CN106917296A - A kind of PVC artificial leather used suitable for jungle environment and preparation method thereof - Google Patents
A kind of PVC artificial leather used suitable for jungle environment and preparation method thereof Download PDFInfo
- Publication number
- CN106917296A CN106917296A CN201710114127.XA CN201710114127A CN106917296A CN 106917296 A CN106917296 A CN 106917296A CN 201710114127 A CN201710114127 A CN 201710114127A CN 106917296 A CN106917296 A CN 106917296A
- Authority
- CN
- China
- Prior art keywords
- artificial leather
- mass parts
- used suitable
- polyvinyl chloride
- leather used
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0059—Organic ingredients with special effects, e.g. oil- or water-repellent, antimicrobial, flame-resistant, magnetic, bactericidal, odour-influencing agents; perfumes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
Abstract
A kind of PVC artificial leather used suitable for jungle environment of the present invention and preparation method thereof, including base fabric and glue-line, the formula of the glue-line includes polyvinyl chloride resin, hexanedioic acid polyester, composite calcium zinc stabilizing agent, acrylic resin, silicone resin, antioxidant 1076, ultraviolet absorber UVP and pigment, durable, long service life effectively improves the heat aging performance of product.
Description
Technical field
The invention belongs to technical field of artificial leather, specifically, it is related to a kind of PVC used suitable for jungle environment artificial
Leather and preparation method thereof.
Background technology
Artificial leather is exactly a kind of plastic products of leather-like.Generally with fabric as base, one is coated with or pasted thereon
Layer resin compound, then heating is allowed to plastify, and flattens or be embossed through rolling, obtains final product product.Natural leather is similar to, is had
Soft, wear-resisting the features such as.Species according to covering is different, there is artificial polyvinyl chloride leather (PVC), polyurethane artificial leather (PU)
Deng.Can almost be replaced in the occasion of any use leather, for making commodity and industrial goods.Sent out according to coating
Whether steep, foamed leather and common artificial leather are divided again.There are footwear artificial leather, case and bag artificial leather etc. according to purposes.
People for the quality and comfort level of PVC artificial leather requirement also more and more higher, in particular for make footwear or
The PVC artificial leather of dress ornament class, not only pursues fashionable appearance, soft, also requires that can possess certain toughness, antiwear characteristic,
Increase the service life, undergo rugged environment without damaging.
The content of the invention
Instant invention overcomes shortcoming of the prior art, there is provided a kind of PVC artificial leather used suitable for jungle environment
And preparation method thereof, durable, long service life.
In order to solve the above-mentioned technical problem, the present invention is achieved by the following technical solutions：
A kind of PVC artificial leather used suitable for jungle environment, including base fabric and glue-line, the formula of the glue-line include
Polyvinyl chloride resin, hexanedioic acid polyester, composite calcium zinc stabilizing agent, acrylic resin, silicone resin, antioxidant 1076, ultraviolet absorber
UVP and pigment.
Further, the mass parts of polyvinyl chloride resin 100, hexanedioic acid polyester 80-100 mass parts, the mass parts of composite calcium zinc stabilizing agent 3,
The mass parts of acrylic resin 5, the mass parts of silicone resin 0.2, the mass parts of antioxidant 1076 0.2, the matter of ultraviolet absorber UVP 0.6
Amount part, pigment 0.2-0.3.
Further, the polyvinyl chloride resin includes the mass parts of polyvinyl chloride resin 95 of the degree of polymerization 2500 and the PVC trees of the degree of polymerization 1000
The mass parts of fat 5.
Further, the acrylic resin is n-butyl acrylate-methylmethacrylate copolymer, molecular weight 5,000,000
~700 ten thousand.
Further, it is additionally added the Graphene EPS of the polyvinyl chloride resin mass fraction 0.1~1.2%.
Further, it is additionally added the organosilicon of the polyvinyl chloride resin mass fraction 2~5%.
Further, it is additionally added the protein powder of the polyvinyl chloride resin mass fraction 0.5~1%.
A kind of preparation method of the PVC artificial leather used suitable for jungle environment, comprises the following steps：
1) each raw material of the formula of glue-line is carried out into banburying after the stirring of homogenizer high speed into banbury, obtains glue
Layer slurry；
2) base fabric enters calender calender lamination with the glue-line slurry, is finally embossed treatment.
