CN109233400A - A kind of preparation method of antibiotic antistatic coating - Google Patents
A kind of preparation method of antibiotic antistatic coating Download PDFInfo
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- CN109233400A CN109233400A CN201811097993.3A CN201811097993A CN109233400A CN 109233400 A CN109233400 A CN 109233400A CN 201811097993 A CN201811097993 A CN 201811097993A CN 109233400 A CN109233400 A CN 109233400A
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- copper
- carbon nanotube
- preparation
- antistatic coating
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/24—Electrically-conducting paints
Abstract
The invention discloses a kind of preparation methods of antibiotic antistatic coating, belong to technical field of paint preparation.Montmorillonite in the present invention, contain MgO in marble, CaO, a large amount of metal oxides such as ZnO, these metal oxides are inorganic antiseptics, it is also good conductive material, tea polyphenols, decanoy acetaldehyde all has the function of antibacterial sterilization, pass through fermentation, it can make both substances in conjunction with inorganic mineral, the polyaniline of nanofibrous structures is compared with the polyaniline of other structures, with higher conductivity, carbon nanotube has good mechanical property and electric property simultaneously, the carbon nanotube of the polyaniline nano fiber mating surface supported copper of area load copper, not only increase the electric conductivity of coating, make coating that there is good antibiotic property and rub resistance simultaneously, using special spray pattern supported copper, copper is set almost to be supported on the surface of polyaniline nano fiber and carbon nanotube, increase antibiotic property and electric conductivity, and And greatly reduce preparation cost.
Description
Technical field
The invention discloses a kind of preparation methods of antibiotic antistatic coating, belong to technical field of paint preparation.
Background technique
The title of static conductive coating, there is antistatic coating and anti-static coatings, with series of standards worked out by country, uses
Static conductive coating uses static conductive coating from industrial building and equipment design, is functionally analyzed from coatings, coating can be 10~20
It in the short time of second, leads and lets out electrostatic pressure savings, avoid generation electric discharge from causing fire alarm or destroy the accident of electronic component, and electrostatic
Production and savings be nature objective reality, the technical ability that do not resist, for fabric without measuring the theory led and let out
Antistatic agent products, the accumulation of clothes electrostatic in the process of wearing can be prevented.
Electrostatic is a kind of objective natural phenomena, can be generated by the various ways such as contact or rub.It is characterized in that electric
Pressure is high, electricity is low, electric current is small and action time is short.Electrostatic is a motionless charged particles, whether conductor or insulator,
It is all electrically charged under the action of electrostatic.Electrostatic is generally existing in our daily life, people pass by chemical fibre carpet electrostatic it is big
It is approximately 35000 volts, the electrostatic for browsing plastics specification is about 7000 volts.Although may usually know from experience less than these electrostatic,
For some sensitive instrumentations, these electrostatic potentials may cause larger harm.
Anti-static coatings are a kind of new coatings that last decade develops rapidly, and road sign, guideboard, billboard etc. are placed
Outdoors, surface in the past using spray painting coating and ordinary powder coating based on, thus spray after do not cross how long, one
As be some months, just will appear discoloration, dusting, burn into fall off, it is necessary to which often replacement wastes talent's material resources.It is existing, Hen Duokang
Although electrostatic coatings can reach certain antisepsis, under the irradiation of sunlight or the abrasion of external force, it is difficult to hold
Reach corrosion-resistant purpose long.
Therefore, inventing a kind of antibiotic antistatic coating has positive effect to technical field of paint preparation.
Summary of the invention
Present invention mainly solves the technical issues of, be easy under external force for common anti-static coatings at present de-
It falls, it is difficult to the problem of persistently reaching antibacterial, anti-static electrification provide a kind of preparation method of antibiotic antistatic coating.
