CN109234066A - A kind of biological antibiotic detergent and preparation method thereof - Google Patents
A kind of biological antibiotic detergent and preparation method thereof Download PDFInfo
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- CN109234066A CN109234066A CN201811277503.8A CN201811277503A CN109234066A CN 109234066 A CN109234066 A CN 109234066A CN 201811277503 A CN201811277503 A CN 201811277503A CN 109234066 A CN109234066 A CN 109234066A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Molecular Biology (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a kind of biological antibiotic detergent and preparation method thereof, belong to household daily use chemicals detergent technical field.The biological antibiotic detergent includes following raw material by weight: 15~18.5 parts of APG, 8~15 parts of Cocoamidopropyl betaine, 5~10 parts of marine biological sterilization agent, 3.5~5 parts of cysteine, 4~5.5 parts of chitin, 1~10 part of sodium carbonate, 0.5~1 part of citric acid, 0.02~0.1 part of ginger juice, 0.02~0.1 part of lemon juice, 55~68 parts of deionized water.Biological antibiotic detergent of the invention has degradation, the good advantage of non-environmental-pollution and decontamination, bacteria-eliminating efficacy.
Description
Technical field
The present invention relates to a kind of detergent and preparation method thereof more particularly to a kind of biological antibiotic detergent and its preparation sides
Method belongs to household daily use chemicals detergent technical field.
Background technique
Detergent is mainly used for washing tableware, tea set and kitchen tools etc.;It can be used for washing water fruits and vegetables and greasy dirt weight
Clothing, be the indispensable washing product of the catering trade and family.
Dish washing detergent belongs to allotment type product, develops at home in recent years very rapidly.Tableware on the market is washed at present
It washs that agent is dazzling, has detergency superpower, having concentrated type and strong sterilizing power etc..Gradually with people's environmental consciousness
Enhancing, the developing direction in dish washing detergent future will be using environment-friendly and green type as mainstream.In addition to have strong detergency, to human body without
Evil, sterilizing, mild high bubble function outside, should also be easy degradation, free from environmental pollution.The effective component of dish washing detergent is main
It is surfactant, conventional cutlery detergent is mainly with synthetic surfactant (such as LAS, AS, AES, SAS)
For raw material, the detergent of synthesis although washing effect and in terms of, have a very big advantage, but safety and
There is very big risk on environment friendly, the abuse of synthetic detergent can teratogenesis or even carcinogenic, caused to user and environment
The damage of unrepairable, it is mostly not degradable or can not degrade, it pollutes the environment.
Therefore, exploitation Environment-friendlytableware tableware detergent has complied with the trend in epoch, especially in Europe, the U.S. and Japan, ring
The use for protecting dish washing detergent is fairly common.But at home, the development of Environment-friendlytableware tableware detergent is slower, especially function
Energy property detergent is just fewer.
Summary of the invention
Present invention seek to address that detergent degradability is bad in the prior art, to the disagreeableness technical problem of environment, provide
A kind of biological antibiotic detergent.
For achieving the above object, technical scheme is as follows:
A kind of biological antibiotic detergent, it is characterised in that: including following raw material by weight: 15~18.5 parts of APG, coconut palm
8~15 parts of oleamide propyl betaine, 5~10 parts of marine biological sterilization agent, 3.5~5 parts of cysteine, chitin 4~5.5
Part, 1~10 part of sodium carbonate, 0.5~1 part of citric acid, 0.02~0.1 part of ginger juice, 0.02~0.1 part of lemon juice, deionized water
55~68 parts.
In order to which the present invention is better achieved, further, the APG is C8-16 alkyl glycosides.
Further, the marine biological sterilization agent is by marine organisms complex enzyme, the poly- multi-ligation of alginic acid and ocean chitosan
Cerebroysin composition.
Further, the ginger juice the preparation method comprises the following steps: crusher is added in blocky ginger and deionized water, be crushed 5
After~7min, filtering, the filtrate of collection is the ginger juice;It is described bulk ginger and deionized water mass ratio be 1:(3~
5).
Further, the lemon juice the preparation method comprises the following steps: crusher is added in the lemon to cut in half and deionized water,
After broken 5~7min, filtering, the filtrate of collection is the lemon juice;The mass ratio of the lemon and deionized water is 1:(2
~3.5).
It is a further object to provide the preparation methods of the biological antibiotic detergent, it is characterised in that: including
Following steps:
A. deionized water is added in stirred tank, is warming up to 70~90 DEG C, in proportion by Cocoamidopropyl betaine and APG
It is added, stirs 5~7min;
B. after the temperature in reaction kettle being dropped to 45 DEG C or less, marine biological sterilization agent, cysteine, chitin are proportionally added into
Matter, ginger juice and lemon juice stir 15~18min, finally stand 20~40min;
C. sodium carbonate, citric acid are proportionally added into reaction kettle, after being again stirring for uniformly, after temperature is down to 20~30 DEG C,
It is again stirring for uniformly, packing up to the biological antibiotic detergent.