Compared with prior art, the beneficial effects of the invention are as follows：
A kind of PVC artificial leather used suitable for jungle environment of the present invention and preparation method thereof, including base fabric and glue
Layer, the formula of the glue-line includes polyvinyl chloride resin, and hexanedioic acid polyester, composite calcium zinc stabilizing agent, acrylic resin, silicone resin resists
Oxygen agent 1076, ultraviolet absorber UVP and pigment, durable, long service life effectively improve the heat aging performance of product.
Specific embodiment
The preferred embodiments of the present invention are illustrated below, it will be appreciated that preferred embodiment described herein is only used
In the description and interpretation present invention, it is not intended to limit the present invention.
A kind of PVC artificial leather used suitable for jungle environment, including base fabric and glue-line, base fabric are looped fabric base terylene base
Cloth, bondline thickness is 0.25mm, and the formula of glue-line includes the mass parts of polyvinyl chloride resin 100, the mass parts of hexanedioic acid polyester 85, and its is relative
Molecular mass about 2000, the mass parts of composite calcium zinc stabilizing agent 3, the mass parts of acrylic resin 5, the mass parts of silicone resin 0.2, antioxygen
The mass parts of agent 1,076 0.2, the mass parts of ultraviolet absorber UVP 0.6, pigment 0.25.
Polyvinyl chloride resin includes the mass parts of polyvinyl chloride resin 95 of the degree of polymerization 2500 and the mass parts of polyvinyl chloride resin 5 of the degree of polymerization 1000.
Acrylic resin is n-butyl acrylate-methylmethacrylate copolymer, molecular weight 5,000,000~7,000,000.
The Graphene EPS of polyvinyl chloride resin mass fraction 0.5% is additionally added, the organosilicon of mass fraction 2.5% is additionally added PVC
The protein powder of resin quality fraction 0.6%.
1st, simple poor using high polymerization degree naval stores quality stability, the resin for adding a small amount of degree of polymerization to be 1000 can have
Effect improves product quality.
2nd, adding specific acrylic resin can be effectively improved the material plasticizing performance of process.
3rd, adding silicone resin can be effectively improved processing characteristics.
4th, specific calcium-zinc composite stabilizing agent can effectively improve the heat aging performance of product.
Graphene has the case hardness of superelevation, when being evenly distributed in artificial leather, can provide product surface superelevation
Wearability.
Organosilicon provides smooth surface and reduces skin-friction coefficient.
Protein powder has the wet conductibility of aspiration, can assign the function of its ventilative moisture absorption.
1st, through 100 DEG C of x400Hrs it is aging after, tortuous 3000 product surfaces are without cracking phenomena under the conditions of -20 DEG C.
2nd, after through under the conditions of 70 DEG C, 95% relative temperature aging 5 weeks, tortuous 3000 product surfaces under the conditions of -20 DEG C
Without cracking phenomena.
3rd, after just changing through the table 7 below test period, tortuous 3000 product surfaces are without cracking phenomena under the conditions of -20 DEG C.
A kind of preparation method of the PVC artificial leather used suitable for jungle environment, comprises the following steps：
1) each raw material of the formula of glue-line is carried out into banburying after the stirring of homogenizer high speed into banbury, obtains glue
Layer slurry；
2) base fabric enters calender calender lamination with the glue-line slurry, is finally embossed treatment.
Finally it should be noted that：The preferred embodiments of the present invention are these are only, is not intended to limit the invention, although
The present invention is described in detail with reference to embodiment, for a person skilled in the art, it still can be to foregoing
Technical scheme described in each embodiment is modified, or equivalent is carried out to which part technical characteristic, but it is all
Within the spirit and principles in the present invention, any modification, equivalent substitution and improvements made etc. should be included in protection of the invention
Within the scope of.
Claims (8)
1. a kind of PVC artificial leather used suitable for jungle environment, it is characterised in that including base fabric and glue-line, the glue-line
Formula includes polyvinyl chloride resin, and hexanedioic acid polyester, composite calcium zinc stabilizing agent, acrylic resin, silicone resin, antioxidant 1076 is ultraviolet
Absorbent UVP and pigment.
2. a kind of PVC artificial leather used suitable for jungle environment according to claim 1, it is characterised in that the PVC trees
The mass parts of fat 100, hexanedioic acid polyester 80-100 mass parts, the mass parts of composite calcium zinc stabilizing agent 3, the mass parts of acrylic resin 5, silicon
The mass parts of ketone resin 0.2, the mass parts of antioxidant 1076 0.2, the mass parts of ultraviolet absorber UVP 0.6, pigment 0.2-0.3.