In order to solve the above-mentioned technical problem, the technical scheme adopted by the invention is that:
A kind of preparation method of antibiotic antistatic coating, it is characterised in that specific preparation step are as follows:
(1) it is put into 1~2h of crushing in pulverizer after mixing montmorillonite, marble, 150 meshes are crossed after crushing, are collected
To sieving powder；
(2) mixture is obtained after mixing tea polyphenols, decanoy acetaldehyde, wood oligose and is added in fermentor, while saccharomycete is added
Bacteria suspension, sealed fermenter, and adjust temperature in fermentor and ferment 2~3 weeks to 30~40 DEG C, gained tunning is to change
Property inorganic mineral, it is spare；
(3) ammonium hydroxide is added into copper-bath to be completely dissolved until precipitating, obtains copper ammon solution, the copper ammon solution that will be obtained,
Under the conditions of 38~40 DEG C, copper ammon solution is sprayed to carbon nanotube powder surface, to carbon nanotube powder surface complete wetting
Afterwards, then rapidly acetaldehyde is sprayed to carbon nano tube surface, stands 20~30min, obtains copper-loaded carbon nanotube, it is spare；
(4) ammonium hydroxide is added into copper-bath to be completely dissolved until precipitating, obtains copper ammon solution, the copper ammon solution that will be obtained,
Under the conditions of 38~40 DEG C, copper ammon solution is sprayed to carbon nanotube powder surface, the surface to polyaniline nano fiber powder
After complete wetting, then acetaldehyde is sprayed to polyaniline nano fiber surface rapidly, stands 1 minute, obtain outer surface supported copper
Polyaniline nano fiber；
(5) 10~20 parts of spare copper-loaded carbon nanotubes, 15~25 parts of above-mentioned copper-loaded polyaniline nano fibers, 30~40 parts are weighed
Water, 3~4 parts of triethyl group hexyl phosphoric acids and 3~5 parts of carboxymethyl celluloses are added in colloid mill, discharge after stirring, tinning
Up to antibiotic antistatic coating.
Montmorillonite described in step (1), marmorean mass ratio are 2:3.
Tea polyphenols described in step (2), decanoy acetaldehyde, wood oligose mass ratio be 2:1:1, the quality of saccharomycete bacteria suspension
For mixture quality 7~10%, concentration 107cfu/mL。
Copper-bath concentration described in step (3) is 0.02mol/L, and the concentration of ammonium hydroxide is 0.8mol/L, fountain height 2
~3mL/cm2。
Copper-bath concentration described in step (4) is 0.02mol/L, and the concentration of ammonium hydroxide is 0.8mol/L, fountain height 2
~3mL/cm2。
The revolving speed of colloid mill described in step (5) is 300~400r/min, and mixing time is 3~4h.
The beneficial effects of the present invention are:
(1) present invention after crushing, is sent out first using montmorillonite, marble as raw material together with tea polyphenols, decanoy acetaldehyde, wood oligose
Ferment, obtains that modified inorganic mineral are spare, then prepares the carbon nanotube of outer surface supported copper and the polyaniline of outer surface supported copper
Spare inorganic matter, copper-loaded carbon nanotube and copper-loaded polyaniline nano fiber and other raw materials are mixed nanofiber
To antibiotic antistatic coating, montmorillonite in the present invention, in marble containing a large amount of metal oxides such as MgO, CaO, ZnO, these
Metal oxide is inorganic antiseptic and good conductive material, and tea polyphenols, decanoy acetaldehyde all have the work of antibacterial sterilization
With, by fermentation, can make both substances in conjunction with inorganic mineral, generate have antibacterial sterilization effect modified inorganic mine
Object, and as filler, improve the anti-microbial property of anti-static coatings of the present invention；
(2) tunning not only has antibiotic property, and there are a large amount of active groups on surface, and the active group on tunning is introduced into
In coating, the active group of coating matrix can be increased, adhesiveness, the adsorption capacity of coating and metope substrate are improved, so that coating is not
Easy to fall off, durable antibiotic antistatic；
(3) polyaniline nano fiber that the present invention uses has good electric conductivity and stability, the polyphenyl of nanofibrous structures
Amine has higher conductivity compared with the polyaniline of other structures, and carbon nanotube has good mechanical property and electricity simultaneously
Performance is learned, the carbon nanotube of the polyaniline nano fiber mating surface supported copper of area load copper not only increases leading for coating
Electrically, while making coating that there is good antibiotic property and rub resistance, using special spray pattern supported copper, keep copper sufficiently negative
It is loaded in the surface of polyaniline nano fiber and carbon nanotube, increases antibiotic property and electric conductivity, they play conduction in coating
The effect in channel, so that coating produced by the present invention has good conductive property, can have wide application with conducting static electricity
Prospect.
