CN109243737A - PTC ceramics chip and preparation method thereof - Google Patents

PTC ceramics chip and preparation method thereof Download PDF

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Publication number
CN109243737A
CN109243737A CN201811129259.0A CN201811129259A CN109243737A CN 109243737 A CN109243737 A CN 109243737A CN 201811129259 A CN201811129259 A CN 201811129259A CN 109243737 A CN109243737 A CN 109243737A
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China
Prior art keywords
table plane
plane
elongated surfaces
ptc ceramics
electrode
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CN201811129259.0A
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Inventor
晏秋实
吴周立
杨成
龚浩臣
杨航
张雷
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Xiaogan Huagong Gaoli Electron Co Ltd
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Xiaogan Huagong Gaoli Electron Co Ltd
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Priority to CN201811129259.0A priority Critical patent/CN109243737A/en
Publication of CN109243737A publication Critical patent/CN109243737A/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01CRESISTORS
    • H01C7/00Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material
    • H01C7/02Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material having positive temperature coefficient
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    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/46Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on titanium oxides or titanates
    • C04B35/462Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on titanium oxides or titanates based on titanates
    • C04B35/465Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on titanium oxides or titanates based on titanates based on alkaline earth metal titanates
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    • C04B35/4684Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on titanium oxides or titanates based on titanates based on alkaline earth metal titanates based on barium titanates based on BaTiO3 perovskite phase containing lead compounds
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Abstract

The present invention provides a kind of PTC ceramics chips and preparation method thereof, are related to technical field of electronic ceramic, comprising: electrode, the first table plane, the elongated surfaces of the second table plane and the first table plane and the second table plane;Electrode is set in the first table plane and the second table plane;First table plane is arranged in parallel with the second table plane;Elongated surfaces are set to the first table plane and the second table interplanar;It is attached between first table plane and the second table plane by elongated surfaces;Elongated surfaces, the first table plane and the second table plane are in Different Plane;First table plane and the second table plane control the safe distance of the first table plane and the second table interplanar electrode by elongated surfaces, solves the technical problem that safe distance is not easy to control between PTC ceramics chip electrode, safe distance between PTC ceramics chip electrode is improved, the security performance of PTC ceramic element and device is increased.

Description

PTC ceramics chip and preparation method thereof
Technical field
The present invention relates to technical field of electronic ceramic, more particularly, to a kind of PTC ceramics chip and preparation method thereof.
Background technique
Posive temperature coefficient thermistor (Positive Temperature Coefficient, abbreviation PTC) is widely applied In fields such as household electrical appliances, automobiles, only the distance between two electrode of PTC, which reaches requirement just, can guarantee the safety that PTC is used.
Usually distance safe between increase electrode can carry out silk-screen increasing by using the printing equipment with precise locating function Gap value between power-up pole and potsherd easily causes deviation when realizing, but printing, interelectrode safe distance it is difficult to ensure that; It can also be realized by increasing chip thickness and increase interelectrode safe distance, but the method PTC thickness increases, and causes to heat The amount of thinking highly of increases, and is not able to satisfy auto heater miniaturization, light-weighted design requirement.
Summary of the invention
In view of this, the purpose of the present invention is to provide a kind of PTC ceramics chip and preparation method thereof, to solve existing skill The inconvenient technical problem of safe distance control in PTC ceramics chip present in art.
In a first aspect, the embodiment of the invention provides a kind of PTC ceramics chips, comprising: electrode, the first table plane, second The elongated surfaces of table plane and the first table plane and the second table plane;Electrode is set to the first table plane and the second table plane On;First table plane is arranged in parallel with the second table plane;Elongated surfaces are set to the first table plane and the second table interplanar;First table It is attached between plane and the second table plane by elongated surfaces;Elongated surfaces, the first table plane and the second table plane are in Different Plane;First table plane and the second table plane control the peace of the first table plane and the second table interplanar electrode by elongated surfaces Full distance.
With reference to first aspect, the embodiment of the invention provides the first possible embodiments of first aspect, wherein the Ohm contact electrode is coated in one table plane and the second table plane.