Beneficial effects of the present invention:
(1) present invention is by using degradable surfactant A PG and natural antibacterial, degerming component: marine organisms remove
Microbial inoculum, lemon juice, chitin and cysteine, and by specific Proportionality design, form biological antibiotic detergent of the invention
Composition, can and while degreasing, do not cause environmental pollution, and antibacterial bacteriostatic effect is good, form a benign cycle,
Meanwhile ginger juice plays the role of raw meat of dispelling, when can reduce tableware after peculiar smell, further promote the user experience of product
By.
(2) preferably, the APG in the present invention is C8-16 alkyl glycosides, first APG and traditional surfactant phase
Than, have the advantage that a to human body, skin is nontoxic has no stimulation;B. there is good emulsifiability;C. it will not change skin
The pH value of skin;D. with other surfaces activating agent: anion, nonionic and benign ion have good compatibility;E. have
Good moisturizing and wetability.And C atomicity thickens in the alkyl glycosides of 8-16 and foaming dirt-removing power is stronger.
Specific embodiment
The present invention is described in further detail below with reference to embodiment, embodiments of the present invention are not limited thereto.
Embodiment 1
A kind of biological antibiotic detergent, including following raw material by weight: 15 parts of APG, Cocoamidopropyl betaine 8
Part, 5 parts of marine biological sterilization agent, 5 parts of cysteine, 5.5 parts of chitin, 10 parts of sodium carbonate, 1 part of citric acid, ginger juice 0.1
Part, 0.1 part of lemon juice, 68 parts of deionized water.
APG in the present embodiment is C8-16 alkyl glycosides.
Marine biological sterilization agent in the present embodiment is living by marine organisms complex enzyme, the poly- multi-ligation of alginic acid and ocean chitosan
Element composition, its ratio be 1:1:1.
Ginger juice in the present embodiment the preparation method comprises the following steps: crusher is added in blocky ginger and deionized water, be crushed
After 5min, filtering, the filtrate of collection is the ginger juice;The bulk ginger and the mass ratio of deionized water are 1:3.
Lemon juice in the present embodiment the preparation method comprises the following steps: crusher is added in the lemon to cut in half and deionized water,
After broken 7min, filtering, the filtrate of collection is the lemon juice;The mass ratio of the lemon and deionized water is 1:2.
The preparation method of the biological antibiotic detergent of the present embodiment, comprising the following steps:
A. deionized water is added in stirred tank, is warming up to 70 DEG C, Cocoamidopropyl betaine and APG is proportionally added into,
Stir 5min;
B. after the temperature in reaction kettle being dropped to 35 DEG C, marine biological sterilization agent, cysteine, chitin, life are proportionally added into
Ginger juice and lemon juice stir 15min, finally stand 20min;
C. sodium carbonate, citric acid are proportionally added into reaction kettle, after being again stirring for uniformly, after temperature is down to 20 DEG C, again
It stirs evenly, packs up to the biological antibiotic detergent.
Embodiment 2
A kind of biological antibiotic detergent, including following raw material by weight: 18.5 parts of APG, Cocoamidopropyl betaine
15 parts, 10 parts of marine biological sterilization agent, 3.5 parts of cysteine, 4 parts of chitin, 1 part of sodium carbonate, 0.5 part of citric acid, ginger juice
0.02 part, 0.02 part of lemon juice, 55 parts of deionized water.
In the present embodiment, APG is C8-16 alkyl glycosides.
In the present embodiment, marine biological sterilization agent is living by marine organisms complex enzyme, the poly- multi-ligation of alginic acid and ocean chitosan
Element composition.
In the present embodiment, ginger juice the preparation method comprises the following steps: crusher is added in blocky ginger and deionized water, be crushed 7min
Afterwards, it filters, the filtrate of collection is the ginger juice;The bulk ginger and the mass ratio of deionized water are 1:5.
In the present embodiment, lemon juice the preparation method comprises the following steps: crusher is added in the lemon to cut in half and deionized water, break
After broken 5min, filtering, the filtrate of collection is the lemon juice;The mass ratio of the lemon and deionized water is 1:3.5.
