 1, wherein the vegetable gum is one or more of peach gum, rosin, sesbania gum, guar gum, flax gum and fenugreek gum.
3. The preparation method of the energy-saving and environment-friendly viscose glue as claimed in claim 1 is characterized by comprising the following steps:
(1) taking 30-50 parts of vegetable gum, heating to melt at 60-120 ℃, adding 150 parts of epoxy resin 100 and 30-50 parts of polyimide, and stirring for 3-5 minutes;
(2) cooling to 40-50 ℃, adding 10-20 parts of bronze powder and 30-50 parts of ceramic powder, and stirring for 5-10 minutes;
(3) cooling to room temperature, adding 1-3 parts of 3-amino-3- (4-hydroxyphenyl) propionic acid and 1-3 parts of carbon nano tube, and stirring for 10-30 minutes to prepare the nano-composite material.
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| CN201710577341.9A CN109251708B (en) | 2017-07-14 | 2017-07-14 | Energy-saving and environment-friendly adhesive |
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| CN201710577341.9A CN109251708B (en) | 2017-07-14 | 2017-07-14 | Energy-saving and environment-friendly adhesive |
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| CN109251708A CN109251708A (en) | 2019-01-22 |
| CN109251708B true CN109251708B (en) | 2021-04-02 |
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| CN112480850A (en) * | 2020-12-19 | 2021-03-12 | 重庆禄成建筑工程有限公司 | Environment-friendly high-strength adhesive |
Citations (6)
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|---|---|---|---|---|
| WO2010038484A1 (en) * | 2008-10-03 | 2010-04-08 | 島根県 | Heat-resistant and highly heat-conductive adhesive agent |
| WO2011055887A1 (en) * | 2009-11-05 | 2011-05-12 | (주)덕산테코피아 | Conductive adhesive, method for manufacturing same, and electronic device including the conductive adhesive |
| CN102786901A (en) * | 2012-08-17 | 2012-11-21 | 山东省科学院新材料研究所 | Conductive silver adhesive for high-power LED (light-emitting diode) and preparation method and curing and using method thereof |
| CN104610896A (en) * | 2015-01-13 | 2015-05-13 | 潮州三环（集团）股份有限公司 | Adhesive and preparation method thereof |
| CN104861893A (en) * | 2015-04-30 | 2015-08-26 | 昆山文创建筑装饰工程有限公司 | Plant-based multifunctional building adhesive |
| CN106893540A (en) * | 2015-12-17 | 2017-06-27 | 天津市亘元科技发展有限公司 | A kind of high-temperature Resistance Adhesives |
-
2017
- 2017-07-14 CN CN201710577341.9A patent/CN109251708B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010038484A1 (en) * | 2008-10-03 | 2010-04-08 | 島根県 | Heat-resistant and highly heat-conductive adhesive agent |
| WO2011055887A1 (en) * | 2009-11-05 | 2011-05-12 | (주)덕산테코피아 | Conductive adhesive, method for manufacturing same, and electronic device including the conductive adhesive |
| CN102786901A (en) * | 2012-08-17 | 2012-11-21 | 山东省科学院新材料研究所 | Conductive silver adhesive for high-power LED (light-emitting diode) and preparation method and curing and using method thereof |
| CN104610896A (en) * | 2015-01-13 | 2015-05-13 | 潮州三环（集团）股份有限公司 | Adhesive and preparation method thereof |
| CN104861893A (en) * | 2015-04-30 | 2015-08-26 | 昆山文创建筑装饰工程有限公司 | Plant-based multifunctional building adhesive |
| CN106893540A (en) * | 2015-12-17 | 2017-06-27 | 天津市亘元科技发展有限公司 | A kind of high-temperature Resistance Adhesives |
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