With reference to first aspect, the embodiment of the invention provides second of possible embodiments of first aspect, wherein prolongs Long face are as follows: convex body or concaver.
The possible embodiment of second with reference to first aspect, the embodiment of the invention provides the third of first aspect Possible embodiment, wherein convex body includes: curved body and/or multiple plane bodies;Concaver includes: curved body and/or more A plane body.
With reference to first aspect, the embodiment of the invention provides the 4th kind of possible embodiments of first aspect, wherein prolongs The cutting plane of long face are as follows: convex shape or concave body;Wherein, cutting plane is perpendicular to the first table plane and the second table plane.
The 4th kind of possible embodiment with reference to first aspect, the embodiment of the invention provides the 5th kind of first aspect Possible embodiment, wherein convex shape is curl shape or polygon;Concave body is curl shape or polygon.
The 5th kind of possible embodiment with reference to first aspect, the embodiment of the invention provides the 6th kind of first aspect Possible embodiment, wherein the number of edges of polygon is at least four.
The 5th kind of possible embodiment with reference to first aspect, the embodiment of the invention provides the 7th kind of first aspect Possible embodiment, wherein when the number of edges of polygon is four, it is diamond shape or trapezoidal that polygon, which is formed by quadrangle,.
Second aspect, the embodiment of the present invention also provide a kind of production method of PTC ceramics chip, comprising: configuration chip system Raw material needed for making;Raw material are fired as ceramic matrix according to preset model, and the screen printing electrode on ceramic matrix; Production processing ceramic matrix is ground by beveling, so that ceramic matrix forms the first table plane, the second table plane and the first table The elongated surfaces of plane and the second table plane;First table plane is arranged in parallel with the second table plane;It is flat that elongated surfaces are set to the first table Face and the second table interplanar;It is attached between first table plane and the second table plane by elongated surfaces;Elongated surfaces, the first table are flat Face and the second table plane are in Different Plane;First table plane and the second table plane pass through elongated surfaces the first table plane of control With the second interelectrode safe distance of table interplanar.
Technical solution provided in an embodiment of the present invention bring it is following the utility model has the advantages that
The present invention provides a kind of PTC ceramics chips and preparation method thereof, comprising: electrode, the first table plane, the second table are flat The elongated surfaces of face and the first table plane and the second table plane;Wherein, electrode is set to the first table plane and second first In table plane;After first table plane and the second table plane are arranged in parallel;Then by elongated surfaces be set to the first table plane with it is described Second table interplanar;It will be attached between the first table plane and the second table plane by elongated surfaces later;Last elongated surfaces, the One table plane and the second table plane are in Different Plane;To which the first table plane and the second table plane are controlled by elongated surfaces Therefore the safe distance of first table plane and the second table interplanar electrode passes through prolonging for setting the first table plane and the second plane The spatial relation of long face and the first table plane, the second table interplanar, ensure the interelectrode safety of PTC ceramics chip chamber away from From to solve between PTC ceramics chip electrode, safe distance is difficult to control technical problem, improves PTC ceramics chip electrode Between safe distance, increase PTC ceramic element and device security performance.
Other features and advantages of the present invention will illustrate in the following description, also, partly become from specification It obtains it is clear that understand through the implementation of the invention.The objectives and other advantages of the invention are in specification and attached drawing Specifically noted structure is achieved and obtained.
To enable the above objects, features and advantages of the present invention to be clearer and more comprehensible, preferred embodiment is cited below particularly, and cooperate Appended attached drawing, is described in detail below.
Detailed description of the invention
It, below will be to specific in order to illustrate more clearly of the specific embodiment of the invention or technical solution in the prior art Embodiment or attached drawing needed to be used in the description of the prior art be briefly described, it should be apparent that, it is described below Attached drawing is some embodiments of the present invention, for those of ordinary skill in the art, before not making the creative labor It puts, is also possible to obtain other drawings based on these drawings.
