CN109233691A - A kind of TPR material sole glue and preparation method thereof - Google Patents
A kind of TPR material sole glue and preparation method thereof Download PDFInfo
- Publication number
- CN109233691A CN109233691A CN201810948494.4A CN201810948494A CN109233691A CN 109233691 A CN109233691 A CN 109233691A CN 201810948494 A CN201810948494 A CN 201810948494A CN 109233691 A CN109233691 A CN 109233691A
- Authority
- CN
- China
- Prior art keywords
- parts
- raw material
- glue
- vinyl acetate
- tpr
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
- C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J123/04—Homopolymers or copolymers of ethene
- C09J123/08—Copolymers of ethene
- C09J123/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C09J123/0853—Vinylacetate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of TPR material sole glue, it is made of raw material from the following weight: 90-110 parts of ethylene-vinyl acetate copolymer, 25-35 parts of butyl rubber, 20-30 parts of coumarone-indene resin, paraffin resin 5-8 parts, 15-25 parts of talcum powder, 4-6 parts of calcium carbonate of synthesis, 0.5-1.5 parts of 2,6-di-tert-butyl p-cresol.Glue product softening temperature provided by the invention is high, and brittle temperature is low, can adapt to most of temperature uses without losing viscous stickiness, and to a variety of materials by preferable bonding property, nitrile rubber, which is added, improves the flexibility and elasticity of glue, improves glue-joint strength, shortens curing time.
Description
Technical field
The present invention relates to glue more particularly to a kind of TPR material sole glue and preparation method thereof.
Background technique
Glue be connect two kinds of materials intermediate, mostly occur with aqua, belong to fine chemistry industry class, it is many kinds of, mainly with
Sizing, physical aspect, method for curing and adherend material are classified.It common are instant glue, epoxy adhesive, detest
Oxygen glue, UV glue (ultraviolet photo-curing class), hot melt adhesive, pressure sensitive adhesive, latex class etc..
When being bonded to TRP material sole, traditional glue bonding is insecure, is easy to come unglued, and heat-resisting water resistance
Difference, curing time is long when bonding, and considerably increasing bonding institute, time-consuming, reduces efficiency, is unable to satisfy use demand, thus I
Design a kind of TPR material sole glue and preparation method thereof, to solve the above problems.
Summary of the invention
The purpose of the present invention is to solve disadvantages existing in the prior art, and a kind of TPR material sole proposed is used
Glue and preparation method thereof.
To achieve the goals above, present invention employs following technical solutions:
A kind of TPR material sole glue, is made of raw material from the following weight: ethylene-vinyl acetate copolymer 90-
110 parts, 25-35 parts of butyl rubber, 20-30 parts of coumarone-indene resin, paraffin resin 5-8 parts of synthesis, 15-25 parts of talcum powder, carbon
Sour calcium 4-6 parts, 0.5-1.5 parts of 2,6-di-tert-butyl p-cresol.
Preferably, it is made of raw material from the following weight: 100 parts of ethylene-vinyl acetate copolymer, 30 parts of butyl rubber,
25 parts of coumarone-indene resin, synthesize 7 parts of paraffin resin, 20 parts of talcum powder, 5 parts of calcium carbonate, 1 part of 2,6-di-tert-butyl p-cresol.
Preferably, low-molecular-weight ethylenic-vinyl acetate copolymer that the ethylene-vinyl acetate copolymer is 28%.
A kind of preparation method of TPR material sole glue, comprising the following steps:
S1, raw material preparation: choosing each component raw material, and separate and carry out refinement screening by the device with mesh structure,
The agglomeration in each raw material is screened out, raw material degree of refinement is improved；
S2, weighing are spare: carrying out weighing according to the above ratio to each component raw material after refinement spare；
S3, addition substrate raw material: ethylene-vinyl acetate copolymer being added into reaction kettle, and carries out heating and be heated to 90
DEG C, it is constantly slowly stirred in heating process；
S4, addO-on therapy raw material；Butyl rubber is sequentially added into solution described in S3, coumarone-indene resin synthesizes paraffin
Resin, talcum powder, calcium carbonate and 2,6-di-tert-butyl p-cresol are added during raw material, and stirring is uninterrupted, persistently stir 2-
3h；
S5, cooling discharging: being cooled to room temperature the glue obtained after being stirred, and tinning saves.
Preferably, the reaction kettle is three mouthfuls of reaction kettles equipped with electric mixer, condenser pipe and thermometer.
Preferably, the mixing speed in the S3 and S4 is 30-60 rev/min.
Compared with prior art, the beneficial effects of the present invention are:
A kind of TPR material sole glue provided by the invention and preparation method thereof, glue product softening temperature is high, embrittlement
Temperature is low, can adapt to most of temperature uses and is added without losing viscous stickiness, and to a variety of materials by preferable bonding property
Entering nitrile rubber improves the flexibility and elasticity of glue, improves glue-joint strength, shortens curing time.
