CN109249664A - A kind of PVC film modelled after an antique and preparation method thereof - Google Patents

A kind of PVC film modelled after an antique and preparation method thereof Download PDF

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Publication number
CN109249664A
CN109249664A CN201810936084.8A CN201810936084A CN109249664A CN 109249664 A CN109249664 A CN 109249664A CN 201810936084 A CN201810936084 A CN 201810936084A CN 109249664 A CN109249664 A CN 109249664A
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CN
China
Prior art keywords
pvc
parts
temperature
modelled
preparation
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Pending
Application number
CN201810936084.8A
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Chinese (zh)
Inventor
曾勇华
何荣忠
甘荣生
钟震国
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Guangdong Tian Jin New Material Co Ltd
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Guangdong Tian Jin New Material Co Ltd
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Priority to CN201810936084.8A priority Critical patent/CN109249664A/en
Publication of CN109249664A publication Critical patent/CN109249664A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/30Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/304Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/06Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/06Printing inks based on fatty oils
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00Layers arrangement
    • B32B2250/24All layers being polymeric
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/10Coating on the layer surface on synthetic resin layer or on natural or synthetic rubber layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2451/00Decorative or ornamental articles

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Shaping Of Tube Ends By Bending Or Straightening (AREA)

Abstract

A kind of PVC film modelled after an antique of the present invention and preparation method thereof, including layer of PVC and ink layer, the ink layer raw material includes: 15-20 parts of polishes according to parts by weight, 2-5 parts of butanone, 3-6 parts of pigment, 0.1-0.3 parts of scratch resistance agent, preparation method, the following steps are included: 1) PVC base and PVC decorative layer are prepared first, printing ink layer on the PVC decorative layer;2) then PVC base and PVC decorative layer are bonded by make-up machine;3) finally ink layer is wiped using wiping agent, ink layer is wiped by wiping agent, so that ink layer shows decorative pattern and pattern modelled after an antique, there is antique effect, meet the needs of people.