Fig. 1 is a kind of structural schematic diagram of PTC ceramics chip provided in an embodiment of the present invention;
Fig. 2 is the structural schematic diagram of convex shape provided in an embodiment of the present invention;
Fig. 3 is the structural schematic diagram of concave body provided in an embodiment of the present invention;
Fig. 4 is a kind of flow chart of PTC ceramics chip manufacture method provided in an embodiment of the present invention.
Icon: 1-PTC ceramic chip;11- the first table plane;12- the second table plane;13- elongated surfaces.
Specific embodiment
In order to make the object, technical scheme and advantages of the embodiment of the invention clearer, below in conjunction with attached drawing to the present invention Technical solution be clearly and completely described, it is clear that described embodiments are some of the embodiments of the present invention, rather than Whole embodiments.Based on the embodiments of the present invention, those of ordinary skill in the art are not making creative work premise Under every other embodiment obtained, shall fall within the protection scope of the present invention.
Currently, safe distance is not easy to control between existing PTC ceramics chip electrode, be easy to cause under high pressure conditions discharge into And cause component failure, it is based on this, a kind of PTC ceramics chip provided in an embodiment of the present invention and preparation method thereof can solve The inconvenient technical problem of safe distance control in TC ceramic chip existing in the prior art.
For convenient for understanding the present embodiment, first to a kind of PTC ceramics chip disclosed in the embodiment of the present invention and Its production method describes in detail.
Embodiment one:
The embodiment of the present invention provides a kind of PTC ceramics chip, as shown in Figure 1, PTC ceramics chip 1 includes: electrode, first The elongated surfaces 13 of table plane 11, the second table plane 12 and the first table plane 11 and the second table plane 12.
Specifically, electrode is set in the first table plane 11 and the second table plane 12;Wherein, the first table plane 11 with Ohm contact electrode is coated in second table plane 12, wherein the coating of Ohm contact electrode is to pass through screen printing electrode It realizes.Further, the first table plane 11 is arranged in parallel with the second table plane 12;Wherein, elongated surfaces 13 are set to the first table Between plane 11 and the second table plane 12;And first is attached between table plane 11 and the second table plane 12 by elongated surfaces 13; Elongated surfaces 13, the first table plane 11 and the second table plane 12 are in Different Plane.Above-mentioned elongated surfaces are as follows: convex body is recessed Face body.Any section of convex body is all convex-edge shape, and any section of concaver is all concave edge shape.Wherein, convex body includes: song Face body and/or multiple plane bodies, i.e. elongated surfaces can be the convex body or be respectively that curved body and multiple plane bodies are combined into Curved body and multiple plane bodies;Wherein concaver includes: curved body and/or multiple plane bodies, i.e. elongated surfaces can be curved body The concaver that is combined into multiple plane bodies or respectively curved body and multiple plane bodies.By setting convex surface for elongated surfaces Body or concaver improve the safe distance between PTC ceramics chip electrode to extend interelectrode distance, and without increasing electricity The thickness of interpolar.
The cutting plane of above-mentioned elongated surfaces 13 are as follows: convex shape or concave body;Wherein, cutting plane perpendicular to the first table plane 11 with And the second table plane 12.As shown in Fig. 2, cutting plane is convex shape, as shown in figure 3, cutting plane is concave body, in Fig. 2 and Fig. 3 with For four kinds of different figures, wherein convex shape is curl shape or polygon;Concave body is curl shape or polygon.And it is polygon The number of edges of shape is at least four, wherein when the number of edges of polygon is four, it is diamond shape or ladder that polygon, which is formed by quadrangle, Shape can extend interelectrode distance specifically, the four edges of quadrangle are not mutually perpendicular to that condition can be met entirely, improve Safe distance between PTC ceramics chip electrode, and without increasing interelectrode thickness.
In addition, the first table plane 11 and the second table plane 12 are flat by the first table plane 11 of control of elongated surfaces 13 and the second table The safe distance of 12 electrodes in face.