Specific embodiment
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation
Example is only a part of the embodiment of the present invention, instead of all the embodiments.
Embodiment one
A kind of TPR material sole glue, is made of raw material from the following weight: 90 parts of ethylene-vinyl acetate copolymer,
25 parts of butyl rubber, 20 parts of coumarone-indene resin, 5 parts of paraffin resin of synthesis, 15 parts of talcum powder, 4 parts of calcium carbonate, 2,6- bis- uncles
0.5 part of butyl paracresol.
Preferably, low-molecular-weight ethylenic-vinyl acetate copolymer that ethylene-vinyl acetate copolymer is 28%.
A kind of preparation method of TPR material sole glue, comprising the following steps:
S1, raw material preparation: choosing each component raw material, and separate and carry out refinement screening by the device with mesh structure,
The agglomeration in each raw material is screened out, raw material degree of refinement is improved；
S2, weighing are spare: carrying out weighing according to the above ratio to each component raw material after refinement spare；
S3, addition substrate raw material: ethylene-vinyl acetate copolymer being added into reaction kettle, and carries out heating and be heated to 90
DEG C, it is constantly slowly stirred in heating process；
S4, addO-on therapy raw material；Butyl rubber, coumarone-indene resin, compound stone wax tree are sequentially added into S3 solution
Rouge, talcum powder, calcium carbonate and 2,6-di-tert-butyl p-cresol are added during raw material, and stirring is uninterrupted, persistently stir 2-3h；
S5, cooling discharging: being cooled to room temperature the glue obtained after being stirred, and tinning saves.
Preferably, reaction kettle is three mouthfuls of reaction kettles equipped with electric mixer, condenser pipe and thermometer.
Preferably, the mixing speed in S3 and S4 is 30-60 rev/min.
Embodiment two
A kind of TPR material sole glue, is made of raw material from the following weight: ethylene-vinyl acetate copolymer 100
Part, 30 parts of butyl rubber, 25 parts of coumarone-indene resin, 7 parts of paraffin resin of synthesis, 20 parts of talcum powder, 5 parts of calcium carbonate, 2,6- bis-
1 part of Butylated Hydroxytoluene
Preferably, low-molecular-weight ethylenic-vinyl acetate copolymer that ethylene-vinyl acetate copolymer is 28%.
A kind of preparation method of TPR material sole glue, comprising the following steps:
S1, raw material preparation: choosing each component raw material, and separate and carry out refinement screening by the device with mesh structure,
The agglomeration in each raw material is screened out, raw material degree of refinement is improved；
S2, weighing are spare: carrying out weighing according to the above ratio to each component raw material after refinement spare；
S3, addition substrate raw material: ethylene-vinyl acetate copolymer being added into reaction kettle, and carries out heating and be heated to 90
DEG C, it is constantly slowly stirred in heating process；
S4, addO-on therapy raw material；Butyl rubber, coumarone-indene resin, compound stone wax tree are sequentially added into S3 solution
Rouge, talcum powder, calcium carbonate and 2,6-di-tert-butyl p-cresol are added during raw material, and stirring is uninterrupted, persistently stir 2-3h；
S5, cooling discharging: being cooled to room temperature the glue obtained after being stirred, and tinning saves.
Preferably, reaction kettle is three mouthfuls of reaction kettles equipped with electric mixer, condenser pipe and thermometer.
Preferably, the mixing speed in S3 and S4 is 30-60 rev/min.
Embodiment three
A kind of TPR material sole glue, is made of raw material from the following weight: ethylene-vinyl acetate copolymer 110
Part, 35 parts of butyl rubber, 30 parts of coumarone-indene resin, 8 parts of paraffin resin of synthesis, 25 parts of talcum powder, 6 parts of calcium carbonate, 2,6- bis-
1.5 parts of Butylated Hydroxytoluene.
Preferably, low-molecular-weight ethylenic-vinyl acetate copolymer that ethylene-vinyl acetate copolymer is 28%.
A kind of preparation method of TPR material sole glue, comprising the following steps:
S1, raw material preparation: choosing each component raw material, and separate and carry out refinement screening by the device with mesh structure,
The agglomeration in each raw material is screened out, raw material degree of refinement is improved；
S2, weighing are spare: carrying out weighing according to the above ratio to each component raw material after refinement spare；
S3, addition substrate raw material: ethylene-vinyl acetate copolymer being added into reaction kettle, and carries out heating and be heated to 90
DEG C, it is constantly slowly stirred in heating process；
S4, addO-on therapy raw material；Butyl rubber, coumarone-indene resin, compound stone wax tree are sequentially added into S3 solution
Rouge, talcum powder, calcium carbonate and 2,6-di-tert-butyl p-cresol are added during raw material, and stirring is uninterrupted, persistently stir 2-3h；
S5, cooling discharging: being cooled to room temperature the glue obtained after being stirred, and tinning saves.
