CN109233420A - A kind of UV is with removing aldehyde additive - Google Patents

A kind of UV is with removing aldehyde additive Download PDF

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Publication number
CN109233420A
CN109233420A CN201811367478.2A CN201811367478A CN109233420A CN 109233420 A CN109233420 A CN 109233420A CN 201811367478 A CN201811367478 A CN 201811367478A CN 109233420 A CN109233420 A CN 109233420A
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CN
China
Prior art keywords
parts
removing aldehyde
additive
aldehyde additive
nano
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811367478.2A
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Chinese (zh)
Inventor
崔华
荣夕龙
朱建
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nantong Wan Tuo New Mstar Technology Ltd
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Nantong Wan Tuo New Mstar Technology Ltd
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Publication date
Application filed by Nantong Wan Tuo New Mstar Technology Ltd filed Critical Nantong Wan Tuo New Mstar Technology Ltd
Priority to CN201811367478.2A priority Critical patent/CN109233420A/en
Publication of CN109233420A publication Critical patent/CN109233420A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/66Additives characterised by particle size
    • C09D7/67Particle size smaller than 100 nm

Abstract

The invention discloses a kind of UV with removing aldehyde additive, each component including following parts by weight: 30-35 parts of ethylene urea, 20-30 parts of nano-titanium dioxide, 20-36 parts of phosphoric acid diamines, 20-30 parts of carbohydrazide, 20-40 parts of Chitosan (1-4) -2- amino-B-D glucose, 10-20 parts of diatom ooze, 30-40 parts of glycerine, 4-12 parts of kaolin, 8-15 parts of nano montmorillonite, 1-5 parts of fish glue from skin, 4-8 parts of negative ion powder and 3-8 parts of bagasse.UV of the invention removes aldehyde raw material with removing aldehyde additive and combine anion, biomass material, traditional chemical, high molecular nanometer filler, various active group formaldehyde are counter to give birth to irreversible chemical reaction, thoroughly eliminate formaldehyde, except aldehyde rate is up to 96%, and not will cause environmental pollution, air can be purified, the anion concentration in air is increased.