The embodiment of the invention provides a kind of PTC ceramics chips, comprising: electrode, the first table plane, the second table plane and The elongated surfaces of first table plane and the second table plane;Electrode is set in the first table plane and the second table plane;First table is flat Face is arranged in parallel with the second table plane;Elongated surfaces are set to the first table plane and the second table interplanar;First table plane with It is attached between second table plane by elongated surfaces;Elongated surfaces, the first table plane and the second table plane are in different flat Face;First table plane and the second table plane by elongated surfaces control the first table plane and the second table interplanar electrode safely away from From improving the safe distance between PTC ceramics chip electrode, increase the security performance of PTC ceramic element and device.
Embodiment two:
The production method that the embodiment of the present invention provides a kind of PTC ceramics chip is as shown in Figure 4, comprising:
Step S402, raw material needed for configuring chip manufacturing.
Step S404 fires raw material for ceramic matrix according to preset model, and the silk-screen printing electricity on ceramic matrix Pole.
Step S406 grinds production processing ceramic matrix by beveling, so that ceramic matrix forms the first table plane, second The elongated surfaces of table plane and the first table plane and the second table plane.
Step S408, the first table plane are arranged in parallel with the second table plane.
Step S410, elongated surfaces are set to the first table plane and the second table interplanar.
Step S412, is attached between the first table plane and the second table plane by elongated surfaces.
Step S414, elongated surfaces, the first table plane and the second table plane are in Different Plane.
Step S416, the first table plane and the second table plane control the first table plane and the second table interplanar by elongated surfaces Interelectrode safe distance.
Above-mentioned step S402- step S416 is mainly to be realized by following step, comprising:
1. primary weighing, ball milling, press filt: pressing molecular formula Ba first0.74Pb0.22Ca0.04Ti1.01O3+ 0.13%NbO52Respectively Weigh BaCO3, TiO2, CaCO3, PbO2, Nb2O5;Then raw material are subjected to a mix grinding using ball mill, according to material: ball: water =1:1.2:1.5 ball milling 20 hours, wherein ball mill is polyurethane liner, and abrasive media is agate ball;Finally by a ball milling Good slurry injects slip drying press, and controls press filt time and pressure and make to discharge moisture control below 30%.
2. pre-burning: the good material of press filt is packed into mullite sagger, in continuous push-plate type tunnel oven, 300 DEG C of foundation- 600 DEG C -1150 DEG C -1150 DEG C -800 DEG C, 25Hz technique carries out pre-burning, and the powder that pre-burning is completed is fitted into plastic barrel and seals It is good.
3. two weighings, ball millings: in Preburning material mole ratio, adding 1.5%Al2O3, 2%SiO2, 0.07%MnO2, 0.05%Y2O3, raw material are subjected to a mix grinding using ball mill, ball mill is polyurethane liner, and abrasive media is agate ball, Material: ball: water=1:1.2:0.7, Ball-milling Time 20 hours.
4. with slurry, granulation: by the polyvinyl alcohol (polyvinyl of secondary material mass ratio 1:10% addition concentration 8% Alcohol, abbreviation PVA solution), while 0.3% release agent is introduced, stirring 3 hours or more, by peristaltic pump by configured slurry Material is transported to atomizer pelletizer, forms 30-100 μm of sphere through flash baking.
5. molding: the powder being granulated is formed by the rotary press of 50T, wherein blank 3.8 ± 0.02mm of thickness, Substance 8.0-8.3g, mold and punching head size 27.7*17.5mm.
6. chip, sintering: doing combustion pot body using corundum crucible, the neat code of the blank of forming is entered, is spread between blank The ZrO of 60-80 mesh2Powder prevents blank adhesion.By 300 DEG C -600 DEG C -1150 DEG C -1290 DEG C -1290 DEG C -1290 DEG C of technique - 1100 DEG C -800 DEG C, 28Hz technique sintering, gained chip coats In_Ga electrode test resistance value 5-8k Ω, and pressure-resistant 1500VDC is kept 3 minutes.
