CN109224106A - A kind of biological antibiotic deodorizer and preparation method thereof - Google Patents
A kind of biological antibiotic deodorizer and preparation method thereof Download PDFInfo
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- CN109224106A CN109224106A CN201811008109.4A CN201811008109A CN109224106A CN 109224106 A CN109224106 A CN 109224106A CN 201811008109 A CN201811008109 A CN 201811008109A CN 109224106 A CN109224106 A CN 109224106A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
- A61L9/013—Deodorant compositions containing animal or plant extracts, or vegetable material
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/22—Lamiaceae or Labiatae [Mint family], e.g. thyme, rosemary, skullcap, selfheal, lavender, perilla, pennyroyal, peppermint or spearmint
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/40—Liliopsida [monocotyledons]
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/50—Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38618—Protease or amylase in liquid compositions only
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38627—Preparations containing enzymes, e.g. protease or amylase containing lipase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38645—Preparations containing enzymes, e.g. protease or amylase containing cellulase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/02—Odour removal or prevention of malodour
Abstract
The invention discloses a kind of biological antibiotic deodorizers and preparation method thereof.Biological antibiotic deodorizer of the invention is prepared using the natural plants such as gleditsia sinensis skin, timbol and brown sugar, rice washing water, pericarp and fresh food waste as raw material；Biological antibiotic deodorizer ingredient of the present invention is natural, containing a variety of hydrolases such as cellulase, protease, lipase, deodorization can be carried out using the specificity and efficient catalytic performance of enzyme by the effect of a variety of biological enzyme, there is cleaning capacity and nursing role simultaneously, and there is antibacterial vermins-proof effect；Inventive formulation uses natural materials, more environmentally-friendly and be easily handled compared with general chemistry deodorant, and pericarp and fresh food waste are used in formula, and the comprehensive utilization to discarded pericarp and fresh food waste may be implemented, and reduces discharge and environmental pollution.
Description
Technical field
The present invention relates to a kind of biological antibiotic deodorizers and preparation method thereof, belong to deodorant preparation technical field.
Background technique
Deodorant is mainly the following type: physical deodorization agent, chemical deodorizing agent, microbiocidal deodorant and compound
Deodorant etc..
Physical deodorization is mainly to carry out deodorization with the substance that alum, drystone ashes, charcoal, tealeaves etc. have suction-operated；
Chemical deodorizing is to generate new odorless substance by the way that irreversible chemical reaction occurs between chemical substance and stink odor to reach
The purpose of deodorization；Biological deodorizing mainly utilizes microbial deodorant, will have substance frowzy by the physiological metabolism of microorganism
It is converted, so that target contaminant is decomposed removal by effective, to reach the improvement purpose of stench.Some removing with biocidal efficacies
Smelly dose, there is the chemical composition of aromatic odor by being added, such as acetic acid linalool, citronellol, benzyl carbinol, to chloro-m-xylene
Phenol, lauryl methacrylate, essence etc. are covered, and not only stink not can be removed, and the residual of compound such as contacts human body,
There are security risks.
Summary of the invention
It is an object of that present invention to provide a kind of biological antibiotic deodorizers, and the deodorant is with natural plants and rice washing water, pericarp
And fresh food waste is prepared as raw material through the methods of everfermentation, the higher-order of oscillation, is had good deodorization effect, is readily biodegradable, is right
It is environmental-friendly, have no toxic side effect, it is at low cost, the features such as antibacterial insect prevention.
Another object of the present invention is to provide a kind of above-mentioned preparation methods of biological antibiotic deodorizer.
The invention adopts the following technical scheme: a kind of biological antibiotic deodorizer, is prepared: soap by the raw material of following mass fraction
70-90 parts of cuticle, 60-80 parts of timbol, 60-80 parts of rosemary, 50-70 parts of grassleaf sweetflag leaf, 20-45 parts of mulberry leaf, brown sugar 20-
30 parts, pericarp and food waste 20-30 parts fresh, 400-1000 parts of rice washing water, 40-100 parts of enzyme solution；The enzyme solution is with fresh straw
For raw material, it is made through fermentation of bacillus subtilis.