Specific embodiment
It is in mass ratio that 1~2h of crushing, mistake after crushing in pulverizer are put into after 2:3 is mixed by montmorillonite, marble
150 meshes, collection obtain sieving powder；It is in mass ratio to be mixed after 2:1:1 is mixed by tea polyphenols, decanoy acetaldehyde, wood oligose
The concentration closing object and being added in fermentor, while mixture quality 7~10% is added is 107The saccharomycete bacteria suspension of cfu/mL, it is close
Seal fermentation tank, and adjust temperature in fermentor and ferment 2~3 weeks, gained tunning is modified inorganic mine to 30~40 DEG C
Object, it is spare；The ammonium hydroxide that concentration is 0.8mol/L is added in the copper-bath for being 0.02mol/L to concentration until precipitating is completely molten
Solution, obtains copper ammon solution, the copper ammon solution that will be obtained, under the conditions of 38~40 DEG C, with 2~3mL/cm2Fountain height by cuprammonium
Spray solution is to carbon nanotube powder surface, after the complete wetting of carbon nanotube powder surface, then rapidly with 2~3mL/ cm2's
Acetaldehyde is sprayed to carbon nano tube surface by fountain height, is stood 20~30min, is obtained copper-loaded carbon nanotube, spare；It is to concentration
The ammonium hydroxide that concentration is 0.8mol/L is added in the copper-bath of 0.02mol/L to be completely dissolved until precipitating, obtains copper ammon solution,
The copper ammon solution that will be obtained, under the conditions of 38~40 DEG C, with 2~3mL/cm2Fountain height copper ammon solution is sprayed to carbon nanometer
Pipe powder surface, after the surface complete wetting of polyaniline nano fiber powder, then rapidly with 2~3mL/ cm2Fountain height will
Acetaldehyde is sprayed to polyaniline nano fiber surface, stands 1 minute, obtains the polyaniline nano fiber of outer surface supported copper；It weighs
10~20 parts of spare copper-loaded carbon nanotubes, 15~25 parts of above-mentioned copper-loaded polyaniline nano fibers, 30~40 parts of water, 3~4 part three
Ethylhexyl phosphoric acid and 3~5 parts of carboxymethyl celluloses are added in colloid mill, with the revolving speed of 300~400r/min, are mixed 3
~4h discharges after stirring, and tinning is up to antibiotic antistatic coating.
Example 1
In mass ratio it is to be put into pulverizer to crush 1h after 2:3 is mixed by montmorillonite, marble, 150 meshes is crossed after crushing,
Collection obtains sieving powder；It is in mass ratio to obtain mixture after 2:1:1 is mixed and add by tea polyphenols, decanoy acetaldehyde, wood oligose
The concentration for entering in fermentor, while mixture quality 7% being added is 107The saccharomycete bacteria suspension of cfu/mL, sealed fermenter, and
Temperature in fermentor is adjusted to ferment 2 weeks, gained tunning is modified inorganic mineral, spare to 30 DEG C；It is to concentration
The ammonium hydroxide that concentration is 0.8mol/L is added in the copper-bath of 0.02mol/L to be completely dissolved until precipitating, obtains copper ammon solution,
The copper ammon solution that will be obtained, under the conditions of 38 DEG C, with 2mL/cm2Fountain height copper ammon solution is sprayed to carbon nanotube powder table
Face, after the complete wetting of carbon nanotube powder surface, then rapidly with 2mL/ cm2Fountain height acetaldehyde is sprayed to carbon nanotube
Surface stands 20min, obtains copper-loaded carbon nanotube, spare；Concentration is added into the copper-bath that concentration is 0.02mol/L
It is completely dissolved for the ammonium hydroxide of 0.8mol/L until precipitating, obtains copper ammon solution, the copper ammon solution that will be obtained, under the conditions of 38 DEG C,
With 2mL/cm2Fountain height copper ammon solution is sprayed to carbon nanotube powder surface, the surface to polyaniline nano fiber powder
After complete wetting, then rapidly with 2mL/ cm2Fountain height acetaldehyde is sprayed to polyaniline nano fiber surface, stand 1 minute,
Obtain the polyaniline nano fiber of outer surface supported copper；Weigh 10 parts of spare copper-loaded carbon nanotubes, 15 parts of above-mentioned copper-loaded polyphenyl
Amine nanofiber, 30 parts of water, 3 parts of triethyl group hexyl phosphoric acids and 3 parts of carboxymethyl celluloses are added in colloid mill, with 300r/min
Revolving speed, be mixed 3h, discharge after stirring, tinning is up to antibiotic antistatic coating.