7. dimensioned, screen printed electrode: being processed first to the plane of potsherd, potsherd is machined to thickness 2.97 ± 0.02mm, cleaning, drying are starched, 570 DEG C, 5Hz using screen printer print ohm slurry, such as Ag-Zn;Then net is used Belt burning infiltration kiln carries out burning infiltration, and the chip that burning infiltration is completed carries out dimensioneds to 4 sides using beveler, by beveler plus Side after work is bevel edge, wherein the value range of the length of the hypotenuse is 2.5mm-3mm;Finally ceramic chip is cleaned, is dried It is dry.
8. voltage-withstand test: pressing 300VAC 1min, 700VAC 2min is arranged pressure-resistant testing machine and carries out pressure-resistant inspection to chip It surveys.
9. picking according to resistance: under 25 ± 2 DEG C of environment after chip constant temperature 4 hours, pressing 5-6.5k using automatic picking according to resistance machine Ω, 6.5-8k Ω carry out picking according to resistance.
10. visual examination is packed and stored: being marked by appearance limit, in the case where 800-1200 lumen of light is according to strength environment to core Piece carries out visual examination, and is fitted into corresponding packaging material and vacuumizes.
The embodiment of the invention provides a kind of production methods of PTC ceramics chip, wherein the first table plane and the second table are flat Face controls the first table plane and the second interelectrode safe distance of table interplanar by elongated surfaces, improves PTC ceramics chip electricity Interpolar safe distance increases the security performance of PTC ceramic element and device.
PTC ceramics chip manufacture method provided in an embodiment of the present invention has with PTC ceramics chip provided by the above embodiment There is identical technical characteristic, so also can solve identical technical problem, reaches identical technical effect.
In the description of the present invention, it should be noted that term " center ", "upper", "lower", "left", "right", "vertical", The orientation or positional relationship of the instructions such as "horizontal", "inner", "outside" be based on the orientation or positional relationship shown in the drawings, merely to Convenient for description the present invention and simplify description, rather than the device or element of indication or suggestion meaning must have a particular orientation, It is constructed and operated in a specific orientation, therefore is not considered as limiting the invention.In addition, term " first ", " second ", " third " is used for descriptive purposes only and cannot be understood as indicating or suggesting relative importance.
In several embodiments provided herein, it should be understood that disclosed systems, devices and methods, it can be with It realizes by another way.The apparatus embodiments described above are merely exemplary, for example, the division of the unit, Only a kind of logical function partition, there may be another division manner in actual implementation, in another example, multiple units or components can To combine or be desirably integrated into another system, or some features can be ignored or not executed.
The unit as illustrated by the separation member may or may not be physically separated, aobvious as unit The component shown may or may not be physical unit, it can and it is in one place, or may be distributed over multiple In network unit.It can select some or all of unit therein according to the actual needs to realize the mesh of this embodiment scheme 's.
It, can also be in addition, the functional units in various embodiments of the present invention may be integrated into one processing unit It is that each unit physically exists alone, can also be integrated in one unit with two or more units.
Finally, it should be noted that embodiment described above, only a specific embodiment of the invention, to illustrate the present invention Technical solution, rather than its limitations, scope of protection of the present invention is not limited thereto, although with reference to the foregoing embodiments to this hair It is bright to be described in detail, those skilled in the art should understand that: anyone skilled in the art In the technical scope disclosed by the present invention, it can still modify to technical solution documented by previous embodiment or can be light It is readily conceivable that variation or equivalent replacement of some of the technical features;And these modifications, variation or replacement, do not make The essence of corresponding technical solution is detached from the spirit and scope of technical solution of the embodiment of the present invention, should all cover in protection of the invention Within the scope of.Therefore, the protection scope of the present invention shall be subject to the protection scope of the claims.

Claims (9)

1. a kind of PTC ceramics chip characterized by comprising electrode, the first table plane, the second table plane and described first The elongated surfaces of table plane and the second table plane;
The electrode is set in the first table plane and the second table plane;
The first table plane is arranged in parallel with the second table plane;
The elongated surfaces are set to the first table plane and the second table interplanar;
It is attached between the first table plane and the second table plane by the elongated surfaces;
The elongated surfaces, the first table plane and the second table plane are in Different Plane;
The first table plane and the second table plane pass through elongated surfaces control the first table plane and described second The safe distance of table interplanar electrode.