Biological antibiotic deodorizer of the invention, preparation method comprise the following specific steps that:
(1) raw material preparation:
A, fresh gleditsia sinensis is taken, both ends is gone to, squeezes out seed, crust is placed in 30-40 DEG C of warm water, after impregnating 1-2h, is taken out in being protected from light
It is dried at gravity-flow ventilation, obtains gleditsia sinensis skin, it is spare；
B, fresh soapberry is taken, seed is gone to take off meat, retains outer layer skin, is dried under daylight, obtain timbol；
C, rosemary is taken, stem, leaf, flower mixing are smashed to pieces, it is spare；
D, fresh grassleaf sweetflag leaf is taken, is placed in 30-40 DEG C of warm water, after impregnating 1-2h, takes out and dries in being protected from light at gravity-flow ventilation, it is standby
With；
E, new fresh mulberry leaf is taken, is placed in 30-40 DEG C of warm water, after impregnating 1-2h, takes out and dries in being protected from light at gravity-flow ventilation, be ground into
100-200 mesh fine powder, obtains mulberry leaf powder；
F, prepare brown sugar, rice washing water, pericarp and fresh food waste, no specially treated；
(2) prepared by enzyme solution: taking fresh straw, removes impurity, after natural air drying, cleans and drain, be ground into 80-100 mesh fine powder；It will
Fine powder is soaked in the calcium bicarbonate solution that concentration is 25-45% for 24 hours, drains redundant solution, and the withered of fine powder quality 10-15% is added
Careless bacillus is uniformly mixed, and is placed in fermentation 72h or more in sealed fermenter, filters, and centrifugation obtains enzyme solution；
(3) brown sugar, pericarp and fresh food waste, part rice washing water are mixed to join in dispersion machine A, are dispersed with stirring 2-3h, obtained molten
Liquid A；Gleditsia sinensis skin, timbol, part rice washing water are mixed to join in dispersion machine B, 1-2h is dispersed with stirring, 30min is stood, takes
Supernatant liquor obtains solution B；Rosemary, grassleaf sweetflag leaf, remaining rice washing water are mixed to join in dispersion machine C, 1-2h is dispersed with stirring,
30min is stood, supernatant liquor is taken, obtains solution C；
(4) dispersion machine A oral area is sealed, container finish need to be opened daily and deflate and stir primary, sealing storage after continuing 30 days,
Sealing storage 60 days, then filter, obtain solution D under normal temperature and pressure；
(5) solution B is placed in higher-order of oscillation machine, vibrates 1-2h；Solution B after oscillation is added in solution D and is uniformly mixed,
Filtering, then filtrate is poured into blender, the mixed solution in blender is persistently stirred with speed 60r/min；Solution B with it is molten
Liquid D mixing mass ratio is 1:3；
(7) solution C is packed into industrial ejecting gun, be uniformly ejected into the blender of step (5)；It is mixed in solution C and blender
The mass ratio of liquid is 1:4；
(8) after the solution C addition in step (7), blender persistently stirs 10-30min, stops stirring, and step (2) are made
Enzyme solution, the mulberry leaf powder obtained is added, and is uniformly mixed, filters to get biological antibiotic deodorizer.
Preferably, in step (2) described fermentation process, 30-35 DEG C of fermentation temperature of control, humidity 80 ~ 85%, pH8 ~ 8.5；
Gas in 12h discharge fermentor.
Preferably, step (3) dispersion machine A, dispersion machine B revolving speed be 100-120r/min, dispersion temperature be 40-50 DEG C.
Preferably, the mixing speed of step (4) is 40r/min, and filtering mesh number is 100 mesh.
Preferably, the frequency of oscillation of the vibrating machine in step (5) is 60-80Hz, amplitude 30-40mm.
Preferably, step (2) described centrifugal condition is: 5 ~ 15min is centrifuged under the revolving speed of 800 ~ 3000r/min.
Further, step (2) fermentation is secondary fermentation: fine powder being uniformly mixed with bacillus subtilis, is placed in
In sealed fermenter, first ferment 48h, opens fermentor, and fermentation materials are taken out in exhaust, carries out ultrasonic wave added hydrolysis, then set again
In sealed fermenter, continue the 48h that ferments, filter, centrifuge separation obtains enzyme solution.