Description

A kind of UV is with removing aldehyde additive
Technical field
The present invention relates to a kind of UV with removing aldehyde additive.
Background technique
As the improvement of people's living standards, requirement of the people to environment is also higher and higher, especially to habitual residence The environmental requirement in living space is even more stringent.It is well known that the house just fitted up always gives out a kind of pungent smell, if Residence time is a little longer, and people will feel there are the adverse reactions such as dizzy, dazzling, laryngalgia, uncomfortable in chest, this is formaldehyde danger mostly Harmful intuitive performance.It is analyzed according to room air detection data in all parts of the country, the room air after finishing all exists in various degree Air pollution, wherein the most serious with formaldehyde pollution.The main source of indoor formaldehyde is indoor hardware fitting and furniture, especially with Wood-based plate used is very.
If the effective auxiliary agent having except formaldehyde is added in finishing coat in the production of UV woodwork coating, it will have very Huge market value.But the current aldehyde additive that removes haves the defects that not cleaning up or be easy to produce secondary pollution.
Summary of the invention
The technical problem to be solved by the present invention is to overcome aldehyde removers in the prior art to remove the undesirable defect of effect of formaldehyde, One kind is provided.
In order to solve the above-mentioned technical problems, the present invention provides the following technical solutions:
A kind of UV is with removing aldehyde additive, each component including following parts by weight: 30-35 parts of ethylene urea, nanometer titanium dioxide 20-30 parts of titanium, 20-36 parts of phosphoric acid diamines, 20-30 parts of carbohydrazide, Chitosan (1-4) -2- amino-B-D glucose 20-40 Part, 10-20 parts of diatom ooze, 30-40 parts of glycerine, 4-12 parts of kaolin, 8-15 parts of nano montmorillonite, 1-5 parts of fish glue from skin, bear from Sub- powder 4-8 parts and bagasse 3-8 parts.
Further, each component including following parts by weight: 32 parts of ethylene urea, 24 parts of nano-titanium dioxide, di(2-ethylhexyl)phosphate 28 parts of amine, 26 parts of carbohydrazide, 32 parts of Chitosan (1-4) -2- amino-B-D glucose, 16 parts of diatom ooze, 36 parts of glycerine, 8 parts of kaolin, 10 parts of nano montmorillonite, 3 parts of fish glue from skin, 6 parts of negative ion powder and 6 parts of bagasse.
Preferably, the fish glue from skin middle-molecular-weihydroxyethyl is 800Da content of peptides > 90% below.
Further, the negative ion powder is made of following weight parts raw material: 60~80 parts of tourmaline, astroies 10~ 20 parts, 18 parts of neodymia, 14 parts and 50~80 parts of polyester resin of terbium peroxide.
Further, the partial size < 100nm of the nano montmorillonite.
Further, the kaolinic partial size is 200-300 mesh.
The beneficial effects obtained by the present invention are as follows being: UV of the invention combines anion, biomass original with aldehyde additive is removed Material, traditional chemical remove aldehyde raw material, and high molecular nanometer filler, various active group formaldehyde are counter to give birth to irreversible chemical reaction, thoroughly Formaldehyde is eliminated, except aldehyde rate is up to 96%, and not will cause environmental pollution, air can be purified, increases the anion in air Content.
Specific embodiment
Hereinafter, preferred embodiments of the present invention will be described, it should be understood that preferred embodiment described herein is only used In the description and interpretation present invention, it is not intended to limit the present invention.
Embodiment 1
A kind of UV is with removing aldehyde additive, each component including following parts by weight: 30 parts of ethylene urea, nano-titanium dioxide 20 Part, 20 parts of phosphoric acid diamines, 20 parts of carbohydrazide, 20 parts of Chitosan (1-4) -2- amino-B-D glucose, 10 parts of diatom ooze, third 30 parts of triol, 4 parts of kaolin, 8 parts of nano montmorillonite, 1 part of fish glue from skin, 4 parts of negative ion powder and 3 parts of bagasse.Wherein, anion Powder is made of following weight parts raw material: 60 parts of tourmaline, 10 parts of astroies, 18 parts of neodymia, and 14 parts of terbium peroxide and poly- 50 parts of ester resin.
Embodiment 2
A kind of UV is with removing aldehyde additive, each component including following parts by weight: 35 parts of ethylene urea, nano-titanium dioxide 30 Part, 36 parts of phosphoric acid diamines, 30 parts of carbohydrazide, 40 parts of Chitosan (1-4) -2- amino-B-D glucose, 20 parts of diatom ooze, third 40 parts of triol, 12 parts of kaolin, 15 parts of nano montmorillonite, 5 parts of fish glue from skin, 8 parts of negative ion powder and 8 parts of bagasse.Wherein, bear from Sub- powder is made of following weight parts raw material: 80 parts of tourmaline, 20 parts of astroies, 18 parts of neodymia, 14 parts of terbium peroxide and 80 parts of polyester resin.
Embodiment 3
A kind of UV is with removing aldehyde additive, each component including following parts by weight: 32 parts of ethylene urea, nano-titanium dioxide 24 Part, 28 parts of phosphoric acid diamines, 26 parts of carbohydrazide, 32 parts of Chitosan (1-4) -2- amino-B-D glucose, 16 parts of diatom ooze, third 36 parts of triol, 8 parts of kaolin, 10 parts of nano montmorillonite, 3 parts of fish glue from skin, 6 parts of negative ion powder and 6 parts of bagasse.Wherein, bear from Sub- powder is made of following weight parts raw material: 70 parts of tourmaline, 15 parts of astroies, 18 parts of neodymia, 14 parts of terbium peroxide and 68 parts of polyester resin.
By the UV of the present embodiment with remove aldehyde additive and acrylic acid and UV finishing coat according to the ratio of 7:8:85 carry out mixing stir It can be used after mixing.
Oiliness PU is allowed to complete molten in use, slightly stirring after first mix 45% except aldehyde additive with 55% acrylic acid Xie Hou filters the solution (33%) spare, then above-mentioned preparation is completed, and is added after dilution (67%) is stirred and is mixed Diluent afterwards is spare;According to adding proportion (PU host agent): 1.2 (diluents after mixing): after 0.5 (curing agent) is stirred It uses.
According to 15 (removing aldehyde additive) when oiliness acryl resin uses: slightly being stirred after 85 (acryl resins) mixing It can be used.
After first 10% is mixed except aldehyde additive with 90% (melamine glue and curing agent) when melamine glue uses Stirring is to dissolution that is, paying attention to only making an addition to last (as second up and down fort) together.
7 parts remove slightly is stirred after aldehyde additive is mixed with 93 parts of water-base resin or ink to complete when being used in wallpaper It is spare after fully dissolved.
Using being by 2.5% except slightly being stirred after aldehyde additive and 97.5% water cement lacquer conjunction in water cement lacquer It can be used to after being completely dissolved.
Finally, it should be noted that the foregoing is only a preferred embodiment of the present invention, it is not intended to restrict the invention, Although the present invention is described in detail referring to the foregoing embodiments, for those skilled in the art, still may be used To modify the technical solutions described in the foregoing embodiments or equivalent replacement of some of the technical features. All within the spirits and principles of the present invention, any modification, equivalent replacement, improvement and so on should be included in of the invention Within protection scope.

