CN106948183A - A kind of super abrasive aqueous coating PVC leather and processing technology - Google Patents

A kind of super abrasive aqueous coating PVC leather and processing technology Download PDF

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Publication number
CN106948183A
CN106948183A CN201710113374.8A CN201710113374A CN106948183A CN 106948183 A CN106948183 A CN 106948183A CN 201710113374 A CN201710113374 A CN 201710113374A CN 106948183 A CN106948183 A CN 106948183A
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China
Prior art keywords
pvc
aqueous coating
super abrasive
layer
agent
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Pending
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CN201710113374.8A
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Inventor
洪爱军
杨昌友
赵艳庆
苏红伟
黄亮忠
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Foshan Weishida New Materials Co., Ltd.
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Foshan City Gaoming Wise Star Plastic Co Ltd
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Application filed by Foshan City Gaoming Wise Star Plastic Co Ltd filed Critical Foshan City Gaoming Wise Star Plastic Co Ltd
Priority to CN201710113374.8A priority Critical patent/CN106948183A/en
Publication of CN106948183A publication Critical patent/CN106948183A/en
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/06—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyvinylchloride or its copolymerisation products
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0043—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by their foraminous structure; Characteristics of the foamed layer or of cellular layers
    • D06N3/005—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by their foraminous structure; Characteristics of the foamed layer or of cellular layers obtained by blowing or swelling agent
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0061—Organic fillers or organic fibrous fillers, e.g. ground leather waste, wood bark, cork powder, vegetable flour; Other organic compounding ingredients; Post-treatment with organic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/007—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by mechanical or physical treatments
    • D06N3/0077—Embossing; Pressing of the surface; Tumbling and crumbling; Cracking; Cooling; Heating, e.g. mirror finish
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0086—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
    • D06N3/0088—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by directly applying the resin
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0086—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
    • D06N3/0095—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by inversion technique; by transfer processes
    • D06N3/0097—Release surface, e.g. separation sheets; Silicone papers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/14—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
    • D06N3/145—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes two or more layers of polyurethanes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/16—Properties of the materials having other properties
    • D06N2209/1685—Wear resistance
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00—Specially adapted uses
    • D06N2211/12—Decorative or sun protection articles
    • D06N2211/28—Artificial leather

Abstract

A kind of super abrasive aqueous coating PVC leather and processing technology of the present invention, applied including aspect at layer primary coat at the base fabric set from bottom to top, glue adhesive layer, PVC foam layer, PVC surface layers, table and table, its processing technology includes PVC surface layers and PVC foam layer preparation of batch, coating, surface treatment and embossing, after MIE weares and teares 2 hours, peak abrasion≤5mm, vertical direction is without abrasion.