Further, the condition of the ultrasonic wave added hydrolysis are as follows: fermentation materials quality 0.5%- is added in fermentation materials
The brown sugar of 1.0% calcium chloride, 0.2-0.5% is ultrasonically treated 10 ~ 30min at 20 ~ 40kHz.
Biological antibiotic deodorizer of the invention can be used for the deodorization of air, sewage, article, especially for protein point
The stink processing of foul smell, smelly water or article caused by solution, putrid and deteriorated etc. has more preferably effect；It can also be used in clothing, fur
The washing of fabric, luggage, furniture, household items etc. or surface cleaning.
The beneficial effects of the present invention are:
(1) for the present invention using natural plant raw material as main component, the damage to environment, human body is small；It is passed through using natural material
After everfermentation, the compound enzyme system containing a variety of hydrolases such as cellulase, protease, lipase is obtained, a variety of biologies are passed through
The effect of enzyme carries out deodorization, when as washing or detergent, fine molecular weight using the specificity and efficient catalytic performance of enzyme
It can be deep into the fibrous inside of clothing, fabric etc., deep layer removes various compound tough stains, especially sweat stain, grease etc.；
(2) more environmentally-friendly and be easy to compared with general chemistry inorganic agent using the sewage of the raw antibacterial deodorant processing of the present invention
Processing；Rice washing water has been used in the formula of deodorant of the present invention, wherein minerals rich in and starch, for article
When deodorization, while there are also protections and repairing effect to article；
(3) rosemary in formula has good antibacterial insect prevention effect, and grassleaf sweetflag leaf has the function of adsorbing micronic dust and antibacterial；
(4) pericarp and fresh food waste are used in formula, can be made full use of the nutrient in discarded pericarp and fresh food waste, be accomplished
The secondary use of rubbish reduces discharge and environmental pollution.
Specific embodiment
The present invention is described in further details below by embodiment, these embodiments are only used to illustrate the present invention, and
It does not limit the scope of the invention.
Embodiment 1 prepares biological antibiotic deodorizer of the invention using the raw material of following mass fraction: 80 parts of gleditsia sinensis skin,
70 parts of timbol, 70 parts of rosemary, 60 parts of grassleaf sweetflag leaf, 35 parts of mulberry leaf, 25 parts of brown sugar, pericarp and 25 parts of fresh food waste, rice washing
750 parts of water, 70 parts of enzyme solution；The preparation method is as follows:
(1) raw material preparation:
A, fresh gleditsia sinensis is taken, both ends is gone to, squeezes out seed, crust is placed in 30-40 DEG C of warm water, after impregnating 1-2h, is taken out in being protected from light
It is dried at gravity-flow ventilation, obtains gleditsia sinensis skin, it is spare；
B, fresh soapberry is taken, seed is gone to take off meat, retains outer layer skin, is dried under daylight, obtain timbol；
C, rosemary is taken, stem, leaf, flower mixing are smashed to pieces, it is spare；
D, fresh grassleaf sweetflag leaf is taken, is placed in 30-40 DEG C of warm water, after impregnating 1.5h, takes out and dries in being protected from light at gravity-flow ventilation, it is standby
With；
E, new fresh mulberry leaf is taken, is placed in 30-40 DEG C of warm water, after impregnating 1.5h, takes out and dries in being protected from light at gravity-flow ventilation, be ground into
200 mesh fine powders, obtain mulberry leaf powder；
F, prepare brown sugar, rice washing water, pericarp and fresh food waste, no specially treated；