Claims (6)

1. a kind of UV is with removing aldehyde additive, which is characterized in that each component including following parts by weight: 30-35 parts of ethylene urea is received Rice 20-30 parts of titanium dioxide, 20-36 parts of phosphoric acid diamines, 20-30 parts of carbohydrazide, the Portugal Chitosan (1-4) -2- amino-B-D 20-40 parts of grape sugar, 10-20 parts of diatom ooze, 30-40 parts of glycerine, 4-12 parts of kaolin, 8-15 parts of nano montmorillonite, fish glue from skin 1-5 parts, 4-8 parts of negative ion powder and 3-8 parts of bagasse.
2. UV as described in claim 1 is with removing aldehyde additive, which is characterized in that each component including following parts by weight: second 32 parts of alkene urea, 24 parts of nano-titanium dioxide, 28 parts of phosphoric acid diamines, 26 parts of carbohydrazide, Chitosan (1-4) -2- amino-B-D 32 parts of glucose, 16 parts of diatom ooze, 36 parts of glycerine, 8 parts of kaolin, 10 parts of nano montmorillonite, 3 parts of fish glue from skin, negative ion powder 6 Part and 6 parts of bagasse.
3. UV as described in claim 1 is with removing aldehyde additive, which is characterized in that the fish glue from skin middle-molecular-weihydroxyethyl be 800Da with Under content of peptides > 90%.
4. UV as described in claim 1 is with removing aldehyde additive, which is characterized in that the negative ion powder is by following weight parts raw material Composition: 60~80 parts of tourmaline, 10~20 parts of astroies, 18 parts of neodymia, 14 parts of terbium peroxide and polyester resin 50~ 80 parts.
5. UV as described in claim 1 is with removing aldehyde additive, which is characterized in that the partial size < 100nm of the nano montmorillonite.
6. UV as described in claim 1 is with removing aldehyde additive, which is characterized in that the kaolinic partial size is 200-300 mesh.
CN201811367478.2A 2018-11-16 2018-11-16 A kind of UV is with removing aldehyde additive Pending CN109233420A (en)

Priority Applications (1)

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CN201811367478.2A CN109233420A (en) 2018-11-16 2018-11-16 A kind of UV is with removing aldehyde additive

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811367478.2A CN109233420A (en) 2018-11-16 2018-11-16 A kind of UV is with removing aldehyde additive

Publications (1)

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Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102060557A (en) * 2010-11-02 2011-05-18 吉林省兰舍硅藻新材料有限公司 Nanocomposite diatom ooze material and construction method thereof
KR20130004777A (en) * 2011-07-04 2013-01-14 이상철 Environment-friendly multi-functional natural paint and the manufacturing method thereof
CN104689707A (en) * 2015-02-10 2015-06-10 宁波高新区巴艺新材料科技有限公司 Negative ion powder for building
CN104984741A (en) * 2015-06-24 2015-10-21 青岛恩高运动控制技术有限公司 Efficient formaldehyde adsorbing material
CN105001803A (en) * 2015-07-30 2015-10-28 四川珍福堂商贸有限公司 Formaldehyde removal agent
CN106345215A (en) * 2016-08-17 2017-01-25 保护伞环保科技成都有限公司 Formaldehyde removing agent
CN107201065A (en) * 2017-07-19 2017-09-26 合肥广民建材有限公司 A kind of diatom ooze ornament materials and preparation method thereof
CN107433124A (en) * 2017-09-22 2017-12-05 太仓弘杉环保科技有限公司 A kind of anion biomass aldehyde remover
CN108130355A (en) * 2018-02-11 2018-06-08 华南理工大学 A kind of collagen polypeptide rich in glycine and formaldehyde scavenger prepared therefrom
CN108187629A (en) * 2017-12-22 2018-06-22 苏州萨瑟斯兰环境科技有限公司 A kind of formaldehyde adsorbent and preparation method thereof

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102060557A (en) * 2010-11-02 2011-05-18 吉林省兰舍硅藻新材料有限公司 Nanocomposite diatom ooze material and construction method thereof
KR20130004777A (en) * 2011-07-04 2013-01-14 이상철 Environment-friendly multi-functional natural paint and the manufacturing method thereof
CN104689707A (en) * 2015-02-10 2015-06-10 宁波高新区巴艺新材料科技有限公司 Negative ion powder for building
CN104984741A (en) * 2015-06-24 2015-10-21 青岛恩高运动控制技术有限公司 Efficient formaldehyde adsorbing material
CN105001803A (en) * 2015-07-30 2015-10-28 四川珍福堂商贸有限公司 Formaldehyde removal agent
CN106345215A (en) * 2016-08-17 2017-01-25 保护伞环保科技成都有限公司 Formaldehyde removing agent
CN107201065A (en) * 2017-07-19 2017-09-26 合肥广民建材有限公司 A kind of diatom ooze ornament materials and preparation method thereof
CN107433124A (en) * 2017-09-22 2017-12-05 太仓弘杉环保科技有限公司 A kind of anion biomass aldehyde remover
CN108187629A (en) * 2017-12-22 2018-06-22 苏州萨瑟斯兰环境科技有限公司 A kind of formaldehyde adsorbent and preparation method thereof
CN108130355A (en) * 2018-02-11 2018-06-08 华南理工大学 A kind of collagen polypeptide rich in glycine and formaldehyde scavenger prepared therefrom

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