The preparation method of biological antibiotic detergent in the present embodiment, comprising the following steps:
A. deionized water is added in stirred tank, is warming up to 90 DEG C, Cocoamidopropyl betaine and APG is proportionally added into,
Stir 7min;
B. after the temperature in reaction kettle being dropped to 25 DEG C, marine biological sterilization agent, cysteine, chitin, life are proportionally added into
Ginger juice and lemon juice stir 18min, finally stand 40min;
C. sodium carbonate, citric acid are proportionally added into reaction kettle, after being again stirring for uniformly, after temperature is down to 30 DEG C, again
It stirs evenly, packs up to the biological antibiotic detergent.
Embodiment 3
A kind of biological antibiotic detergent, including following raw material by weight: 16 parts of APG, Cocoamidopropyl betaine 10
Part, 6 parts of marine biological sterilization agent, 4 parts of cysteine, 4.5 parts of chitin, 2 parts of sodium carbonate, 1 part of citric acid, ginger juice 0.06
Part, 0.05 part of lemon juice, 60 parts of deionized water.
In the present embodiment, APG is C8-16 alkyl glycosides.
In the present embodiment, marine biological sterilization agent is living by marine organisms complex enzyme, the poly- multi-ligation of alginic acid and ocean chitosan
Element composition, ratio can be arbitrary proportion, and the ratio of three kinds of ingredients is 2:1:1 in the present embodiment.
In the present embodiment, ginger juice the preparation method comprises the following steps: crusher is added in blocky ginger and deionized water, be crushed
After 5.5min, filtering, the filtrate of collection is the ginger juice;The bulk ginger and the mass ratio of deionized water are 1:4.
In the present embodiment, lemon juice the preparation method comprises the following steps: crusher is added in the lemon to cut in half and deionized water, break
After broken 6min, filtering, the filtrate of collection is the lemon juice;The mass ratio of the lemon and deionized water is 1:3.5.
The preparation method of biological antibiotic detergent in the present embodiment, comprising the following steps:
A. deionized water is added in stirred tank, is warming up to 85 DEG C, Cocoamidopropyl betaine and APG is proportionally added into,
Stir 5.5min;
B. after the temperature in reaction kettle being dropped to 45 DEG C, marine biological sterilization agent, cysteine, chitin, life are proportionally added into
Ginger juice and lemon juice stir 16min, finally stand 30min;
C. sodium carbonate, citric acid are proportionally added into reaction kettle, after being again stirring for uniformly, after temperature is down to 22 DEG C, again
It stirs evenly, packs up to the biological antibiotic detergent.
Embodiment 4
A kind of biological antibiotic detergent, including following raw material by weight: 17 parts of APG, Cocoamidopropyl betaine 10
Part, 8 parts of marine biological sterilization agent, 4 parts of cysteine, 4 parts of chitin, 1 part of sodium carbonate, 0.5 part of citric acid, ginger juice 0.02
Part, 0.02 part of lemon juice, 55 parts of deionized water.
In the present embodiment, APG is C8-16 alkyl glycosides.
In the present embodiment, marine biological sterilization agent is living by marine organisms complex enzyme, the poly- multi-ligation of alginic acid and ocean chitosan
Element composition, ratio can be arbitrary proportion, and the ratio of three kinds of ingredients is 2:2:1 in the present embodiment.
In the present embodiment, ginger juice the preparation method comprises the following steps: crusher is added in blocky ginger and deionized water, be crushed 5min
Afterwards, it filters, the filtrate of collection is the ginger juice;The bulk ginger and the mass ratio of deionized water are 1:5.
In the present embodiment, lemon juice the preparation method comprises the following steps: crusher is added in the lemon to cut in half and deionized water, break
After broken 6min, filtering, the filtrate of collection is the lemon juice;The mass ratio of the lemon and deionized water is 1:3.
The preparation method of biological antibiotic detergent in the present embodiment, comprising the following steps:
A. deionized water is added in stirred tank, is warming up to 85 DEG C, Cocoamidopropyl betaine and APG is proportionally added into,
Stir 6min;
B. after the temperature in reaction kettle being dropped to 40 DEG C, marine biological sterilization agent, cysteine, chitin, life are proportionally added into
Ginger juice and lemon juice stir 15min, finally stand 25min;
C. sodium carbonate, citric acid are proportionally added into reaction kettle, after being again stirring for uniformly, after temperature is down to 25 DEG C, again
It stirs evenly, packs up to the biological antibiotic detergent.
Embodiment 5
A kind of biological antibiotic detergent, including following raw material by weight: 17 parts of APG, Cocoamidopropyl betaine 10
Part, 5 parts of marine biological sterilization agent, 5 parts of cysteine, 5.5 parts of chitin, 10 parts of sodium carbonate, 1 part of citric acid, ginger juice 0.1
Part, 0.1 part of lemon juice, 68 parts of deionized water.