(2) prepared by enzyme solution: taking fresh straw, removes impurity, after natural air drying, cleans and drain, be ground into 80-100 mesh fine powder；It will
Fine powder is soaked in the calcium bicarbonate solution that concentration is 25% for 24 hours, drains redundant solution, and the withered grass of fine powder quality 10-15% is added
Bacillus is uniformly mixed, and is placed in sealed fermenter fermentation 72h or more, and 30-35 DEG C of fermentation temperature, humidity 80 ~ 85%, pH8 ~
8.5；Gas in 12h discharge fermentor, fermentation ends filter, and centrifugation obtains enzyme solution；
(3) brown sugar, pericarp and fresh food waste, part rice washing water are mixed to join in dispersion machine A, are dispersed with stirring 2-3h, obtained molten
Liquid A；Gleditsia sinensis skin, timbol, part rice washing water are mixed to join in dispersion machine B, 1.5h is dispersed with stirring, 30min is stood, takes
Supernatant liquor obtains solution B；Rosemary, grassleaf sweetflag leaf, remaining rice washing water are mixed to join in dispersion machine C, 1-2h is dispersed with stirring,
30min is stood, supernatant liquor is taken, obtains solution C；Dispersion machine A, dispersion machine B revolving speed be 100-120r/min, dispersion temperature is
40-50℃；
(4) dispersion machine A oral area is sealed, container finish need to be opened daily and deflate and stirred once with 40r/min, it is close after continuing 30 days
It seals up for safekeeping and puts, sealing storage at normal temperatures and pressures 60 days, then 100 mesh filter, and obtain solution D；
(5) solution B is placed in higher-order of oscillation machine, vibrates 1-2h；Solution B after oscillation is added in solution D and is uniformly mixed,
Filtering, then filtrate is poured into blender, the mixed solution in blender is persistently stirred with speed 60r/min；Solution B with it is molten
Liquid D mixing mass ratio is 1:3；The frequency of oscillation of vibrating machine is 60-80Hz, amplitude 30-40mm；
(7) solution C is packed into industrial ejecting gun, be uniformly ejected into the blender of step (5)；It is mixed in solution C and blender
The mass ratio of liquid is 1:4；
(8) after the solution C addition in step (7), blender persistently stirs 10-30min, stops stirring, and step (2) are made
Enzyme solution, the mulberry leaf powder obtained is added, and is uniformly mixed, filters to get biological antibiotic deodorizer.
Embodiment 2 prepares biological antibiotic deodorizer of the invention using the raw material of following mass fraction: 90 parts of gleditsia sinensis skin,
60 parts of timbol, 60 parts of rosemary, 70 parts of grassleaf sweetflag leaf, 45 parts of mulberry leaf, 30 parts of brown sugar, pericarp and 30 parts of fresh food waste, rice washing
1000 parts of water, 100 parts of enzyme solution；The preparation method is as follows:
(1) raw material preparation:
A, take fresh gleditsia sinensis, go both ends, squeeze out seed, crust is placed in 30-40 DEG C of warm water, impregnate 1h after, take out in be protected from light from
Right ventilation is dried, and gleditsia sinensis skin is obtained, spare；
B, fresh soapberry is taken, seed is gone to take off meat, retains outer layer skin, is dried under daylight, obtain timbol；
C, rosemary is taken, stem, leaf, flower mixing are smashed to pieces, it is spare；
D, fresh grassleaf sweetflag leaf is taken, is placed in 30-40 DEG C of warm water, after impregnating 2h, takes out and dries in being protected from light at gravity-flow ventilation, it is spare；
E, new fresh mulberry leaf is taken, is placed in 30-40 DEG C of warm water, after impregnating 1h, takes out and dries in being protected from light at gravity-flow ventilation, be ground into
200 mesh fine powders, obtain mulberry leaf powder；
F, prepare brown sugar, rice washing water, pericarp and fresh food waste, no specially treated；