Description

A kind of super abrasive aqueous coating PVC leather and processing technology
Technical field
The invention belongs to technical field of artificial leather, specifically, it is related to a kind of super abrasive aqueous coating PVC leather and processing work Skill.
Background technology
PVC (Polyvinylchloride) is the artificial leather material invented earliest in the world, is also the maximum modeling of yield Expect one of product, PVC Main Ingredients and Appearances are polyvinyl chloride, can also be increased in its manufacture course of products by adding other compositions Its strong heat resistance, toughness, ductility, wearability etc., it is good with processing characteristics, it is cheap, the features such as corrosion-resistant, therefore It is widely used in world wide, common PVC material product such as PVC water pipes, PVC foam plate, PVC is used to make imitative The Suitcases ＆ Leatherware of leather, sporting goods etc..
With the deep application of PVC artificial leather, people for the quality and comfort level of PVC artificial leather requirement also increasingly Height, in particular for making the PVC artificial leather of automobile leather and sofa artificial leather, not only pursues fashionable appearance, soft, also requires that energy Possess certain toughness, antiwear characteristic, increase the service life, strengthen practicality, this can singly not reduce family's daily expenditure, also can Mitigate environmental pollution, meet the theory of environmental protection.
Artificial leather application more and more extensively, is such as widely used on the product that seat is contacted for a long time equal to human body, tradition Artificial leather surface layer easily grind flower, gall.
The content of the invention
Instant invention overcomes shortcoming of the prior art there is provided a kind of super abrasive aqueous coating PVC leather and processing technology, The super abrasive artificial leather manufacturing approach craft is simple, and its artificial leather manufactured has wear-resisting, is difficult the advantage of decortication, it uses the longevity Life length.
In order to solve the above-mentioned technical problem, the present invention is achieved by the following technical solutions：
A kind of super abrasive aqueous coating PVC leather, including set from bottom to top base fabric, glue adhesive layer, PVC foam layer, At PVC surface layers, table layer primary coat and table at aspect apply.
Further, the raw material of the PVC surface layers includes：PVC paste resin 100, according to mass ratio, plasticizer is 75-90, surely Agent is determined for 1-5, and pigment is 1-15, the PVC paste resin K values：70-85, plasticizer is phthalic ester plasticizer, stable Agent is calcium zinc metalloid salt, and pigment is organic or inorganic pigment.
Further, the raw material of the PVC foam layer includes：PVC paste resin 100, according to mass ratio, plasticizer is 75-90, Stabilizer is 1-5, and foaming agent is 1-5, and pigment is 1-15.
Further, in the PVC foam layer, the PVC paste resin K values：70-85, the plasticizer is phthalic acid Ester plasticizer, stabilizer is calcium zinc metalloid salt, and foaming agent is azodicarbonamide, and pigment is organic or inorganic pigment.
Further, layer primary coat includes at the table：According to mass ratio, the aqueous mute slurry 100~60 of aliphatic polyurethane, it is consolidated Containing 15~35%, aqueous aliphatic polyurethane light slurry 0~40, admittedly containing 15~35%, crosslinking agent 1~10, auxiliary agent 0.1~3.
Further, at the table in layer primary coat, the crosslinking agent is poly- carbodiimide type or isocyanate-based, the auxiliary agent For levelling agent, thickener and defoamer.
Further, aspect painting includes at the table：According to mass ratio, the mute slurry 100~60 of waterborne, polycarbonate type polyurethane, It contains 15~35% admittedly, aqueous aliphatic polyurethane light slurry 0~40, and it contains 15~35% admittedly, crosslinking agent 1~10, and hand feeling agent 1~ 25th, graphene EPS 0.1~1.2 and auxiliary agent 0.1~3, the crosslinking agent are poly- carbodiimide type or isocyanate-based, the hand Sense agent is organosilicon, and the auxiliary agent is levelling agent, thickener and defoamer.
A kind of processing technology of super abrasive aqueous coating PVC leather, including：
(1) PVC surface layers and PVC foam layer preparation of batch；
1) high-speed stirred will be carried out in the material input cylinder in PVC paste resin and auxiliary agent, uniform mixture is made；
2) material mixed is ground, vacuumized；
3) by being filtered from 80/100/120/200 mesh screen pack；
(2) it is coated with
1) PVC surface layers are scraped in thickness painting on request in release liners；Then by high temperature oven, processing temperature about 170~210 ℃；Baking time about 1~3 minute；
2) PVC foam layer, then by high temperature oven, processing temperature about 170 are scraped in thickness painting on request on the basis of surface layer ~210 DEG C；Baking time about 1~3 minute；
3) glue is scraped in grammes per square metre painting on request on the basis of foaming layer；
4) by base fabric laminating and glue face, then by high temperature oven, about 120~190 DEG C of processing temperature；Baking time is about 1~3 minute；
5) bundling and then in release liners is peeled off, PVC semi-finished product give process production；
(3) it is surface-treated
1) layer primary coat at table and face are applied in the material input cylinder in formula respectively and carries out high-speed stirred；It is made uniform mixed It is fit；
2) primary coat is evenly applied to product PVC surface, coated weight about 15~45g/m2 (weight in wet base) from suitable roller； 60~120 DEG C of baking temperature, baking time 1~3 minute；
3) face is applied from suitable roller and be evenly applied on product primed surface, coated weight about 15~45g/m2 is (wet Weight)；60~120 DEG C of baking temperature, baking time 1~3 minute；
(4) it is embossed
The product that surface treatment is finished is heated, about 160~260 DEG C of heating-up temperature, and PVC surface temperature about 120~ 160 DEG C, then it is embossed from suitable patterned roll, finished product is made in cooling shaping.
Compared with prior art, the beneficial effects of the invention are as follows：
A kind of super abrasive aqueous coating PVC leather and processing technology of the present invention, including set from bottom to top base fabric, glue Water adhesive layer, PVC foam layer, aspect is applied at layer primary coat and table at PVC surface layers, table, after MIE weares and teares 2 hours, and peak abrasion≤ 5mm, vertical direction is without abrasion.
Brief description of the drawings
Accompanying drawing is used for providing a further understanding of the present invention, together with embodiments of the present invention for explaining the present invention, It is not construed as limiting the invention, in the accompanying drawings：
Fig. 1 is a kind of structural representation of super abrasive aqueous coating PVC leather of the present invention.
Embodiment
The preferred embodiments of the present invention are illustrated below in conjunction with accompanying drawing, it will be appreciated that preferred reality described herein Apply example to be merely to illustrate and explain the present invention, be not intended to limit the present invention.
As shown in figure 1, the formula and material of a kind of super abrasive aqueous coating PVC leather of the present invention are：PVC surface layers：It is thick Spend 0.15~0.4mm
PVC foam layer：0.3~0.8mm of thickness after foaming
Layer formula at table -- primary coat formula
Layer formula at table -- face applies formula
Other auxiliary materials：
Processing technology：
The technical indicator met：
Finally it should be noted that：The preferred embodiments of the present invention are these are only, are not intended to limit the invention, although The present invention is described in detail with reference to embodiment, for a person skilled in the art, it still can be to foregoing Technical scheme described in each embodiment is modified, or to which part technical characteristic carry out equivalent, but it is all Within the spirit and principles in the present invention, any modifications, equivalent substitutions and improvements made etc. should be included in the protection of the present invention Within the scope of.