Example 2
In mass ratio it is to be put into pulverizer to crush 1.5h after 2:3 is mixed by montmorillonite, marble, 150 mesh is crossed after crushing
Sieve, collection obtain sieving powder；It is in mass ratio to obtain mixture simultaneously after 2:1:1 is mixed by tea polyphenols, decanoy acetaldehyde, wood oligose
The concentration for being added in fermentor, while mixture quality 8% being added is 107The saccharomycete bacteria suspension of cfu/mL, sealed fermenter,
And it adjusts temperature in fermentor and ferments 2 weeks, gained tunning is modified inorganic mineral, spare to 35 DEG C；It is to concentration
The ammonium hydroxide that concentration is 0.8mol/L is added in the copper-bath of 0.02mol/L to be completely dissolved until precipitating, obtains copper ammon solution,
The copper ammon solution that will be obtained, under the conditions of 39 DEG C, with 2mL/cm2Fountain height copper ammon solution is sprayed to carbon nanotube powder table
Face, after the complete wetting of carbon nanotube powder surface, then rapidly with 2mL/ cm2Fountain height acetaldehyde is sprayed to carbon nanotube
Surface stands 25min, obtains copper-loaded carbon nanotube, spare；Concentration is added into the copper-bath that concentration is 0.02mol/L
It is completely dissolved for the ammonium hydroxide of 0.8mol/L until precipitating, obtains copper ammon solution, the copper ammon solution that will be obtained, under the conditions of 39 DEG C,
With 2mL/cm2Fountain height copper ammon solution is sprayed to carbon nanotube powder surface, the surface to polyaniline nano fiber powder
After complete wetting, then rapidly with 2mL/ cm2Fountain height acetaldehyde is sprayed to polyaniline nano fiber surface, stand 1 minute,
Obtain the polyaniline nano fiber of outer surface supported copper；Weigh 15 parts of spare copper-loaded carbon nanotubes, 20 parts of above-mentioned copper-loaded polyphenyl
Amine nanofiber, 35 parts of water, 3 parts of triethyl group hexyl phosphoric acids and 4 parts of carboxymethyl celluloses are added in colloid mill, with 350r/min
Revolving speed, be mixed 3.5h, discharge after stirring, tinning is up to antibiotic antistatic coating.