(2) prepared by enzyme solution: taking fresh straw, removes impurity, after natural air drying, cleans and drain, be ground into 100 mesh fine powders；It will be thin
Powder is soaked in the calcium bicarbonate solution that concentration is 30% for 24 hours, drains redundant solution, and the bacillus subtilis of fine powder quality 10% is added
Bacterium is uniformly mixed, and is placed in sealed fermenter, and first ferment 48h, opens fermentor, and fermentation materials are taken out in exhaust, and it is auxiliary to carry out ultrasound
Help hydrolysis, then be replaced in sealed fermenter, continue ferment 48h, 30-35 DEG C of fermentation temperature, humidity 80 ~ 85%, pH8 ~ 8.5；
Gas in 12h discharge fermentor, fermentation ends filter, and centrifugation obtains enzyme solution；The condition of ultrasonic wave added hydrolysis are as follows: sending out
The calcium chloride of fermentation materials quality 0.5%, 0.5% brown sugar are added in ferment material, is ultrasonically treated 30min at 40kHz；
(3) brown sugar, pericarp and fresh food waste, part rice washing water are mixed to join in dispersion machine A, are dispersed with stirring 2-3h, obtained molten
Liquid A；Gleditsia sinensis skin, timbol, part rice washing water are mixed to join in dispersion machine B, 1-2h is dispersed with stirring, 30min is stood, takes
Supernatant liquor obtains solution B；Rosemary, grassleaf sweetflag leaf, remaining rice washing water are mixed to join in dispersion machine C, 1-2h is dispersed with stirring,
30min is stood, supernatant liquor is taken, obtains solution C；Dispersion machine A, dispersion machine B revolving speed be 100-120r/min, dispersion temperature is
40-50℃；
(4) dispersion machine A oral area is sealed, container finish need to be opened daily and deflate and stirred once with 40r/min, it is close after continuing 30 days
It seals up for safekeeping and puts, sealing storage at normal temperatures and pressures 60 days, then 100 mesh filter, and obtain solution D；
(5) solution B is placed in higher-order of oscillation machine, vibrates 1h；Solution B after oscillation is added in solution D and is uniformly mixed, mistake
Filter, then filtrate is poured into blender, the mixed solution in blender is persistently stirred with speed 60r/min；Solution B and solution
D mixing mass ratio is 1:3；The frequency of oscillation of vibrating machine is 60-80Hz, amplitude 30-40mm；
(7) solution C is packed into industrial ejecting gun, be uniformly ejected into the blender of step (5)；It is mixed in solution C and blender
The mass ratio of liquid is 1:4；
(8) after the solution C addition in step (7), blender persistently stirs 10-30min, stops stirring, and step (2) are made
Enzyme solution, the mulberry leaf powder obtained is added, and is uniformly mixed, filters to get biological antibiotic deodorizer.
Embodiment 3 prepares biological antibiotic deodorizer of the invention using the raw material of following mass fraction: 70 parts of gleditsia sinensis skin,
80 parts of timbol, 80 parts of rosemary, 50 parts of grassleaf sweetflag leaf, 20 parts of mulberry leaf, 20 parts of brown sugar, pericarp and 20 parts of fresh food waste, rice washing
400 parts of water, 90 parts of enzyme solution；The preparation method is as follows:
(1) raw material preparation:
A, take fresh gleditsia sinensis, go both ends, squeeze out seed, crust is placed in 30-40 DEG C of warm water, impregnate 2h after, take out in be protected from light from
Right ventilation is dried, and gleditsia sinensis skin is obtained, spare；
B, fresh soapberry is taken, seed is gone to take off meat, retains outer layer skin, is dried under daylight, obtain timbol；
C, rosemary is taken, stem, leaf, flower mixing are smashed to pieces, it is spare；