Description

A kind of PVC film modelled after an antique and preparation method thereof
Technical field
The invention belongs to high-molecular compound technical fields, and in particular to a kind of PVC film modelled after an antique and preparation method thereof.
Background technique
Polyvinyl chloride English abbreviation PVC, with less toxic, fire-retardant, cold-resistant, the environmentally friendly excellent performance of PVC film, increasingly To vast purposes, it is widely used in the fields such as certificate, Bao Ce, packaging, luggage, clothes, footwear, automobile decoration, develops to Visible PVC product everywhere in daily life field.By a little as it can be seen that the demand of PVC film is increasing.
PVC film main ingredient is polyvinyl chloride, separately has and other compositions are added to enhance its heat resistance, toughness, ductility Deng.PVC film be liked deeply in the world today, a kind of rather popular and synthetic material for being also widely used.PVC film Global usage amount be in second in various synthetic materials.In the material that can produce three-dimensional table facial mask, PVC film is most Suitable material.
Currently, and having part as the improvement of people's living standards, part population likes pursuing the home decoration of modernization People likes the furniture decoration and ornament that have pseudo-classic style, and there is presently no the PVC films for meeting this demand of people.
Summary of the invention
The present invention overcomes the disadvantages of the prior art, provides a kind of PVC film modelled after an antique and preparation method thereof, has imitative Ancient effect, meets the needs of people.
In order to solve the above-mentioned technical problem, the present invention is achieved by the following technical solutions:
A kind of PVC film modelled after an antique comprising layer of PVC and ink layer, the ink layer raw material includes: polishes according to parts by weight 15-20 parts, 2-5 parts of butanone, 3-6 parts of pigment, 0.1-0.3 parts of scratch resistance agent.
Further, the pigment includes red 0.87 part of R-122, and Y-21 is 2.75 parts, black 0.5 part of B-27 yellow.
A kind of preparation method of PVC film modelled after an antique, comprising the following steps:
1) PVC base and PVC decorative layer, printing ink layer on the PVC decorative layer are prepared first;
2) then PVC base and PVC decorative layer are bonded by make-up machine;
3) finally ink layer is wiped using wiping agent.
Further, according to parts by weight, the wiping agent is 40-70 parts of ethyl ester and 30-40 parts of butanone.
Further, in the step 2), the PVC base and PVC decorative layer pass through face preheating wheel and middle preheating first Then wheel passes through embossed wheel, rubber tire, temperature refining wheel and cooling wheel then by main heat opinion and delivery wheel.
Further, the face preheating wheel speed is 11.742m/min, and temperature is 120 DEG C, and middle preheating wheel speed is 12.023m/min, temperature are 130 DEG C.
Further, it is 12.48m/min that the main heat, which discusses speed, and temperature is 155 DEG C, and conveying wheel speed is 12.156m/ Min, temperature are 160 DEG C.
Further, the embossing wheel speed is 11.102m/min, and temperature is 30 DEG C.
Further, the rubber tire temperature is ice water temperature, and temperature refining wheel speed is 12.256m/min, and temperature is 30 DEG C, cooling Wheel speed is 12.368m/min, and temperature is ice water temperature.
Compared with prior art, the beneficial effects of the present invention are:
A kind of PVC film modelled after an antique of the present invention and preparation method thereof, including layer of PVC and ink layer, the ink layer raw material It according to parts by weight include: 15-20 parts of polishes, 2-5 parts of butanone, 3-6 parts of pigment, 0.1-0.3 parts of scratch resistance agent, preparation method, The following steps are included: 1) PVC base and PVC decorative layer are prepared first, printing ink layer on the PVC decorative layer;2) then logical Make-up machine is crossed to be bonded PVC base and PVC decorative layer;3) finally ink layer is wiped using wiping agent, is passed through Wiping agent wipes ink layer, so that ink layer shows decorative pattern and pattern modelled after an antique, has antique effect, meets people Demand.
Specific embodiment
Hereinafter, preferred embodiments of the present invention will be described, it should be understood that preferred embodiment described herein is only used In the description and interpretation present invention, it is not intended to limit the present invention.
A kind of PVC film modelled after an antique comprising layer of PVC and ink layer, ink layer raw material include: polyester resin according to parts by weight 50 parts, 35 parts of butyl glycol ether, 10 parts of filler, 2 parts of dispersing agent, 3 parts of defoaming agent, 19.2 parts of polishes TJ110,3.43 parts of butanone, 4.12 parts of pigment, 0.25 part of KA-910 scratch resistance agent, polishes TJ110 is for adjusting ink colors, wherein pigment includes R-122 red 0.87 part, Y-21 is 2.75 parts, black 0.5 part of B-27 yellow.
A kind of preparation method of PVC film modelled after an antique, comprising the following steps:
1) PVC base and PVC decorative layer, printing ink layer on the PVC decorative layer are prepared first;
2) then PVC base and PVC decorative layer are bonded by make-up machine;
3) finally ink layer is wiped using wiping agent, according to parts by weight, the ethyl ester that the wiping agent is 60 parts With 36 parts of butanone.
Wherein, in step 2), then PVC base and PVC decorative layer pass through first by face preheating wheel and middle preheating wheel Then main heat opinion and delivery wheel pass through embossed wheel, rubber tire, temperature refining wheel and cooling wheel.
It is 11.742m/min that face, which preheats wheel speed, and temperature is 120 DEG C, and middle preheating wheel speed is 12.023m/min, temperature It is 130 DEG C.
It is 12.48m/min that main heat, which discusses speed, and temperature is 155 DEG C, and conveying wheel speed is 12.156m/min, temperature 160 ℃。
Embossing wheel speed is 11.102m/min, and temperature is 30 DEG C.
Rubber tire temperature is ice water temperature, and temperature refining wheel speed is 12.256m/min, and temperature is 30 DEG C, and cooling wheel speed is 12.368m/min, temperature are ice water temperature.
The present invention makes pigment cooperate, then by using wiping agent to ink by above-mentioned specific speed and temperature Layer is wiped, and the PVC film of pseudo-classic effect is obtained.
Finally, it should be noted that these are only the preferred embodiment of the present invention, it is not intended to restrict the invention, although Referring to embodiment, invention is explained in detail, for those skilled in the art, still can be to aforementioned Technical solution documented by each embodiment is modified or equivalent replacement of some of the technical features, but it is all Within the spirit and principles in the present invention, any modification, equivalent replacement, improvement and so on should be included in protection of the invention Within the scope of.