Example 3
In mass ratio it is to be put into pulverizer to crush 2h after 2:3 is mixed by montmorillonite, marble, 150 meshes is crossed after crushing,
Collection obtains sieving powder；It is in mass ratio to obtain mixture after 2:1:1 is mixed and add by tea polyphenols, decanoy acetaldehyde, wood oligose
The concentration for entering in fermentor, while mixture quality 10% being added is 107The saccharomycete bacteria suspension of cfu/mL, sealed fermenter, and
Temperature in fermentor is adjusted to ferment 3 weeks, gained tunning is modified inorganic mineral, spare to 40 DEG C；It is to concentration
The ammonium hydroxide that concentration is 0.8mol/L is added in the copper-bath of 0.02mol/L to be completely dissolved until precipitating, obtains copper ammon solution,
The copper ammon solution that will be obtained, under the conditions of 40 DEG C, with 3mL/cm2Fountain height copper ammon solution is sprayed to carbon nanotube powder table
Face, after the complete wetting of carbon nanotube powder surface, then rapidly with 3mL/ cm2Fountain height acetaldehyde is sprayed to carbon nanotube
Surface stands 30min, obtains copper-loaded carbon nanotube, spare；Concentration is added into the copper-bath that concentration is 0.02mol/L
It is completely dissolved for the ammonium hydroxide of 0.8mol/L until precipitating, obtains copper ammon solution, the copper ammon solution that will be obtained, under the conditions of 40 DEG C,
With 3mL/cm2Fountain height copper ammon solution is sprayed to carbon nanotube powder surface, the surface to polyaniline nano fiber powder
After complete wetting, then rapidly with 3mL/ cm2Fountain height acetaldehyde is sprayed to polyaniline nano fiber surface, stand 1 minute,
Obtain the polyaniline nano fiber of outer surface supported copper；Weigh 20 parts of spare copper-loaded carbon nanotubes, 25 parts of above-mentioned copper-loaded polyphenyl
Amine nanofiber, 40 parts of water, 4 parts of triethyl group hexyl phosphoric acids and 5 parts of carboxymethyl celluloses are added in colloid mill, with 400r/min
Revolving speed, be mixed 4h, discharge after stirring, tinning is up to antibiotic antistatic coating.
Comparative example
With the antibiotic antistatic coating of Shenzhen company production as a comparison case to antibiotic antistatic coating produced by the present invention and
Antibiotic antistatic coating in comparative example carries out performance detection, and testing result is as shown in table 1:
Test method:
Abrasive size test is detected using abrasive grain machinery instrument, and abrasive size is bigger, and wear-resisting property is higher；
Wear-resisting revolution test method: according to national standards, the coating in example 1~3 and comparative example being spread evenly across on plank,
It is tested with 180 mesh sand paper, every 500 conversion one, sand paper.Measure last wear-resisting revolution；
Adhesive force test is detected by GB/T 1720 " paint film adhesion measuring method " scratch；
Impact resistance test is detected by the test of GB/T 1732-1993 coating impact resistance；
Conductivity test is detected by GB/T 1720-79 standard；
Anticorrosive property test is detected using salt spray test method under sunlight, detection method are as follows: by example 1~3 and right
Anti-static coatings in ratio, which are coated on billboard to be placed under sunlight, to be irradiated after a certain period of time, then is exposed to salt spray test
During (5%NaCl) solution is sprayed in case, after 144h, sample is taken out, observes surface corrosion situation.
Escherichia coli be averaged bacterium number test by JC/T897-2002 regulation progress bacteriostasis property detection；
Staphylococcus aureus be averaged bacterium number test by JC/T897-2002 regulation progress bacteriostasis property detection；
The test of Candida albicans bacteriostasis rate carries out performance detection by the regulation of GB/T20944.2-2007.
1 anti-static coatings performance measurement result of table
According to above-mentioned detection data, antibiotic antistatic coating wearability of the invention is good, does not influence vulnerable to external force, power
It is good to learn performance, conductivity is high, and antistatic effect is good, and anticorrosive property is good, and antibiotic rate is high, has broad application prospects.