D, fresh grassleaf sweetflag leaf is taken, is placed in 30-40 DEG C of warm water, after impregnating 1h, takes out and dries in being protected from light at gravity-flow ventilation, it is spare；
E, new fresh mulberry leaf is taken, is placed in 30-40 DEG C of warm water, after impregnating 2h, takes out and dries in being protected from light at gravity-flow ventilation, be ground into
100 mesh fine powders, obtain mulberry leaf powder；
F, prepare brown sugar, rice washing water, pericarp and fresh food waste, no specially treated；
(2) prepared by enzyme solution: taking fresh straw, removes impurity, after natural air drying, cleans and drain, be ground into 100 mesh fine powders；It will be thin
Powder is soaked in the calcium bicarbonate solution that concentration is 35% for 24 hours, drains redundant solution, and the bacillus subtilis of fine powder quality 15% is added
Bacterium is uniformly mixed, and is placed in sealed fermenter, and first ferment 48h, opens fermentor, and fermentation materials are taken out in exhaust, and it is auxiliary to carry out ultrasound
Help hydrolysis, then be replaced in sealed fermenter, continue ferment 48h, 30-35 DEG C of fermentation temperature, humidity 80 ~ 85%, pH8 ~ 8.5；
Gas in 12h discharge fermentor, fermentation ends filter, and centrifugation obtains enzyme solution；The condition of ultrasonic wave added hydrolysis are as follows: sending out
The calcium chloride of fermentation materials quality 1.0%, 0.2% brown sugar are added in ferment material, is ultrasonically treated 30min at 30kHz；
(3) brown sugar, pericarp and fresh food waste, part rice washing water are mixed to join in dispersion machine A, are dispersed with stirring 2-3h, obtained molten
Liquid A；Gleditsia sinensis skin, timbol, part rice washing water are mixed to join in dispersion machine B, 2h is dispersed with stirring, 30min is stood, takes
Layer clear liquid, obtains solution B；Rosemary, grassleaf sweetflag leaf, remaining rice washing water are mixed to join in dispersion machine C, 1-2h is dispersed with stirring, it is quiet
30min is set, supernatant liquor is taken, obtains solution C；Dispersion machine A, dispersion machine B revolving speed be 100-120r/min, dispersion temperature 40-
50℃；
(4) dispersion machine A oral area is sealed, container finish need to be opened daily and deflate and stirred once with 40r/min, it is close after continuing 30 days
It seals up for safekeeping and puts, sealing storage at normal temperatures and pressures 60 days, then 100 mesh filter, and obtain solution D；
(5) solution B is placed in higher-order of oscillation machine, vibrates 2h；Solution B after oscillation is added in solution D and is uniformly mixed, mistake
Filter, then filtrate is poured into blender, the mixed solution in blender is persistently stirred with speed 60r/min；Solution B and solution
D mixing mass ratio is 1:3；The frequency of oscillation of vibrating machine is 60-80Hz, amplitude 30-40mm；
(7) solution C is packed into industrial ejecting gun, be uniformly ejected into the blender of step (5)；It is mixed in solution C and blender
The mass ratio of liquid is 1:4；
(8) after the solution C addition in step (7), blender persistently stirs 10-30min, stops stirring, and step (2) are made
Enzyme solution, the mulberry leaf powder obtained is added, and is uniformly mixed, filters to get biological antibiotic deodorizer.
Claims (9)
1. a kind of biological antibiotic deodorizer, it is characterised in that: prepared by the raw material of following mass fraction: 70-90 parts of gleditsia sinensis skin,
60-80 parts of timbol, 60-80 parts of rosemary, 50-70 parts of grassleaf sweetflag leaf, 20-45 parts of mulberry leaf, 20-30 parts of brown sugar, pericarp and new
Fresh food waste 20-30 parts, 400-1000 parts of rice washing water, 40-100 parts of enzyme solution；The enzyme solution is using fresh straw as raw material, through withered grass
Fermentation of bacillus is made.