Claims (8)

1. a kind of super abrasive aqueous coating PVC leather, it is characterised in that including the base fabric set from bottom to top, glue adhesive layer, At PVC foam layer, PVC surface layers, table layer primary coat and table at aspect apply.
2. a kind of super abrasive aqueous coating PVC leather according to claim 1, it is characterised in that the raw material bag of the PVC surface layers Include：PVC paste resin 100, according to mass ratio, plasticizer is 75-90, and stabilizer is 1-5, and pigment is 1-15, the PVC paste resin K values：70-85, plasticizer is phthalic ester plasticizer, and stabilizer is calcium zinc metalloid salt, and pigment is organic or inorganic Pigment.
3. a kind of super abrasive aqueous coating PVC leather according to claim 1, it is characterised in that the raw material of the PVC foam layer Including：PVC paste resin 100, according to mass ratio, plasticizer is 75-90, and stabilizer is 1-5, and foaming agent is 1-5, and pigment is 1- 15。
4. a kind of super abrasive aqueous coating PVC leather according to claim 3, it is characterised in that in the PVC foam layer, institute State PVC paste resin K values：70-85, the plasticizer is phthalic ester plasticizer, and stabilizer is calcium zinc metalloid salt, hair Infusion is azodicarbonamide, and pigment is organic or inorganic pigment.
5. a kind of super abrasive aqueous coating PVC leather according to claim 1, it is characterised in that a layer primary coat includes at the table： According to mass ratio, the mute slurry 100~60 of aqueous aliphatic polyurethane, it contains 15~35% admittedly, aqueous aliphatic polyurethane light slurry 0~ 40, admittedly containing 15~35%, crosslinking agent 1~10, auxiliary agent 0.1~3.
6. a kind of super abrasive aqueous coating PVC leather according to claim 5, it is characterised in that at the table in layer primary coat, institute Crosslinking agent is stated for poly- carbodiimide type or isocyanate-based, the auxiliary agent is levelling agent, thickener and defoamer.
7. a kind of super abrasive aqueous coating PVC leather according to claim 1, it is characterised in that aspect is applied and included at the table： According to mass ratio, the mute slurry 100~60 of waterborne, polycarbonate type polyurethane, it contains 15~35%, aqueous aliphatic polyurethane light admittedly Slurry 0~40, its admittedly contain 15~35%, crosslinking agent 1~10, hand feeling agent 1~25, graphene EPS 0.1~1.2 and auxiliary agent 0.1~ 3, the crosslinking agent is poly- carbodiimide type or isocyanate-based, and the hand feeling agent is organosilicon, and the auxiliary agent is levelling agent, increased Thick dose and defoamer.
8. a kind of processing technology of super abrasive aqueous coating PVC leather, it is characterised in that including：
(1) PVC surface layers and PVC foam layer preparation of batch；
1) high-speed stirred will be carried out in the material input cylinder in PVC paste resin and auxiliary agent, uniform mixture is made；
2) material mixed is ground, vacuumized；
3) by being filtered from 80/100/120/200 mesh screen pack；
(2) it is coated with
1) PVC surface layers are scraped in thickness painting on request in release liners；Then by high temperature oven, about 170~210 DEG C of processing temperature； Baking time about 1~3 minute；
2) PVC foam layer, then by high temperature oven, processing temperature about 170~210 are scraped in thickness painting on request on the basis of surface layer ℃；Baking time about 1~3 minute；
3) glue is scraped in grammes per square metre painting on request on the basis of foaming layer；
4) by base fabric laminating and glue face, then by high temperature oven, about 120~190 DEG C of processing temperature；Baking time about 1~3 Minute；
5) bundling and then in release liners is peeled off, PVC semi-finished product give process production；
(3) it is surface-treated
1) layer primary coat at table and face are applied in the material input cylinder in formula respectively and carries out high-speed stirred；Uniform mixing is made Body；
2) primary coat is evenly applied to product PVC surface, coated weight about 15~45g/m2 (weight in wet base) from suitable roller；Baking 60~120 DEG C of temperature, baking time 1~3 minute；
3) face is applied from suitable roller and be evenly applied on product primed surface, coated weight about 15~45g/m2 (weight in wet base)； 60~120 DEG C of baking temperature, baking time 1~3 minute；
(4) it is embossed
The product that surface treatment is finished is heated, about 160~260 DEG C of heating-up temperature, PVC surface temperature about 120~160 DEG C, then it is embossed from suitable patterned roll, finished product is made in cooling shaping.
CN201710113374.8A 2017-02-28 2017-02-28 A kind of super abrasive aqueous coating PVC leather and processing technology Pending CN106948183A (en)