3. a kind of PVC artificial leather used suitable for jungle environment according to claim 1, it is characterised in that the PVC trees
Fat includes the mass parts of polyvinyl chloride resin 95 of the degree of polymerization 2500 and the mass parts of polyvinyl chloride resin 5 of the degree of polymerization 1000.
4. a kind of PVC artificial leather used suitable for jungle environment according to claim 1, it is characterised in that the propylene
Acid resin is n-butyl acrylate-methylmethacrylate copolymer, molecular weight 5,000,000~7,000,000.
5. a kind of PVC artificial leather used suitable for jungle environment according to claim 1, it is characterised in that be additionally added institute
State the Graphene EPS of polyvinyl chloride resin mass fraction 0.1~1.2%.
6. a kind of PVC artificial leather used suitable for jungle environment according to claim 1, it is characterised in that be additionally added institute
State the organosilicon of polyvinyl chloride resin mass fraction 2~5%.
7. a kind of PVC artificial leather used suitable for jungle environment according to claim 1, it is characterised in that be additionally added institute
State the protein powder of polyvinyl chloride resin mass fraction 0.5~1%.
8. a kind of preparation method of the PVC artificial leather used suitable for jungle environment, it is characterised in that comprise the following steps：
1) each raw material of the formula of glue-line is carried out into banburying after the stirring of homogenizer high speed into banbury, obtains glue-line slurry
Material；
2) base fabric enters calender calender lamination with the glue-line slurry, is finally embossed treatment.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710114127.XA CN106917296A (en) | 2017-02-28 | 2017-02-28 | A kind of PVC artificial leather used suitable for jungle environment and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710114127.XA CN106917296A (en) | 2017-02-28 | 2017-02-28 | A kind of PVC artificial leather used suitable for jungle environment and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106917296A true CN106917296A (en) | 2017-07-04 |
Family
ID=59454296
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710114127.XA Pending CN106917296A (en) | 2017-02-28 | 2017-02-28 | A kind of PVC artificial leather used suitable for jungle environment and preparation method thereof |
Country Status (1)
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| CN (1) | CN106917296A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107724099A (en) * | 2017-10-27 | 2018-02-23 | 佛山威明塑胶有限公司 | A kind of antistatic PVC artificial leather and its production method |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102839547A (en) * | 2011-06-24 | 2012-12-26 | 昆山阿基里斯人造皮有限公司 | Preparation method of impact-resistant artificial leather |
| CN102851998A (en) * | 2012-09-04 | 2013-01-02 | 李永平 | Environmental protection type PVC synthetic leather and preparation method thereof |
| CN103015218A (en) * | 2012-12-22 | 2013-04-03 | 河南宝隆实业有限公司 | PVC artificial leather scrape paint and method of preparing PVC artificial leather with scrape paint |
| CN104532599A (en) * | 2014-11-28 | 2015-04-22 | 佛山市高明区塑料行业协会 | Environment-friendly synthetic leather and preparation method thereof |
-
2017
- 2017-02-28 CN CN201710114127.XA patent/CN106917296A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102839547A (en) * | 2011-06-24 | 2012-12-26 | 昆山阿基里斯人造皮有限公司 | Preparation method of impact-resistant artificial leather |
| CN102851998A (en) * | 2012-09-04 | 2013-01-02 | 李永平 | Environmental protection type PVC synthetic leather and preparation method thereof |
| CN103015218A (en) * | 2012-12-22 | 2013-04-03 | 河南宝隆实业有限公司 | PVC artificial leather scrape paint and method of preparing PVC artificial leather with scrape paint |
| CN104532599A (en) * | 2014-11-28 | 2015-04-22 | 佛山市高明区塑料行业协会 | Environment-friendly synthetic leather and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107724099A (en) * | 2017-10-27 | 2018-02-23 | 佛山威明塑胶有限公司 | A kind of antistatic PVC artificial leather and its production method |
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| Date | Code | Title | Description |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20190308 Address after: 528500 No. 1, Yanghe Zhenweitai Road, Cangjiang Industrial Park, Gaoming District, Foshan City, Guangdong Province Applicant after: Foshan Weishida New Materials Co., Ltd. Address before: 528500 Yanghe Zhenweitai Road, Cangjiang Industrial Park, Gaoming District, Foshan City, Guangdong Province Applicant before: Foshan city Gaoming wise Star Plastic Co Ltd |
|
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170704 |