2. biological antibiotic deodorizer according to claim 1, which is characterized in that preparation method includes following specific step
It is rapid:
(1) raw material preparation:
A, fresh gleditsia sinensis is taken, both ends is gone to, squeezes out seed, crust is placed in 30-40 DEG C of warm water, after impregnating 1-2h, is taken out in being protected from light
It is dried at gravity-flow ventilation, obtains gleditsia sinensis skin, it is spare；
B, fresh soapberry is taken, seed is gone to take off meat, retains outer layer skin, is dried under daylight, obtain timbol；
C, rosemary is taken, stem, leaf, flower mixing are smashed to pieces, it is spare；
D, fresh grassleaf sweetflag leaf is taken, is placed in 30-40 DEG C of warm water, after impregnating 1-2h, takes out and dries in being protected from light at gravity-flow ventilation, it is standby
With；
E, new fresh mulberry leaf is taken, is placed in 30-40 DEG C of warm water, after impregnating 1-2h, takes out and dries in being protected from light at gravity-flow ventilation, be ground into
100-200 mesh fine powder, obtains mulberry leaf powder；
F, prepare brown sugar, rice washing water, pericarp and fresh food waste, no specially treated；
(2) prepared by enzyme solution: taking fresh straw, removes impurity, after natural air drying, cleans and drain, be ground into 80-100 mesh fine powder；It will
Fine powder is soaked in the calcium bicarbonate solution that concentration is 25-45% for 24 hours, drains redundant solution, and the withered of fine powder quality 10-15% is added
Careless bacillus is uniformly mixed, and is placed in fermentation 72h or more in sealed fermenter, filters, and centrifugation obtains enzyme solution；
(3) brown sugar, pericarp and fresh food waste, part rice washing water are mixed to join in dispersion machine A, are dispersed with stirring 2-3h, obtained molten
Liquid A；Gleditsia sinensis skin, timbol, part rice washing water are mixed to join in dispersion machine B, 1-2h is dispersed with stirring, 30min is stood, takes
Supernatant liquor obtains solution B；Rosemary, grassleaf sweetflag leaf, remaining rice washing water are mixed to join in dispersion machine C, 1-2h is dispersed with stirring,
30min is stood, supernatant liquor is taken, obtains solution C；
(4) dispersion machine A oral area is sealed, container finish need to be opened daily and deflate and stir primary, sealing storage after continuing 30 days,
Sealing storage 60 days, then filter, obtain solution D under normal temperature and pressure；
(5) solution B is placed in higher-order of oscillation machine, vibrates 1-2h；Solution B after oscillation is added in solution D and is uniformly mixed,
Filtering, then filtrate is poured into blender, the mixed solution in blender is persistently stirred with speed 60r/min；Solution B with it is molten
Liquid D mixing mass ratio is 1:3；
(7) solution C is packed into industrial ejecting gun, be uniformly ejected into the blender of step (5)；It is mixed in solution C and blender
The mass ratio of liquid is 1:4；
(8) after the solution C addition in step (7), blender persistently stirs 10-30min, stops stirring, and step (2) are made
Enzyme solution, the mulberry leaf powder obtained is added, and is uniformly mixed, filters to get biological antibiotic deodorizer.
3. biological antibiotic deodorizer according to claim 2, which is characterized in that in step (2) described fermentation process, control
30-35 DEG C of fermentation temperature, humidity 80 ~ 85%, pH8 ~ 8.5；Gas in 12h discharge fermentor.
4. biological antibiotic deodorizer according to claim 2, which is characterized in that step (2) fermentation is secondary fermentation:
Fine powder is uniformly mixed with bacillus subtilis, is placed in sealed fermenter, first ferment 48h, opens fermentor, is vented, and takes out
Fermentation materials carry out ultrasonic wave added hydrolysis, then are replaced in sealed fermenter, continue the 48h that ferments, and filter, and centrifuge separation obtains
Enzyme solution.
5. biological antibiotic deodorizer according to claim 4, which is characterized in that the condition of the ultrasonic wave added hydrolysis are as follows:
The calcium chloride of fermentation materials quality 0.5%-1.0%, the brown sugar of 0.2-0.5% are added in fermentation materials, it is ultrasonic at 20 ~ 40kHz
Handle 10 ~ 30min.
6. biological antibiotic deodorizer according to claim 2, which is characterized in that turn of step (3) dispersion machine A, dispersion machine B
Speed is 100-120r/min, and dispersion temperature is 40-50 DEG C.
7. biological antibiotic deodorizer according to claim 2, which is characterized in that the mixing speed of step (4) is 40r/
Min, filtering mesh number are 100 mesh.
8. biological antibiotic deodorizer according to claim 2, which is characterized in that the oscillation frequency of the vibrating machine in step (5)
Rate is 60-80Hz, amplitude 30-40mm.
9. biological antibiotic deodorizer according to claim 4, which is characterized in that step (2) described centrifugal condition is: 800 ~
5 ~ 15min is centrifuged under the revolving speed of 3000r/min.
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| CN114345112A (en) * | 2022-02-16 | 2022-04-15 | 尹珲太 | Deodorant and preparation method thereof |
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| KR20130022681A (en) * | 2011-08-26 | 2013-03-07 | (주)에코바이오 | Eco-friendly deodorant manufacturing method |
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