In the present embodiment, APG is C8-16 alkyl glycosides.
In the present embodiment, marine biological sterilization agent is living by marine organisms complex enzyme, the poly- multi-ligation of alginic acid and ocean chitosan
Element composition, ratio can be arbitrary proportion, and the ratio of three kinds of ingredients is 2:1:2 in the present embodiment.
In the present embodiment, ginger juice the preparation method comprises the following steps: crusher is added in blocky ginger and deionized water, be crushed
After 5.5min, filtering, the filtrate of collection is the ginger juice;The bulk ginger and the mass ratio of deionized water are 1:5.
In the present embodiment, lemon juice the preparation method comprises the following steps: crusher is added in the lemon to cut in half and deionized water, break
After broken 6min, filtering, the filtrate of collection is the lemon juice;The mass ratio of the lemon and deionized water is 1:3.5.
The preparation method of biological antibiotic detergent in the present embodiment, comprising the following steps:
A. deionized water is added in stirred tank, is warming up to 80 DEG C, Cocoamidopropyl betaine and APG is proportionally added into,
Stir 5.5min;
B. after the temperature in reaction kettle being dropped to 45 DEG C, marine biological sterilization agent, cysteine, chitin, life are proportionally added into
Ginger juice and lemon juice stir 16min, finally stand 35min;
C. sodium carbonate, citric acid are proportionally added into reaction kettle, after being again stirring for uniformly, after temperature is down to 25 DEG C, again
It stirs evenly, packs up to the biological antibiotic detergent.
The above is only presently preferred embodiments of the present invention, not does limitation in any form to the present invention, it is all according to
According to technical spirit any simple modification to the above embodiments of the invention, equivalent variations, protection of the invention is each fallen within
Within the scope of.
Claims (6)
1. a kind of biological antibiotic detergent, it is characterised in that: including following raw material by weight: 15~18.5 parts of APG,
8~15 parts of Cocoamidopropyl betaine, 5~10 parts of marine biological sterilization agent, 3.5~5 parts of cysteine, chitin 4~5.5
Part, 1~10 part of sodium carbonate, 0.5~1 part of citric acid, 0.02~0.1 part of ginger juice, 0.02~0.1 part of lemon juice, deionized water
55~68 parts.
2. biological antibiotic detergent as described in claim 1, it is characterised in that: the APG is C8-16 alkyl glycosides.
3. biological antibiotic detergent as described in claim 1, it is characterised in that: the marine biological sterilization agent is by marine organisms
The poly- multi-ligation of complex enzyme, alginic acid and ocean chitosan activin composition.
4. biological antibiotic detergent as described in claim 1, it is characterised in that: the ginger juice the preparation method comprises the following steps: by block
Crusher is added in shape ginger and deionized water, and after being crushed 5~7min, filtering, the filtrate of collection is the ginger juice;Described piece
Shape ginger and the mass ratio of deionized water are 1:(3~5).
5. biological antibiotic detergent as described in claim 1, it is characterised in that: the lemon juice the preparation method comprises the following steps: will cut
Crusher is added in lemon and deionized water into two, and after being crushed 5~7min, filtering, the filtrate of collection is the lemon juice;
The mass ratio of the lemon and deionized water is 1:(2~3.5).
6. the preparation method of biological antibiotic detergent as described in claim 1, it is characterised in that: the following steps are included:
A. deionized water is added in stirred tank, is warming up to 70~90 DEG C, in proportion by Cocoamidopropyl betaine and APG
It is added, stirs 5~7min;
B. after the temperature in reaction kettle being dropped to 45 DEG C or less, marine biological sterilization agent, cysteine, chitin are proportionally added into
Matter, ginger juice and lemon juice stir 15~18min, finally stand 20~40min;
C. sodium carbonate, citric acid are proportionally added into reaction kettle, after being again stirring for uniformly, after temperature is down to 20~30 DEG C,
It is again stirring for uniformly, packing up to the biological antibiotic detergent.
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Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN106137813A (en) * | 2015-04-03 | 2016-11-23 | 苏州聚和堂生物科技有限公司 | A kind of marine bioactivity detergent and preparation method thereof |
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2018
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Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN106137813A (en) * | 2015-04-03 | 2016-11-23 | 苏州聚和堂生物科技有限公司 | A kind of marine bioactivity detergent and preparation method thereof |
Non-Patent Citations (2)
Title |
---|
徐宝财等: "《洗涤剂配方设计6步》", 30 April 2010, 化学工业出版社 * |
李希新: "《蔬菜的营养与保健》", 30 August 2009, 北京:中国物资出版社 * |
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Application publication date: 20190118 |