Claims (9)

1. a kind of PVC film modelled after an antique, which is characterized in that it includes layer of PVC and ink layer, and the ink layer raw material is according to parts by weight It include: 15-20 parts of polishes, 2-5 parts of butanone, 3-6 parts of pigment, 0.1-0.3 parts of scratch resistance agent.
2. a kind of PVC film modelled after an antique according to claim 1, which is characterized in that the pigment includes red 0.87 part of R-122, Y- 21 is 2.75 parts, black 0.5 part of B-27 yellow.
3. a kind of preparation method of PVC film modelled after an antique according to claim 1, which comprises the following steps:
1) PVC base and PVC decorative layer, printing ink layer on the PVC decorative layer are prepared first;
2) then PVC base and PVC decorative layer are bonded by make-up machine;
3) finally ink layer is wiped using wiping agent.
4. a kind of preparation method of PVC film modelled after an antique according to claim 3, which is characterized in that according to parts by weight, the wiping Wiping agent is 40-70 parts of ethyl ester and 30-40 parts of butanone.
5. a kind of preparation method of PVC film modelled after an antique according to claim 3, which is characterized in that described in the step 2) PVC base and PVC decorative layer, then by main heat opinion and delivery wheel, then lead to first by face preheating wheel and middle preheating wheel Cross embossed wheel, rubber tire, temperature refining wheel and cooling wheel.
6. a kind of preparation method of PVC film modelled after an antique according to claim 5, which is characterized in that the face preheats wheel speed and is 11.742m/min, temperature are 120 DEG C, and middle preheating wheel speed is 12.023m/min, and temperature is 130 DEG C.
7. a kind of preparation method of PVC film modelled after an antique according to claim 5, which is characterized in that the main heat by speed is 12.48m/min, temperature are 155 DEG C, and conveying wheel speed is 12.156m/min, and temperature is 160 DEG C.
8. a kind of preparation method of PVC film modelled after an antique according to claim 5, which is characterized in that the embossing wheel speed is 11.102m/min, temperature are 30 DEG C.
9. a kind of preparation method of PVC film modelled after an antique according to claim 4, which is characterized in that the rubber tire temperature is ice water Temperature, temperature refining wheel speed are 12.256m/min, and temperature is 30 DEG C, and cooling wheel speed is 12.368m/min, and temperature is ice water temperature Degree.
CN201810936084.8A 2018-08-16 2018-08-16 A kind of PVC film modelled after an antique and preparation method thereof Pending CN109249664A (en)

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Application Number Priority Date Filing Date Title
CN201810936084.8A CN109249664A (en) 2018-08-16 2018-08-16 A kind of PVC film modelled after an antique and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810936084.8A CN109249664A (en) 2018-08-16 2018-08-16 A kind of PVC film modelled after an antique and preparation method thereof

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110576662A (en) * 2019-08-29 2019-12-17 成都帝龙新材料有限公司 PVC (polyvinyl chloride) coated silk polymer decorative film, preparation method and application thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN204151597U (en) * 2014-08-26 2015-02-11 南通亿华塑胶有限公司 Wiping water-soluble resin leather
CN105133814A (en) * 2015-07-24 2015-12-09 浙江帝龙新材料股份有限公司 Manufacturing technology of environment-friendly high-temperature resistant compression-resistant floor color film
CN105437710A (en) * 2015-04-01 2016-03-30 广东天安新材料股份有限公司 PVC composite film and preparation method therefor

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN204151597U (en) * 2014-08-26 2015-02-11 南通亿华塑胶有限公司 Wiping water-soluble resin leather
CN105437710A (en) * 2015-04-01 2016-03-30 广东天安新材料股份有限公司 PVC composite film and preparation method therefor
CN105133814A (en) * 2015-07-24 2015-12-09 浙江帝龙新材料股份有限公司 Manufacturing technology of environment-friendly high-temperature resistant compression-resistant floor color film

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110576662A (en) * 2019-08-29 2019-12-17 成都帝龙新材料有限公司 PVC (polyvinyl chloride) coated silk polymer decorative film, preparation method and application thereof

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Application publication date: 20190122

RJ01 Rejection of invention patent application after publication