Preferably, reaction kettle is three mouthfuls of reaction kettles equipped with electric mixer, condenser pipe and thermometer.
Preferably, the mixing speed in S3 and S4 is 30-60 rev/min.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (6)
1. a kind of TPR material sole glue, which is characterized in that be made of raw material from the following weight: ethene-vinyl acetate is total
90-110 parts of aggressiveness, 25-35 parts of butyl rubber, 20-30 parts of coumarone-indene resin, paraffin resin 5-8 parts is synthesized, talcum powder 15-
25 parts, 4-6 parts of calcium carbonate, 0.5-1.5 parts of 2,6-di-tert-butyl p-cresol.
2. a kind of TPR material sole glue according to claim 1, which is characterized in that by the raw material of following parts by weight
It is made: 100 parts of ethylene-vinyl acetate copolymer, 30 parts of butyl rubber, 25 parts of coumarone-indene resin, synthesizing 7 parts of paraffin resin,
20 parts of talcum powder, 5 parts of calcium carbonate, 1 part of 2,6-di-tert-butyl p-cresol.
3. a kind of TPR material sole glue according to claim 1, which is characterized in that the ethene-vinyl acetate is total
Low-molecular-weight ethylenic-vinyl acetate copolymer that aggressiveness is 28%.
4. a kind of preparation method of TPR material sole glue, which comprises the following steps:
S1, raw material preparation: each component raw material is chosen, and separates and refinement screening is carried out by the device with mesh structure, is screened out
Agglomeration in each raw material improves raw material degree of refinement；
S2, weighing are spare: in ratio described in claim 1 weigh to each component raw material after refinement spare；
S3, addition substrate raw material: ethylene-vinyl acetate copolymer being added into reaction kettle, and carries out heating and be heated to 90 DEG C, adds
It is constantly slowly stirred in thermal process；
S4, addO-on therapy raw material；Butyl rubber, coumarone-indene resin, compound stone wax tree are sequentially added into solution described in S3
Rouge, talcum powder, calcium carbonate and 2,6-di-tert-butyl p-cresol are added during raw material, and stirring is uninterrupted, persistently stir 2-3h；
S5, cooling discharging: being cooled to room temperature the glue obtained after being stirred, and tinning saves.
5. according to right want 4 described in a kind of preparation method of TPR material sole glue, which is characterized in that the reaction kettle
For three mouthfuls of reaction kettles equipped with electric mixer, condenser pipe and thermometer.
6. according to right want 4 described in a kind of preparation method of TPR material sole glue, which is characterized in that the S3 and S4
In mixing speed be 30-60 rev/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810948494.4A CN109233691A (en) | 2018-08-20 | 2018-08-20 | A kind of TPR material sole glue and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810948494.4A CN109233691A (en) | 2018-08-20 | 2018-08-20 | A kind of TPR material sole glue and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109233691A true CN109233691A (en) | 2019-01-18 |
Family
ID=65071786
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810948494.4A Pending CN109233691A (en) | 2018-08-20 | 2018-08-20 | A kind of TPR material sole glue and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109233691A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113881352A (en) * | 2021-11-05 | 2022-01-04 | 徐州元丰新材料科技有限公司 | Industrial environment-friendly glue and production process thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4127545A (en) * | 1976-05-24 | 1978-11-28 | Cities Service Company | Hot melt crosslinked butyl sealant |
| CN101210082A (en) * | 2006-12-31 | 2008-07-02 | 比亚迪股份有限公司 | Composition for forming hot-melt adhesive, hot-melt adhesive, and preparing method thereof |
| CN107556944A (en) * | 2017-09-01 | 2018-01-09 | 成绵广 | A kind of compound jelly of high glue-joint strength |
-
2018
- 2018-08-20 CN CN201810948494.4A patent/CN109233691A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4127545A (en) * | 1976-05-24 | 1978-11-28 | Cities Service Company | Hot melt crosslinked butyl sealant |
| CN101210082A (en) * | 2006-12-31 | 2008-07-02 | 比亚迪股份有限公司 | Composition for forming hot-melt adhesive, hot-melt adhesive, and preparing method thereof |
| CN107556944A (en) * | 2017-09-01 | 2018-01-09 | 成绵广 | A kind of compound jelly of high glue-joint strength |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113881352A (en) * | 2021-11-05 | 2022-01-04 | 徐州元丰新材料科技有限公司 | Industrial environment-friendly glue and production process thereof |
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190118 |
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| RJ01 | Rejection of invention patent application after publication |