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Cited By (20)

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CN108148472A (en) * 2017-12-20 2018-06-12 上海水趣户外用品有限公司 Vinyl coating, preparation method, its application method and purposes
CN108547158A (en) * 2018-05-15 2018-09-18 佛山市高明威仕达塑料有限公司 A kind of aqueous coating sofa artificial leather and preparation method thereof
CN108642895A (en) * 2018-05-15 2018-10-12 佛山市高明威仕达塑料有限公司 A kind of aqueous coating automobile artificial leather and preparation method thereof
CN108729250A (en) * 2018-07-18 2018-11-02 苏州瑞高新材料有限公司 A kind of automobile-used coating member of modified PVC and preparation method thereof
CN108774454A (en) * 2018-07-18 2018-11-09 苏州瑞高新材料有限公司 A kind of preparation method and applications of wear-resisting scratch resistance waterborne surface treatment agent for automobile leather
CN108797145A (en) * 2018-07-27 2018-11-13 加通汽车内饰(常熟)有限公司 A kind of albumen noise reduction PVC artificial leather and preparation method thereof
CN108909125A (en) * 2018-07-18 2018-11-30 苏州瑞高新材料有限公司 It is a kind of to can be used as the PVC epidermis and preparation method thereof that mold uses
CN108912653A (en) * 2018-07-18 2018-11-30 华伦皮塑（苏州）有限公司 The preparation method of graphene/waterborne polyurethane conductive composite material for civilian leather and its preparation method of graphene dispersing solution
CN109023985A (en) * 2018-07-18 2018-12-18 苏州瑞高新材料有限公司 A kind of high-tensile waterborne surface treatment agent and preparation method thereof for automobile leather
CN109134916A (en) * 2018-07-18 2019-01-04 苏州瑞高新材料有限公司 A kind of PVC-PP foam composite material and preparation method thereof
CN109575772A (en) * 2018-11-05 2019-04-05 加通汽车内饰(常熟)有限公司 A kind of modified water treatment agent of animal protein, preparation method and its application
CN110373912A (en) * 2019-07-23 2019-10-25 东风汽车集团有限公司 A kind of PVC artificial leather and preparation method thereof, the automotive seat containing the PVC artificial leather
CN110938358A (en) * 2018-09-21 2020-03-31 贝内克-长顺汽车内饰材料（张家港）有限公司 Waterborne polyurethane paint, high-water-resistance product prepared from same and high-water-resistance leather
CN111197264A (en) * 2018-11-16 2020-05-26 贝内克-长顺汽车内饰材料（张家港）有限公司 PVC artificial leather with support
CN111197263A (en) * 2018-11-16 2020-05-26 贝内克-长顺汽车内饰材料（张家港）有限公司 PVC artificial leather with support
CN111691196A (en) * 2020-06-10 2020-09-22 浙江康成新材料科技有限公司 Easy-to-clean PU automobile leather and preparation method thereof
CN112593419A (en) * 2020-12-07 2021-04-02 安徽安利材料科技股份有限公司 Preparation method of water-based low-temperature printing environment-friendly polyurethane synthetic leather
CN113442475A (en) * 2021-06-04 2021-09-28 佛山市威仕达新材料有限公司 Preparation method of water-based coating certificate leather
CN115247381A (en) * 2022-04-08 2022-10-28 加通汽车内饰(常熟)有限公司 Preparation method of wear-resistant artificial leather, wear-resistant artificial leather and automotive interior
CN115613362A (en) * 2021-07-12 2023-01-17 本田技研工业(中国)投资有限公司 Artificial leather and automobile seat