Claims (6)
1. a kind of preparation method of antibiotic antistatic coating, it is characterised in that specific preparation step are as follows:
(1) it is put into 1~2h of crushing in pulverizer after mixing montmorillonite, marble, 150 meshes are crossed after crushing, are collected
To sieving powder；
(2) mixture is obtained after mixing tea polyphenols, decanoy acetaldehyde, wood oligose and is added in fermentor, while saccharomycete is added
Bacteria suspension, sealed fermenter, and adjust temperature in fermentor and ferment 2~3 weeks to 30~40 DEG C, gained tunning is to change
Property inorganic mineral, it is spare；
(3) ammonium hydroxide is added into copper-bath to be completely dissolved until precipitating, obtains copper ammon solution, the copper ammon solution that will be obtained,
Under the conditions of 38~40 DEG C, copper ammon solution is sprayed to carbon nanotube powder surface, to carbon nanotube powder surface complete wetting
Afterwards, then rapidly acetaldehyde is sprayed to carbon nano tube surface, stands 20~30min, obtains copper-loaded carbon nanotube, it is spare；
(4) ammonium hydroxide is added into copper-bath to be completely dissolved until precipitating, obtains copper ammon solution, the copper ammon solution that will be obtained,
Under the conditions of 38~40 DEG C, copper ammon solution is sprayed to carbon nanotube powder surface, the surface to polyaniline nano fiber powder
After complete wetting, then acetaldehyde is sprayed to polyaniline nano fiber surface rapidly, stands 1 minute, obtain outer surface supported copper
Polyaniline nano fiber；
(5) 10~20 parts of spare copper-loaded carbon nanotubes, 15~25 parts of above-mentioned copper-loaded polyaniline nano fibers, 30~40 parts are weighed
Water, 3~4 parts of triethyl group hexyl phosphoric acids and 3~5 parts of carboxymethyl celluloses are added in colloid mill, discharge after stirring, tinning
Up to antibiotic antistatic coating.
2. a kind of preparation method of antibiotic antistatic coating according to claim 1, it is characterised in that: step (1) is described
Montmorillonite, marmorean mass ratio be 2:3.
3. a kind of preparation method of antibiotic antistatic coating according to claim 1, it is characterised in that: step (2) is described
Tea polyphenols, decanoy acetaldehyde, wood oligose mass ratio be 2:1:1, the quality of saccharomycete bacteria suspension is mixture quality 7~10%,
Concentration is 107cfu/mL。
4. a kind of preparation method of antibiotic antistatic coating according to claim 1, it is characterised in that: step (3) is described
Copper-bath concentration be 0.02mol/L, the concentration of ammonium hydroxide is 0.8mol/L, and fountain height is 2~3mL/cm2。
5. a kind of preparation method of antibiotic antistatic coating according to claim 1, it is characterised in that: step (4) is described
Copper-bath concentration be 0.02mol/L, the concentration of ammonium hydroxide is 0.8mol/L, and fountain height is 2~3mL/cm2。
6. a kind of preparation method of antibiotic antistatic coating according to claim 1, it is characterised in that: step (5) is described
Colloid mill revolving speed be 300~400r/min, mixing time be 3~4h.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112662220A (en) * | 2020-12-17 | 2021-04-16 | 桂林理工大学 | Corrosion-resistant antibacterial antistatic coating and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102234128A (en) * | 2010-05-05 | 2011-11-09 | 温佳丽 | Process for preparing nano copper hydroxide by homogeneous precipitation |
| CN104449150A (en) * | 2014-12-26 | 2015-03-25 | 富阳鸿祥技术服务有限公司 | Preparation method of antibacterial anti-static paint |
| CN106085156A (en) * | 2016-08-29 | 2016-11-09 | 佛山市高明区尚润盈科技有限公司 | A kind of wash resistant anti static antibacterial coating and preparation method thereof |
-
2018
- 2018-09-20 CN CN201811097993.3A patent/CN109233400A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102234128A (en) * | 2010-05-05 | 2011-11-09 | 温佳丽 | Process for preparing nano copper hydroxide by homogeneous precipitation |
| CN104449150A (en) * | 2014-12-26 | 2015-03-25 | 富阳鸿祥技术服务有限公司 | Preparation method of antibacterial anti-static paint |
| CN106085156A (en) * | 2016-08-29 | 2016-11-09 | 佛山市高明区尚润盈科技有限公司 | A kind of wash resistant anti static antibacterial coating and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112662220A (en) * | 2020-12-17 | 2021-04-16 | 桂林理工大学 | Corrosion-resistant antibacterial antistatic coating and preparation method thereof |
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