2. PTC ceramics chip according to claim 1, which is characterized in that the first table plane and second table are flat Ohm contact electrode is coated on face.
3. PTC ceramics chip according to claim 1, which is characterized in that the elongated surfaces are as follows: convex body or concaver.
4. PTC ceramics chip according to claim 3, which is characterized in that the convex body includes: curved body and/or more A plane body;
The concaver includes: curved body and/or multiple plane bodies.
5. PTC ceramics chip according to claim 1, which is characterized in that the cutting plane of the elongated surfaces are as follows: convex shape or Concave body;Wherein, the cutting plane is perpendicular to the first table plane and the second table plane.
6. PTC ceramics chip according to claim 5, which is characterized in that the convex shape is curl shape or polygon;
The concave body is curl shape or polygon.
7. PTC ceramics chip according to claim 6, which is characterized in that the number of edges of the polygon is at least four.
8. PTC ceramics chip according to claim 6, which is characterized in that when the number of edges of the polygon is four, institute Stating polygon and being formed by quadrangle is diamond shape or trapezoidal.
9. a kind of production method of PTC ceramics chip characterized by comprising
Raw material needed for configuring chip manufacturing;
The raw material are fired as ceramic matrix according to preset model, and the screen printing electrode on the ceramic matrix;
Production is ground by beveling and processes the ceramic matrix, so that the first table plane of ceramic matrix formation, the second table are flat The elongated surfaces of face and the first table plane and the second table plane;
The first table plane is arranged in parallel with the second table plane;
The elongated surfaces are set to the first table plane and the second table interplanar;
It is attached between the first table plane and the second table plane by the elongated surfaces;
The elongated surfaces, the first table plane and the second table plane are in Different Plane;
The first table plane and the second table plane pass through elongated surfaces control the first table plane and described second The interelectrode safe distance of table interplanar.
CN201811129259.0A 2018-09-26 2018-09-26 PTC ceramics chip and preparation method thereof Pending CN109243737A (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003203822A (en) * 2002-01-07 2003-07-18 Murata Mfg Co Ltd Method of manufacturing laminated ceramic electronic component
CN203134491U (en) * 2012-12-11 2013-08-14 厦门莱纳电子有限公司 High-dielectric-strength macromolecule PTC (positive temperature coefficient) thermistor
CN105047338A (en) * 2015-08-20 2015-11-11 国家电网公司 Zinc oxide resistor disc with high side flashover voltage
CN106205911A (en) * 2016-08-30 2016-12-07 广东爱晟电子科技有限公司 A kind of heat sensitive chip of anti-short circuit and preparation method thereof
CN106782953A (en) * 2017-02-09 2017-05-31 昆山万丰电子有限公司 A kind of piezoresistor and manufacturing process
CN206497793U (en) * 2017-02-17 2017-09-15 广东汇万电子科技有限公司 A kind of concave surface piezoresistor

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003203822A (en) * 2002-01-07 2003-07-18 Murata Mfg Co Ltd Method of manufacturing laminated ceramic electronic component
CN203134491U (en) * 2012-12-11 2013-08-14 厦门莱纳电子有限公司 High-dielectric-strength macromolecule PTC (positive temperature coefficient) thermistor
CN105047338A (en) * 2015-08-20 2015-11-11 国家电网公司 Zinc oxide resistor disc with high side flashover voltage
CN106205911A (en) * 2016-08-30 2016-12-07 广东爱晟电子科技有限公司 A kind of heat sensitive chip of anti-short circuit and preparation method thereof
CN106782953A (en) * 2017-02-09 2017-05-31 昆山万丰电子有限公司 A kind of piezoresistor and manufacturing process
CN206497793U (en) * 2017-02-17 2017-09-15 广东汇万电子科技有限公司 A kind of concave surface piezoresistor

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Application publication date: 20190118