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CN108148472A (en) * 2017-12-20 2018-06-12 上海水趣户外用品有限公司 Vinyl coating, preparation method, its application method and purposes
CN108547158A (en) * 2018-05-15 2018-09-18 佛山市高明威仕达塑料有限公司 A kind of aqueous coating sofa artificial leather and preparation method thereof
CN108642895A (en) * 2018-05-15 2018-10-12 佛山市高明威仕达塑料有限公司 A kind of aqueous coating automobile artificial leather and preparation method thereof
CN108729250A (en) * 2018-07-18 2018-11-02 苏州瑞高新材料有限公司 A kind of automobile-used coating member of modified PVC and preparation method thereof
CN108774454A (en) * 2018-07-18 2018-11-09 苏州瑞高新材料有限公司 A kind of preparation method and applications of wear-resisting scratch resistance waterborne surface treatment agent for automobile leather
CN108909125A (en) * 2018-07-18 2018-11-30 苏州瑞高新材料有限公司 It is a kind of to can be used as the PVC epidermis and preparation method thereof that mold uses
CN108912653A (en) * 2018-07-18 2018-11-30 华伦皮塑（苏州）有限公司 The preparation method of graphene/waterborne polyurethane conductive composite material for civilian leather and its preparation method of graphene dispersing solution
CN109023985A (en) * 2018-07-18 2018-12-18 苏州瑞高新材料有限公司 A kind of high-tensile waterborne surface treatment agent and preparation method thereof for automobile leather
CN109134916A (en) * 2018-07-18 2019-01-04 苏州瑞高新材料有限公司 A kind of PVC-PP foam composite material and preparation method thereof
CN108797145A (en) * 2018-07-27 2018-11-13 加通汽车内饰(常熟)有限公司 A kind of albumen noise reduction PVC artificial leather and preparation method thereof
CN108797145B (en) * 2018-07-27 2019-06-21 加通汽车内饰(常熟)有限公司 A kind of albumen noise reduction PVC artificial leather and preparation method thereof
CN110938358A (en) * 2018-09-21 2020-03-31 贝内克-长顺汽车内饰材料（张家港）有限公司 Waterborne polyurethane paint, high-water-resistance product prepared from same and high-water-resistance leather
CN109575772A (en) * 2018-11-05 2019-04-05 加通汽车内饰(常熟)有限公司 A kind of modified water treatment agent of animal protein, preparation method and its application
CN111197264A (en) * 2018-11-16 2020-05-26 贝内克-长顺汽车内饰材料（张家港）有限公司 PVC artificial leather with support
CN111197263A (en) * 2018-11-16 2020-05-26 贝内克-长顺汽车内饰材料（张家港）有限公司 PVC artificial leather with support
CN110373912A (en) * 2019-07-23 2019-10-25 东风汽车集团有限公司 A kind of PVC artificial leather and preparation method thereof, the automotive seat containing the PVC artificial leather
CN111691196A (en) * 2020-06-10 2020-09-22 浙江康成新材料科技有限公司 Easy-to-clean PU automobile leather and preparation method thereof
CN111691196B (en) * 2020-06-10 2021-05-07 浙江康成新材料科技有限公司 Easy-to-clean PU automobile leather and preparation method thereof
CN112593419A (en) * 2020-12-07 2021-04-02 安徽安利材料科技股份有限公司 Preparation method of water-based low-temperature printing environment-friendly polyurethane synthetic leather
CN112593419B (en) * 2020-12-07 2023-09-08 安徽安利材料科技股份有限公司 Preparation method of water-based low-temperature printing environment-friendly polyurethane synthetic leather
CN113442475A (en) * 2021-06-04 2021-09-28 佛山市威仕达新材料有限公司 Preparation method of water-based coating certificate leather
CN115613362A (en) * 2021-07-12 2023-01-17 本田技研工业(中国)投资有限公司 Artificial leather and automobile seat
CN115247381A (en) * 2022-04-08 2022-10-28 加通汽车内饰(常熟)有限公司 Preparation method of wear-resistant artificial leather, wear-resistant artificial leather and automotive interior

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